Critical evaluation of partial molar volumes and excess partial molar volumes of molten fluoride melts

Abstract Different procedures of evaluation of partial molar volume and excess partial molar volume have been applied for three binary or quasi-binary molten fluoride systems: KF–$ K_{2} %$ TaF_{7} $, $ K_{2} %$ ZrF_{6} $–$ K_{2} %$ TaF_{7} $ and (LiF–NaF–KF)eut–$ K_{2} %$ ZrF_{6} $. In the first pr...
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Autor*in:	Kubíková, Blanka [verfasserIn] Boča, Miroslav [verfasserIn] Mlynáriková, Jarmila [verfasserIn] Netriová, Zuzana [verfasserIn] Vasková, Zuzana [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2016

Schlagwörter:	Density Molar volume Partial molar volume and excess partial molar volume Molten fluoride salts

Übergeordnetes Werk:	Enthalten in: Journal of thermal analysis and calorimetry - Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969, 125(2016), 1 vom: 25. Feb., Seite 497-508
Übergeordnetes Werk:	volume:125 ; year:2016 ; number:1 ; day:25 ; month:02 ; pages:497-508

Links:	Volltext

DOI / URN:	10.1007/s10973-016-5324-y

Katalog-ID:	SPR015541630

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520			\|a Abstract Different procedures of evaluation of partial molar volume and excess partial molar volume have been applied for three binary or quasi-binary molten fluoride systems: KF–$ K_{2} %$ TaF_{7} $, $ K_{2} %$ ZrF_{6} $–$ K_{2} %$ TaF_{7} $ and (LiF–NaF–KF)eut–$ K_{2} %$ ZrF_{6} $. In the first procedure partial molar volume is calculated based on mathematical fitting of molar volume, while in the second procedure partial molar volume is calculated based on mathematical fitting of excess molar volume. It was shown that both procedures are in principle consistent. However, some inconsistencies on values of partial molar volume can occur when local extremes are observed on concentration dependence of molar volume. In such situation, proper selection of mathematical functions is essential which requires relatively high density of experimental data. Moreover, when data on only restricted concentration range are available, only procedure of molar volume fitting is applicable for calculation of partial molar volume.
650		4	\|a Density \|7 (dpeaa)DE-He213
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650		4	\|a Molten fluoride salts \|7 (dpeaa)DE-He213
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700	1		\|a Vasková, Zuzana \|e verfasserin \|4 aut
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912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_206
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
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912			\|a GBV_ILN_2003
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912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
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allfields	10.1007/s10973-016-5324-y doi (DE-627)SPR015541630 (SPR)s10973-016-5324-y-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Kubíková, Blanka verfasserin aut Critical evaluation of partial molar volumes and excess partial molar volumes of molten fluoride melts 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Different procedures of evaluation of partial molar volume and excess partial molar volume have been applied for three binary or quasi-binary molten fluoride systems: KF–$ K_{2} %$ TaF_{7} $, $ K_{2} %$ ZrF_{6} $–$ K_{2} %$ TaF_{7} $ and (LiF–NaF–KF)eut–$ K_{2} %$ ZrF_{6} $. In the first procedure partial molar volume is calculated based on mathematical fitting of molar volume, while in the second procedure partial molar volume is calculated based on mathematical fitting of excess molar volume. It was shown that both procedures are in principle consistent. However, some inconsistencies on values of partial molar volume can occur when local extremes are observed on concentration dependence of molar volume. In such situation, proper selection of mathematical functions is essential which requires relatively high density of experimental data. Moreover, when data on only restricted concentration range are available, only procedure of molar volume fitting is applicable for calculation of partial molar volume. Density (dpeaa)DE-He213 Molar volume (dpeaa)DE-He213 Partial molar volume and excess partial molar volume (dpeaa)DE-He213 Molten fluoride salts (dpeaa)DE-He213 Boča, Miroslav verfasserin aut Mlynáriková, Jarmila verfasserin aut Netriová, Zuzana verfasserin aut Vasková, Zuzana verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 125(2016), 1 vom: 25. Feb., Seite 497-508 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:125 year:2016 number:1 day:25 month:02 pages:497-508 https://dx.doi.org/10.1007/s10973-016-5324-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 125 2016 1 25 02 497-508
spelling	10.1007/s10973-016-5324-y doi (DE-627)SPR015541630 (SPR)s10973-016-5324-y-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Kubíková, Blanka verfasserin aut Critical evaluation of partial molar volumes and excess partial molar volumes of molten fluoride melts 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Different procedures of evaluation of partial molar volume and excess partial molar volume have been applied for three binary or quasi-binary molten fluoride systems: KF–$ K_{2} %$ TaF_{7} $, $ K_{2} %$ ZrF_{6} $–$ K_{2} %$ TaF_{7} $ and (LiF–NaF–KF)eut–$ K_{2} %$ ZrF_{6} $. In the first procedure partial molar volume is calculated based on mathematical fitting of molar volume, while in the second procedure partial molar volume is calculated based on mathematical fitting of excess molar volume. It was shown that both procedures are in principle consistent. However, some inconsistencies on values of partial molar volume can occur when local extremes are observed on concentration dependence of molar volume. In such situation, proper selection of mathematical functions is essential which requires relatively high density of experimental data. Moreover, when data on only restricted concentration range are available, only procedure of molar volume fitting is applicable for calculation of partial molar volume. Density (dpeaa)DE-He213 Molar volume (dpeaa)DE-He213 Partial molar volume and excess partial molar volume (dpeaa)DE-He213 Molten fluoride salts (dpeaa)DE-He213 Boča, Miroslav verfasserin aut Mlynáriková, Jarmila verfasserin aut Netriová, Zuzana verfasserin aut Vasková, Zuzana verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 125(2016), 1 vom: 25. Feb., Seite 497-508 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:125 year:2016 number:1 day:25 month:02 pages:497-508 https://dx.doi.org/10.1007/s10973-016-5324-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 125 2016 1 25 02 497-508
allfields_unstemmed	10.1007/s10973-016-5324-y doi (DE-627)SPR015541630 (SPR)s10973-016-5324-y-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Kubíková, Blanka verfasserin aut Critical evaluation of partial molar volumes and excess partial molar volumes of molten fluoride melts 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Different procedures of evaluation of partial molar volume and excess partial molar volume have been applied for three binary or quasi-binary molten fluoride systems: KF–$ K_{2} %$ TaF_{7} $, $ K_{2} %$ ZrF_{6} $–$ K_{2} %$ TaF_{7} $ and (LiF–NaF–KF)eut–$ K_{2} %$ ZrF_{6} $. In the first procedure partial molar volume is calculated based on mathematical fitting of molar volume, while in the second procedure partial molar volume is calculated based on mathematical fitting of excess molar volume. It was shown that both procedures are in principle consistent. However, some inconsistencies on values of partial molar volume can occur when local extremes are observed on concentration dependence of molar volume. In such situation, proper selection of mathematical functions is essential which requires relatively high density of experimental data. Moreover, when data on only restricted concentration range are available, only procedure of molar volume fitting is applicable for calculation of partial molar volume. Density (dpeaa)DE-He213 Molar volume (dpeaa)DE-He213 Partial molar volume and excess partial molar volume (dpeaa)DE-He213 Molten fluoride salts (dpeaa)DE-He213 Boča, Miroslav verfasserin aut Mlynáriková, Jarmila verfasserin aut Netriová, Zuzana verfasserin aut Vasková, Zuzana verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 125(2016), 1 vom: 25. Feb., Seite 497-508 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:125 year:2016 number:1 day:25 month:02 pages:497-508 https://dx.doi.org/10.1007/s10973-016-5324-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 125 2016 1 25 02 497-508
allfieldsGer	10.1007/s10973-016-5324-y doi (DE-627)SPR015541630 (SPR)s10973-016-5324-y-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Kubíková, Blanka verfasserin aut Critical evaluation of partial molar volumes and excess partial molar volumes of molten fluoride melts 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Different procedures of evaluation of partial molar volume and excess partial molar volume have been applied for three binary or quasi-binary molten fluoride systems: KF–$ K_{2} %$ TaF_{7} $, $ K_{2} %$ ZrF_{6} $–$ K_{2} %$ TaF_{7} $ and (LiF–NaF–KF)eut–$ K_{2} %$ ZrF_{6} $. In the first procedure partial molar volume is calculated based on mathematical fitting of molar volume, while in the second procedure partial molar volume is calculated based on mathematical fitting of excess molar volume. It was shown that both procedures are in principle consistent. However, some inconsistencies on values of partial molar volume can occur when local extremes are observed on concentration dependence of molar volume. In such situation, proper selection of mathematical functions is essential which requires relatively high density of experimental data. Moreover, when data on only restricted concentration range are available, only procedure of molar volume fitting is applicable for calculation of partial molar volume. Density (dpeaa)DE-He213 Molar volume (dpeaa)DE-He213 Partial molar volume and excess partial molar volume (dpeaa)DE-He213 Molten fluoride salts (dpeaa)DE-He213 Boča, Miroslav verfasserin aut Mlynáriková, Jarmila verfasserin aut Netriová, Zuzana verfasserin aut Vasková, Zuzana verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 125(2016), 1 vom: 25. Feb., Seite 497-508 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:125 year:2016 number:1 day:25 month:02 pages:497-508 https://dx.doi.org/10.1007/s10973-016-5324-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 125 2016 1 25 02 497-508
allfieldsSound	10.1007/s10973-016-5324-y doi (DE-627)SPR015541630 (SPR)s10973-016-5324-y-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Kubíková, Blanka verfasserin aut Critical evaluation of partial molar volumes and excess partial molar volumes of molten fluoride melts 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Different procedures of evaluation of partial molar volume and excess partial molar volume have been applied for three binary or quasi-binary molten fluoride systems: KF–$ K_{2} %$ TaF_{7} $, $ K_{2} %$ ZrF_{6} $–$ K_{2} %$ TaF_{7} $ and (LiF–NaF–KF)eut–$ K_{2} %$ ZrF_{6} $. In the first procedure partial molar volume is calculated based on mathematical fitting of molar volume, while in the second procedure partial molar volume is calculated based on mathematical fitting of excess molar volume. It was shown that both procedures are in principle consistent. However, some inconsistencies on values of partial molar volume can occur when local extremes are observed on concentration dependence of molar volume. In such situation, proper selection of mathematical functions is essential which requires relatively high density of experimental data. Moreover, when data on only restricted concentration range are available, only procedure of molar volume fitting is applicable for calculation of partial molar volume. Density (dpeaa)DE-He213 Molar volume (dpeaa)DE-He213 Partial molar volume and excess partial molar volume (dpeaa)DE-He213 Molten fluoride salts (dpeaa)DE-He213 Boča, Miroslav verfasserin aut Mlynáriková, Jarmila verfasserin aut Netriová, Zuzana verfasserin aut Vasková, Zuzana verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 125(2016), 1 vom: 25. Feb., Seite 497-508 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:125 year:2016 number:1 day:25 month:02 pages:497-508 https://dx.doi.org/10.1007/s10973-016-5324-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 125 2016 1 25 02 497-508
language	English
source	Enthalten in Journal of thermal analysis and calorimetry 125(2016), 1 vom: 25. Feb., Seite 497-508 volume:125 year:2016 number:1 day:25 month:02 pages:497-508
sourceStr	Enthalten in Journal of thermal analysis and calorimetry 125(2016), 1 vom: 25. Feb., Seite 497-508 volume:125 year:2016 number:1 day:25 month:02 pages:497-508
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Density Molar volume Partial molar volume and excess partial molar volume Molten fluoride salts
dewey-raw	660
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container_title	Journal of thermal analysis and calorimetry
authorswithroles_txt_mv	Kubíková, Blanka @@aut@@ Boča, Miroslav @@aut@@ Mlynáriková, Jarmila @@aut@@ Netriová, Zuzana @@aut@@ Vasková, Zuzana @@aut@@
publishDateDaySort_date	2016-02-25T00:00:00Z
hierarchy_top_id	315295422
dewey-sort	3660
id	SPR015541630
language_de	englisch
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author	Kubíková, Blanka
spellingShingle	Kubíková, Blanka ddc 660 bkl 35.00 misc Density misc Molar volume misc Partial molar volume and excess partial molar volume misc Molten fluoride salts Critical evaluation of partial molar volumes and excess partial molar volumes of molten fluoride melts
authorStr	Kubíková, Blanka
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topic_title	660 ASE 35.00 bkl Critical evaluation of partial molar volumes and excess partial molar volumes of molten fluoride melts Density (dpeaa)DE-He213 Molar volume (dpeaa)DE-He213 Partial molar volume and excess partial molar volume (dpeaa)DE-He213 Molten fluoride salts (dpeaa)DE-He213
topic	ddc 660 bkl 35.00 misc Density misc Molar volume misc Partial molar volume and excess partial molar volume misc Molten fluoride salts
topic_unstemmed	ddc 660 bkl 35.00 misc Density misc Molar volume misc Partial molar volume and excess partial molar volume misc Molten fluoride salts
topic_browse	ddc 660 bkl 35.00 misc Density misc Molar volume misc Partial molar volume and excess partial molar volume misc Molten fluoride salts
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title	Critical evaluation of partial molar volumes and excess partial molar volumes of molten fluoride melts
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title_full	Critical evaluation of partial molar volumes and excess partial molar volumes of molten fluoride melts
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title_sort	critical evaluation of partial molar volumes and excess partial molar volumes of molten fluoride melts
title_auth	Critical evaluation of partial molar volumes and excess partial molar volumes of molten fluoride melts
abstract	Abstract Different procedures of evaluation of partial molar volume and excess partial molar volume have been applied for three binary or quasi-binary molten fluoride systems: KF–$ K_{2} %$ TaF_{7} $, $ K_{2} %$ ZrF_{6} $–$ K_{2} %$ TaF_{7} $ and (LiF–NaF–KF)eut–$ K_{2} %$ ZrF_{6} $. In the first procedure partial molar volume is calculated based on mathematical fitting of molar volume, while in the second procedure partial molar volume is calculated based on mathematical fitting of excess molar volume. It was shown that both procedures are in principle consistent. However, some inconsistencies on values of partial molar volume can occur when local extremes are observed on concentration dependence of molar volume. In such situation, proper selection of mathematical functions is essential which requires relatively high density of experimental data. Moreover, when data on only restricted concentration range are available, only procedure of molar volume fitting is applicable for calculation of partial molar volume.
abstractGer	Abstract Different procedures of evaluation of partial molar volume and excess partial molar volume have been applied for three binary or quasi-binary molten fluoride systems: KF–$ K_{2} %$ TaF_{7} $, $ K_{2} %$ ZrF_{6} $–$ K_{2} %$ TaF_{7} $ and (LiF–NaF–KF)eut–$ K_{2} %$ ZrF_{6} $. In the first procedure partial molar volume is calculated based on mathematical fitting of molar volume, while in the second procedure partial molar volume is calculated based on mathematical fitting of excess molar volume. It was shown that both procedures are in principle consistent. However, some inconsistencies on values of partial molar volume can occur when local extremes are observed on concentration dependence of molar volume. In such situation, proper selection of mathematical functions is essential which requires relatively high density of experimental data. Moreover, when data on only restricted concentration range are available, only procedure of molar volume fitting is applicable for calculation of partial molar volume.
abstract_unstemmed	Abstract Different procedures of evaluation of partial molar volume and excess partial molar volume have been applied for three binary or quasi-binary molten fluoride systems: KF–$ K_{2} %$ TaF_{7} $, $ K_{2} %$ ZrF_{6} $–$ K_{2} %$ TaF_{7} $ and (LiF–NaF–KF)eut–$ K_{2} %$ ZrF_{6} $. In the first procedure partial molar volume is calculated based on mathematical fitting of molar volume, while in the second procedure partial molar volume is calculated based on mathematical fitting of excess molar volume. It was shown that both procedures are in principle consistent. However, some inconsistencies on values of partial molar volume can occur when local extremes are observed on concentration dependence of molar volume. In such situation, proper selection of mathematical functions is essential which requires relatively high density of experimental data. Moreover, when data on only restricted concentration range are available, only procedure of molar volume fitting is applicable for calculation of partial molar volume.
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container_issue	1
title_short	Critical evaluation of partial molar volumes and excess partial molar volumes of molten fluoride melts
url	https://dx.doi.org/10.1007/s10973-016-5324-y
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author2	Boča, Miroslav Mlynáriková, Jarmila Netriová, Zuzana Vasková, Zuzana
author2Str	Boča, Miroslav Mlynáriková, Jarmila Netriová, Zuzana Vasková, Zuzana
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doi_str	10.1007/s10973-016-5324-y
up_date	2024-07-03T16:54:56.678Z
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Critical evaluation of partial molar volumes and excess partial molar volumes of molten fluoride melts

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