Thermal properties of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O

Abstract The hexahydrate of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O shows no phase transitions in the range of −40 to 76 °C when it melts in its own water of crystallization. It was shown that the thermal decomposition is a complex step-wise process, which starts with the simultaneo...
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Autor*in:	Melnikov, P. [verfasserIn] Arkhangelsky, I. V. [verfasserIn] Nascimento, V. A. [verfasserIn] de Oliveira, L. C. S. [verfasserIn] Silva, A. F. [verfasserIn] Zanoni, L. Z. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2016

Schlagwörter:	Rare earth Europium nitrate hexahydrate Thermal decomposition Oxynitrates

Übergeordnetes Werk:	Enthalten in: Journal of thermal analysis and calorimetry - Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969, 128(2016), 3 vom: 28. Dez., Seite 1353-1358
Übergeordnetes Werk:	volume:128 ; year:2016 ; number:3 ; day:28 ; month:12 ; pages:1353-1358

Links:	Volltext

DOI / URN:	10.1007/s10973-016-6047-9

Katalog-ID:	SPR015576612

Internformat


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520			\|a Abstract The hexahydrate of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O shows no phase transitions in the range of −40 to 76 °C when it melts in its own water of crystallization. It was shown that the thermal decomposition is a complex step-wise process, which starts with the simultaneous condensation of 6 mol of the initial monomer Eu($ NO_{3} $)3·$ 6H_{2} $O into a cyclic cluster 6[Eu($ NO_{3} $)3·$ 6H_{2} $O]. This hexamer gradually loses water and nitric acid, and a series of intermediate amorphous oxynitrates is formed. The removal of $ HNO_{3} $ azeotrope is essentially a continuous process occurring in the liquid phase. At higher temperatures, oxynitrates undergo further degradation, lose water, nitrogen dioxide, and oxygen, and finally, after having lost lattice water, are transformed into europium oxide. All mass losses are satisfactorily accounted for under the proposed scheme of thermal decomposition.
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700	1		\|a Zanoni, L. Z. \|e verfasserin \|4 aut
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912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_206
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
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912			\|a GBV_ILN_2010
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912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
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912			\|a GBV_ILN_2048
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912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2057
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912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
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matchkey_str	article:15728943:2016----::hrapoeteoerpuntaeeayr
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bklnumber	35.00
publishDate	2016
allfields	10.1007/s10973-016-6047-9 doi (DE-627)SPR015576612 (SPR)s10973-016-6047-9-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Melnikov, P. verfasserin aut Thermal properties of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The hexahydrate of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O shows no phase transitions in the range of −40 to 76 °C when it melts in its own water of crystallization. It was shown that the thermal decomposition is a complex step-wise process, which starts with the simultaneous condensation of 6 mol of the initial monomer Eu($ NO_{3} $)3·$ 6H_{2} $O into a cyclic cluster 6[Eu($ NO_{3} $)3·$ 6H_{2} $O]. This hexamer gradually loses water and nitric acid, and a series of intermediate amorphous oxynitrates is formed. The removal of $ HNO_{3} $ azeotrope is essentially a continuous process occurring in the liquid phase. At higher temperatures, oxynitrates undergo further degradation, lose water, nitrogen dioxide, and oxygen, and finally, after having lost lattice water, are transformed into europium oxide. All mass losses are satisfactorily accounted for under the proposed scheme of thermal decomposition. Rare earth (dpeaa)DE-He213 Europium nitrate hexahydrate (dpeaa)DE-He213 Thermal decomposition (dpeaa)DE-He213 Oxynitrates (dpeaa)DE-He213 Arkhangelsky, I. V. verfasserin aut Nascimento, V. A. verfasserin aut de Oliveira, L. C. S. verfasserin aut Silva, A. F. verfasserin aut Zanoni, L. Z. verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 128(2016), 3 vom: 28. Dez., Seite 1353-1358 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:128 year:2016 number:3 day:28 month:12 pages:1353-1358 https://dx.doi.org/10.1007/s10973-016-6047-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 128 2016 3 28 12 1353-1358
spelling	10.1007/s10973-016-6047-9 doi (DE-627)SPR015576612 (SPR)s10973-016-6047-9-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Melnikov, P. verfasserin aut Thermal properties of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The hexahydrate of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O shows no phase transitions in the range of −40 to 76 °C when it melts in its own water of crystallization. It was shown that the thermal decomposition is a complex step-wise process, which starts with the simultaneous condensation of 6 mol of the initial monomer Eu($ NO_{3} $)3·$ 6H_{2} $O into a cyclic cluster 6[Eu($ NO_{3} $)3·$ 6H_{2} $O]. This hexamer gradually loses water and nitric acid, and a series of intermediate amorphous oxynitrates is formed. The removal of $ HNO_{3} $ azeotrope is essentially a continuous process occurring in the liquid phase. At higher temperatures, oxynitrates undergo further degradation, lose water, nitrogen dioxide, and oxygen, and finally, after having lost lattice water, are transformed into europium oxide. All mass losses are satisfactorily accounted for under the proposed scheme of thermal decomposition. Rare earth (dpeaa)DE-He213 Europium nitrate hexahydrate (dpeaa)DE-He213 Thermal decomposition (dpeaa)DE-He213 Oxynitrates (dpeaa)DE-He213 Arkhangelsky, I. V. verfasserin aut Nascimento, V. A. verfasserin aut de Oliveira, L. C. S. verfasserin aut Silva, A. F. verfasserin aut Zanoni, L. Z. verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 128(2016), 3 vom: 28. Dez., Seite 1353-1358 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:128 year:2016 number:3 day:28 month:12 pages:1353-1358 https://dx.doi.org/10.1007/s10973-016-6047-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 128 2016 3 28 12 1353-1358
allfields_unstemmed	10.1007/s10973-016-6047-9 doi (DE-627)SPR015576612 (SPR)s10973-016-6047-9-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Melnikov, P. verfasserin aut Thermal properties of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The hexahydrate of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O shows no phase transitions in the range of −40 to 76 °C when it melts in its own water of crystallization. It was shown that the thermal decomposition is a complex step-wise process, which starts with the simultaneous condensation of 6 mol of the initial monomer Eu($ NO_{3} $)3·$ 6H_{2} $O into a cyclic cluster 6[Eu($ NO_{3} $)3·$ 6H_{2} $O]. This hexamer gradually loses water and nitric acid, and a series of intermediate amorphous oxynitrates is formed. The removal of $ HNO_{3} $ azeotrope is essentially a continuous process occurring in the liquid phase. At higher temperatures, oxynitrates undergo further degradation, lose water, nitrogen dioxide, and oxygen, and finally, after having lost lattice water, are transformed into europium oxide. All mass losses are satisfactorily accounted for under the proposed scheme of thermal decomposition. Rare earth (dpeaa)DE-He213 Europium nitrate hexahydrate (dpeaa)DE-He213 Thermal decomposition (dpeaa)DE-He213 Oxynitrates (dpeaa)DE-He213 Arkhangelsky, I. V. verfasserin aut Nascimento, V. A. verfasserin aut de Oliveira, L. C. S. verfasserin aut Silva, A. F. verfasserin aut Zanoni, L. Z. verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 128(2016), 3 vom: 28. Dez., Seite 1353-1358 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:128 year:2016 number:3 day:28 month:12 pages:1353-1358 https://dx.doi.org/10.1007/s10973-016-6047-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 128 2016 3 28 12 1353-1358
allfieldsGer	10.1007/s10973-016-6047-9 doi (DE-627)SPR015576612 (SPR)s10973-016-6047-9-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Melnikov, P. verfasserin aut Thermal properties of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The hexahydrate of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O shows no phase transitions in the range of −40 to 76 °C when it melts in its own water of crystallization. It was shown that the thermal decomposition is a complex step-wise process, which starts with the simultaneous condensation of 6 mol of the initial monomer Eu($ NO_{3} $)3·$ 6H_{2} $O into a cyclic cluster 6[Eu($ NO_{3} $)3·$ 6H_{2} $O]. This hexamer gradually loses water and nitric acid, and a series of intermediate amorphous oxynitrates is formed. The removal of $ HNO_{3} $ azeotrope is essentially a continuous process occurring in the liquid phase. At higher temperatures, oxynitrates undergo further degradation, lose water, nitrogen dioxide, and oxygen, and finally, after having lost lattice water, are transformed into europium oxide. All mass losses are satisfactorily accounted for under the proposed scheme of thermal decomposition. Rare earth (dpeaa)DE-He213 Europium nitrate hexahydrate (dpeaa)DE-He213 Thermal decomposition (dpeaa)DE-He213 Oxynitrates (dpeaa)DE-He213 Arkhangelsky, I. V. verfasserin aut Nascimento, V. A. verfasserin aut de Oliveira, L. C. S. verfasserin aut Silva, A. F. verfasserin aut Zanoni, L. Z. verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 128(2016), 3 vom: 28. Dez., Seite 1353-1358 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:128 year:2016 number:3 day:28 month:12 pages:1353-1358 https://dx.doi.org/10.1007/s10973-016-6047-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 128 2016 3 28 12 1353-1358
allfieldsSound	10.1007/s10973-016-6047-9 doi (DE-627)SPR015576612 (SPR)s10973-016-6047-9-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Melnikov, P. verfasserin aut Thermal properties of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The hexahydrate of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O shows no phase transitions in the range of −40 to 76 °C when it melts in its own water of crystallization. It was shown that the thermal decomposition is a complex step-wise process, which starts with the simultaneous condensation of 6 mol of the initial monomer Eu($ NO_{3} $)3·$ 6H_{2} $O into a cyclic cluster 6[Eu($ NO_{3} $)3·$ 6H_{2} $O]. This hexamer gradually loses water and nitric acid, and a series of intermediate amorphous oxynitrates is formed. The removal of $ HNO_{3} $ azeotrope is essentially a continuous process occurring in the liquid phase. At higher temperatures, oxynitrates undergo further degradation, lose water, nitrogen dioxide, and oxygen, and finally, after having lost lattice water, are transformed into europium oxide. All mass losses are satisfactorily accounted for under the proposed scheme of thermal decomposition. Rare earth (dpeaa)DE-He213 Europium nitrate hexahydrate (dpeaa)DE-He213 Thermal decomposition (dpeaa)DE-He213 Oxynitrates (dpeaa)DE-He213 Arkhangelsky, I. V. verfasserin aut Nascimento, V. A. verfasserin aut de Oliveira, L. C. S. verfasserin aut Silva, A. F. verfasserin aut Zanoni, L. Z. verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 128(2016), 3 vom: 28. Dez., Seite 1353-1358 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:128 year:2016 number:3 day:28 month:12 pages:1353-1358 https://dx.doi.org/10.1007/s10973-016-6047-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 128 2016 3 28 12 1353-1358
language	English
source	Enthalten in Journal of thermal analysis and calorimetry 128(2016), 3 vom: 28. Dez., Seite 1353-1358 volume:128 year:2016 number:3 day:28 month:12 pages:1353-1358
sourceStr	Enthalten in Journal of thermal analysis and calorimetry 128(2016), 3 vom: 28. Dez., Seite 1353-1358 volume:128 year:2016 number:3 day:28 month:12 pages:1353-1358
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Rare earth Europium nitrate hexahydrate Thermal decomposition Oxynitrates
dewey-raw	660
isfreeaccess_bool	false
container_title	Journal of thermal analysis and calorimetry
authorswithroles_txt_mv	Melnikov, P. @@aut@@ Arkhangelsky, I. V. @@aut@@ Nascimento, V. A. @@aut@@ de Oliveira, L. C. S. @@aut@@ Silva, A. F. @@aut@@ Zanoni, L. Z. @@aut@@
publishDateDaySort_date	2016-12-28T00:00:00Z
hierarchy_top_id	315295422
dewey-sort	3660
id	SPR015576612
language_de	englisch
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author	Melnikov, P.
spellingShingle	Melnikov, P. ddc 660 bkl 35.00 misc Rare earth misc Europium nitrate hexahydrate misc Thermal decomposition misc Oxynitrates Thermal properties of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O
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topic_title	660 ASE 35.00 bkl Thermal properties of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O Rare earth (dpeaa)DE-He213 Europium nitrate hexahydrate (dpeaa)DE-He213 Thermal decomposition (dpeaa)DE-He213 Oxynitrates (dpeaa)DE-He213
topic	ddc 660 bkl 35.00 misc Rare earth misc Europium nitrate hexahydrate misc Thermal decomposition misc Oxynitrates
topic_unstemmed	ddc 660 bkl 35.00 misc Rare earth misc Europium nitrate hexahydrate misc Thermal decomposition misc Oxynitrates
topic_browse	ddc 660 bkl 35.00 misc Rare earth misc Europium nitrate hexahydrate misc Thermal decomposition misc Oxynitrates
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title	Thermal properties of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O
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title_full	Thermal properties of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O
author_sort	Melnikov, P.
journal	Journal of thermal analysis and calorimetry
journalStr	Journal of thermal analysis and calorimetry
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author_browse	Melnikov, P. Arkhangelsky, I. V. Nascimento, V. A. de Oliveira, L. C. S. Silva, A. F. Zanoni, L. Z.
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author-letter	Melnikov, P.
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title_sort	thermal properties of europium nitrate hexahydrate eu($ no_{3} $)3·$ 6h_{2} $o
title_auth	Thermal properties of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O
abstract	Abstract The hexahydrate of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O shows no phase transitions in the range of −40 to 76 °C when it melts in its own water of crystallization. It was shown that the thermal decomposition is a complex step-wise process, which starts with the simultaneous condensation of 6 mol of the initial monomer Eu($ NO_{3} $)3·$ 6H_{2} $O into a cyclic cluster 6[Eu($ NO_{3} $)3·$ 6H_{2} $O]. This hexamer gradually loses water and nitric acid, and a series of intermediate amorphous oxynitrates is formed. The removal of $ HNO_{3} $ azeotrope is essentially a continuous process occurring in the liquid phase. At higher temperatures, oxynitrates undergo further degradation, lose water, nitrogen dioxide, and oxygen, and finally, after having lost lattice water, are transformed into europium oxide. All mass losses are satisfactorily accounted for under the proposed scheme of thermal decomposition.
abstractGer	Abstract The hexahydrate of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O shows no phase transitions in the range of −40 to 76 °C when it melts in its own water of crystallization. It was shown that the thermal decomposition is a complex step-wise process, which starts with the simultaneous condensation of 6 mol of the initial monomer Eu($ NO_{3} $)3·$ 6H_{2} $O into a cyclic cluster 6[Eu($ NO_{3} $)3·$ 6H_{2} $O]. This hexamer gradually loses water and nitric acid, and a series of intermediate amorphous oxynitrates is formed. The removal of $ HNO_{3} $ azeotrope is essentially a continuous process occurring in the liquid phase. At higher temperatures, oxynitrates undergo further degradation, lose water, nitrogen dioxide, and oxygen, and finally, after having lost lattice water, are transformed into europium oxide. All mass losses are satisfactorily accounted for under the proposed scheme of thermal decomposition.
abstract_unstemmed	Abstract The hexahydrate of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O shows no phase transitions in the range of −40 to 76 °C when it melts in its own water of crystallization. It was shown that the thermal decomposition is a complex step-wise process, which starts with the simultaneous condensation of 6 mol of the initial monomer Eu($ NO_{3} $)3·$ 6H_{2} $O into a cyclic cluster 6[Eu($ NO_{3} $)3·$ 6H_{2} $O]. This hexamer gradually loses water and nitric acid, and a series of intermediate amorphous oxynitrates is formed. The removal of $ HNO_{3} $ azeotrope is essentially a continuous process occurring in the liquid phase. At higher temperatures, oxynitrates undergo further degradation, lose water, nitrogen dioxide, and oxygen, and finally, after having lost lattice water, are transformed into europium oxide. All mass losses are satisfactorily accounted for under the proposed scheme of thermal decomposition.
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title_short	Thermal properties of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O
url	https://dx.doi.org/10.1007/s10973-016-6047-9
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author2	Arkhangelsky, I. V. Nascimento, V. A. de Oliveira, L. C. S. Silva, A. F. Zanoni, L. Z.
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doi_str	10.1007/s10973-016-6047-9
up_date	2024-07-03T17:07:25.942Z
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It was shown that the thermal decomposition is a complex step-wise process, which starts with the simultaneous condensation of 6 mol of the initial monomer Eu($ NO_{3} $)3·$ 6H_{2} $O into a cyclic cluster 6[Eu($ NO_{3} $)3·$ 6H_{2} $O]. This hexamer gradually loses water and nitric acid, and a series of intermediate amorphous oxynitrates is formed. The removal of $ HNO_{3} $ azeotrope is essentially a continuous process occurring in the liquid phase. At higher temperatures, oxynitrates undergo further degradation, lose water, nitrogen dioxide, and oxygen, and finally, after having lost lattice water, are transformed into europium oxide. All mass losses are satisfactorily accounted for under the proposed scheme of thermal decomposition.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Rare earth</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Europium nitrate hexahydrate</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Thermal decomposition</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Oxynitrates</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Arkhangelsky, I. V.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Nascimento, V. 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Thermal properties of europium nitrate hexahydrate Eu($ NO_{3} $)3·$ 6H_{2} $O

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