Thermal behavior of a sol–gel system containing aniline and organic phosphonates
Abstract Samples of an organic–inorganic hybrid were prepared by solvolysis and polycondensation in formic acid of tetraethoxysilane and diethylbenzyl phosphonate, simultaneous with the oxidative polymerization of aniline. The thermal behavior of the samples in dynamic air atmosphere and non-isother...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Vlase, G. [verfasserIn] Vlase, T. [verfasserIn] Doca, N. [verfasserIn] Perţa, M. [verfasserIn] Ilia, G. [verfasserIn] Plesu, N. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2009 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of thermal analysis and calorimetry - Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969, 97(2009), 2 vom: 28. Juli |
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| Übergeordnetes Werk: |
volume:97 ; year:2009 ; number:2 ; day:28 ; month:07 |
| Links: |
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| DOI / URN: |
10.1007/s10973-009-0216-z |
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| Katalog-ID: |
SPR015606147 |
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| 245 | 1 | 0 | |a Thermal behavior of a sol–gel system containing aniline and organic phosphonates |
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| 520 | |a Abstract Samples of an organic–inorganic hybrid were prepared by solvolysis and polycondensation in formic acid of tetraethoxysilane and diethylbenzyl phosphonate, simultaneous with the oxidative polymerization of aniline. The thermal behavior of the samples in dynamic air atmosphere and non-isothermal conditions was determined by a coupled thermogravimetric/evolved gas analysis. Two significant thermal events were established: the elimination from the polymeric matrix of low mass molecules, respectively the thermooxidative degradation of the organic part of the matrix. The kinetic analysis was performed with the Flynn-Wall-Ozawa, Friedman and modified Non-Parametric-Kinetic methods. Only the last one allowed an objective analysis of the first process as a process of two simultaneous thermally induced phenomena with the kinetic functions of the type $ α^{m} $(1 − α)n. | ||
| 650 | 4 | |a Coupled TG-EGA |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Non-isothermal kinetics |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Organophosphoric compounds |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Polyaniline |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Thermal analysis |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Vlase, T. |e verfasserin |4 aut | |
| 700 | 1 | |a Doca, N. |e verfasserin |4 aut | |
| 700 | 1 | |a Perţa, M. |e verfasserin |4 aut | |
| 700 | 1 | |a Ilia, G. |e verfasserin |4 aut | |
| 700 | 1 | |a Plesu, N. |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Journal of thermal analysis and calorimetry |d Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 |g 97(2009), 2 vom: 28. Juli |w (DE-627)315295422 |w (DE-600)2017304-0 |x 1572-8943 |7 nnns |
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10.1007/s10973-009-0216-z doi (DE-627)SPR015606147 (SPR)s10973-009-0216-z-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Vlase, G. verfasserin aut Thermal behavior of a sol–gel system containing aniline and organic phosphonates 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Samples of an organic–inorganic hybrid were prepared by solvolysis and polycondensation in formic acid of tetraethoxysilane and diethylbenzyl phosphonate, simultaneous with the oxidative polymerization of aniline. The thermal behavior of the samples in dynamic air atmosphere and non-isothermal conditions was determined by a coupled thermogravimetric/evolved gas analysis. Two significant thermal events were established: the elimination from the polymeric matrix of low mass molecules, respectively the thermooxidative degradation of the organic part of the matrix. The kinetic analysis was performed with the Flynn-Wall-Ozawa, Friedman and modified Non-Parametric-Kinetic methods. Only the last one allowed an objective analysis of the first process as a process of two simultaneous thermally induced phenomena with the kinetic functions of the type $ α^{m} $(1 − α)n. Coupled TG-EGA (dpeaa)DE-He213 Non-isothermal kinetics (dpeaa)DE-He213 Organophosphoric compounds (dpeaa)DE-He213 Polyaniline (dpeaa)DE-He213 Thermal analysis (dpeaa)DE-He213 Vlase, T. verfasserin aut Doca, N. verfasserin aut Perţa, M. verfasserin aut Ilia, G. verfasserin aut Plesu, N. verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 97(2009), 2 vom: 28. Juli (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:97 year:2009 number:2 day:28 month:07 https://dx.doi.org/10.1007/s10973-009-0216-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 97 2009 2 28 07 |
| spelling |
10.1007/s10973-009-0216-z doi (DE-627)SPR015606147 (SPR)s10973-009-0216-z-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Vlase, G. verfasserin aut Thermal behavior of a sol–gel system containing aniline and organic phosphonates 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Samples of an organic–inorganic hybrid were prepared by solvolysis and polycondensation in formic acid of tetraethoxysilane and diethylbenzyl phosphonate, simultaneous with the oxidative polymerization of aniline. The thermal behavior of the samples in dynamic air atmosphere and non-isothermal conditions was determined by a coupled thermogravimetric/evolved gas analysis. Two significant thermal events were established: the elimination from the polymeric matrix of low mass molecules, respectively the thermooxidative degradation of the organic part of the matrix. The kinetic analysis was performed with the Flynn-Wall-Ozawa, Friedman and modified Non-Parametric-Kinetic methods. Only the last one allowed an objective analysis of the first process as a process of two simultaneous thermally induced phenomena with the kinetic functions of the type $ α^{m} $(1 − α)n. Coupled TG-EGA (dpeaa)DE-He213 Non-isothermal kinetics (dpeaa)DE-He213 Organophosphoric compounds (dpeaa)DE-He213 Polyaniline (dpeaa)DE-He213 Thermal analysis (dpeaa)DE-He213 Vlase, T. verfasserin aut Doca, N. verfasserin aut Perţa, M. verfasserin aut Ilia, G. verfasserin aut Plesu, N. verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 97(2009), 2 vom: 28. Juli (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:97 year:2009 number:2 day:28 month:07 https://dx.doi.org/10.1007/s10973-009-0216-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 97 2009 2 28 07 |
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10.1007/s10973-009-0216-z doi (DE-627)SPR015606147 (SPR)s10973-009-0216-z-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Vlase, G. verfasserin aut Thermal behavior of a sol–gel system containing aniline and organic phosphonates 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Samples of an organic–inorganic hybrid were prepared by solvolysis and polycondensation in formic acid of tetraethoxysilane and diethylbenzyl phosphonate, simultaneous with the oxidative polymerization of aniline. The thermal behavior of the samples in dynamic air atmosphere and non-isothermal conditions was determined by a coupled thermogravimetric/evolved gas analysis. Two significant thermal events were established: the elimination from the polymeric matrix of low mass molecules, respectively the thermooxidative degradation of the organic part of the matrix. The kinetic analysis was performed with the Flynn-Wall-Ozawa, Friedman and modified Non-Parametric-Kinetic methods. Only the last one allowed an objective analysis of the first process as a process of two simultaneous thermally induced phenomena with the kinetic functions of the type $ α^{m} $(1 − α)n. Coupled TG-EGA (dpeaa)DE-He213 Non-isothermal kinetics (dpeaa)DE-He213 Organophosphoric compounds (dpeaa)DE-He213 Polyaniline (dpeaa)DE-He213 Thermal analysis (dpeaa)DE-He213 Vlase, T. verfasserin aut Doca, N. verfasserin aut Perţa, M. verfasserin aut Ilia, G. verfasserin aut Plesu, N. verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 97(2009), 2 vom: 28. Juli (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:97 year:2009 number:2 day:28 month:07 https://dx.doi.org/10.1007/s10973-009-0216-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 97 2009 2 28 07 |
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10.1007/s10973-009-0216-z doi (DE-627)SPR015606147 (SPR)s10973-009-0216-z-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Vlase, G. verfasserin aut Thermal behavior of a sol–gel system containing aniline and organic phosphonates 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Samples of an organic–inorganic hybrid were prepared by solvolysis and polycondensation in formic acid of tetraethoxysilane and diethylbenzyl phosphonate, simultaneous with the oxidative polymerization of aniline. The thermal behavior of the samples in dynamic air atmosphere and non-isothermal conditions was determined by a coupled thermogravimetric/evolved gas analysis. Two significant thermal events were established: the elimination from the polymeric matrix of low mass molecules, respectively the thermooxidative degradation of the organic part of the matrix. The kinetic analysis was performed with the Flynn-Wall-Ozawa, Friedman and modified Non-Parametric-Kinetic methods. Only the last one allowed an objective analysis of the first process as a process of two simultaneous thermally induced phenomena with the kinetic functions of the type $ α^{m} $(1 − α)n. Coupled TG-EGA (dpeaa)DE-He213 Non-isothermal kinetics (dpeaa)DE-He213 Organophosphoric compounds (dpeaa)DE-He213 Polyaniline (dpeaa)DE-He213 Thermal analysis (dpeaa)DE-He213 Vlase, T. verfasserin aut Doca, N. verfasserin aut Perţa, M. verfasserin aut Ilia, G. verfasserin aut Plesu, N. verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 97(2009), 2 vom: 28. Juli (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:97 year:2009 number:2 day:28 month:07 https://dx.doi.org/10.1007/s10973-009-0216-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 97 2009 2 28 07 |
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10.1007/s10973-009-0216-z doi (DE-627)SPR015606147 (SPR)s10973-009-0216-z-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Vlase, G. verfasserin aut Thermal behavior of a sol–gel system containing aniline and organic phosphonates 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Samples of an organic–inorganic hybrid were prepared by solvolysis and polycondensation in formic acid of tetraethoxysilane and diethylbenzyl phosphonate, simultaneous with the oxidative polymerization of aniline. The thermal behavior of the samples in dynamic air atmosphere and non-isothermal conditions was determined by a coupled thermogravimetric/evolved gas analysis. Two significant thermal events were established: the elimination from the polymeric matrix of low mass molecules, respectively the thermooxidative degradation of the organic part of the matrix. The kinetic analysis was performed with the Flynn-Wall-Ozawa, Friedman and modified Non-Parametric-Kinetic methods. Only the last one allowed an objective analysis of the first process as a process of two simultaneous thermally induced phenomena with the kinetic functions of the type $ α^{m} $(1 − α)n. Coupled TG-EGA (dpeaa)DE-He213 Non-isothermal kinetics (dpeaa)DE-He213 Organophosphoric compounds (dpeaa)DE-He213 Polyaniline (dpeaa)DE-He213 Thermal analysis (dpeaa)DE-He213 Vlase, T. verfasserin aut Doca, N. verfasserin aut Perţa, M. verfasserin aut Ilia, G. verfasserin aut Plesu, N. verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 97(2009), 2 vom: 28. Juli (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:97 year:2009 number:2 day:28 month:07 https://dx.doi.org/10.1007/s10973-009-0216-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 97 2009 2 28 07 |
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Enthalten in Journal of thermal analysis and calorimetry 97(2009), 2 vom: 28. Juli volume:97 year:2009 number:2 day:28 month:07 |
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Coupled TG-EGA Non-isothermal kinetics Organophosphoric compounds Polyaniline Thermal analysis |
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Vlase, G. @@aut@@ Vlase, T. @@aut@@ Doca, N. @@aut@@ Perţa, M. @@aut@@ Ilia, G. @@aut@@ Plesu, N. @@aut@@ |
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Vlase, G. |
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Vlase, G. ddc 660 bkl 35.00 misc Coupled TG-EGA misc Non-isothermal kinetics misc Organophosphoric compounds misc Polyaniline misc Thermal analysis Thermal behavior of a sol–gel system containing aniline and organic phosphonates |
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660 ASE 35.00 bkl Thermal behavior of a sol–gel system containing aniline and organic phosphonates Coupled TG-EGA (dpeaa)DE-He213 Non-isothermal kinetics (dpeaa)DE-He213 Organophosphoric compounds (dpeaa)DE-He213 Polyaniline (dpeaa)DE-He213 Thermal analysis (dpeaa)DE-He213 |
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Vlase, G. Vlase, T. Doca, N. Perţa, M. Ilia, G. Plesu, N. |
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thermal behavior of a sol–gel system containing aniline and organic phosphonates |
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Thermal behavior of a sol–gel system containing aniline and organic phosphonates |
| abstract |
Abstract Samples of an organic–inorganic hybrid were prepared by solvolysis and polycondensation in formic acid of tetraethoxysilane and diethylbenzyl phosphonate, simultaneous with the oxidative polymerization of aniline. The thermal behavior of the samples in dynamic air atmosphere and non-isothermal conditions was determined by a coupled thermogravimetric/evolved gas analysis. Two significant thermal events were established: the elimination from the polymeric matrix of low mass molecules, respectively the thermooxidative degradation of the organic part of the matrix. The kinetic analysis was performed with the Flynn-Wall-Ozawa, Friedman and modified Non-Parametric-Kinetic methods. Only the last one allowed an objective analysis of the first process as a process of two simultaneous thermally induced phenomena with the kinetic functions of the type $ α^{m} $(1 − α)n. |
| abstractGer |
Abstract Samples of an organic–inorganic hybrid were prepared by solvolysis and polycondensation in formic acid of tetraethoxysilane and diethylbenzyl phosphonate, simultaneous with the oxidative polymerization of aniline. The thermal behavior of the samples in dynamic air atmosphere and non-isothermal conditions was determined by a coupled thermogravimetric/evolved gas analysis. Two significant thermal events were established: the elimination from the polymeric matrix of low mass molecules, respectively the thermooxidative degradation of the organic part of the matrix. The kinetic analysis was performed with the Flynn-Wall-Ozawa, Friedman and modified Non-Parametric-Kinetic methods. Only the last one allowed an objective analysis of the first process as a process of two simultaneous thermally induced phenomena with the kinetic functions of the type $ α^{m} $(1 − α)n. |
| abstract_unstemmed |
Abstract Samples of an organic–inorganic hybrid were prepared by solvolysis and polycondensation in formic acid of tetraethoxysilane and diethylbenzyl phosphonate, simultaneous with the oxidative polymerization of aniline. The thermal behavior of the samples in dynamic air atmosphere and non-isothermal conditions was determined by a coupled thermogravimetric/evolved gas analysis. Two significant thermal events were established: the elimination from the polymeric matrix of low mass molecules, respectively the thermooxidative degradation of the organic part of the matrix. The kinetic analysis was performed with the Flynn-Wall-Ozawa, Friedman and modified Non-Parametric-Kinetic methods. Only the last one allowed an objective analysis of the first process as a process of two simultaneous thermally induced phenomena with the kinetic functions of the type $ α^{m} $(1 − α)n. |
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2 |
| title_short |
Thermal behavior of a sol–gel system containing aniline and organic phosphonates |
| url |
https://dx.doi.org/10.1007/s10973-009-0216-z |
| remote_bool |
true |
| author2 |
Vlase, T. Doca, N. Perţa, M. Ilia, G. Plesu, N. |
| author2Str |
Vlase, T. Doca, N. Perţa, M. Ilia, G. Plesu, N. |
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| doi_str |
10.1007/s10973-009-0216-z |
| up_date |
2024-07-03T17:19:47.478Z |
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| score |
7.4021635 |