Thermal hazard analysis of a dehydrogenation system involving methylcyclohexane and toluene
Abstract The development of hydrogen infrastructure is important because its commercialization will help reduce carbon dioxide emissions significantly. The construction of hydrogen fueling stations will increase the demand for fuel cell vehicles. While the risk associated with various types of fueli...
Ausführliche Beschreibung
Autor*in: |
Nakayama, Jo [verfasserIn] Aoki, Hiroyuki [verfasserIn] Homma, Tomohiro [verfasserIn] Yamaki, Nana [verfasserIn] Miyake, Atsumi [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2018 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Journal of thermal analysis and calorimetry - Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969, 133(2018), 1 vom: 19. Jan., Seite 805-812 |
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Übergeordnetes Werk: |
volume:133 ; year:2018 ; number:1 ; day:19 ; month:01 ; pages:805-812 |
Links: |
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DOI / URN: |
10.1007/s10973-018-6971-y |
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Katalog-ID: |
SPR015613887 |
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520 | |a Abstract The development of hydrogen infrastructure is important because its commercialization will help reduce carbon dioxide emissions significantly. The construction of hydrogen fueling stations will increase the demand for fuel cell vehicles. While the risk associated with various types of fueling stations has been assessed, and appropriate safety regulations have been proposed, there have been few studies on hydrogen fueling stations with on-site dehydrogenation systems that use methylcyclohexane (MCH). This is because such stations are very new. In particular, the thermal hazards associated with such systems must be analyzed because they could lead to equipment damage. The purpose of the present study was to identify the thermal hazards of such systems using various thermal analysis methods. Thermal analyses were performed while assuming spontaneous ignition and oxidation under normal and abnormal conditions, in order to identify the thermal hazards associated with the storage of MCH, toluene, and heat carriers in underground storage tanks as well as their use in the dehydrogenation reactor. In addition, the thermal safety of the tank and the reactor was estimated based on the results of the thermal analyses. It was found that the underground storage tanks for MCH and toluene have a lower thermal risk because the process conditions are mild, and the thermal hazards related to the chemicals are low. Further, in the case of the dehydrogenation reactor, the risk of the spontaneous ignition of the heat carrier is low under quasi-adiabatic conditions and moderate air ventilation, in case the heat carrier leaks from damaged piping and equipment. However, it is important to regularly inspect the reactor to prevent any issues that may arise from an exothermic reaction of the heat carrier. | ||
650 | 4 | |a Hydrogen fueling station |7 (dpeaa)DE-He213 | |
650 | 4 | |a On-site hydrogen production system |7 (dpeaa)DE-He213 | |
650 | 4 | |a Methylcyclohexane |7 (dpeaa)DE-He213 | |
650 | 4 | |a Toluene |7 (dpeaa)DE-He213 | |
650 | 4 | |a Thermal hazard |7 (dpeaa)DE-He213 | |
700 | 1 | |a Aoki, Hiroyuki |e verfasserin |4 aut | |
700 | 1 | |a Homma, Tomohiro |e verfasserin |4 aut | |
700 | 1 | |a Yamaki, Nana |e verfasserin |4 aut | |
700 | 1 | |a Miyake, Atsumi |e verfasserin |4 aut | |
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773 | 1 | 8 | |g volume:133 |g year:2018 |g number:1 |g day:19 |g month:01 |g pages:805-812 |
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10.1007/s10973-018-6971-y doi (DE-627)SPR015613887 (SPR)s10973-018-6971-y-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Nakayama, Jo verfasserin aut Thermal hazard analysis of a dehydrogenation system involving methylcyclohexane and toluene 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The development of hydrogen infrastructure is important because its commercialization will help reduce carbon dioxide emissions significantly. The construction of hydrogen fueling stations will increase the demand for fuel cell vehicles. While the risk associated with various types of fueling stations has been assessed, and appropriate safety regulations have been proposed, there have been few studies on hydrogen fueling stations with on-site dehydrogenation systems that use methylcyclohexane (MCH). This is because such stations are very new. In particular, the thermal hazards associated with such systems must be analyzed because they could lead to equipment damage. The purpose of the present study was to identify the thermal hazards of such systems using various thermal analysis methods. Thermal analyses were performed while assuming spontaneous ignition and oxidation under normal and abnormal conditions, in order to identify the thermal hazards associated with the storage of MCH, toluene, and heat carriers in underground storage tanks as well as their use in the dehydrogenation reactor. In addition, the thermal safety of the tank and the reactor was estimated based on the results of the thermal analyses. It was found that the underground storage tanks for MCH and toluene have a lower thermal risk because the process conditions are mild, and the thermal hazards related to the chemicals are low. Further, in the case of the dehydrogenation reactor, the risk of the spontaneous ignition of the heat carrier is low under quasi-adiabatic conditions and moderate air ventilation, in case the heat carrier leaks from damaged piping and equipment. However, it is important to regularly inspect the reactor to prevent any issues that may arise from an exothermic reaction of the heat carrier. Hydrogen fueling station (dpeaa)DE-He213 On-site hydrogen production system (dpeaa)DE-He213 Methylcyclohexane (dpeaa)DE-He213 Toluene (dpeaa)DE-He213 Thermal hazard (dpeaa)DE-He213 Aoki, Hiroyuki verfasserin aut Homma, Tomohiro verfasserin aut Yamaki, Nana verfasserin aut Miyake, Atsumi verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 133(2018), 1 vom: 19. Jan., Seite 805-812 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:133 year:2018 number:1 day:19 month:01 pages:805-812 https://dx.doi.org/10.1007/s10973-018-6971-y kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 133 2018 1 19 01 805-812 |
spelling |
10.1007/s10973-018-6971-y doi (DE-627)SPR015613887 (SPR)s10973-018-6971-y-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Nakayama, Jo verfasserin aut Thermal hazard analysis of a dehydrogenation system involving methylcyclohexane and toluene 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The development of hydrogen infrastructure is important because its commercialization will help reduce carbon dioxide emissions significantly. The construction of hydrogen fueling stations will increase the demand for fuel cell vehicles. While the risk associated with various types of fueling stations has been assessed, and appropriate safety regulations have been proposed, there have been few studies on hydrogen fueling stations with on-site dehydrogenation systems that use methylcyclohexane (MCH). This is because such stations are very new. In particular, the thermal hazards associated with such systems must be analyzed because they could lead to equipment damage. The purpose of the present study was to identify the thermal hazards of such systems using various thermal analysis methods. Thermal analyses were performed while assuming spontaneous ignition and oxidation under normal and abnormal conditions, in order to identify the thermal hazards associated with the storage of MCH, toluene, and heat carriers in underground storage tanks as well as their use in the dehydrogenation reactor. In addition, the thermal safety of the tank and the reactor was estimated based on the results of the thermal analyses. It was found that the underground storage tanks for MCH and toluene have a lower thermal risk because the process conditions are mild, and the thermal hazards related to the chemicals are low. Further, in the case of the dehydrogenation reactor, the risk of the spontaneous ignition of the heat carrier is low under quasi-adiabatic conditions and moderate air ventilation, in case the heat carrier leaks from damaged piping and equipment. However, it is important to regularly inspect the reactor to prevent any issues that may arise from an exothermic reaction of the heat carrier. Hydrogen fueling station (dpeaa)DE-He213 On-site hydrogen production system (dpeaa)DE-He213 Methylcyclohexane (dpeaa)DE-He213 Toluene (dpeaa)DE-He213 Thermal hazard (dpeaa)DE-He213 Aoki, Hiroyuki verfasserin aut Homma, Tomohiro verfasserin aut Yamaki, Nana verfasserin aut Miyake, Atsumi verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 133(2018), 1 vom: 19. Jan., Seite 805-812 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:133 year:2018 number:1 day:19 month:01 pages:805-812 https://dx.doi.org/10.1007/s10973-018-6971-y kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 133 2018 1 19 01 805-812 |
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10.1007/s10973-018-6971-y doi (DE-627)SPR015613887 (SPR)s10973-018-6971-y-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Nakayama, Jo verfasserin aut Thermal hazard analysis of a dehydrogenation system involving methylcyclohexane and toluene 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The development of hydrogen infrastructure is important because its commercialization will help reduce carbon dioxide emissions significantly. The construction of hydrogen fueling stations will increase the demand for fuel cell vehicles. While the risk associated with various types of fueling stations has been assessed, and appropriate safety regulations have been proposed, there have been few studies on hydrogen fueling stations with on-site dehydrogenation systems that use methylcyclohexane (MCH). This is because such stations are very new. In particular, the thermal hazards associated with such systems must be analyzed because they could lead to equipment damage. The purpose of the present study was to identify the thermal hazards of such systems using various thermal analysis methods. Thermal analyses were performed while assuming spontaneous ignition and oxidation under normal and abnormal conditions, in order to identify the thermal hazards associated with the storage of MCH, toluene, and heat carriers in underground storage tanks as well as their use in the dehydrogenation reactor. In addition, the thermal safety of the tank and the reactor was estimated based on the results of the thermal analyses. It was found that the underground storage tanks for MCH and toluene have a lower thermal risk because the process conditions are mild, and the thermal hazards related to the chemicals are low. Further, in the case of the dehydrogenation reactor, the risk of the spontaneous ignition of the heat carrier is low under quasi-adiabatic conditions and moderate air ventilation, in case the heat carrier leaks from damaged piping and equipment. However, it is important to regularly inspect the reactor to prevent any issues that may arise from an exothermic reaction of the heat carrier. Hydrogen fueling station (dpeaa)DE-He213 On-site hydrogen production system (dpeaa)DE-He213 Methylcyclohexane (dpeaa)DE-He213 Toluene (dpeaa)DE-He213 Thermal hazard (dpeaa)DE-He213 Aoki, Hiroyuki verfasserin aut Homma, Tomohiro verfasserin aut Yamaki, Nana verfasserin aut Miyake, Atsumi verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 133(2018), 1 vom: 19. Jan., Seite 805-812 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:133 year:2018 number:1 day:19 month:01 pages:805-812 https://dx.doi.org/10.1007/s10973-018-6971-y kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 133 2018 1 19 01 805-812 |
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10.1007/s10973-018-6971-y doi (DE-627)SPR015613887 (SPR)s10973-018-6971-y-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Nakayama, Jo verfasserin aut Thermal hazard analysis of a dehydrogenation system involving methylcyclohexane and toluene 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The development of hydrogen infrastructure is important because its commercialization will help reduce carbon dioxide emissions significantly. The construction of hydrogen fueling stations will increase the demand for fuel cell vehicles. While the risk associated with various types of fueling stations has been assessed, and appropriate safety regulations have been proposed, there have been few studies on hydrogen fueling stations with on-site dehydrogenation systems that use methylcyclohexane (MCH). This is because such stations are very new. In particular, the thermal hazards associated with such systems must be analyzed because they could lead to equipment damage. The purpose of the present study was to identify the thermal hazards of such systems using various thermal analysis methods. Thermal analyses were performed while assuming spontaneous ignition and oxidation under normal and abnormal conditions, in order to identify the thermal hazards associated with the storage of MCH, toluene, and heat carriers in underground storage tanks as well as their use in the dehydrogenation reactor. In addition, the thermal safety of the tank and the reactor was estimated based on the results of the thermal analyses. It was found that the underground storage tanks for MCH and toluene have a lower thermal risk because the process conditions are mild, and the thermal hazards related to the chemicals are low. Further, in the case of the dehydrogenation reactor, the risk of the spontaneous ignition of the heat carrier is low under quasi-adiabatic conditions and moderate air ventilation, in case the heat carrier leaks from damaged piping and equipment. However, it is important to regularly inspect the reactor to prevent any issues that may arise from an exothermic reaction of the heat carrier. Hydrogen fueling station (dpeaa)DE-He213 On-site hydrogen production system (dpeaa)DE-He213 Methylcyclohexane (dpeaa)DE-He213 Toluene (dpeaa)DE-He213 Thermal hazard (dpeaa)DE-He213 Aoki, Hiroyuki verfasserin aut Homma, Tomohiro verfasserin aut Yamaki, Nana verfasserin aut Miyake, Atsumi verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 133(2018), 1 vom: 19. Jan., Seite 805-812 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:133 year:2018 number:1 day:19 month:01 pages:805-812 https://dx.doi.org/10.1007/s10973-018-6971-y kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 133 2018 1 19 01 805-812 |
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10.1007/s10973-018-6971-y doi (DE-627)SPR015613887 (SPR)s10973-018-6971-y-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Nakayama, Jo verfasserin aut Thermal hazard analysis of a dehydrogenation system involving methylcyclohexane and toluene 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The development of hydrogen infrastructure is important because its commercialization will help reduce carbon dioxide emissions significantly. The construction of hydrogen fueling stations will increase the demand for fuel cell vehicles. While the risk associated with various types of fueling stations has been assessed, and appropriate safety regulations have been proposed, there have been few studies on hydrogen fueling stations with on-site dehydrogenation systems that use methylcyclohexane (MCH). This is because such stations are very new. In particular, the thermal hazards associated with such systems must be analyzed because they could lead to equipment damage. The purpose of the present study was to identify the thermal hazards of such systems using various thermal analysis methods. Thermal analyses were performed while assuming spontaneous ignition and oxidation under normal and abnormal conditions, in order to identify the thermal hazards associated with the storage of MCH, toluene, and heat carriers in underground storage tanks as well as their use in the dehydrogenation reactor. In addition, the thermal safety of the tank and the reactor was estimated based on the results of the thermal analyses. It was found that the underground storage tanks for MCH and toluene have a lower thermal risk because the process conditions are mild, and the thermal hazards related to the chemicals are low. Further, in the case of the dehydrogenation reactor, the risk of the spontaneous ignition of the heat carrier is low under quasi-adiabatic conditions and moderate air ventilation, in case the heat carrier leaks from damaged piping and equipment. However, it is important to regularly inspect the reactor to prevent any issues that may arise from an exothermic reaction of the heat carrier. Hydrogen fueling station (dpeaa)DE-He213 On-site hydrogen production system (dpeaa)DE-He213 Methylcyclohexane (dpeaa)DE-He213 Toluene (dpeaa)DE-He213 Thermal hazard (dpeaa)DE-He213 Aoki, Hiroyuki verfasserin aut Homma, Tomohiro verfasserin aut Yamaki, Nana verfasserin aut Miyake, Atsumi verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 133(2018), 1 vom: 19. Jan., Seite 805-812 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:133 year:2018 number:1 day:19 month:01 pages:805-812 https://dx.doi.org/10.1007/s10973-018-6971-y kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 133 2018 1 19 01 805-812 |
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Enthalten in Journal of thermal analysis and calorimetry 133(2018), 1 vom: 19. Jan., Seite 805-812 volume:133 year:2018 number:1 day:19 month:01 pages:805-812 |
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Hydrogen fueling station On-site hydrogen production system Methylcyclohexane Toluene Thermal hazard |
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Nakayama, Jo @@aut@@ Aoki, Hiroyuki @@aut@@ Homma, Tomohiro @@aut@@ Yamaki, Nana @@aut@@ Miyake, Atsumi @@aut@@ |
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The construction of hydrogen fueling stations will increase the demand for fuel cell vehicles. While the risk associated with various types of fueling stations has been assessed, and appropriate safety regulations have been proposed, there have been few studies on hydrogen fueling stations with on-site dehydrogenation systems that use methylcyclohexane (MCH). This is because such stations are very new. In particular, the thermal hazards associated with such systems must be analyzed because they could lead to equipment damage. The purpose of the present study was to identify the thermal hazards of such systems using various thermal analysis methods. Thermal analyses were performed while assuming spontaneous ignition and oxidation under normal and abnormal conditions, in order to identify the thermal hazards associated with the storage of MCH, toluene, and heat carriers in underground storage tanks as well as their use in the dehydrogenation reactor. In addition, the thermal safety of the tank and the reactor was estimated based on the results of the thermal analyses. It was found that the underground storage tanks for MCH and toluene have a lower thermal risk because the process conditions are mild, and the thermal hazards related to the chemicals are low. Further, in the case of the dehydrogenation reactor, the risk of the spontaneous ignition of the heat carrier is low under quasi-adiabatic conditions and moderate air ventilation, in case the heat carrier leaks from damaged piping and equipment. However, it is important to regularly inspect the reactor to prevent any issues that may arise from an exothermic reaction of the heat carrier.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hydrogen fueling station</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">On-site hydrogen production system</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Methylcyclohexane</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Toluene</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Thermal hazard</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Aoki, Hiroyuki</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Homma, Tomohiro</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yamaki, Nana</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Miyake, Atsumi</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of thermal analysis and calorimetry</subfield><subfield code="d">Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969</subfield><subfield code="g">133(2018), 1 vom: 19. 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|
author |
Nakayama, Jo |
spellingShingle |
Nakayama, Jo ddc 660 bkl 35.00 misc Hydrogen fueling station misc On-site hydrogen production system misc Methylcyclohexane misc Toluene misc Thermal hazard Thermal hazard analysis of a dehydrogenation system involving methylcyclohexane and toluene |
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Nakayama, Jo |
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660 - Chemical engineering |
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1572-8943 |
topic_title |
660 ASE 35.00 bkl Thermal hazard analysis of a dehydrogenation system involving methylcyclohexane and toluene Hydrogen fueling station (dpeaa)DE-He213 On-site hydrogen production system (dpeaa)DE-He213 Methylcyclohexane (dpeaa)DE-He213 Toluene (dpeaa)DE-He213 Thermal hazard (dpeaa)DE-He213 |
topic |
ddc 660 bkl 35.00 misc Hydrogen fueling station misc On-site hydrogen production system misc Methylcyclohexane misc Toluene misc Thermal hazard |
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ddc 660 bkl 35.00 misc Hydrogen fueling station misc On-site hydrogen production system misc Methylcyclohexane misc Toluene misc Thermal hazard |
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ddc 660 bkl 35.00 misc Hydrogen fueling station misc On-site hydrogen production system misc Methylcyclohexane misc Toluene misc Thermal hazard |
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Elektronische Aufsätze Aufsätze Elektronische Ressource |
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Thermal hazard analysis of a dehydrogenation system involving methylcyclohexane and toluene |
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Thermal hazard analysis of a dehydrogenation system involving methylcyclohexane and toluene |
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Nakayama, Jo |
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Journal of thermal analysis and calorimetry |
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Journal of thermal analysis and calorimetry |
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Nakayama, Jo Aoki, Hiroyuki Homma, Tomohiro Yamaki, Nana Miyake, Atsumi |
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660 ASE 35.00 bkl |
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Elektronische Aufsätze |
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Nakayama, Jo |
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10.1007/s10973-018-6971-y |
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660 |
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verfasserin |
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thermal hazard analysis of a dehydrogenation system involving methylcyclohexane and toluene |
title_auth |
Thermal hazard analysis of a dehydrogenation system involving methylcyclohexane and toluene |
abstract |
Abstract The development of hydrogen infrastructure is important because its commercialization will help reduce carbon dioxide emissions significantly. The construction of hydrogen fueling stations will increase the demand for fuel cell vehicles. While the risk associated with various types of fueling stations has been assessed, and appropriate safety regulations have been proposed, there have been few studies on hydrogen fueling stations with on-site dehydrogenation systems that use methylcyclohexane (MCH). This is because such stations are very new. In particular, the thermal hazards associated with such systems must be analyzed because they could lead to equipment damage. The purpose of the present study was to identify the thermal hazards of such systems using various thermal analysis methods. Thermal analyses were performed while assuming spontaneous ignition and oxidation under normal and abnormal conditions, in order to identify the thermal hazards associated with the storage of MCH, toluene, and heat carriers in underground storage tanks as well as their use in the dehydrogenation reactor. In addition, the thermal safety of the tank and the reactor was estimated based on the results of the thermal analyses. It was found that the underground storage tanks for MCH and toluene have a lower thermal risk because the process conditions are mild, and the thermal hazards related to the chemicals are low. Further, in the case of the dehydrogenation reactor, the risk of the spontaneous ignition of the heat carrier is low under quasi-adiabatic conditions and moderate air ventilation, in case the heat carrier leaks from damaged piping and equipment. However, it is important to regularly inspect the reactor to prevent any issues that may arise from an exothermic reaction of the heat carrier. |
abstractGer |
Abstract The development of hydrogen infrastructure is important because its commercialization will help reduce carbon dioxide emissions significantly. The construction of hydrogen fueling stations will increase the demand for fuel cell vehicles. While the risk associated with various types of fueling stations has been assessed, and appropriate safety regulations have been proposed, there have been few studies on hydrogen fueling stations with on-site dehydrogenation systems that use methylcyclohexane (MCH). This is because such stations are very new. In particular, the thermal hazards associated with such systems must be analyzed because they could lead to equipment damage. The purpose of the present study was to identify the thermal hazards of such systems using various thermal analysis methods. Thermal analyses were performed while assuming spontaneous ignition and oxidation under normal and abnormal conditions, in order to identify the thermal hazards associated with the storage of MCH, toluene, and heat carriers in underground storage tanks as well as their use in the dehydrogenation reactor. In addition, the thermal safety of the tank and the reactor was estimated based on the results of the thermal analyses. It was found that the underground storage tanks for MCH and toluene have a lower thermal risk because the process conditions are mild, and the thermal hazards related to the chemicals are low. Further, in the case of the dehydrogenation reactor, the risk of the spontaneous ignition of the heat carrier is low under quasi-adiabatic conditions and moderate air ventilation, in case the heat carrier leaks from damaged piping and equipment. However, it is important to regularly inspect the reactor to prevent any issues that may arise from an exothermic reaction of the heat carrier. |
abstract_unstemmed |
Abstract The development of hydrogen infrastructure is important because its commercialization will help reduce carbon dioxide emissions significantly. The construction of hydrogen fueling stations will increase the demand for fuel cell vehicles. While the risk associated with various types of fueling stations has been assessed, and appropriate safety regulations have been proposed, there have been few studies on hydrogen fueling stations with on-site dehydrogenation systems that use methylcyclohexane (MCH). This is because such stations are very new. In particular, the thermal hazards associated with such systems must be analyzed because they could lead to equipment damage. The purpose of the present study was to identify the thermal hazards of such systems using various thermal analysis methods. Thermal analyses were performed while assuming spontaneous ignition and oxidation under normal and abnormal conditions, in order to identify the thermal hazards associated with the storage of MCH, toluene, and heat carriers in underground storage tanks as well as their use in the dehydrogenation reactor. In addition, the thermal safety of the tank and the reactor was estimated based on the results of the thermal analyses. It was found that the underground storage tanks for MCH and toluene have a lower thermal risk because the process conditions are mild, and the thermal hazards related to the chemicals are low. Further, in the case of the dehydrogenation reactor, the risk of the spontaneous ignition of the heat carrier is low under quasi-adiabatic conditions and moderate air ventilation, in case the heat carrier leaks from damaged piping and equipment. However, it is important to regularly inspect the reactor to prevent any issues that may arise from an exothermic reaction of the heat carrier. |
collection_details |
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container_issue |
1 |
title_short |
Thermal hazard analysis of a dehydrogenation system involving methylcyclohexane and toluene |
url |
https://dx.doi.org/10.1007/s10973-018-6971-y |
remote_bool |
true |
author2 |
Aoki, Hiroyuki Homma, Tomohiro Yamaki, Nana Miyake, Atsumi |
author2Str |
Aoki, Hiroyuki Homma, Tomohiro Yamaki, Nana Miyake, Atsumi |
ppnlink |
315295422 |
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hochschulschrift_bool |
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doi_str |
10.1007/s10973-018-6971-y |
up_date |
2024-07-03T17:23:16.977Z |
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|
score |
7.4030848 |