Analysis of the thermal hazards of 1-butyl-3-methylimidazolium chloride mixtures with cellulose and various metals

Abstract Ionic liquids (ILs) are a relatively new class of environmentally benign and comparatively safe solvents and are expected to have numerous applications in chemical processes. Although pure ILs are thermally stable, the presence of impurities can affect their thermal stability and decomposit...
Ausführliche Beschreibung

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Autor*in:	Yamaki, Nana [verfasserIn] Shiota, Kento [verfasserIn] Izato, Yu-ichiro [verfasserIn] Miyake, Atsumi [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2018

Schlagwörter:	Ionic liquids Thermal hazards Cellulose dissolving 1-Butyl-3-methylimidazolium chloride Evolved gas analysis

Übergeordnetes Werk:	Enthalten in: Journal of thermal analysis and calorimetry - Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969, 133(2018), 1 vom: 09. Feb., Seite 797-803
Übergeordnetes Werk:	volume:133 ; year:2018 ; number:1 ; day:09 ; month:02 ; pages:797-803

Links:	Volltext

DOI / URN:	10.1007/s10973-018-6993-5

Katalog-ID:	SPR015614220

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520			\|a Abstract Ionic liquids (ILs) are a relatively new class of environmentally benign and comparatively safe solvents and are expected to have numerous applications in chemical processes. Although pure ILs are thermally stable, the presence of impurities can affect their thermal stability and decomposition behavior. In addition, ILs decomposition products include flammable gases that may present a fire hazard. When designing safer processes and operating conditions, it is therefore important to investigate IL thermal properties and decomposition products in combination with additives. The present work focused on cellulose dissolution which is promising application of ILs to obtain better understanding of thermal hazards. Mixtures of cellulose, iron (III) oxide ($ Fe_{2} %$ O_{3} $), copper(II) oxide (CuO), chromium, and nickel with 1-butyl-3-methylimidazolium chloride (BmimCl) were examined, using differential scanning calorimetry, high-sensitivity calorimetry, and thermogravimetry–differential thermal analysis–mass spectrometry. The addition of CuO was found to generate an exothermic reaction below the decomposition temperature of BmimCl and also to lower the decomposition temperature. BmimCl/CuO mixtures also produced extremely flammable gases below the decomposition temperature of pure BmimCl.
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publishDate	2018
allfields	10.1007/s10973-018-6993-5 doi (DE-627)SPR015614220 (SPR)s10973-018-6993-5-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Yamaki, Nana verfasserin aut Analysis of the thermal hazards of 1-butyl-3-methylimidazolium chloride mixtures with cellulose and various metals 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Ionic liquids (ILs) are a relatively new class of environmentally benign and comparatively safe solvents and are expected to have numerous applications in chemical processes. Although pure ILs are thermally stable, the presence of impurities can affect their thermal stability and decomposition behavior. In addition, ILs decomposition products include flammable gases that may present a fire hazard. When designing safer processes and operating conditions, it is therefore important to investigate IL thermal properties and decomposition products in combination with additives. The present work focused on cellulose dissolution which is promising application of ILs to obtain better understanding of thermal hazards. Mixtures of cellulose, iron (III) oxide ($ Fe_{2} %$ O_{3} $), copper(II) oxide (CuO), chromium, and nickel with 1-butyl-3-methylimidazolium chloride (BmimCl) were examined, using differential scanning calorimetry, high-sensitivity calorimetry, and thermogravimetry–differential thermal analysis–mass spectrometry. The addition of CuO was found to generate an exothermic reaction below the decomposition temperature of BmimCl and also to lower the decomposition temperature. BmimCl/CuO mixtures also produced extremely flammable gases below the decomposition temperature of pure BmimCl. Ionic liquids (dpeaa)DE-He213 Thermal hazards (dpeaa)DE-He213 Cellulose dissolving (dpeaa)DE-He213 1-Butyl-3-methylimidazolium chloride (dpeaa)DE-He213 Evolved gas analysis (dpeaa)DE-He213 Shiota, Kento verfasserin aut Izato, Yu-ichiro verfasserin aut Miyake, Atsumi verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 133(2018), 1 vom: 09. Feb., Seite 797-803 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:133 year:2018 number:1 day:09 month:02 pages:797-803 https://dx.doi.org/10.1007/s10973-018-6993-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 133 2018 1 09 02 797-803
spelling	10.1007/s10973-018-6993-5 doi (DE-627)SPR015614220 (SPR)s10973-018-6993-5-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Yamaki, Nana verfasserin aut Analysis of the thermal hazards of 1-butyl-3-methylimidazolium chloride mixtures with cellulose and various metals 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Ionic liquids (ILs) are a relatively new class of environmentally benign and comparatively safe solvents and are expected to have numerous applications in chemical processes. Although pure ILs are thermally stable, the presence of impurities can affect their thermal stability and decomposition behavior. In addition, ILs decomposition products include flammable gases that may present a fire hazard. When designing safer processes and operating conditions, it is therefore important to investigate IL thermal properties and decomposition products in combination with additives. The present work focused on cellulose dissolution which is promising application of ILs to obtain better understanding of thermal hazards. Mixtures of cellulose, iron (III) oxide ($ Fe_{2} %$ O_{3} $), copper(II) oxide (CuO), chromium, and nickel with 1-butyl-3-methylimidazolium chloride (BmimCl) were examined, using differential scanning calorimetry, high-sensitivity calorimetry, and thermogravimetry–differential thermal analysis–mass spectrometry. The addition of CuO was found to generate an exothermic reaction below the decomposition temperature of BmimCl and also to lower the decomposition temperature. BmimCl/CuO mixtures also produced extremely flammable gases below the decomposition temperature of pure BmimCl. Ionic liquids (dpeaa)DE-He213 Thermal hazards (dpeaa)DE-He213 Cellulose dissolving (dpeaa)DE-He213 1-Butyl-3-methylimidazolium chloride (dpeaa)DE-He213 Evolved gas analysis (dpeaa)DE-He213 Shiota, Kento verfasserin aut Izato, Yu-ichiro verfasserin aut Miyake, Atsumi verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 133(2018), 1 vom: 09. Feb., Seite 797-803 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:133 year:2018 number:1 day:09 month:02 pages:797-803 https://dx.doi.org/10.1007/s10973-018-6993-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 133 2018 1 09 02 797-803
allfields_unstemmed	10.1007/s10973-018-6993-5 doi (DE-627)SPR015614220 (SPR)s10973-018-6993-5-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Yamaki, Nana verfasserin aut Analysis of the thermal hazards of 1-butyl-3-methylimidazolium chloride mixtures with cellulose and various metals 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Ionic liquids (ILs) are a relatively new class of environmentally benign and comparatively safe solvents and are expected to have numerous applications in chemical processes. Although pure ILs are thermally stable, the presence of impurities can affect their thermal stability and decomposition behavior. In addition, ILs decomposition products include flammable gases that may present a fire hazard. When designing safer processes and operating conditions, it is therefore important to investigate IL thermal properties and decomposition products in combination with additives. The present work focused on cellulose dissolution which is promising application of ILs to obtain better understanding of thermal hazards. Mixtures of cellulose, iron (III) oxide ($ Fe_{2} %$ O_{3} $), copper(II) oxide (CuO), chromium, and nickel with 1-butyl-3-methylimidazolium chloride (BmimCl) were examined, using differential scanning calorimetry, high-sensitivity calorimetry, and thermogravimetry–differential thermal analysis–mass spectrometry. The addition of CuO was found to generate an exothermic reaction below the decomposition temperature of BmimCl and also to lower the decomposition temperature. BmimCl/CuO mixtures also produced extremely flammable gases below the decomposition temperature of pure BmimCl. Ionic liquids (dpeaa)DE-He213 Thermal hazards (dpeaa)DE-He213 Cellulose dissolving (dpeaa)DE-He213 1-Butyl-3-methylimidazolium chloride (dpeaa)DE-He213 Evolved gas analysis (dpeaa)DE-He213 Shiota, Kento verfasserin aut Izato, Yu-ichiro verfasserin aut Miyake, Atsumi verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 133(2018), 1 vom: 09. Feb., Seite 797-803 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:133 year:2018 number:1 day:09 month:02 pages:797-803 https://dx.doi.org/10.1007/s10973-018-6993-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 133 2018 1 09 02 797-803
allfieldsGer	10.1007/s10973-018-6993-5 doi (DE-627)SPR015614220 (SPR)s10973-018-6993-5-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Yamaki, Nana verfasserin aut Analysis of the thermal hazards of 1-butyl-3-methylimidazolium chloride mixtures with cellulose and various metals 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Ionic liquids (ILs) are a relatively new class of environmentally benign and comparatively safe solvents and are expected to have numerous applications in chemical processes. Although pure ILs are thermally stable, the presence of impurities can affect their thermal stability and decomposition behavior. In addition, ILs decomposition products include flammable gases that may present a fire hazard. When designing safer processes and operating conditions, it is therefore important to investigate IL thermal properties and decomposition products in combination with additives. The present work focused on cellulose dissolution which is promising application of ILs to obtain better understanding of thermal hazards. Mixtures of cellulose, iron (III) oxide ($ Fe_{2} %$ O_{3} $), copper(II) oxide (CuO), chromium, and nickel with 1-butyl-3-methylimidazolium chloride (BmimCl) were examined, using differential scanning calorimetry, high-sensitivity calorimetry, and thermogravimetry–differential thermal analysis–mass spectrometry. The addition of CuO was found to generate an exothermic reaction below the decomposition temperature of BmimCl and also to lower the decomposition temperature. BmimCl/CuO mixtures also produced extremely flammable gases below the decomposition temperature of pure BmimCl. Ionic liquids (dpeaa)DE-He213 Thermal hazards (dpeaa)DE-He213 Cellulose dissolving (dpeaa)DE-He213 1-Butyl-3-methylimidazolium chloride (dpeaa)DE-He213 Evolved gas analysis (dpeaa)DE-He213 Shiota, Kento verfasserin aut Izato, Yu-ichiro verfasserin aut Miyake, Atsumi verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 133(2018), 1 vom: 09. Feb., Seite 797-803 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:133 year:2018 number:1 day:09 month:02 pages:797-803 https://dx.doi.org/10.1007/s10973-018-6993-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 133 2018 1 09 02 797-803
allfieldsSound	10.1007/s10973-018-6993-5 doi (DE-627)SPR015614220 (SPR)s10973-018-6993-5-e DE-627 ger DE-627 rakwb eng 660 ASE 35.00 bkl Yamaki, Nana verfasserin aut Analysis of the thermal hazards of 1-butyl-3-methylimidazolium chloride mixtures with cellulose and various metals 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Ionic liquids (ILs) are a relatively new class of environmentally benign and comparatively safe solvents and are expected to have numerous applications in chemical processes. Although pure ILs are thermally stable, the presence of impurities can affect their thermal stability and decomposition behavior. In addition, ILs decomposition products include flammable gases that may present a fire hazard. When designing safer processes and operating conditions, it is therefore important to investigate IL thermal properties and decomposition products in combination with additives. The present work focused on cellulose dissolution which is promising application of ILs to obtain better understanding of thermal hazards. Mixtures of cellulose, iron (III) oxide ($ Fe_{2} %$ O_{3} $), copper(II) oxide (CuO), chromium, and nickel with 1-butyl-3-methylimidazolium chloride (BmimCl) were examined, using differential scanning calorimetry, high-sensitivity calorimetry, and thermogravimetry–differential thermal analysis–mass spectrometry. The addition of CuO was found to generate an exothermic reaction below the decomposition temperature of BmimCl and also to lower the decomposition temperature. BmimCl/CuO mixtures also produced extremely flammable gases below the decomposition temperature of pure BmimCl. Ionic liquids (dpeaa)DE-He213 Thermal hazards (dpeaa)DE-He213 Cellulose dissolving (dpeaa)DE-He213 1-Butyl-3-methylimidazolium chloride (dpeaa)DE-He213 Evolved gas analysis (dpeaa)DE-He213 Shiota, Kento verfasserin aut Izato, Yu-ichiro verfasserin aut Miyake, Atsumi verfasserin aut Enthalten in Journal of thermal analysis and calorimetry Dordrecht [u.a.] : Springer Science + Business Media B.V., 1969 133(2018), 1 vom: 09. Feb., Seite 797-803 (DE-627)315295422 (DE-600)2017304-0 1572-8943 nnns volume:133 year:2018 number:1 day:09 month:02 pages:797-803 https://dx.doi.org/10.1007/s10973-018-6993-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 133 2018 1 09 02 797-803
language	English
source	Enthalten in Journal of thermal analysis and calorimetry 133(2018), 1 vom: 09. Feb., Seite 797-803 volume:133 year:2018 number:1 day:09 month:02 pages:797-803
sourceStr	Enthalten in Journal of thermal analysis and calorimetry 133(2018), 1 vom: 09. Feb., Seite 797-803 volume:133 year:2018 number:1 day:09 month:02 pages:797-803
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Ionic liquids Thermal hazards Cellulose dissolving 1-Butyl-3-methylimidazolium chloride Evolved gas analysis
dewey-raw	660
isfreeaccess_bool	false
container_title	Journal of thermal analysis and calorimetry
authorswithroles_txt_mv	Yamaki, Nana @@aut@@ Shiota, Kento @@aut@@ Izato, Yu-ichiro @@aut@@ Miyake, Atsumi @@aut@@
publishDateDaySort_date	2018-02-09T00:00:00Z
hierarchy_top_id	315295422
dewey-sort	3660
id	SPR015614220
language_de	englisch
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author	Yamaki, Nana
spellingShingle	Yamaki, Nana ddc 660 bkl 35.00 misc Ionic liquids misc Thermal hazards misc Cellulose dissolving misc 1-Butyl-3-methylimidazolium chloride misc Evolved gas analysis Analysis of the thermal hazards of 1-butyl-3-methylimidazolium chloride mixtures with cellulose and various metals
authorStr	Yamaki, Nana
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topic_title	660 ASE 35.00 bkl Analysis of the thermal hazards of 1-butyl-3-methylimidazolium chloride mixtures with cellulose and various metals Ionic liquids (dpeaa)DE-He213 Thermal hazards (dpeaa)DE-He213 Cellulose dissolving (dpeaa)DE-He213 1-Butyl-3-methylimidazolium chloride (dpeaa)DE-He213 Evolved gas analysis (dpeaa)DE-He213
topic	ddc 660 bkl 35.00 misc Ionic liquids misc Thermal hazards misc Cellulose dissolving misc 1-Butyl-3-methylimidazolium chloride misc Evolved gas analysis
topic_unstemmed	ddc 660 bkl 35.00 misc Ionic liquids misc Thermal hazards misc Cellulose dissolving misc 1-Butyl-3-methylimidazolium chloride misc Evolved gas analysis
topic_browse	ddc 660 bkl 35.00 misc Ionic liquids misc Thermal hazards misc Cellulose dissolving misc 1-Butyl-3-methylimidazolium chloride misc Evolved gas analysis
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title	Analysis of the thermal hazards of 1-butyl-3-methylimidazolium chloride mixtures with cellulose and various metals
ctrlnum	(DE-627)SPR015614220 (SPR)s10973-018-6993-5-e
title_full	Analysis of the thermal hazards of 1-butyl-3-methylimidazolium chloride mixtures with cellulose and various metals
author_sort	Yamaki, Nana
journal	Journal of thermal analysis and calorimetry
journalStr	Journal of thermal analysis and calorimetry
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author_browse	Yamaki, Nana Shiota, Kento Izato, Yu-ichiro Miyake, Atsumi
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doi_str_mv	10.1007/s10973-018-6993-5
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title_sort	analysis of the thermal hazards of 1-butyl-3-methylimidazolium chloride mixtures with cellulose and various metals
title_auth	Analysis of the thermal hazards of 1-butyl-3-methylimidazolium chloride mixtures with cellulose and various metals
abstract	Abstract Ionic liquids (ILs) are a relatively new class of environmentally benign and comparatively safe solvents and are expected to have numerous applications in chemical processes. Although pure ILs are thermally stable, the presence of impurities can affect their thermal stability and decomposition behavior. In addition, ILs decomposition products include flammable gases that may present a fire hazard. When designing safer processes and operating conditions, it is therefore important to investigate IL thermal properties and decomposition products in combination with additives. The present work focused on cellulose dissolution which is promising application of ILs to obtain better understanding of thermal hazards. Mixtures of cellulose, iron (III) oxide ($ Fe_{2} %$ O_{3} $), copper(II) oxide (CuO), chromium, and nickel with 1-butyl-3-methylimidazolium chloride (BmimCl) were examined, using differential scanning calorimetry, high-sensitivity calorimetry, and thermogravimetry–differential thermal analysis–mass spectrometry. The addition of CuO was found to generate an exothermic reaction below the decomposition temperature of BmimCl and also to lower the decomposition temperature. BmimCl/CuO mixtures also produced extremely flammable gases below the decomposition temperature of pure BmimCl.
abstractGer	Abstract Ionic liquids (ILs) are a relatively new class of environmentally benign and comparatively safe solvents and are expected to have numerous applications in chemical processes. Although pure ILs are thermally stable, the presence of impurities can affect their thermal stability and decomposition behavior. In addition, ILs decomposition products include flammable gases that may present a fire hazard. When designing safer processes and operating conditions, it is therefore important to investigate IL thermal properties and decomposition products in combination with additives. The present work focused on cellulose dissolution which is promising application of ILs to obtain better understanding of thermal hazards. Mixtures of cellulose, iron (III) oxide ($ Fe_{2} %$ O_{3} $), copper(II) oxide (CuO), chromium, and nickel with 1-butyl-3-methylimidazolium chloride (BmimCl) were examined, using differential scanning calorimetry, high-sensitivity calorimetry, and thermogravimetry–differential thermal analysis–mass spectrometry. The addition of CuO was found to generate an exothermic reaction below the decomposition temperature of BmimCl and also to lower the decomposition temperature. BmimCl/CuO mixtures also produced extremely flammable gases below the decomposition temperature of pure BmimCl.
abstract_unstemmed	Abstract Ionic liquids (ILs) are a relatively new class of environmentally benign and comparatively safe solvents and are expected to have numerous applications in chemical processes. Although pure ILs are thermally stable, the presence of impurities can affect their thermal stability and decomposition behavior. In addition, ILs decomposition products include flammable gases that may present a fire hazard. When designing safer processes and operating conditions, it is therefore important to investigate IL thermal properties and decomposition products in combination with additives. The present work focused on cellulose dissolution which is promising application of ILs to obtain better understanding of thermal hazards. Mixtures of cellulose, iron (III) oxide ($ Fe_{2} %$ O_{3} $), copper(II) oxide (CuO), chromium, and nickel with 1-butyl-3-methylimidazolium chloride (BmimCl) were examined, using differential scanning calorimetry, high-sensitivity calorimetry, and thermogravimetry–differential thermal analysis–mass spectrometry. The addition of CuO was found to generate an exothermic reaction below the decomposition temperature of BmimCl and also to lower the decomposition temperature. BmimCl/CuO mixtures also produced extremely flammable gases below the decomposition temperature of pure BmimCl.
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title_short	Analysis of the thermal hazards of 1-butyl-3-methylimidazolium chloride mixtures with cellulose and various metals
url	https://dx.doi.org/10.1007/s10973-018-6993-5
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author2	Shiota, Kento Izato, Yu-ichiro Miyake, Atsumi
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up_date	2024-07-03T17:23:25.561Z
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Analysis of the thermal hazards of 1-butyl-3-methylimidazolium chloride mixtures with cellulose and various metals

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