Synthesis and thermoelectric characterisation of bismuth nanoparticles

Abstract An effective method of preparation of bismuth nanopowders by thermal decomposition of bismuth dodecyl-mercaptide Bi($ SC_{12} %$ H_{25} $)3 and preliminary results on their thermoelectric properties are reported. The thermolysis process leads to Bi nanoparticles due to the efficient capping...
Ausführliche Beschreibung

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Autor*in:	Carotenuto, Gianfranco [verfasserIn] Hison, Cornelia L. [verfasserIn] Capezzuto, Filomena [verfasserIn] Palomba, Mariano [verfasserIn] Perlo, Pietro [verfasserIn] Conte, Pellegrino [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2008

Schlagwörter:	Bismuth nanoparticles Mercaptide thermolysis Semimetal–semiconductor transition Thermoelectric characteristics Nanopowder

Übergeordnetes Werk:	Enthalten in: Journal of nanoparticle research - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1999, 11(2008), 7 vom: 31. Okt.
Übergeordnetes Werk:	volume:11 ; year:2008 ; number:7 ; day:31 ; month:10

Links:	Volltext

DOI / URN:	10.1007/s11051-008-9541-6

Katalog-ID:	SPR016505166

Internformat


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520			\|a Abstract An effective method of preparation of bismuth nanopowders by thermal decomposition of bismuth dodecyl-mercaptide Bi($ SC_{12} %$ H_{25} $)3 and preliminary results on their thermoelectric properties are reported. The thermolysis process leads to Bi nanoparticles due to the efficient capping agent effect of the dodecyl-disulfide by-product, which strongly bonds the surface of the Bi clusters, preventing their aggregation and significantly reducing their growth rate. The structure and morphology of the thermolysis products were investigated by differential scanning calorimetry, thermogravimetry, X-ray diffractometry, 1H nuclear magnetic resonance spectroscopy, scanning electron microscopy, and energy dispersive spectroscopy. It has been shown that the prepared Bi nanopowder consists of spherical shape nanoparticles, with the average diameter depending on the thermolysis temperature. The first results on the thermoelectric characterization of the prepared Bi nanopowders reveal a peculiar behavior characterized by a semimetal–semiconductor transition, and a significant increase in the Seebeck coefficient when compared to bulk Bi in the case of the lowest grain size (170 nm).
650		4	\|a Bismuth nanoparticles \|7 (dpeaa)DE-He213
650		4	\|a Mercaptide thermolysis \|7 (dpeaa)DE-He213
650		4	\|a Semimetal–semiconductor transition \|7 (dpeaa)DE-He213
650		4	\|a Thermoelectric characteristics \|7 (dpeaa)DE-He213
650		4	\|a Nanopowder \|7 (dpeaa)DE-He213
700	1		\|a Hison, Cornelia L. \|e verfasserin \|4 aut
700	1		\|a Capezzuto, Filomena \|e verfasserin \|4 aut
700	1		\|a Palomba, Mariano \|e verfasserin \|4 aut
700	1		\|a Perlo, Pietro \|e verfasserin \|4 aut
700	1		\|a Conte, Pellegrino \|e verfasserin \|4 aut
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912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
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912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
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912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
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912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
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912			\|a GBV_ILN_2025
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912			\|a GBV_ILN_2048
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912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
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Indexfelder

author_variant	g c gc c l h cl clh f c fc m p mp p p pp p c pc
matchkey_str	article:1572896X:2008----::yteiadhrolcrchrceiainfim
hierarchy_sort_str	2008
bklnumber	51.45
publishDate	2008
allfields	10.1007/s11051-008-9541-6 doi (DE-627)SPR016505166 (SPR)s11051-008-9541-6-e DE-627 ger DE-627 rakwb eng 570 ASE 51.45 bkl Carotenuto, Gianfranco verfasserin aut Synthesis and thermoelectric characterisation of bismuth nanoparticles 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract An effective method of preparation of bismuth nanopowders by thermal decomposition of bismuth dodecyl-mercaptide Bi($ SC_{12} %$ H_{25} $)3 and preliminary results on their thermoelectric properties are reported. The thermolysis process leads to Bi nanoparticles due to the efficient capping agent effect of the dodecyl-disulfide by-product, which strongly bonds the surface of the Bi clusters, preventing their aggregation and significantly reducing their growth rate. The structure and morphology of the thermolysis products were investigated by differential scanning calorimetry, thermogravimetry, X-ray diffractometry, 1H nuclear magnetic resonance spectroscopy, scanning electron microscopy, and energy dispersive spectroscopy. It has been shown that the prepared Bi nanopowder consists of spherical shape nanoparticles, with the average diameter depending on the thermolysis temperature. The first results on the thermoelectric characterization of the prepared Bi nanopowders reveal a peculiar behavior characterized by a semimetal–semiconductor transition, and a significant increase in the Seebeck coefficient when compared to bulk Bi in the case of the lowest grain size (170 nm). Bismuth nanoparticles (dpeaa)DE-He213 Mercaptide thermolysis (dpeaa)DE-He213 Semimetal–semiconductor transition (dpeaa)DE-He213 Thermoelectric characteristics (dpeaa)DE-He213 Nanopowder (dpeaa)DE-He213 Hison, Cornelia L. verfasserin aut Capezzuto, Filomena verfasserin aut Palomba, Mariano verfasserin aut Perlo, Pietro verfasserin aut Conte, Pellegrino verfasserin aut Enthalten in Journal of nanoparticle research Dordrecht [u.a.] : Springer Science + Business Media B.V, 1999 11(2008), 7 vom: 31. Okt. (DE-627)320575667 (DE-600)2017013-0 1572-896X nnns volume:11 year:2008 number:7 day:31 month:10 https://dx.doi.org/10.1007/s11051-008-9541-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.45 ASE AR 11 2008 7 31 10
spelling	10.1007/s11051-008-9541-6 doi (DE-627)SPR016505166 (SPR)s11051-008-9541-6-e DE-627 ger DE-627 rakwb eng 570 ASE 51.45 bkl Carotenuto, Gianfranco verfasserin aut Synthesis and thermoelectric characterisation of bismuth nanoparticles 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract An effective method of preparation of bismuth nanopowders by thermal decomposition of bismuth dodecyl-mercaptide Bi($ SC_{12} %$ H_{25} $)3 and preliminary results on their thermoelectric properties are reported. The thermolysis process leads to Bi nanoparticles due to the efficient capping agent effect of the dodecyl-disulfide by-product, which strongly bonds the surface of the Bi clusters, preventing their aggregation and significantly reducing their growth rate. The structure and morphology of the thermolysis products were investigated by differential scanning calorimetry, thermogravimetry, X-ray diffractometry, 1H nuclear magnetic resonance spectroscopy, scanning electron microscopy, and energy dispersive spectroscopy. It has been shown that the prepared Bi nanopowder consists of spherical shape nanoparticles, with the average diameter depending on the thermolysis temperature. The first results on the thermoelectric characterization of the prepared Bi nanopowders reveal a peculiar behavior characterized by a semimetal–semiconductor transition, and a significant increase in the Seebeck coefficient when compared to bulk Bi in the case of the lowest grain size (170 nm). Bismuth nanoparticles (dpeaa)DE-He213 Mercaptide thermolysis (dpeaa)DE-He213 Semimetal–semiconductor transition (dpeaa)DE-He213 Thermoelectric characteristics (dpeaa)DE-He213 Nanopowder (dpeaa)DE-He213 Hison, Cornelia L. verfasserin aut Capezzuto, Filomena verfasserin aut Palomba, Mariano verfasserin aut Perlo, Pietro verfasserin aut Conte, Pellegrino verfasserin aut Enthalten in Journal of nanoparticle research Dordrecht [u.a.] : Springer Science + Business Media B.V, 1999 11(2008), 7 vom: 31. Okt. (DE-627)320575667 (DE-600)2017013-0 1572-896X nnns volume:11 year:2008 number:7 day:31 month:10 https://dx.doi.org/10.1007/s11051-008-9541-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.45 ASE AR 11 2008 7 31 10
allfields_unstemmed	10.1007/s11051-008-9541-6 doi (DE-627)SPR016505166 (SPR)s11051-008-9541-6-e DE-627 ger DE-627 rakwb eng 570 ASE 51.45 bkl Carotenuto, Gianfranco verfasserin aut Synthesis and thermoelectric characterisation of bismuth nanoparticles 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract An effective method of preparation of bismuth nanopowders by thermal decomposition of bismuth dodecyl-mercaptide Bi($ SC_{12} %$ H_{25} $)3 and preliminary results on their thermoelectric properties are reported. The thermolysis process leads to Bi nanoparticles due to the efficient capping agent effect of the dodecyl-disulfide by-product, which strongly bonds the surface of the Bi clusters, preventing their aggregation and significantly reducing their growth rate. The structure and morphology of the thermolysis products were investigated by differential scanning calorimetry, thermogravimetry, X-ray diffractometry, 1H nuclear magnetic resonance spectroscopy, scanning electron microscopy, and energy dispersive spectroscopy. It has been shown that the prepared Bi nanopowder consists of spherical shape nanoparticles, with the average diameter depending on the thermolysis temperature. The first results on the thermoelectric characterization of the prepared Bi nanopowders reveal a peculiar behavior characterized by a semimetal–semiconductor transition, and a significant increase in the Seebeck coefficient when compared to bulk Bi in the case of the lowest grain size (170 nm). Bismuth nanoparticles (dpeaa)DE-He213 Mercaptide thermolysis (dpeaa)DE-He213 Semimetal–semiconductor transition (dpeaa)DE-He213 Thermoelectric characteristics (dpeaa)DE-He213 Nanopowder (dpeaa)DE-He213 Hison, Cornelia L. verfasserin aut Capezzuto, Filomena verfasserin aut Palomba, Mariano verfasserin aut Perlo, Pietro verfasserin aut Conte, Pellegrino verfasserin aut Enthalten in Journal of nanoparticle research Dordrecht [u.a.] : Springer Science + Business Media B.V, 1999 11(2008), 7 vom: 31. Okt. (DE-627)320575667 (DE-600)2017013-0 1572-896X nnns volume:11 year:2008 number:7 day:31 month:10 https://dx.doi.org/10.1007/s11051-008-9541-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.45 ASE AR 11 2008 7 31 10
allfieldsGer	10.1007/s11051-008-9541-6 doi (DE-627)SPR016505166 (SPR)s11051-008-9541-6-e DE-627 ger DE-627 rakwb eng 570 ASE 51.45 bkl Carotenuto, Gianfranco verfasserin aut Synthesis and thermoelectric characterisation of bismuth nanoparticles 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract An effective method of preparation of bismuth nanopowders by thermal decomposition of bismuth dodecyl-mercaptide Bi($ SC_{12} %$ H_{25} $)3 and preliminary results on their thermoelectric properties are reported. The thermolysis process leads to Bi nanoparticles due to the efficient capping agent effect of the dodecyl-disulfide by-product, which strongly bonds the surface of the Bi clusters, preventing their aggregation and significantly reducing their growth rate. The structure and morphology of the thermolysis products were investigated by differential scanning calorimetry, thermogravimetry, X-ray diffractometry, 1H nuclear magnetic resonance spectroscopy, scanning electron microscopy, and energy dispersive spectroscopy. It has been shown that the prepared Bi nanopowder consists of spherical shape nanoparticles, with the average diameter depending on the thermolysis temperature. The first results on the thermoelectric characterization of the prepared Bi nanopowders reveal a peculiar behavior characterized by a semimetal–semiconductor transition, and a significant increase in the Seebeck coefficient when compared to bulk Bi in the case of the lowest grain size (170 nm). Bismuth nanoparticles (dpeaa)DE-He213 Mercaptide thermolysis (dpeaa)DE-He213 Semimetal–semiconductor transition (dpeaa)DE-He213 Thermoelectric characteristics (dpeaa)DE-He213 Nanopowder (dpeaa)DE-He213 Hison, Cornelia L. verfasserin aut Capezzuto, Filomena verfasserin aut Palomba, Mariano verfasserin aut Perlo, Pietro verfasserin aut Conte, Pellegrino verfasserin aut Enthalten in Journal of nanoparticle research Dordrecht [u.a.] : Springer Science + Business Media B.V, 1999 11(2008), 7 vom: 31. Okt. (DE-627)320575667 (DE-600)2017013-0 1572-896X nnns volume:11 year:2008 number:7 day:31 month:10 https://dx.doi.org/10.1007/s11051-008-9541-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.45 ASE AR 11 2008 7 31 10
allfieldsSound	10.1007/s11051-008-9541-6 doi (DE-627)SPR016505166 (SPR)s11051-008-9541-6-e DE-627 ger DE-627 rakwb eng 570 ASE 51.45 bkl Carotenuto, Gianfranco verfasserin aut Synthesis and thermoelectric characterisation of bismuth nanoparticles 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract An effective method of preparation of bismuth nanopowders by thermal decomposition of bismuth dodecyl-mercaptide Bi($ SC_{12} %$ H_{25} $)3 and preliminary results on their thermoelectric properties are reported. The thermolysis process leads to Bi nanoparticles due to the efficient capping agent effect of the dodecyl-disulfide by-product, which strongly bonds the surface of the Bi clusters, preventing their aggregation and significantly reducing their growth rate. The structure and morphology of the thermolysis products were investigated by differential scanning calorimetry, thermogravimetry, X-ray diffractometry, 1H nuclear magnetic resonance spectroscopy, scanning electron microscopy, and energy dispersive spectroscopy. It has been shown that the prepared Bi nanopowder consists of spherical shape nanoparticles, with the average diameter depending on the thermolysis temperature. The first results on the thermoelectric characterization of the prepared Bi nanopowders reveal a peculiar behavior characterized by a semimetal–semiconductor transition, and a significant increase in the Seebeck coefficient when compared to bulk Bi in the case of the lowest grain size (170 nm). Bismuth nanoparticles (dpeaa)DE-He213 Mercaptide thermolysis (dpeaa)DE-He213 Semimetal–semiconductor transition (dpeaa)DE-He213 Thermoelectric characteristics (dpeaa)DE-He213 Nanopowder (dpeaa)DE-He213 Hison, Cornelia L. verfasserin aut Capezzuto, Filomena verfasserin aut Palomba, Mariano verfasserin aut Perlo, Pietro verfasserin aut Conte, Pellegrino verfasserin aut Enthalten in Journal of nanoparticle research Dordrecht [u.a.] : Springer Science + Business Media B.V, 1999 11(2008), 7 vom: 31. Okt. (DE-627)320575667 (DE-600)2017013-0 1572-896X nnns volume:11 year:2008 number:7 day:31 month:10 https://dx.doi.org/10.1007/s11051-008-9541-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.45 ASE AR 11 2008 7 31 10
language	English
source	Enthalten in Journal of nanoparticle research 11(2008), 7 vom: 31. Okt. volume:11 year:2008 number:7 day:31 month:10
sourceStr	Enthalten in Journal of nanoparticle research 11(2008), 7 vom: 31. Okt. volume:11 year:2008 number:7 day:31 month:10
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Bismuth nanoparticles Mercaptide thermolysis Semimetal–semiconductor transition Thermoelectric characteristics Nanopowder
dewey-raw	570
isfreeaccess_bool	false
container_title	Journal of nanoparticle research
authorswithroles_txt_mv	Carotenuto, Gianfranco @@aut@@ Hison, Cornelia L. @@aut@@ Capezzuto, Filomena @@aut@@ Palomba, Mariano @@aut@@ Perlo, Pietro @@aut@@ Conte, Pellegrino @@aut@@
publishDateDaySort_date	2008-10-31T00:00:00Z
hierarchy_top_id	320575667
dewey-sort	3570
id	SPR016505166
language_de	englisch
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author	Carotenuto, Gianfranco
spellingShingle	Carotenuto, Gianfranco ddc 570 bkl 51.45 misc Bismuth nanoparticles misc Mercaptide thermolysis misc Semimetal–semiconductor transition misc Thermoelectric characteristics misc Nanopowder Synthesis and thermoelectric characterisation of bismuth nanoparticles
authorStr	Carotenuto, Gianfranco
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topic_title	570 ASE 51.45 bkl Synthesis and thermoelectric characterisation of bismuth nanoparticles Bismuth nanoparticles (dpeaa)DE-He213 Mercaptide thermolysis (dpeaa)DE-He213 Semimetal–semiconductor transition (dpeaa)DE-He213 Thermoelectric characteristics (dpeaa)DE-He213 Nanopowder (dpeaa)DE-He213
topic	ddc 570 bkl 51.45 misc Bismuth nanoparticles misc Mercaptide thermolysis misc Semimetal–semiconductor transition misc Thermoelectric characteristics misc Nanopowder
topic_unstemmed	ddc 570 bkl 51.45 misc Bismuth nanoparticles misc Mercaptide thermolysis misc Semimetal–semiconductor transition misc Thermoelectric characteristics misc Nanopowder
topic_browse	ddc 570 bkl 51.45 misc Bismuth nanoparticles misc Mercaptide thermolysis misc Semimetal–semiconductor transition misc Thermoelectric characteristics misc Nanopowder
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title	Synthesis and thermoelectric characterisation of bismuth nanoparticles
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title_full	Synthesis and thermoelectric characterisation of bismuth nanoparticles
author_sort	Carotenuto, Gianfranco
journal	Journal of nanoparticle research
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author_browse	Carotenuto, Gianfranco Hison, Cornelia L. Capezzuto, Filomena Palomba, Mariano Perlo, Pietro Conte, Pellegrino
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title_sort	synthesis and thermoelectric characterisation of bismuth nanoparticles
title_auth	Synthesis and thermoelectric characterisation of bismuth nanoparticles
abstract	Abstract An effective method of preparation of bismuth nanopowders by thermal decomposition of bismuth dodecyl-mercaptide Bi($ SC_{12} %$ H_{25} $)3 and preliminary results on their thermoelectric properties are reported. The thermolysis process leads to Bi nanoparticles due to the efficient capping agent effect of the dodecyl-disulfide by-product, which strongly bonds the surface of the Bi clusters, preventing their aggregation and significantly reducing their growth rate. The structure and morphology of the thermolysis products were investigated by differential scanning calorimetry, thermogravimetry, X-ray diffractometry, 1H nuclear magnetic resonance spectroscopy, scanning electron microscopy, and energy dispersive spectroscopy. It has been shown that the prepared Bi nanopowder consists of spherical shape nanoparticles, with the average diameter depending on the thermolysis temperature. The first results on the thermoelectric characterization of the prepared Bi nanopowders reveal a peculiar behavior characterized by a semimetal–semiconductor transition, and a significant increase in the Seebeck coefficient when compared to bulk Bi in the case of the lowest grain size (170 nm).
abstractGer	Abstract An effective method of preparation of bismuth nanopowders by thermal decomposition of bismuth dodecyl-mercaptide Bi($ SC_{12} %$ H_{25} $)3 and preliminary results on their thermoelectric properties are reported. The thermolysis process leads to Bi nanoparticles due to the efficient capping agent effect of the dodecyl-disulfide by-product, which strongly bonds the surface of the Bi clusters, preventing their aggregation and significantly reducing their growth rate. The structure and morphology of the thermolysis products were investigated by differential scanning calorimetry, thermogravimetry, X-ray diffractometry, 1H nuclear magnetic resonance spectroscopy, scanning electron microscopy, and energy dispersive spectroscopy. It has been shown that the prepared Bi nanopowder consists of spherical shape nanoparticles, with the average diameter depending on the thermolysis temperature. The first results on the thermoelectric characterization of the prepared Bi nanopowders reveal a peculiar behavior characterized by a semimetal–semiconductor transition, and a significant increase in the Seebeck coefficient when compared to bulk Bi in the case of the lowest grain size (170 nm).
abstract_unstemmed	Abstract An effective method of preparation of bismuth nanopowders by thermal decomposition of bismuth dodecyl-mercaptide Bi($ SC_{12} %$ H_{25} $)3 and preliminary results on their thermoelectric properties are reported. The thermolysis process leads to Bi nanoparticles due to the efficient capping agent effect of the dodecyl-disulfide by-product, which strongly bonds the surface of the Bi clusters, preventing their aggregation and significantly reducing their growth rate. The structure and morphology of the thermolysis products were investigated by differential scanning calorimetry, thermogravimetry, X-ray diffractometry, 1H nuclear magnetic resonance spectroscopy, scanning electron microscopy, and energy dispersive spectroscopy. It has been shown that the prepared Bi nanopowder consists of spherical shape nanoparticles, with the average diameter depending on the thermolysis temperature. The first results on the thermoelectric characterization of the prepared Bi nanopowders reveal a peculiar behavior characterized by a semimetal–semiconductor transition, and a significant increase in the Seebeck coefficient when compared to bulk Bi in the case of the lowest grain size (170 nm).
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title_short	Synthesis and thermoelectric characterisation of bismuth nanoparticles
url	https://dx.doi.org/10.1007/s11051-008-9541-6
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author2	Hison, Cornelia L. Capezzuto, Filomena Palomba, Mariano Perlo, Pietro Conte, Pellegrino
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up_date	2024-07-03T23:26:44.618Z
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The thermolysis process leads to Bi nanoparticles due to the efficient capping agent effect of the dodecyl-disulfide by-product, which strongly bonds the surface of the Bi clusters, preventing their aggregation and significantly reducing their growth rate. The structure and morphology of the thermolysis products were investigated by differential scanning calorimetry, thermogravimetry, X-ray diffractometry, 1H nuclear magnetic resonance spectroscopy, scanning electron microscopy, and energy dispersive spectroscopy. It has been shown that the prepared Bi nanopowder consists of spherical shape nanoparticles, with the average diameter depending on the thermolysis temperature. 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Synthesis and thermoelectric characterisation of bismuth nanoparticles

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