Influence of cobalt and nickel sorption on the texture of crystalline α-titanium phosphate
Crystalline titanium phosphate α-Ti($ HPO_{4} $)2 ⋅ $ H_{2} $O (α-TiP) has been prepared by reaction between phosphoric acid solution and titanium chloride in the temperature range 60–80 °C. The solid obtained has been treated, in solid state with different concentrations of either cobalt or nickel....
Ausführliche Beschreibung
Autor*in: |
Kassem, M. [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2012 |
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Übergeordnetes Werk: |
Enthalten in: Powder metallurgy and metal ceramics - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1962, 51(2012), 1-2 vom: Mai, Seite 121-127 |
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Übergeordnetes Werk: |
volume:51 ; year:2012 ; number:1-2 ; month:05 ; pages:121-127 |
Links: |
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DOI / URN: |
10.1007/s11106-012-9406-5 |
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Katalog-ID: |
SPR01678765X |
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520 | |a Crystalline titanium phosphate α-Ti($ HPO_{4} $)2 ⋅ $ H_{2} $O (α-TiP) has been prepared by reaction between phosphoric acid solution and titanium chloride in the temperature range 60–80 °C. The solid obtained has been treated, in solid state with different concentrations of either cobalt or nickel. The pure and derivative materials are characterised using X-ray powder diffraction, Fourier transform IR, differential thermal analysis, and nitrogen adsorption. Due to their higher degree of hydration, the cobalt atoms are more sorbed by (α-TiP), where they enter into the cavities (containing the water molecules) between the layers of titanium phosphate. It is found that this process can induce small expanding of the interlayer spacing in the C direction and losing the crystallinity in the other directions. For the nickel, after sorption of more than 20%, an atomic layer may be formed preventing (α-TiP) from accommodating any more nickel ions in its framework, this is displayed by the appearance of diffraction peaks related to unsorbed nickel. The DTA curves indicate that more crystalline α-TiP materials have higher transition temperature. The nitrogen adsorption isotherms give an indication that when the cobalt atoms are sorbed by α-TiP, the latter is transformed from microporous to mesoporous material while it keeps its pore uniformity in the case of nickel. | ||
650 | 4 | |a α titanium phosphate |7 (dpeaa)DE-He213 | |
650 | 4 | |a cobalt |7 (dpeaa)DE-He213 | |
650 | 4 | |a nickel |7 (dpeaa)DE-He213 | |
650 | 4 | |a atoms |7 (dpeaa)DE-He213 | |
650 | 4 | |a sorption |7 (dpeaa)DE-He213 | |
650 | 4 | |a DTA curves |7 (dpeaa)DE-He213 | |
650 | 4 | |a isotherms |7 (dpeaa)DE-He213 | |
650 | 4 | |a texture |7 (dpeaa)DE-He213 | |
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10.1007/s11106-012-9406-5 doi (DE-627)SPR01678765X (SPR)s11106-012-9406-5-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Kassem, M. verfasserin aut Influence of cobalt and nickel sorption on the texture of crystalline α-titanium phosphate 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Crystalline titanium phosphate α-Ti($ HPO_{4} $)2 ⋅ $ H_{2} $O (α-TiP) has been prepared by reaction between phosphoric acid solution and titanium chloride in the temperature range 60–80 °C. The solid obtained has been treated, in solid state with different concentrations of either cobalt or nickel. The pure and derivative materials are characterised using X-ray powder diffraction, Fourier transform IR, differential thermal analysis, and nitrogen adsorption. Due to their higher degree of hydration, the cobalt atoms are more sorbed by (α-TiP), where they enter into the cavities (containing the water molecules) between the layers of titanium phosphate. It is found that this process can induce small expanding of the interlayer spacing in the C direction and losing the crystallinity in the other directions. For the nickel, after sorption of more than 20%, an atomic layer may be formed preventing (α-TiP) from accommodating any more nickel ions in its framework, this is displayed by the appearance of diffraction peaks related to unsorbed nickel. The DTA curves indicate that more crystalline α-TiP materials have higher transition temperature. The nitrogen adsorption isotherms give an indication that when the cobalt atoms are sorbed by α-TiP, the latter is transformed from microporous to mesoporous material while it keeps its pore uniformity in the case of nickel. α titanium phosphate (dpeaa)DE-He213 cobalt (dpeaa)DE-He213 nickel (dpeaa)DE-He213 atoms (dpeaa)DE-He213 sorption (dpeaa)DE-He213 DTA curves (dpeaa)DE-He213 isotherms (dpeaa)DE-He213 texture (dpeaa)DE-He213 Enthalten in Powder metallurgy and metal ceramics Dordrecht [u.a.] : Springer Science + Business Media B.V, 1962 51(2012), 1-2 vom: Mai, Seite 121-127 (DE-627)325570272 (DE-600)2037317-X 1573-9066 nnns volume:51 year:2012 number:1-2 month:05 pages:121-127 https://dx.doi.org/10.1007/s11106-012-9406-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 51 2012 1-2 05 121-127 |
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10.1007/s11106-012-9406-5 doi (DE-627)SPR01678765X (SPR)s11106-012-9406-5-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Kassem, M. verfasserin aut Influence of cobalt and nickel sorption on the texture of crystalline α-titanium phosphate 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Crystalline titanium phosphate α-Ti($ HPO_{4} $)2 ⋅ $ H_{2} $O (α-TiP) has been prepared by reaction between phosphoric acid solution and titanium chloride in the temperature range 60–80 °C. The solid obtained has been treated, in solid state with different concentrations of either cobalt or nickel. The pure and derivative materials are characterised using X-ray powder diffraction, Fourier transform IR, differential thermal analysis, and nitrogen adsorption. Due to their higher degree of hydration, the cobalt atoms are more sorbed by (α-TiP), where they enter into the cavities (containing the water molecules) between the layers of titanium phosphate. It is found that this process can induce small expanding of the interlayer spacing in the C direction and losing the crystallinity in the other directions. For the nickel, after sorption of more than 20%, an atomic layer may be formed preventing (α-TiP) from accommodating any more nickel ions in its framework, this is displayed by the appearance of diffraction peaks related to unsorbed nickel. The DTA curves indicate that more crystalline α-TiP materials have higher transition temperature. The nitrogen adsorption isotherms give an indication that when the cobalt atoms are sorbed by α-TiP, the latter is transformed from microporous to mesoporous material while it keeps its pore uniformity in the case of nickel. α titanium phosphate (dpeaa)DE-He213 cobalt (dpeaa)DE-He213 nickel (dpeaa)DE-He213 atoms (dpeaa)DE-He213 sorption (dpeaa)DE-He213 DTA curves (dpeaa)DE-He213 isotherms (dpeaa)DE-He213 texture (dpeaa)DE-He213 Enthalten in Powder metallurgy and metal ceramics Dordrecht [u.a.] : Springer Science + Business Media B.V, 1962 51(2012), 1-2 vom: Mai, Seite 121-127 (DE-627)325570272 (DE-600)2037317-X 1573-9066 nnns volume:51 year:2012 number:1-2 month:05 pages:121-127 https://dx.doi.org/10.1007/s11106-012-9406-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 51 2012 1-2 05 121-127 |
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10.1007/s11106-012-9406-5 doi (DE-627)SPR01678765X (SPR)s11106-012-9406-5-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Kassem, M. verfasserin aut Influence of cobalt and nickel sorption on the texture of crystalline α-titanium phosphate 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Crystalline titanium phosphate α-Ti($ HPO_{4} $)2 ⋅ $ H_{2} $O (α-TiP) has been prepared by reaction between phosphoric acid solution and titanium chloride in the temperature range 60–80 °C. The solid obtained has been treated, in solid state with different concentrations of either cobalt or nickel. The pure and derivative materials are characterised using X-ray powder diffraction, Fourier transform IR, differential thermal analysis, and nitrogen adsorption. Due to their higher degree of hydration, the cobalt atoms are more sorbed by (α-TiP), where they enter into the cavities (containing the water molecules) between the layers of titanium phosphate. It is found that this process can induce small expanding of the interlayer spacing in the C direction and losing the crystallinity in the other directions. For the nickel, after sorption of more than 20%, an atomic layer may be formed preventing (α-TiP) from accommodating any more nickel ions in its framework, this is displayed by the appearance of diffraction peaks related to unsorbed nickel. The DTA curves indicate that more crystalline α-TiP materials have higher transition temperature. The nitrogen adsorption isotherms give an indication that when the cobalt atoms are sorbed by α-TiP, the latter is transformed from microporous to mesoporous material while it keeps its pore uniformity in the case of nickel. α titanium phosphate (dpeaa)DE-He213 cobalt (dpeaa)DE-He213 nickel (dpeaa)DE-He213 atoms (dpeaa)DE-He213 sorption (dpeaa)DE-He213 DTA curves (dpeaa)DE-He213 isotherms (dpeaa)DE-He213 texture (dpeaa)DE-He213 Enthalten in Powder metallurgy and metal ceramics Dordrecht [u.a.] : Springer Science + Business Media B.V, 1962 51(2012), 1-2 vom: Mai, Seite 121-127 (DE-627)325570272 (DE-600)2037317-X 1573-9066 nnns volume:51 year:2012 number:1-2 month:05 pages:121-127 https://dx.doi.org/10.1007/s11106-012-9406-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 51 2012 1-2 05 121-127 |
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10.1007/s11106-012-9406-5 doi (DE-627)SPR01678765X (SPR)s11106-012-9406-5-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Kassem, M. verfasserin aut Influence of cobalt and nickel sorption on the texture of crystalline α-titanium phosphate 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Crystalline titanium phosphate α-Ti($ HPO_{4} $)2 ⋅ $ H_{2} $O (α-TiP) has been prepared by reaction between phosphoric acid solution and titanium chloride in the temperature range 60–80 °C. The solid obtained has been treated, in solid state with different concentrations of either cobalt or nickel. The pure and derivative materials are characterised using X-ray powder diffraction, Fourier transform IR, differential thermal analysis, and nitrogen adsorption. Due to their higher degree of hydration, the cobalt atoms are more sorbed by (α-TiP), where they enter into the cavities (containing the water molecules) between the layers of titanium phosphate. It is found that this process can induce small expanding of the interlayer spacing in the C direction and losing the crystallinity in the other directions. For the nickel, after sorption of more than 20%, an atomic layer may be formed preventing (α-TiP) from accommodating any more nickel ions in its framework, this is displayed by the appearance of diffraction peaks related to unsorbed nickel. The DTA curves indicate that more crystalline α-TiP materials have higher transition temperature. The nitrogen adsorption isotherms give an indication that when the cobalt atoms are sorbed by α-TiP, the latter is transformed from microporous to mesoporous material while it keeps its pore uniformity in the case of nickel. α titanium phosphate (dpeaa)DE-He213 cobalt (dpeaa)DE-He213 nickel (dpeaa)DE-He213 atoms (dpeaa)DE-He213 sorption (dpeaa)DE-He213 DTA curves (dpeaa)DE-He213 isotherms (dpeaa)DE-He213 texture (dpeaa)DE-He213 Enthalten in Powder metallurgy and metal ceramics Dordrecht [u.a.] : Springer Science + Business Media B.V, 1962 51(2012), 1-2 vom: Mai, Seite 121-127 (DE-627)325570272 (DE-600)2037317-X 1573-9066 nnns volume:51 year:2012 number:1-2 month:05 pages:121-127 https://dx.doi.org/10.1007/s11106-012-9406-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 51 2012 1-2 05 121-127 |
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10.1007/s11106-012-9406-5 doi (DE-627)SPR01678765X (SPR)s11106-012-9406-5-e DE-627 ger DE-627 rakwb eng 670 ASE 51.00 bkl Kassem, M. verfasserin aut Influence of cobalt and nickel sorption on the texture of crystalline α-titanium phosphate 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Crystalline titanium phosphate α-Ti($ HPO_{4} $)2 ⋅ $ H_{2} $O (α-TiP) has been prepared by reaction between phosphoric acid solution and titanium chloride in the temperature range 60–80 °C. The solid obtained has been treated, in solid state with different concentrations of either cobalt or nickel. The pure and derivative materials are characterised using X-ray powder diffraction, Fourier transform IR, differential thermal analysis, and nitrogen adsorption. Due to their higher degree of hydration, the cobalt atoms are more sorbed by (α-TiP), where they enter into the cavities (containing the water molecules) between the layers of titanium phosphate. It is found that this process can induce small expanding of the interlayer spacing in the C direction and losing the crystallinity in the other directions. For the nickel, after sorption of more than 20%, an atomic layer may be formed preventing (α-TiP) from accommodating any more nickel ions in its framework, this is displayed by the appearance of diffraction peaks related to unsorbed nickel. The DTA curves indicate that more crystalline α-TiP materials have higher transition temperature. The nitrogen adsorption isotherms give an indication that when the cobalt atoms are sorbed by α-TiP, the latter is transformed from microporous to mesoporous material while it keeps its pore uniformity in the case of nickel. α titanium phosphate (dpeaa)DE-He213 cobalt (dpeaa)DE-He213 nickel (dpeaa)DE-He213 atoms (dpeaa)DE-He213 sorption (dpeaa)DE-He213 DTA curves (dpeaa)DE-He213 isotherms (dpeaa)DE-He213 texture (dpeaa)DE-He213 Enthalten in Powder metallurgy and metal ceramics Dordrecht [u.a.] : Springer Science + Business Media B.V, 1962 51(2012), 1-2 vom: Mai, Seite 121-127 (DE-627)325570272 (DE-600)2037317-X 1573-9066 nnns volume:51 year:2012 number:1-2 month:05 pages:121-127 https://dx.doi.org/10.1007/s11106-012-9406-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.00 ASE AR 51 2012 1-2 05 121-127 |
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Enthalten in Powder metallurgy and metal ceramics 51(2012), 1-2 vom: Mai, Seite 121-127 volume:51 year:2012 number:1-2 month:05 pages:121-127 |
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The solid obtained has been treated, in solid state with different concentrations of either cobalt or nickel. The pure and derivative materials are characterised using X-ray powder diffraction, Fourier transform IR, differential thermal analysis, and nitrogen adsorption. Due to their higher degree of hydration, the cobalt atoms are more sorbed by (α-TiP), where they enter into the cavities (containing the water molecules) between the layers of titanium phosphate. It is found that this process can induce small expanding of the interlayer spacing in the C direction and losing the crystallinity in the other directions. For the nickel, after sorption of more than 20%, an atomic layer may be formed preventing (α-TiP) from accommodating any more nickel ions in its framework, this is displayed by the appearance of diffraction peaks related to unsorbed nickel. The DTA curves indicate that more crystalline α-TiP materials have higher transition temperature. 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Kassem, M. |
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Kassem, M. ddc 670 bkl 51.00 misc α titanium phosphate misc cobalt misc nickel misc atoms misc sorption misc DTA curves misc isotherms misc texture Influence of cobalt and nickel sorption on the texture of crystalline α-titanium phosphate |
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670 ASE 51.00 bkl Influence of cobalt and nickel sorption on the texture of crystalline α-titanium phosphate α titanium phosphate (dpeaa)DE-He213 cobalt (dpeaa)DE-He213 nickel (dpeaa)DE-He213 atoms (dpeaa)DE-He213 sorption (dpeaa)DE-He213 DTA curves (dpeaa)DE-He213 isotherms (dpeaa)DE-He213 texture (dpeaa)DE-He213 |
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ddc 670 bkl 51.00 misc α titanium phosphate misc cobalt misc nickel misc atoms misc sorption misc DTA curves misc isotherms misc texture |
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Influence of cobalt and nickel sorption on the texture of crystalline α-titanium phosphate |
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Influence of cobalt and nickel sorption on the texture of crystalline α-titanium phosphate |
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influence of cobalt and nickel sorption on the texture of crystalline α-titanium phosphate |
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Influence of cobalt and nickel sorption on the texture of crystalline α-titanium phosphate |
abstract |
Crystalline titanium phosphate α-Ti($ HPO_{4} $)2 ⋅ $ H_{2} $O (α-TiP) has been prepared by reaction between phosphoric acid solution and titanium chloride in the temperature range 60–80 °C. The solid obtained has been treated, in solid state with different concentrations of either cobalt or nickel. The pure and derivative materials are characterised using X-ray powder diffraction, Fourier transform IR, differential thermal analysis, and nitrogen adsorption. Due to their higher degree of hydration, the cobalt atoms are more sorbed by (α-TiP), where they enter into the cavities (containing the water molecules) between the layers of titanium phosphate. It is found that this process can induce small expanding of the interlayer spacing in the C direction and losing the crystallinity in the other directions. For the nickel, after sorption of more than 20%, an atomic layer may be formed preventing (α-TiP) from accommodating any more nickel ions in its framework, this is displayed by the appearance of diffraction peaks related to unsorbed nickel. The DTA curves indicate that more crystalline α-TiP materials have higher transition temperature. The nitrogen adsorption isotherms give an indication that when the cobalt atoms are sorbed by α-TiP, the latter is transformed from microporous to mesoporous material while it keeps its pore uniformity in the case of nickel. |
abstractGer |
Crystalline titanium phosphate α-Ti($ HPO_{4} $)2 ⋅ $ H_{2} $O (α-TiP) has been prepared by reaction between phosphoric acid solution and titanium chloride in the temperature range 60–80 °C. The solid obtained has been treated, in solid state with different concentrations of either cobalt or nickel. The pure and derivative materials are characterised using X-ray powder diffraction, Fourier transform IR, differential thermal analysis, and nitrogen adsorption. Due to their higher degree of hydration, the cobalt atoms are more sorbed by (α-TiP), where they enter into the cavities (containing the water molecules) between the layers of titanium phosphate. It is found that this process can induce small expanding of the interlayer spacing in the C direction and losing the crystallinity in the other directions. For the nickel, after sorption of more than 20%, an atomic layer may be formed preventing (α-TiP) from accommodating any more nickel ions in its framework, this is displayed by the appearance of diffraction peaks related to unsorbed nickel. The DTA curves indicate that more crystalline α-TiP materials have higher transition temperature. The nitrogen adsorption isotherms give an indication that when the cobalt atoms are sorbed by α-TiP, the latter is transformed from microporous to mesoporous material while it keeps its pore uniformity in the case of nickel. |
abstract_unstemmed |
Crystalline titanium phosphate α-Ti($ HPO_{4} $)2 ⋅ $ H_{2} $O (α-TiP) has been prepared by reaction between phosphoric acid solution and titanium chloride in the temperature range 60–80 °C. The solid obtained has been treated, in solid state with different concentrations of either cobalt or nickel. The pure and derivative materials are characterised using X-ray powder diffraction, Fourier transform IR, differential thermal analysis, and nitrogen adsorption. Due to their higher degree of hydration, the cobalt atoms are more sorbed by (α-TiP), where they enter into the cavities (containing the water molecules) between the layers of titanium phosphate. It is found that this process can induce small expanding of the interlayer spacing in the C direction and losing the crystallinity in the other directions. For the nickel, after sorption of more than 20%, an atomic layer may be formed preventing (α-TiP) from accommodating any more nickel ions in its framework, this is displayed by the appearance of diffraction peaks related to unsorbed nickel. The DTA curves indicate that more crystalline α-TiP materials have higher transition temperature. The nitrogen adsorption isotherms give an indication that when the cobalt atoms are sorbed by α-TiP, the latter is transformed from microporous to mesoporous material while it keeps its pore uniformity in the case of nickel. |
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container_issue |
1-2 |
title_short |
Influence of cobalt and nickel sorption on the texture of crystalline α-titanium phosphate |
url |
https://dx.doi.org/10.1007/s11106-012-9406-5 |
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up_date |
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|
score |
7.3996468 |