Electrochemical behavior of nanocrystalline Ni–P alloys containing tin and tungsten

Abstract Autocatalytic ternary Ni-Sn-P, Ni-W-P and quaternary Ni-W-Sn-P films were prepared using an alkaline bath. Plain Ni-P films were also prepared for comparison. Corrosion resistance of the films was evaluated in 3.5% sodium chloride solution in non-deaerated condition by potentiodynamic polar...
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Autor*in:	Balaraju, J. N. [verfasserIn] Ezhil Selvi, V. [verfasserIn] Rajam, K. S. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2010

Schlagwörter:	Sodium Chloride Solution Immersion Test Electroless Nickel Coat Ings Deaerated Condition

Übergeordnetes Werk:	Enthalten in: Protection of metals - Moscow : MAIK Nauka/Interperiodica Publ., 2000, 46(2010), 6 vom: Nov., Seite 686-691
Übergeordnetes Werk:	volume:46 ; year:2010 ; number:6 ; month:11 ; pages:686-691

Links:	Volltext

DOI / URN:	10.1134/S2070205110060109

Katalog-ID:	SPR016845552

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520			\|a Abstract Autocatalytic ternary Ni-Sn-P, Ni-W-P and quaternary Ni-W-Sn-P films were prepared using an alkaline bath. Plain Ni-P films were also prepared for comparison. Corrosion resistance of the films was evaluated in 3.5% sodium chloride solution in non-deaerated condition by potentiodynamic polarization and electrochemical impedance spectroscopy methods. Deposits were also immersed in 3.5% sodium chloride solution for 7 days. All the coatings attained stable equilibrium potential within 30 minutes in NaCl medium. Lower corrosion current density values were obtained for ternary Ni-Sn-P coatings compared to the plain Ni-P coatings. Ternary Ni-W-P and quaternary Ni-W-Sn-P alloys did not show improved corrosion resistance compared to the ternary Ni-Sn-P coatings. Similar behavior of these coatings was further confirmed by the electrochemical impedance studies. After the potentiodynamic polarization test deposits were examined by scanning electron microscope. It was found that more corrosion occurred for the quaternary deposit compared to other deposits. Energy dispersive analysis of X-ray results indicated that more amount of Fe present on NiWP and NiWSnP coated samples. Similar behavior was confirmed from the optical images of the surfaces obtained for the deposits after the immersion test. The article is published in the original.
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allfields	10.1134/S2070205110060109 doi (DE-627)SPR016845552 (SPR)S2070205110060109-e DE-627 ger DE-627 rakwb eng 670 ASE 52.78 bkl Balaraju, J. N. verfasserin aut Electrochemical behavior of nanocrystalline Ni–P alloys containing tin and tungsten 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Autocatalytic ternary Ni-Sn-P, Ni-W-P and quaternary Ni-W-Sn-P films were prepared using an alkaline bath. Plain Ni-P films were also prepared for comparison. Corrosion resistance of the films was evaluated in 3.5% sodium chloride solution in non-deaerated condition by potentiodynamic polarization and electrochemical impedance spectroscopy methods. Deposits were also immersed in 3.5% sodium chloride solution for 7 days. All the coatings attained stable equilibrium potential within 30 minutes in NaCl medium. Lower corrosion current density values were obtained for ternary Ni-Sn-P coatings compared to the plain Ni-P coatings. Ternary Ni-W-P and quaternary Ni-W-Sn-P alloys did not show improved corrosion resistance compared to the ternary Ni-Sn-P coatings. Similar behavior of these coatings was further confirmed by the electrochemical impedance studies. After the potentiodynamic polarization test deposits were examined by scanning electron microscope. It was found that more corrosion occurred for the quaternary deposit compared to other deposits. Energy dispersive analysis of X-ray results indicated that more amount of Fe present on NiWP and NiWSnP coated samples. Similar behavior was confirmed from the optical images of the surfaces obtained for the deposits after the immersion test. The article is published in the original. Sodium Chloride Solution (dpeaa)DE-He213 Immersion Test (dpeaa)DE-He213 Electroless Nickel (dpeaa)DE-He213 Coat Ings (dpeaa)DE-He213 Deaerated Condition (dpeaa)DE-He213 Ezhil Selvi, V. verfasserin aut Rajam, K. S. verfasserin aut Enthalten in Protection of metals Moscow : MAIK Nauka/Interperiodica Publ., 2000 46(2010), 6 vom: Nov., Seite 686-691 (DE-627)334712300 (DE-600)2058128-2 1608-327X nnns volume:46 year:2010 number:6 month:11 pages:686-691 https://dx.doi.org/10.1134/S2070205110060109 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 52.78 ASE AR 46 2010 6 11 686-691
spelling	10.1134/S2070205110060109 doi (DE-627)SPR016845552 (SPR)S2070205110060109-e DE-627 ger DE-627 rakwb eng 670 ASE 52.78 bkl Balaraju, J. N. verfasserin aut Electrochemical behavior of nanocrystalline Ni–P alloys containing tin and tungsten 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Autocatalytic ternary Ni-Sn-P, Ni-W-P and quaternary Ni-W-Sn-P films were prepared using an alkaline bath. Plain Ni-P films were also prepared for comparison. Corrosion resistance of the films was evaluated in 3.5% sodium chloride solution in non-deaerated condition by potentiodynamic polarization and electrochemical impedance spectroscopy methods. Deposits were also immersed in 3.5% sodium chloride solution for 7 days. All the coatings attained stable equilibrium potential within 30 minutes in NaCl medium. Lower corrosion current density values were obtained for ternary Ni-Sn-P coatings compared to the plain Ni-P coatings. Ternary Ni-W-P and quaternary Ni-W-Sn-P alloys did not show improved corrosion resistance compared to the ternary Ni-Sn-P coatings. Similar behavior of these coatings was further confirmed by the electrochemical impedance studies. After the potentiodynamic polarization test deposits were examined by scanning electron microscope. It was found that more corrosion occurred for the quaternary deposit compared to other deposits. Energy dispersive analysis of X-ray results indicated that more amount of Fe present on NiWP and NiWSnP coated samples. Similar behavior was confirmed from the optical images of the surfaces obtained for the deposits after the immersion test. The article is published in the original. Sodium Chloride Solution (dpeaa)DE-He213 Immersion Test (dpeaa)DE-He213 Electroless Nickel (dpeaa)DE-He213 Coat Ings (dpeaa)DE-He213 Deaerated Condition (dpeaa)DE-He213 Ezhil Selvi, V. verfasserin aut Rajam, K. S. verfasserin aut Enthalten in Protection of metals Moscow : MAIK Nauka/Interperiodica Publ., 2000 46(2010), 6 vom: Nov., Seite 686-691 (DE-627)334712300 (DE-600)2058128-2 1608-327X nnns volume:46 year:2010 number:6 month:11 pages:686-691 https://dx.doi.org/10.1134/S2070205110060109 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 52.78 ASE AR 46 2010 6 11 686-691
allfields_unstemmed	10.1134/S2070205110060109 doi (DE-627)SPR016845552 (SPR)S2070205110060109-e DE-627 ger DE-627 rakwb eng 670 ASE 52.78 bkl Balaraju, J. N. verfasserin aut Electrochemical behavior of nanocrystalline Ni–P alloys containing tin and tungsten 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Autocatalytic ternary Ni-Sn-P, Ni-W-P and quaternary Ni-W-Sn-P films were prepared using an alkaline bath. Plain Ni-P films were also prepared for comparison. Corrosion resistance of the films was evaluated in 3.5% sodium chloride solution in non-deaerated condition by potentiodynamic polarization and electrochemical impedance spectroscopy methods. Deposits were also immersed in 3.5% sodium chloride solution for 7 days. All the coatings attained stable equilibrium potential within 30 minutes in NaCl medium. Lower corrosion current density values were obtained for ternary Ni-Sn-P coatings compared to the plain Ni-P coatings. Ternary Ni-W-P and quaternary Ni-W-Sn-P alloys did not show improved corrosion resistance compared to the ternary Ni-Sn-P coatings. Similar behavior of these coatings was further confirmed by the electrochemical impedance studies. After the potentiodynamic polarization test deposits were examined by scanning electron microscope. It was found that more corrosion occurred for the quaternary deposit compared to other deposits. Energy dispersive analysis of X-ray results indicated that more amount of Fe present on NiWP and NiWSnP coated samples. Similar behavior was confirmed from the optical images of the surfaces obtained for the deposits after the immersion test. The article is published in the original. Sodium Chloride Solution (dpeaa)DE-He213 Immersion Test (dpeaa)DE-He213 Electroless Nickel (dpeaa)DE-He213 Coat Ings (dpeaa)DE-He213 Deaerated Condition (dpeaa)DE-He213 Ezhil Selvi, V. verfasserin aut Rajam, K. S. verfasserin aut Enthalten in Protection of metals Moscow : MAIK Nauka/Interperiodica Publ., 2000 46(2010), 6 vom: Nov., Seite 686-691 (DE-627)334712300 (DE-600)2058128-2 1608-327X nnns volume:46 year:2010 number:6 month:11 pages:686-691 https://dx.doi.org/10.1134/S2070205110060109 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 52.78 ASE AR 46 2010 6 11 686-691
allfieldsGer	10.1134/S2070205110060109 doi (DE-627)SPR016845552 (SPR)S2070205110060109-e DE-627 ger DE-627 rakwb eng 670 ASE 52.78 bkl Balaraju, J. N. verfasserin aut Electrochemical behavior of nanocrystalline Ni–P alloys containing tin and tungsten 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Autocatalytic ternary Ni-Sn-P, Ni-W-P and quaternary Ni-W-Sn-P films were prepared using an alkaline bath. Plain Ni-P films were also prepared for comparison. Corrosion resistance of the films was evaluated in 3.5% sodium chloride solution in non-deaerated condition by potentiodynamic polarization and electrochemical impedance spectroscopy methods. Deposits were also immersed in 3.5% sodium chloride solution for 7 days. All the coatings attained stable equilibrium potential within 30 minutes in NaCl medium. Lower corrosion current density values were obtained for ternary Ni-Sn-P coatings compared to the plain Ni-P coatings. Ternary Ni-W-P and quaternary Ni-W-Sn-P alloys did not show improved corrosion resistance compared to the ternary Ni-Sn-P coatings. Similar behavior of these coatings was further confirmed by the electrochemical impedance studies. After the potentiodynamic polarization test deposits were examined by scanning electron microscope. It was found that more corrosion occurred for the quaternary deposit compared to other deposits. Energy dispersive analysis of X-ray results indicated that more amount of Fe present on NiWP and NiWSnP coated samples. Similar behavior was confirmed from the optical images of the surfaces obtained for the deposits after the immersion test. The article is published in the original. Sodium Chloride Solution (dpeaa)DE-He213 Immersion Test (dpeaa)DE-He213 Electroless Nickel (dpeaa)DE-He213 Coat Ings (dpeaa)DE-He213 Deaerated Condition (dpeaa)DE-He213 Ezhil Selvi, V. verfasserin aut Rajam, K. S. verfasserin aut Enthalten in Protection of metals Moscow : MAIK Nauka/Interperiodica Publ., 2000 46(2010), 6 vom: Nov., Seite 686-691 (DE-627)334712300 (DE-600)2058128-2 1608-327X nnns volume:46 year:2010 number:6 month:11 pages:686-691 https://dx.doi.org/10.1134/S2070205110060109 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 52.78 ASE AR 46 2010 6 11 686-691
allfieldsSound	10.1134/S2070205110060109 doi (DE-627)SPR016845552 (SPR)S2070205110060109-e DE-627 ger DE-627 rakwb eng 670 ASE 52.78 bkl Balaraju, J. N. verfasserin aut Electrochemical behavior of nanocrystalline Ni–P alloys containing tin and tungsten 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Autocatalytic ternary Ni-Sn-P, Ni-W-P and quaternary Ni-W-Sn-P films were prepared using an alkaline bath. Plain Ni-P films were also prepared for comparison. Corrosion resistance of the films was evaluated in 3.5% sodium chloride solution in non-deaerated condition by potentiodynamic polarization and electrochemical impedance spectroscopy methods. Deposits were also immersed in 3.5% sodium chloride solution for 7 days. All the coatings attained stable equilibrium potential within 30 minutes in NaCl medium. Lower corrosion current density values were obtained for ternary Ni-Sn-P coatings compared to the plain Ni-P coatings. Ternary Ni-W-P and quaternary Ni-W-Sn-P alloys did not show improved corrosion resistance compared to the ternary Ni-Sn-P coatings. Similar behavior of these coatings was further confirmed by the electrochemical impedance studies. After the potentiodynamic polarization test deposits were examined by scanning electron microscope. It was found that more corrosion occurred for the quaternary deposit compared to other deposits. Energy dispersive analysis of X-ray results indicated that more amount of Fe present on NiWP and NiWSnP coated samples. Similar behavior was confirmed from the optical images of the surfaces obtained for the deposits after the immersion test. The article is published in the original. Sodium Chloride Solution (dpeaa)DE-He213 Immersion Test (dpeaa)DE-He213 Electroless Nickel (dpeaa)DE-He213 Coat Ings (dpeaa)DE-He213 Deaerated Condition (dpeaa)DE-He213 Ezhil Selvi, V. verfasserin aut Rajam, K. S. verfasserin aut Enthalten in Protection of metals Moscow : MAIK Nauka/Interperiodica Publ., 2000 46(2010), 6 vom: Nov., Seite 686-691 (DE-627)334712300 (DE-600)2058128-2 1608-327X nnns volume:46 year:2010 number:6 month:11 pages:686-691 https://dx.doi.org/10.1134/S2070205110060109 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 52.78 ASE AR 46 2010 6 11 686-691
language	English
source	Enthalten in Protection of metals 46(2010), 6 vom: Nov., Seite 686-691 volume:46 year:2010 number:6 month:11 pages:686-691
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author	Balaraju, J. N.
spellingShingle	Balaraju, J. N. ddc 670 bkl 52.78 misc Sodium Chloride Solution misc Immersion Test misc Electroless Nickel misc Coat Ings misc Deaerated Condition Electrochemical behavior of nanocrystalline Ni–P alloys containing tin and tungsten
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topic_title	670 ASE 52.78 bkl Electrochemical behavior of nanocrystalline Ni–P alloys containing tin and tungsten Sodium Chloride Solution (dpeaa)DE-He213 Immersion Test (dpeaa)DE-He213 Electroless Nickel (dpeaa)DE-He213 Coat Ings (dpeaa)DE-He213 Deaerated Condition (dpeaa)DE-He213
topic	ddc 670 bkl 52.78 misc Sodium Chloride Solution misc Immersion Test misc Electroless Nickel misc Coat Ings misc Deaerated Condition
topic_unstemmed	ddc 670 bkl 52.78 misc Sodium Chloride Solution misc Immersion Test misc Electroless Nickel misc Coat Ings misc Deaerated Condition
topic_browse	ddc 670 bkl 52.78 misc Sodium Chloride Solution misc Immersion Test misc Electroless Nickel misc Coat Ings misc Deaerated Condition
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title	Electrochemical behavior of nanocrystalline Ni–P alloys containing tin and tungsten
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title_full	Electrochemical behavior of nanocrystalline Ni–P alloys containing tin and tungsten
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title_sort	electrochemical behavior of nanocrystalline ni–p alloys containing tin and tungsten
title_auth	Electrochemical behavior of nanocrystalline Ni–P alloys containing tin and tungsten
abstract	Abstract Autocatalytic ternary Ni-Sn-P, Ni-W-P and quaternary Ni-W-Sn-P films were prepared using an alkaline bath. Plain Ni-P films were also prepared for comparison. Corrosion resistance of the films was evaluated in 3.5% sodium chloride solution in non-deaerated condition by potentiodynamic polarization and electrochemical impedance spectroscopy methods. Deposits were also immersed in 3.5% sodium chloride solution for 7 days. All the coatings attained stable equilibrium potential within 30 minutes in NaCl medium. Lower corrosion current density values were obtained for ternary Ni-Sn-P coatings compared to the plain Ni-P coatings. Ternary Ni-W-P and quaternary Ni-W-Sn-P alloys did not show improved corrosion resistance compared to the ternary Ni-Sn-P coatings. Similar behavior of these coatings was further confirmed by the electrochemical impedance studies. After the potentiodynamic polarization test deposits were examined by scanning electron microscope. It was found that more corrosion occurred for the quaternary deposit compared to other deposits. Energy dispersive analysis of X-ray results indicated that more amount of Fe present on NiWP and NiWSnP coated samples. Similar behavior was confirmed from the optical images of the surfaces obtained for the deposits after the immersion test. The article is published in the original.
abstractGer	Abstract Autocatalytic ternary Ni-Sn-P, Ni-W-P and quaternary Ni-W-Sn-P films were prepared using an alkaline bath. Plain Ni-P films were also prepared for comparison. Corrosion resistance of the films was evaluated in 3.5% sodium chloride solution in non-deaerated condition by potentiodynamic polarization and electrochemical impedance spectroscopy methods. Deposits were also immersed in 3.5% sodium chloride solution for 7 days. All the coatings attained stable equilibrium potential within 30 minutes in NaCl medium. Lower corrosion current density values were obtained for ternary Ni-Sn-P coatings compared to the plain Ni-P coatings. Ternary Ni-W-P and quaternary Ni-W-Sn-P alloys did not show improved corrosion resistance compared to the ternary Ni-Sn-P coatings. Similar behavior of these coatings was further confirmed by the electrochemical impedance studies. After the potentiodynamic polarization test deposits were examined by scanning electron microscope. It was found that more corrosion occurred for the quaternary deposit compared to other deposits. Energy dispersive analysis of X-ray results indicated that more amount of Fe present on NiWP and NiWSnP coated samples. Similar behavior was confirmed from the optical images of the surfaces obtained for the deposits after the immersion test. The article is published in the original.
abstract_unstemmed	Abstract Autocatalytic ternary Ni-Sn-P, Ni-W-P and quaternary Ni-W-Sn-P films were prepared using an alkaline bath. Plain Ni-P films were also prepared for comparison. Corrosion resistance of the films was evaluated in 3.5% sodium chloride solution in non-deaerated condition by potentiodynamic polarization and electrochemical impedance spectroscopy methods. Deposits were also immersed in 3.5% sodium chloride solution for 7 days. All the coatings attained stable equilibrium potential within 30 minutes in NaCl medium. Lower corrosion current density values were obtained for ternary Ni-Sn-P coatings compared to the plain Ni-P coatings. Ternary Ni-W-P and quaternary Ni-W-Sn-P alloys did not show improved corrosion resistance compared to the ternary Ni-Sn-P coatings. Similar behavior of these coatings was further confirmed by the electrochemical impedance studies. After the potentiodynamic polarization test deposits were examined by scanning electron microscope. It was found that more corrosion occurred for the quaternary deposit compared to other deposits. Energy dispersive analysis of X-ray results indicated that more amount of Fe present on NiWP and NiWSnP coated samples. Similar behavior was confirmed from the optical images of the surfaces obtained for the deposits after the immersion test. The article is published in the original.
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title_short	Electrochemical behavior of nanocrystalline Ni–P alloys containing tin and tungsten
url	https://dx.doi.org/10.1134/S2070205110060109
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