Novel F–$ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts for oxidative dehydrogenation of propane

Abstract The $ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts promoted by fluoride anion and prepared with different F adding sequences were investigated. The samples were characterized by X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, scanning electron microscopy (SEM), X-ray powd...
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Autor*in:	Liu, Yuefeng [verfasserIn] Jiang, Chengfa [verfasserIn] Chu, Wei [verfasserIn] Sun, Wenjing [verfasserIn] Xie, Zaiku [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2010

Schlagwörter:	Vanadia catalyst Fluoride promoter Impregnation sequence Isolation of active sites Oxidative dehydrogenation of propane

Übergeordnetes Werk:	Enthalten in: Reaction kinetics and catalysis letters - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974, 101(2010), 1 vom: 04. Juni, Seite 141-151
Übergeordnetes Werk:	volume:101 ; year:2010 ; number:1 ; day:04 ; month:06 ; pages:141-151

Links:	Volltext

DOI / URN:	10.1007/s11144-010-0207-x

Katalog-ID:	SPR017069459

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520			\|a Abstract The $ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts promoted by fluoride anion and prepared with different F adding sequences were investigated. The samples were characterized by X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, scanning electron microscopy (SEM), X-ray powder diffraction (XRD), temperature-programmed reduction (TPR), oxygen temperature-programmed desorption ($ O_{2} $-TPD) techniques and oxidative dehydrogenation reaction measurements. The results indicated that the fluoride impregnation sequence had a significant effect on the structure and selectivity of propene. Co-impregnation prepared VOF–C catalyst showed a better performance in the ODP reaction. The $ C_{3} %$ H_{6} $ selectivity was 74.9% at 480 °C, compared to 60.9% of V–Si–O sample without promotion. The propane conversion and propene yield were also better. The fluoride addition enhanced the mobility of oxygen in the catalyst.
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allfields	10.1007/s11144-010-0207-x doi (DE-627)SPR017069459 (SPR)s11144-010-0207-x-e DE-627 ger DE-627 rakwb eng 540 ASE 35.13 bkl 35.17 bkl Liu, Yuefeng verfasserin aut Novel F–$ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts for oxidative dehydrogenation of propane 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The $ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts promoted by fluoride anion and prepared with different F adding sequences were investigated. The samples were characterized by X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, scanning electron microscopy (SEM), X-ray powder diffraction (XRD), temperature-programmed reduction (TPR), oxygen temperature-programmed desorption ($ O_{2} $-TPD) techniques and oxidative dehydrogenation reaction measurements. The results indicated that the fluoride impregnation sequence had a significant effect on the structure and selectivity of propene. Co-impregnation prepared VOF–C catalyst showed a better performance in the ODP reaction. The $ C_{3} %$ H_{6} $ selectivity was 74.9% at 480 °C, compared to 60.9% of V–Si–O sample without promotion. The propane conversion and propene yield were also better. The fluoride addition enhanced the mobility of oxygen in the catalyst. Vanadia catalyst (dpeaa)DE-He213 Fluoride promoter (dpeaa)DE-He213 Impregnation sequence (dpeaa)DE-He213 Isolation of active sites (dpeaa)DE-He213 Oxidative dehydrogenation of propane (dpeaa)DE-He213 Jiang, Chengfa verfasserin aut Chu, Wei verfasserin aut Sun, Wenjing verfasserin aut Xie, Zaiku verfasserin aut Enthalten in Reaction kinetics and catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974 101(2010), 1 vom: 04. Juni, Seite 141-151 (DE-627)320588882 (DE-600)2018650-2 1588-2837 nnns volume:101 year:2010 number:1 day:04 month:06 pages:141-151 https://dx.doi.org/10.1007/s11144-010-0207-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.13 ASE 35.17 ASE AR 101 2010 1 04 06 141-151
spelling	10.1007/s11144-010-0207-x doi (DE-627)SPR017069459 (SPR)s11144-010-0207-x-e DE-627 ger DE-627 rakwb eng 540 ASE 35.13 bkl 35.17 bkl Liu, Yuefeng verfasserin aut Novel F–$ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts for oxidative dehydrogenation of propane 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The $ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts promoted by fluoride anion and prepared with different F adding sequences were investigated. The samples were characterized by X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, scanning electron microscopy (SEM), X-ray powder diffraction (XRD), temperature-programmed reduction (TPR), oxygen temperature-programmed desorption ($ O_{2} $-TPD) techniques and oxidative dehydrogenation reaction measurements. The results indicated that the fluoride impregnation sequence had a significant effect on the structure and selectivity of propene. Co-impregnation prepared VOF–C catalyst showed a better performance in the ODP reaction. The $ C_{3} %$ H_{6} $ selectivity was 74.9% at 480 °C, compared to 60.9% of V–Si–O sample without promotion. The propane conversion and propene yield were also better. The fluoride addition enhanced the mobility of oxygen in the catalyst. Vanadia catalyst (dpeaa)DE-He213 Fluoride promoter (dpeaa)DE-He213 Impregnation sequence (dpeaa)DE-He213 Isolation of active sites (dpeaa)DE-He213 Oxidative dehydrogenation of propane (dpeaa)DE-He213 Jiang, Chengfa verfasserin aut Chu, Wei verfasserin aut Sun, Wenjing verfasserin aut Xie, Zaiku verfasserin aut Enthalten in Reaction kinetics and catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974 101(2010), 1 vom: 04. Juni, Seite 141-151 (DE-627)320588882 (DE-600)2018650-2 1588-2837 nnns volume:101 year:2010 number:1 day:04 month:06 pages:141-151 https://dx.doi.org/10.1007/s11144-010-0207-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.13 ASE 35.17 ASE AR 101 2010 1 04 06 141-151
allfields_unstemmed	10.1007/s11144-010-0207-x doi (DE-627)SPR017069459 (SPR)s11144-010-0207-x-e DE-627 ger DE-627 rakwb eng 540 ASE 35.13 bkl 35.17 bkl Liu, Yuefeng verfasserin aut Novel F–$ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts for oxidative dehydrogenation of propane 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The $ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts promoted by fluoride anion and prepared with different F adding sequences were investigated. The samples were characterized by X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, scanning electron microscopy (SEM), X-ray powder diffraction (XRD), temperature-programmed reduction (TPR), oxygen temperature-programmed desorption ($ O_{2} $-TPD) techniques and oxidative dehydrogenation reaction measurements. The results indicated that the fluoride impregnation sequence had a significant effect on the structure and selectivity of propene. Co-impregnation prepared VOF–C catalyst showed a better performance in the ODP reaction. The $ C_{3} %$ H_{6} $ selectivity was 74.9% at 480 °C, compared to 60.9% of V–Si–O sample without promotion. The propane conversion and propene yield were also better. The fluoride addition enhanced the mobility of oxygen in the catalyst. Vanadia catalyst (dpeaa)DE-He213 Fluoride promoter (dpeaa)DE-He213 Impregnation sequence (dpeaa)DE-He213 Isolation of active sites (dpeaa)DE-He213 Oxidative dehydrogenation of propane (dpeaa)DE-He213 Jiang, Chengfa verfasserin aut Chu, Wei verfasserin aut Sun, Wenjing verfasserin aut Xie, Zaiku verfasserin aut Enthalten in Reaction kinetics and catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974 101(2010), 1 vom: 04. Juni, Seite 141-151 (DE-627)320588882 (DE-600)2018650-2 1588-2837 nnns volume:101 year:2010 number:1 day:04 month:06 pages:141-151 https://dx.doi.org/10.1007/s11144-010-0207-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.13 ASE 35.17 ASE AR 101 2010 1 04 06 141-151
allfieldsGer	10.1007/s11144-010-0207-x doi (DE-627)SPR017069459 (SPR)s11144-010-0207-x-e DE-627 ger DE-627 rakwb eng 540 ASE 35.13 bkl 35.17 bkl Liu, Yuefeng verfasserin aut Novel F–$ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts for oxidative dehydrogenation of propane 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The $ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts promoted by fluoride anion and prepared with different F adding sequences were investigated. The samples were characterized by X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, scanning electron microscopy (SEM), X-ray powder diffraction (XRD), temperature-programmed reduction (TPR), oxygen temperature-programmed desorption ($ O_{2} $-TPD) techniques and oxidative dehydrogenation reaction measurements. The results indicated that the fluoride impregnation sequence had a significant effect on the structure and selectivity of propene. Co-impregnation prepared VOF–C catalyst showed a better performance in the ODP reaction. The $ C_{3} %$ H_{6} $ selectivity was 74.9% at 480 °C, compared to 60.9% of V–Si–O sample without promotion. The propane conversion and propene yield were also better. The fluoride addition enhanced the mobility of oxygen in the catalyst. Vanadia catalyst (dpeaa)DE-He213 Fluoride promoter (dpeaa)DE-He213 Impregnation sequence (dpeaa)DE-He213 Isolation of active sites (dpeaa)DE-He213 Oxidative dehydrogenation of propane (dpeaa)DE-He213 Jiang, Chengfa verfasserin aut Chu, Wei verfasserin aut Sun, Wenjing verfasserin aut Xie, Zaiku verfasserin aut Enthalten in Reaction kinetics and catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974 101(2010), 1 vom: 04. Juni, Seite 141-151 (DE-627)320588882 (DE-600)2018650-2 1588-2837 nnns volume:101 year:2010 number:1 day:04 month:06 pages:141-151 https://dx.doi.org/10.1007/s11144-010-0207-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.13 ASE 35.17 ASE AR 101 2010 1 04 06 141-151
allfieldsSound	10.1007/s11144-010-0207-x doi (DE-627)SPR017069459 (SPR)s11144-010-0207-x-e DE-627 ger DE-627 rakwb eng 540 ASE 35.13 bkl 35.17 bkl Liu, Yuefeng verfasserin aut Novel F–$ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts for oxidative dehydrogenation of propane 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The $ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts promoted by fluoride anion and prepared with different F adding sequences were investigated. The samples were characterized by X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, scanning electron microscopy (SEM), X-ray powder diffraction (XRD), temperature-programmed reduction (TPR), oxygen temperature-programmed desorption ($ O_{2} $-TPD) techniques and oxidative dehydrogenation reaction measurements. The results indicated that the fluoride impregnation sequence had a significant effect on the structure and selectivity of propene. Co-impregnation prepared VOF–C catalyst showed a better performance in the ODP reaction. The $ C_{3} %$ H_{6} $ selectivity was 74.9% at 480 °C, compared to 60.9% of V–Si–O sample without promotion. The propane conversion and propene yield were also better. The fluoride addition enhanced the mobility of oxygen in the catalyst. Vanadia catalyst (dpeaa)DE-He213 Fluoride promoter (dpeaa)DE-He213 Impregnation sequence (dpeaa)DE-He213 Isolation of active sites (dpeaa)DE-He213 Oxidative dehydrogenation of propane (dpeaa)DE-He213 Jiang, Chengfa verfasserin aut Chu, Wei verfasserin aut Sun, Wenjing verfasserin aut Xie, Zaiku verfasserin aut Enthalten in Reaction kinetics and catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974 101(2010), 1 vom: 04. Juni, Seite 141-151 (DE-627)320588882 (DE-600)2018650-2 1588-2837 nnns volume:101 year:2010 number:1 day:04 month:06 pages:141-151 https://dx.doi.org/10.1007/s11144-010-0207-x lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.13 ASE 35.17 ASE AR 101 2010 1 04 06 141-151
language	English
source	Enthalten in Reaction kinetics and catalysis letters 101(2010), 1 vom: 04. Juni, Seite 141-151 volume:101 year:2010 number:1 day:04 month:06 pages:141-151
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topic_facet	Vanadia catalyst Fluoride promoter Impregnation sequence Isolation of active sites Oxidative dehydrogenation of propane
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The samples were characterized by X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, scanning electron microscopy (SEM), X-ray powder diffraction (XRD), temperature-programmed reduction (TPR), oxygen temperature-programmed desorption ($ O_{2} $-TPD) techniques and oxidative dehydrogenation reaction measurements. The results indicated that the fluoride impregnation sequence had a significant effect on the structure and selectivity of propene. Co-impregnation prepared VOF–C catalyst showed a better performance in the ODP reaction. The $ C_{3} %$ H_{6} $ selectivity was 74.9% at 480 °C, compared to 60.9% of V–Si–O sample without promotion. The propane conversion and propene yield were also better. 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author	Liu, Yuefeng
spellingShingle	Liu, Yuefeng ddc 540 bkl 35.13 bkl 35.17 misc Vanadia catalyst misc Fluoride promoter misc Impregnation sequence misc Isolation of active sites misc Oxidative dehydrogenation of propane Novel F–$ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts for oxidative dehydrogenation of propane
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topic_title	540 ASE 35.13 bkl 35.17 bkl Novel F–$ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts for oxidative dehydrogenation of propane Vanadia catalyst (dpeaa)DE-He213 Fluoride promoter (dpeaa)DE-He213 Impregnation sequence (dpeaa)DE-He213 Isolation of active sites (dpeaa)DE-He213 Oxidative dehydrogenation of propane (dpeaa)DE-He213
topic	ddc 540 bkl 35.13 bkl 35.17 misc Vanadia catalyst misc Fluoride promoter misc Impregnation sequence misc Isolation of active sites misc Oxidative dehydrogenation of propane
topic_unstemmed	ddc 540 bkl 35.13 bkl 35.17 misc Vanadia catalyst misc Fluoride promoter misc Impregnation sequence misc Isolation of active sites misc Oxidative dehydrogenation of propane
topic_browse	ddc 540 bkl 35.13 bkl 35.17 misc Vanadia catalyst misc Fluoride promoter misc Impregnation sequence misc Isolation of active sites misc Oxidative dehydrogenation of propane
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title	Novel F–$ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts for oxidative dehydrogenation of propane
ctrlnum	(DE-627)SPR017069459 (SPR)s11144-010-0207-x-e
title_full	Novel F–$ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts for oxidative dehydrogenation of propane
author_sort	Liu, Yuefeng
journal	Reaction kinetics and catalysis letters
journalStr	Reaction kinetics and catalysis letters
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author_browse	Liu, Yuefeng Jiang, Chengfa Chu, Wei Sun, Wenjing Xie, Zaiku
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class	540 ASE 35.13 bkl 35.17 bkl
format_se	Elektronische Aufsätze
author-letter	Liu, Yuefeng
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author2-role	verfasserin
title_sort	novel f–$ v_{2} %$ o_{5} $/$ sio_{2} $ catalysts for oxidative dehydrogenation of propane
title_auth	Novel F–$ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts for oxidative dehydrogenation of propane
abstract	Abstract The $ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts promoted by fluoride anion and prepared with different F adding sequences were investigated. The samples were characterized by X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, scanning electron microscopy (SEM), X-ray powder diffraction (XRD), temperature-programmed reduction (TPR), oxygen temperature-programmed desorption ($ O_{2} $-TPD) techniques and oxidative dehydrogenation reaction measurements. The results indicated that the fluoride impregnation sequence had a significant effect on the structure and selectivity of propene. Co-impregnation prepared VOF–C catalyst showed a better performance in the ODP reaction. The $ C_{3} %$ H_{6} $ selectivity was 74.9% at 480 °C, compared to 60.9% of V–Si–O sample without promotion. The propane conversion and propene yield were also better. The fluoride addition enhanced the mobility of oxygen in the catalyst.
abstractGer	Abstract The $ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts promoted by fluoride anion and prepared with different F adding sequences were investigated. The samples were characterized by X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, scanning electron microscopy (SEM), X-ray powder diffraction (XRD), temperature-programmed reduction (TPR), oxygen temperature-programmed desorption ($ O_{2} $-TPD) techniques and oxidative dehydrogenation reaction measurements. The results indicated that the fluoride impregnation sequence had a significant effect on the structure and selectivity of propene. Co-impregnation prepared VOF–C catalyst showed a better performance in the ODP reaction. The $ C_{3} %$ H_{6} $ selectivity was 74.9% at 480 °C, compared to 60.9% of V–Si–O sample without promotion. The propane conversion and propene yield were also better. The fluoride addition enhanced the mobility of oxygen in the catalyst.
abstract_unstemmed	Abstract The $ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts promoted by fluoride anion and prepared with different F adding sequences were investigated. The samples were characterized by X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, scanning electron microscopy (SEM), X-ray powder diffraction (XRD), temperature-programmed reduction (TPR), oxygen temperature-programmed desorption ($ O_{2} $-TPD) techniques and oxidative dehydrogenation reaction measurements. The results indicated that the fluoride impregnation sequence had a significant effect on the structure and selectivity of propene. Co-impregnation prepared VOF–C catalyst showed a better performance in the ODP reaction. The $ C_{3} %$ H_{6} $ selectivity was 74.9% at 480 °C, compared to 60.9% of V–Si–O sample without promotion. The propane conversion and propene yield were also better. The fluoride addition enhanced the mobility of oxygen in the catalyst.
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702
container_issue	1
title_short	Novel F–$ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts for oxidative dehydrogenation of propane
url	https://dx.doi.org/10.1007/s11144-010-0207-x
remote_bool	true
author2	Jiang, Chengfa Chu, Wei Sun, Wenjing Xie, Zaiku
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up_date	2024-07-04T02:05:58.703Z
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The samples were characterized by X-ray photoelectron spectroscopy (XPS), $ N_{2} $ adsorption–desorption, scanning electron microscopy (SEM), X-ray powder diffraction (XRD), temperature-programmed reduction (TPR), oxygen temperature-programmed desorption ($ O_{2} $-TPD) techniques and oxidative dehydrogenation reaction measurements. The results indicated that the fluoride impregnation sequence had a significant effect on the structure and selectivity of propene. Co-impregnation prepared VOF–C catalyst showed a better performance in the ODP reaction. The $ C_{3} %$ H_{6} $ selectivity was 74.9% at 480 °C, compared to 60.9% of V–Si–O sample without promotion. The propane conversion and propene yield were also better. 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Novel F–$ V_{2} %$ O_{5} $/$ SiO_{2} $ catalysts for oxidative dehydrogenation of propane

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