Optimization of laccase catalyzed degradation of reactive textile dyes in supercritical carbon dioxide medium by response surface methodology

Abstract In this work, the laccase catalyzed degradation of reactive textile dyes was studied in supercritical carbon dioxide media. A two level Box–Behnken factorial design with two factors and response surface methodology (RSM) were performed to investigate and optimize the effects of pressure and...
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Autor*in:	Cristóvão, Raquel O. [verfasserIn] Amaral, Priscilla F. F. [verfasserIn] Tavares, Ana P. M. [verfasserIn] Coelho, Maria Alice Z. [verfasserIn] Cammarota, Magali C. [verfasserIn] Loureiro, José M. [verfasserIn] Boaventura, Rui A. R. [verfasserIn] Macedo, Eugénia A. [verfasserIn] Pessoa, Fernando L. P. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2010

Schlagwörter:	Supercritical carbon dioxide Biocatalysis Optimization Reactive dyes Commercial laccase RSM

Übergeordnetes Werk:	Enthalten in: Reaction kinetics and catalysis letters - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974, 99(2010), 2 vom: 13. Jan., Seite 311-323
Übergeordnetes Werk:	volume:99 ; year:2010 ; number:2 ; day:13 ; month:01 ; pages:311-323

Links:	Volltext

DOI / URN:	10.1007/s11144-009-0139-5

Katalog-ID:	SPR017070317

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520			\|a Abstract In this work, the laccase catalyzed degradation of reactive textile dyes was studied in supercritical carbon dioxide media. A two level Box–Behnken factorial design with two factors and response surface methodology (RSM) were performed to investigate and optimize the effects of pressure and temperature on reactive red 239 (RR239), reactive yellow 15 (RY15) and reactive black 5 (RB5) dye degradations by commercial laccase in supercritical carbon dioxide media. Mathematical models were developed for each dye showing the effect of each factor and their interactions on color removal. Pressure and the interaction between temperature and pressure were the main factors affecting the decolorization. The optimum conditions for RB5 and RY15 were found to be high pressure values (>120 bar), whilst the temperature presented a minor effect on their degradation at these pressures. For RR239, both variables influenced the decolorization and the optimum conditions appear to be at low values of pressure and high values of temperature.
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spelling	10.1007/s11144-009-0139-5 doi (DE-627)SPR017070317 (SPR)s11144-009-0139-5-e DE-627 ger DE-627 rakwb eng 540 ASE 35.13 bkl 35.17 bkl Cristóvão, Raquel O. verfasserin aut Optimization of laccase catalyzed degradation of reactive textile dyes in supercritical carbon dioxide medium by response surface methodology 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In this work, the laccase catalyzed degradation of reactive textile dyes was studied in supercritical carbon dioxide media. A two level Box–Behnken factorial design with two factors and response surface methodology (RSM) were performed to investigate and optimize the effects of pressure and temperature on reactive red 239 (RR239), reactive yellow 15 (RY15) and reactive black 5 (RB5) dye degradations by commercial laccase in supercritical carbon dioxide media. Mathematical models were developed for each dye showing the effect of each factor and their interactions on color removal. Pressure and the interaction between temperature and pressure were the main factors affecting the decolorization. The optimum conditions for RB5 and RY15 were found to be high pressure values (>120 bar), whilst the temperature presented a minor effect on their degradation at these pressures. For RR239, both variables influenced the decolorization and the optimum conditions appear to be at low values of pressure and high values of temperature. Supercritical carbon dioxide (dpeaa)DE-He213 Biocatalysis (dpeaa)DE-He213 Optimization (dpeaa)DE-He213 Reactive dyes (dpeaa)DE-He213 Commercial laccase (dpeaa)DE-He213 RSM (dpeaa)DE-He213 Amaral, Priscilla F. F. verfasserin aut Tavares, Ana P. M. verfasserin aut Coelho, Maria Alice Z. verfasserin aut Cammarota, Magali C. verfasserin aut Loureiro, José M. verfasserin aut Boaventura, Rui A. R. verfasserin aut Macedo, Eugénia A. verfasserin aut Pessoa, Fernando L. P. verfasserin aut Enthalten in Reaction kinetics and catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974 99(2010), 2 vom: 13. Jan., Seite 311-323 (DE-627)320588882 (DE-600)2018650-2 1588-2837 nnns volume:99 year:2010 number:2 day:13 month:01 pages:311-323 https://dx.doi.org/10.1007/s11144-009-0139-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.13 ASE 35.17 ASE AR 99 2010 2 13 01 311-323
allfields_unstemmed	10.1007/s11144-009-0139-5 doi (DE-627)SPR017070317 (SPR)s11144-009-0139-5-e DE-627 ger DE-627 rakwb eng 540 ASE 35.13 bkl 35.17 bkl Cristóvão, Raquel O. verfasserin aut Optimization of laccase catalyzed degradation of reactive textile dyes in supercritical carbon dioxide medium by response surface methodology 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In this work, the laccase catalyzed degradation of reactive textile dyes was studied in supercritical carbon dioxide media. A two level Box–Behnken factorial design with two factors and response surface methodology (RSM) were performed to investigate and optimize the effects of pressure and temperature on reactive red 239 (RR239), reactive yellow 15 (RY15) and reactive black 5 (RB5) dye degradations by commercial laccase in supercritical carbon dioxide media. Mathematical models were developed for each dye showing the effect of each factor and their interactions on color removal. Pressure and the interaction between temperature and pressure were the main factors affecting the decolorization. The optimum conditions for RB5 and RY15 were found to be high pressure values (>120 bar), whilst the temperature presented a minor effect on their degradation at these pressures. For RR239, both variables influenced the decolorization and the optimum conditions appear to be at low values of pressure and high values of temperature. Supercritical carbon dioxide (dpeaa)DE-He213 Biocatalysis (dpeaa)DE-He213 Optimization (dpeaa)DE-He213 Reactive dyes (dpeaa)DE-He213 Commercial laccase (dpeaa)DE-He213 RSM (dpeaa)DE-He213 Amaral, Priscilla F. F. verfasserin aut Tavares, Ana P. M. verfasserin aut Coelho, Maria Alice Z. verfasserin aut Cammarota, Magali C. verfasserin aut Loureiro, José M. verfasserin aut Boaventura, Rui A. R. verfasserin aut Macedo, Eugénia A. verfasserin aut Pessoa, Fernando L. P. verfasserin aut Enthalten in Reaction kinetics and catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974 99(2010), 2 vom: 13. Jan., Seite 311-323 (DE-627)320588882 (DE-600)2018650-2 1588-2837 nnns volume:99 year:2010 number:2 day:13 month:01 pages:311-323 https://dx.doi.org/10.1007/s11144-009-0139-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.13 ASE 35.17 ASE AR 99 2010 2 13 01 311-323
allfieldsGer	10.1007/s11144-009-0139-5 doi (DE-627)SPR017070317 (SPR)s11144-009-0139-5-e DE-627 ger DE-627 rakwb eng 540 ASE 35.13 bkl 35.17 bkl Cristóvão, Raquel O. verfasserin aut Optimization of laccase catalyzed degradation of reactive textile dyes in supercritical carbon dioxide medium by response surface methodology 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In this work, the laccase catalyzed degradation of reactive textile dyes was studied in supercritical carbon dioxide media. A two level Box–Behnken factorial design with two factors and response surface methodology (RSM) were performed to investigate and optimize the effects of pressure and temperature on reactive red 239 (RR239), reactive yellow 15 (RY15) and reactive black 5 (RB5) dye degradations by commercial laccase in supercritical carbon dioxide media. Mathematical models were developed for each dye showing the effect of each factor and their interactions on color removal. Pressure and the interaction between temperature and pressure were the main factors affecting the decolorization. The optimum conditions for RB5 and RY15 were found to be high pressure values (>120 bar), whilst the temperature presented a minor effect on their degradation at these pressures. For RR239, both variables influenced the decolorization and the optimum conditions appear to be at low values of pressure and high values of temperature. Supercritical carbon dioxide (dpeaa)DE-He213 Biocatalysis (dpeaa)DE-He213 Optimization (dpeaa)DE-He213 Reactive dyes (dpeaa)DE-He213 Commercial laccase (dpeaa)DE-He213 RSM (dpeaa)DE-He213 Amaral, Priscilla F. F. verfasserin aut Tavares, Ana P. M. verfasserin aut Coelho, Maria Alice Z. verfasserin aut Cammarota, Magali C. verfasserin aut Loureiro, José M. verfasserin aut Boaventura, Rui A. R. verfasserin aut Macedo, Eugénia A. verfasserin aut Pessoa, Fernando L. P. verfasserin aut Enthalten in Reaction kinetics and catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974 99(2010), 2 vom: 13. Jan., Seite 311-323 (DE-627)320588882 (DE-600)2018650-2 1588-2837 nnns volume:99 year:2010 number:2 day:13 month:01 pages:311-323 https://dx.doi.org/10.1007/s11144-009-0139-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.13 ASE 35.17 ASE AR 99 2010 2 13 01 311-323
allfieldsSound	10.1007/s11144-009-0139-5 doi (DE-627)SPR017070317 (SPR)s11144-009-0139-5-e DE-627 ger DE-627 rakwb eng 540 ASE 35.13 bkl 35.17 bkl Cristóvão, Raquel O. verfasserin aut Optimization of laccase catalyzed degradation of reactive textile dyes in supercritical carbon dioxide medium by response surface methodology 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract In this work, the laccase catalyzed degradation of reactive textile dyes was studied in supercritical carbon dioxide media. A two level Box–Behnken factorial design with two factors and response surface methodology (RSM) were performed to investigate and optimize the effects of pressure and temperature on reactive red 239 (RR239), reactive yellow 15 (RY15) and reactive black 5 (RB5) dye degradations by commercial laccase in supercritical carbon dioxide media. Mathematical models were developed for each dye showing the effect of each factor and their interactions on color removal. Pressure and the interaction between temperature and pressure were the main factors affecting the decolorization. The optimum conditions for RB5 and RY15 were found to be high pressure values (>120 bar), whilst the temperature presented a minor effect on their degradation at these pressures. For RR239, both variables influenced the decolorization and the optimum conditions appear to be at low values of pressure and high values of temperature. Supercritical carbon dioxide (dpeaa)DE-He213 Biocatalysis (dpeaa)DE-He213 Optimization (dpeaa)DE-He213 Reactive dyes (dpeaa)DE-He213 Commercial laccase (dpeaa)DE-He213 RSM (dpeaa)DE-He213 Amaral, Priscilla F. F. verfasserin aut Tavares, Ana P. M. verfasserin aut Coelho, Maria Alice Z. verfasserin aut Cammarota, Magali C. verfasserin aut Loureiro, José M. verfasserin aut Boaventura, Rui A. R. verfasserin aut Macedo, Eugénia A. verfasserin aut Pessoa, Fernando L. P. verfasserin aut Enthalten in Reaction kinetics and catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974 99(2010), 2 vom: 13. Jan., Seite 311-323 (DE-627)320588882 (DE-600)2018650-2 1588-2837 nnns volume:99 year:2010 number:2 day:13 month:01 pages:311-323 https://dx.doi.org/10.1007/s11144-009-0139-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.13 ASE 35.17 ASE AR 99 2010 2 13 01 311-323
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source	Enthalten in Reaction kinetics and catalysis letters 99(2010), 2 vom: 13. Jan., Seite 311-323 volume:99 year:2010 number:2 day:13 month:01 pages:311-323
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topic_facet	Supercritical carbon dioxide Biocatalysis Optimization Reactive dyes Commercial laccase RSM
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container_title	Reaction kinetics and catalysis letters
authorswithroles_txt_mv	Cristóvão, Raquel O. @@aut@@ Amaral, Priscilla F. F. @@aut@@ Tavares, Ana P. M. @@aut@@ Coelho, Maria Alice Z. @@aut@@ Cammarota, Magali C. @@aut@@ Loureiro, José M. @@aut@@ Boaventura, Rui A. R. @@aut@@ Macedo, Eugénia A. @@aut@@ Pessoa, Fernando L. P. @@aut@@
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author	Cristóvão, Raquel O.
spellingShingle	Cristóvão, Raquel O. ddc 540 bkl 35.13 bkl 35.17 misc Supercritical carbon dioxide misc Biocatalysis misc Optimization misc Reactive dyes misc Commercial laccase misc RSM Optimization of laccase catalyzed degradation of reactive textile dyes in supercritical carbon dioxide medium by response surface methodology
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topic_title	540 ASE 35.13 bkl 35.17 bkl Optimization of laccase catalyzed degradation of reactive textile dyes in supercritical carbon dioxide medium by response surface methodology Supercritical carbon dioxide (dpeaa)DE-He213 Biocatalysis (dpeaa)DE-He213 Optimization (dpeaa)DE-He213 Reactive dyes (dpeaa)DE-He213 Commercial laccase (dpeaa)DE-He213 RSM (dpeaa)DE-He213
topic	ddc 540 bkl 35.13 bkl 35.17 misc Supercritical carbon dioxide misc Biocatalysis misc Optimization misc Reactive dyes misc Commercial laccase misc RSM
topic_unstemmed	ddc 540 bkl 35.13 bkl 35.17 misc Supercritical carbon dioxide misc Biocatalysis misc Optimization misc Reactive dyes misc Commercial laccase misc RSM
topic_browse	ddc 540 bkl 35.13 bkl 35.17 misc Supercritical carbon dioxide misc Biocatalysis misc Optimization misc Reactive dyes misc Commercial laccase misc RSM
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title	Optimization of laccase catalyzed degradation of reactive textile dyes in supercritical carbon dioxide medium by response surface methodology
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title_full	Optimization of laccase catalyzed degradation of reactive textile dyes in supercritical carbon dioxide medium by response surface methodology
author_sort	Cristóvão, Raquel O.
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author_browse	Cristóvão, Raquel O. Amaral, Priscilla F. F. Tavares, Ana P. M. Coelho, Maria Alice Z. Cammarota, Magali C. Loureiro, José M. Boaventura, Rui A. R. Macedo, Eugénia A. Pessoa, Fernando L. P.
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title_sort	optimization of laccase catalyzed degradation of reactive textile dyes in supercritical carbon dioxide medium by response surface methodology
title_auth	Optimization of laccase catalyzed degradation of reactive textile dyes in supercritical carbon dioxide medium by response surface methodology
abstract	Abstract In this work, the laccase catalyzed degradation of reactive textile dyes was studied in supercritical carbon dioxide media. A two level Box–Behnken factorial design with two factors and response surface methodology (RSM) were performed to investigate and optimize the effects of pressure and temperature on reactive red 239 (RR239), reactive yellow 15 (RY15) and reactive black 5 (RB5) dye degradations by commercial laccase in supercritical carbon dioxide media. Mathematical models were developed for each dye showing the effect of each factor and their interactions on color removal. Pressure and the interaction between temperature and pressure were the main factors affecting the decolorization. The optimum conditions for RB5 and RY15 were found to be high pressure values (>120 bar), whilst the temperature presented a minor effect on their degradation at these pressures. For RR239, both variables influenced the decolorization and the optimum conditions appear to be at low values of pressure and high values of temperature.
abstractGer	Abstract In this work, the laccase catalyzed degradation of reactive textile dyes was studied in supercritical carbon dioxide media. A two level Box–Behnken factorial design with two factors and response surface methodology (RSM) were performed to investigate and optimize the effects of pressure and temperature on reactive red 239 (RR239), reactive yellow 15 (RY15) and reactive black 5 (RB5) dye degradations by commercial laccase in supercritical carbon dioxide media. Mathematical models were developed for each dye showing the effect of each factor and their interactions on color removal. Pressure and the interaction between temperature and pressure were the main factors affecting the decolorization. The optimum conditions for RB5 and RY15 were found to be high pressure values (>120 bar), whilst the temperature presented a minor effect on their degradation at these pressures. For RR239, both variables influenced the decolorization and the optimum conditions appear to be at low values of pressure and high values of temperature.
abstract_unstemmed	Abstract In this work, the laccase catalyzed degradation of reactive textile dyes was studied in supercritical carbon dioxide media. A two level Box–Behnken factorial design with two factors and response surface methodology (RSM) were performed to investigate and optimize the effects of pressure and temperature on reactive red 239 (RR239), reactive yellow 15 (RY15) and reactive black 5 (RB5) dye degradations by commercial laccase in supercritical carbon dioxide media. Mathematical models were developed for each dye showing the effect of each factor and their interactions on color removal. Pressure and the interaction between temperature and pressure were the main factors affecting the decolorization. The optimum conditions for RB5 and RY15 were found to be high pressure values (>120 bar), whilst the temperature presented a minor effect on their degradation at these pressures. For RR239, both variables influenced the decolorization and the optimum conditions appear to be at low values of pressure and high values of temperature.
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title_short	Optimization of laccase catalyzed degradation of reactive textile dyes in supercritical carbon dioxide medium by response surface methodology
url	https://dx.doi.org/10.1007/s11144-009-0139-5
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author2	Amaral, Priscilla F. F. Tavares, Ana P. M. Coelho, Maria Alice Z. Cammarota, Magali C. Loureiro, José M. Boaventura, Rui A. R. Macedo, Eugénia A. Pessoa, Fernando L. P.
author2Str	Amaral, Priscilla F. F. Tavares, Ana P. M. Coelho, Maria Alice Z. Cammarota, Magali C. Loureiro, José M. Boaventura, Rui A. R. Macedo, Eugénia A. Pessoa, Fernando L. P.
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