Oxidation of styrene to benzaldehyde with hydrogen peroxide in the presence of catalysts obtained by the immobilization of $ H_{3} %$ PW_{12} %$ O_{40} $ on SBA-15 mesoporous material

Abstract Mesoporous SBA-15 functionalized catalysts with controllable $ H_{3} %$ PW_{12} %$ O_{40} $ loadings were prepared using a one-step co-condensation method and used for the oxidation of styrene to benzaldehyde with hydrogen peroxide as the oxidant. These catalysts were well characterized by...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Sun, Wenliang [verfasserIn] Hu, Jianglei [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2016

Schlagwörter:	H PW O SBA-15 Styrene Oxidation Benzaldehyde

Übergeordnetes Werk:	Enthalten in: Reaction kinetics and catalysis letters - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974, 119(2016), 1 vom: 28. März, Seite 305-318
Übergeordnetes Werk:	volume:119 ; year:2016 ; number:1 ; day:28 ; month:03 ; pages:305-318

Links:	Volltext

DOI / URN:	10.1007/s11144-016-1024-7

Katalog-ID:	SPR017079063

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245	1	0	\|a Oxidation of styrene to benzaldehyde with hydrogen peroxide in the presence of catalysts obtained by the immobilization of $ H_{3} %$ PW_{12} %$ O_{40} $ on SBA-15 mesoporous material
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520			\|a Abstract Mesoporous SBA-15 functionalized catalysts with controllable $ H_{3} %$ PW_{12} %$ O_{40} $ loadings were prepared using a one-step co-condensation method and used for the oxidation of styrene to benzaldehyde with hydrogen peroxide as the oxidant. These catalysts were well characterized by Fourier transform infrared spectroscopy, Raman scattering spectroscopy, low angle X-ray diffraction, wide angle X-ray diffraction, scanning electronic microscopy, transmission electron microscopy and $ N_{2} $ adsorption–desorption. The results showed that $ H_{3} %$ PW_{12} %$ O_{40} $ was successfully incorporated into the mesoporous channels of SBA-15, which increased the specific surface area of the active components. These catalysts were applied to catalyze styrene oxidation in the presence of cheap and green hydrogen peroxide, and the key reaction parameters including $ H_{3} %$ PW_{12} %$ O_{40} $ loading, reaction temperature, solvent, $ H_{2} %$ O_{2} $ amount, and reaction time on the catalytic performance were investigated. The heterogeneous $ H_{3} %$ PW_{12} %$ O_{40} $-catalyzed styrene oxidations showed the oxidation product was benzaldehyde as the only product. This route showed green and simple property.
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allfields	10.1007/s11144-016-1024-7 doi (DE-627)SPR017079063 (SPR)s11144-016-1024-7-e DE-627 ger DE-627 rakwb eng 540 ASE 35.13 bkl 35.17 bkl Sun, Wenliang verfasserin aut Oxidation of styrene to benzaldehyde with hydrogen peroxide in the presence of catalysts obtained by the immobilization of $ H_{3} %$ PW_{12} %$ O_{40} $ on SBA-15 mesoporous material 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Mesoporous SBA-15 functionalized catalysts with controllable $ H_{3} %$ PW_{12} %$ O_{40} $ loadings were prepared using a one-step co-condensation method and used for the oxidation of styrene to benzaldehyde with hydrogen peroxide as the oxidant. These catalysts were well characterized by Fourier transform infrared spectroscopy, Raman scattering spectroscopy, low angle X-ray diffraction, wide angle X-ray diffraction, scanning electronic microscopy, transmission electron microscopy and $ N_{2} $ adsorption–desorption. The results showed that $ H_{3} %$ PW_{12} %$ O_{40} $ was successfully incorporated into the mesoporous channels of SBA-15, which increased the specific surface area of the active components. These catalysts were applied to catalyze styrene oxidation in the presence of cheap and green hydrogen peroxide, and the key reaction parameters including $ H_{3} %$ PW_{12} %$ O_{40} $ loading, reaction temperature, solvent, $ H_{2} %$ O_{2} $ amount, and reaction time on the catalytic performance were investigated. The heterogeneous $ H_{3} %$ PW_{12} %$ O_{40} $-catalyzed styrene oxidations showed the oxidation product was benzaldehyde as the only product. This route showed green and simple property. H (dpeaa)DE-He213 PW (dpeaa)DE-He213 O (dpeaa)DE-He213 SBA-15 (dpeaa)DE-He213 Styrene (dpeaa)DE-He213 Oxidation (dpeaa)DE-He213 Benzaldehyde (dpeaa)DE-He213 Hu, Jianglei verfasserin aut Enthalten in Reaction kinetics and catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974 119(2016), 1 vom: 28. März, Seite 305-318 (DE-627)320588882 (DE-600)2018650-2 1588-2837 nnns volume:119 year:2016 number:1 day:28 month:03 pages:305-318 https://dx.doi.org/10.1007/s11144-016-1024-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.13 ASE 35.17 ASE AR 119 2016 1 28 03 305-318
spelling	10.1007/s11144-016-1024-7 doi (DE-627)SPR017079063 (SPR)s11144-016-1024-7-e DE-627 ger DE-627 rakwb eng 540 ASE 35.13 bkl 35.17 bkl Sun, Wenliang verfasserin aut Oxidation of styrene to benzaldehyde with hydrogen peroxide in the presence of catalysts obtained by the immobilization of $ H_{3} %$ PW_{12} %$ O_{40} $ on SBA-15 mesoporous material 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Mesoporous SBA-15 functionalized catalysts with controllable $ H_{3} %$ PW_{12} %$ O_{40} $ loadings were prepared using a one-step co-condensation method and used for the oxidation of styrene to benzaldehyde with hydrogen peroxide as the oxidant. These catalysts were well characterized by Fourier transform infrared spectroscopy, Raman scattering spectroscopy, low angle X-ray diffraction, wide angle X-ray diffraction, scanning electronic microscopy, transmission electron microscopy and $ N_{2} $ adsorption–desorption. The results showed that $ H_{3} %$ PW_{12} %$ O_{40} $ was successfully incorporated into the mesoporous channels of SBA-15, which increased the specific surface area of the active components. These catalysts were applied to catalyze styrene oxidation in the presence of cheap and green hydrogen peroxide, and the key reaction parameters including $ H_{3} %$ PW_{12} %$ O_{40} $ loading, reaction temperature, solvent, $ H_{2} %$ O_{2} $ amount, and reaction time on the catalytic performance were investigated. The heterogeneous $ H_{3} %$ PW_{12} %$ O_{40} $-catalyzed styrene oxidations showed the oxidation product was benzaldehyde as the only product. This route showed green and simple property. H (dpeaa)DE-He213 PW (dpeaa)DE-He213 O (dpeaa)DE-He213 SBA-15 (dpeaa)DE-He213 Styrene (dpeaa)DE-He213 Oxidation (dpeaa)DE-He213 Benzaldehyde (dpeaa)DE-He213 Hu, Jianglei verfasserin aut Enthalten in Reaction kinetics and catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974 119(2016), 1 vom: 28. März, Seite 305-318 (DE-627)320588882 (DE-600)2018650-2 1588-2837 nnns volume:119 year:2016 number:1 day:28 month:03 pages:305-318 https://dx.doi.org/10.1007/s11144-016-1024-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.13 ASE 35.17 ASE AR 119 2016 1 28 03 305-318
allfields_unstemmed	10.1007/s11144-016-1024-7 doi (DE-627)SPR017079063 (SPR)s11144-016-1024-7-e DE-627 ger DE-627 rakwb eng 540 ASE 35.13 bkl 35.17 bkl Sun, Wenliang verfasserin aut Oxidation of styrene to benzaldehyde with hydrogen peroxide in the presence of catalysts obtained by the immobilization of $ H_{3} %$ PW_{12} %$ O_{40} $ on SBA-15 mesoporous material 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Mesoporous SBA-15 functionalized catalysts with controllable $ H_{3} %$ PW_{12} %$ O_{40} $ loadings were prepared using a one-step co-condensation method and used for the oxidation of styrene to benzaldehyde with hydrogen peroxide as the oxidant. These catalysts were well characterized by Fourier transform infrared spectroscopy, Raman scattering spectroscopy, low angle X-ray diffraction, wide angle X-ray diffraction, scanning electronic microscopy, transmission electron microscopy and $ N_{2} $ adsorption–desorption. The results showed that $ H_{3} %$ PW_{12} %$ O_{40} $ was successfully incorporated into the mesoporous channels of SBA-15, which increased the specific surface area of the active components. These catalysts were applied to catalyze styrene oxidation in the presence of cheap and green hydrogen peroxide, and the key reaction parameters including $ H_{3} %$ PW_{12} %$ O_{40} $ loading, reaction temperature, solvent, $ H_{2} %$ O_{2} $ amount, and reaction time on the catalytic performance were investigated. The heterogeneous $ H_{3} %$ PW_{12} %$ O_{40} $-catalyzed styrene oxidations showed the oxidation product was benzaldehyde as the only product. This route showed green and simple property. H (dpeaa)DE-He213 PW (dpeaa)DE-He213 O (dpeaa)DE-He213 SBA-15 (dpeaa)DE-He213 Styrene (dpeaa)DE-He213 Oxidation (dpeaa)DE-He213 Benzaldehyde (dpeaa)DE-He213 Hu, Jianglei verfasserin aut Enthalten in Reaction kinetics and catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974 119(2016), 1 vom: 28. März, Seite 305-318 (DE-627)320588882 (DE-600)2018650-2 1588-2837 nnns volume:119 year:2016 number:1 day:28 month:03 pages:305-318 https://dx.doi.org/10.1007/s11144-016-1024-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.13 ASE 35.17 ASE AR 119 2016 1 28 03 305-318
allfieldsGer	10.1007/s11144-016-1024-7 doi (DE-627)SPR017079063 (SPR)s11144-016-1024-7-e DE-627 ger DE-627 rakwb eng 540 ASE 35.13 bkl 35.17 bkl Sun, Wenliang verfasserin aut Oxidation of styrene to benzaldehyde with hydrogen peroxide in the presence of catalysts obtained by the immobilization of $ H_{3} %$ PW_{12} %$ O_{40} $ on SBA-15 mesoporous material 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Mesoporous SBA-15 functionalized catalysts with controllable $ H_{3} %$ PW_{12} %$ O_{40} $ loadings were prepared using a one-step co-condensation method and used for the oxidation of styrene to benzaldehyde with hydrogen peroxide as the oxidant. These catalysts were well characterized by Fourier transform infrared spectroscopy, Raman scattering spectroscopy, low angle X-ray diffraction, wide angle X-ray diffraction, scanning electronic microscopy, transmission electron microscopy and $ N_{2} $ adsorption–desorption. The results showed that $ H_{3} %$ PW_{12} %$ O_{40} $ was successfully incorporated into the mesoporous channels of SBA-15, which increased the specific surface area of the active components. These catalysts were applied to catalyze styrene oxidation in the presence of cheap and green hydrogen peroxide, and the key reaction parameters including $ H_{3} %$ PW_{12} %$ O_{40} $ loading, reaction temperature, solvent, $ H_{2} %$ O_{2} $ amount, and reaction time on the catalytic performance were investigated. The heterogeneous $ H_{3} %$ PW_{12} %$ O_{40} $-catalyzed styrene oxidations showed the oxidation product was benzaldehyde as the only product. This route showed green and simple property. H (dpeaa)DE-He213 PW (dpeaa)DE-He213 O (dpeaa)DE-He213 SBA-15 (dpeaa)DE-He213 Styrene (dpeaa)DE-He213 Oxidation (dpeaa)DE-He213 Benzaldehyde (dpeaa)DE-He213 Hu, Jianglei verfasserin aut Enthalten in Reaction kinetics and catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974 119(2016), 1 vom: 28. März, Seite 305-318 (DE-627)320588882 (DE-600)2018650-2 1588-2837 nnns volume:119 year:2016 number:1 day:28 month:03 pages:305-318 https://dx.doi.org/10.1007/s11144-016-1024-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.13 ASE 35.17 ASE AR 119 2016 1 28 03 305-318
allfieldsSound	10.1007/s11144-016-1024-7 doi (DE-627)SPR017079063 (SPR)s11144-016-1024-7-e DE-627 ger DE-627 rakwb eng 540 ASE 35.13 bkl 35.17 bkl Sun, Wenliang verfasserin aut Oxidation of styrene to benzaldehyde with hydrogen peroxide in the presence of catalysts obtained by the immobilization of $ H_{3} %$ PW_{12} %$ O_{40} $ on SBA-15 mesoporous material 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Mesoporous SBA-15 functionalized catalysts with controllable $ H_{3} %$ PW_{12} %$ O_{40} $ loadings were prepared using a one-step co-condensation method and used for the oxidation of styrene to benzaldehyde with hydrogen peroxide as the oxidant. These catalysts were well characterized by Fourier transform infrared spectroscopy, Raman scattering spectroscopy, low angle X-ray diffraction, wide angle X-ray diffraction, scanning electronic microscopy, transmission electron microscopy and $ N_{2} $ adsorption–desorption. The results showed that $ H_{3} %$ PW_{12} %$ O_{40} $ was successfully incorporated into the mesoporous channels of SBA-15, which increased the specific surface area of the active components. These catalysts were applied to catalyze styrene oxidation in the presence of cheap and green hydrogen peroxide, and the key reaction parameters including $ H_{3} %$ PW_{12} %$ O_{40} $ loading, reaction temperature, solvent, $ H_{2} %$ O_{2} $ amount, and reaction time on the catalytic performance were investigated. The heterogeneous $ H_{3} %$ PW_{12} %$ O_{40} $-catalyzed styrene oxidations showed the oxidation product was benzaldehyde as the only product. This route showed green and simple property. H (dpeaa)DE-He213 PW (dpeaa)DE-He213 O (dpeaa)DE-He213 SBA-15 (dpeaa)DE-He213 Styrene (dpeaa)DE-He213 Oxidation (dpeaa)DE-He213 Benzaldehyde (dpeaa)DE-He213 Hu, Jianglei verfasserin aut Enthalten in Reaction kinetics and catalysis letters Dordrecht [u.a.] : Springer Science + Business Media B.V, 1974 119(2016), 1 vom: 28. März, Seite 305-318 (DE-627)320588882 (DE-600)2018650-2 1588-2837 nnns volume:119 year:2016 number:1 day:28 month:03 pages:305-318 https://dx.doi.org/10.1007/s11144-016-1024-7 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.13 ASE 35.17 ASE AR 119 2016 1 28 03 305-318
language	English
source	Enthalten in Reaction kinetics and catalysis letters 119(2016), 1 vom: 28. März, Seite 305-318 volume:119 year:2016 number:1 day:28 month:03 pages:305-318
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topic_facet	H PW O SBA-15 Styrene Oxidation Benzaldehyde
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container_title	Reaction kinetics and catalysis letters
authorswithroles_txt_mv	Sun, Wenliang @@aut@@ Hu, Jianglei @@aut@@
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These catalysts were well characterized by Fourier transform infrared spectroscopy, Raman scattering spectroscopy, low angle X-ray diffraction, wide angle X-ray diffraction, scanning electronic microscopy, transmission electron microscopy and $ N_{2} $ adsorption–desorption. The results showed that $ H_{3} %$ PW_{12} %$ O_{40} $ was successfully incorporated into the mesoporous channels of SBA-15, which increased the specific surface area of the active components. These catalysts were applied to catalyze styrene oxidation in the presence of cheap and green hydrogen peroxide, and the key reaction parameters including $ H_{3} %$ PW_{12} %$ O_{40} $ loading, reaction temperature, solvent, $ H_{2} %$ O_{2} $ amount, and reaction time on the catalytic performance were investigated. The heterogeneous $ H_{3} %$ PW_{12} %$ O_{40} $-catalyzed styrene oxidations showed the oxidation product was benzaldehyde as the only product. 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author	Sun, Wenliang
spellingShingle	Sun, Wenliang ddc 540 bkl 35.13 bkl 35.17 misc H misc PW misc O misc SBA-15 misc Styrene misc Oxidation misc Benzaldehyde Oxidation of styrene to benzaldehyde with hydrogen peroxide in the presence of catalysts obtained by the immobilization of $ H_{3} %$ PW_{12} %$ O_{40} $ on SBA-15 mesoporous material
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topic_title	540 ASE 35.13 bkl 35.17 bkl Oxidation of styrene to benzaldehyde with hydrogen peroxide in the presence of catalysts obtained by the immobilization of $ H_{3} %$ PW_{12} %$ O_{40} $ on SBA-15 mesoporous material H (dpeaa)DE-He213 PW (dpeaa)DE-He213 O (dpeaa)DE-He213 SBA-15 (dpeaa)DE-He213 Styrene (dpeaa)DE-He213 Oxidation (dpeaa)DE-He213 Benzaldehyde (dpeaa)DE-He213
topic	ddc 540 bkl 35.13 bkl 35.17 misc H misc PW misc O misc SBA-15 misc Styrene misc Oxidation misc Benzaldehyde
topic_unstemmed	ddc 540 bkl 35.13 bkl 35.17 misc H misc PW misc O misc SBA-15 misc Styrene misc Oxidation misc Benzaldehyde
topic_browse	ddc 540 bkl 35.13 bkl 35.17 misc H misc PW misc O misc SBA-15 misc Styrene misc Oxidation misc Benzaldehyde
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title	Oxidation of styrene to benzaldehyde with hydrogen peroxide in the presence of catalysts obtained by the immobilization of $ H_{3} %$ PW_{12} %$ O_{40} $ on SBA-15 mesoporous material
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title_full	Oxidation of styrene to benzaldehyde with hydrogen peroxide in the presence of catalysts obtained by the immobilization of $ H_{3} %$ PW_{12} %$ O_{40} $ on SBA-15 mesoporous material
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author_browse	Sun, Wenliang Hu, Jianglei
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title_sort	oxidation of styrene to benzaldehyde with hydrogen peroxide in the presence of catalysts obtained by the immobilization of $ h_{3} %$ pw_{12} %$ o_{40} $ on sba-15 mesoporous material
title_auth	Oxidation of styrene to benzaldehyde with hydrogen peroxide in the presence of catalysts obtained by the immobilization of $ H_{3} %$ PW_{12} %$ O_{40} $ on SBA-15 mesoporous material
abstract	Abstract Mesoporous SBA-15 functionalized catalysts with controllable $ H_{3} %$ PW_{12} %$ O_{40} $ loadings were prepared using a one-step co-condensation method and used for the oxidation of styrene to benzaldehyde with hydrogen peroxide as the oxidant. These catalysts were well characterized by Fourier transform infrared spectroscopy, Raman scattering spectroscopy, low angle X-ray diffraction, wide angle X-ray diffraction, scanning electronic microscopy, transmission electron microscopy and $ N_{2} $ adsorption–desorption. The results showed that $ H_{3} %$ PW_{12} %$ O_{40} $ was successfully incorporated into the mesoporous channels of SBA-15, which increased the specific surface area of the active components. These catalysts were applied to catalyze styrene oxidation in the presence of cheap and green hydrogen peroxide, and the key reaction parameters including $ H_{3} %$ PW_{12} %$ O_{40} $ loading, reaction temperature, solvent, $ H_{2} %$ O_{2} $ amount, and reaction time on the catalytic performance were investigated. The heterogeneous $ H_{3} %$ PW_{12} %$ O_{40} $-catalyzed styrene oxidations showed the oxidation product was benzaldehyde as the only product. This route showed green and simple property.
abstractGer	Abstract Mesoporous SBA-15 functionalized catalysts with controllable $ H_{3} %$ PW_{12} %$ O_{40} $ loadings were prepared using a one-step co-condensation method and used for the oxidation of styrene to benzaldehyde with hydrogen peroxide as the oxidant. These catalysts were well characterized by Fourier transform infrared spectroscopy, Raman scattering spectroscopy, low angle X-ray diffraction, wide angle X-ray diffraction, scanning electronic microscopy, transmission electron microscopy and $ N_{2} $ adsorption–desorption. The results showed that $ H_{3} %$ PW_{12} %$ O_{40} $ was successfully incorporated into the mesoporous channels of SBA-15, which increased the specific surface area of the active components. These catalysts were applied to catalyze styrene oxidation in the presence of cheap and green hydrogen peroxide, and the key reaction parameters including $ H_{3} %$ PW_{12} %$ O_{40} $ loading, reaction temperature, solvent, $ H_{2} %$ O_{2} $ amount, and reaction time on the catalytic performance were investigated. The heterogeneous $ H_{3} %$ PW_{12} %$ O_{40} $-catalyzed styrene oxidations showed the oxidation product was benzaldehyde as the only product. This route showed green and simple property.
abstract_unstemmed	Abstract Mesoporous SBA-15 functionalized catalysts with controllable $ H_{3} %$ PW_{12} %$ O_{40} $ loadings were prepared using a one-step co-condensation method and used for the oxidation of styrene to benzaldehyde with hydrogen peroxide as the oxidant. These catalysts were well characterized by Fourier transform infrared spectroscopy, Raman scattering spectroscopy, low angle X-ray diffraction, wide angle X-ray diffraction, scanning electronic microscopy, transmission electron microscopy and $ N_{2} $ adsorption–desorption. The results showed that $ H_{3} %$ PW_{12} %$ O_{40} $ was successfully incorporated into the mesoporous channels of SBA-15, which increased the specific surface area of the active components. These catalysts were applied to catalyze styrene oxidation in the presence of cheap and green hydrogen peroxide, and the key reaction parameters including $ H_{3} %$ PW_{12} %$ O_{40} $ loading, reaction temperature, solvent, $ H_{2} %$ O_{2} $ amount, and reaction time on the catalytic performance were investigated. The heterogeneous $ H_{3} %$ PW_{12} %$ O_{40} $-catalyzed styrene oxidations showed the oxidation product was benzaldehyde as the only product. This route showed green and simple property.
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702
container_issue	1
title_short	Oxidation of styrene to benzaldehyde with hydrogen peroxide in the presence of catalysts obtained by the immobilization of $ H_{3} %$ PW_{12} %$ O_{40} $ on SBA-15 mesoporous material
url	https://dx.doi.org/10.1007/s11144-016-1024-7
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up_date	2024-07-04T02:07:53.882Z
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These catalysts were well characterized by Fourier transform infrared spectroscopy, Raman scattering spectroscopy, low angle X-ray diffraction, wide angle X-ray diffraction, scanning electronic microscopy, transmission electron microscopy and $ N_{2} $ adsorption–desorption. The results showed that $ H_{3} %$ PW_{12} %$ O_{40} $ was successfully incorporated into the mesoporous channels of SBA-15, which increased the specific surface area of the active components. These catalysts were applied to catalyze styrene oxidation in the presence of cheap and green hydrogen peroxide, and the key reaction parameters including $ H_{3} %$ PW_{12} %$ O_{40} $ loading, reaction temperature, solvent, $ H_{2} %$ O_{2} $ amount, and reaction time on the catalytic performance were investigated. The heterogeneous $ H_{3} %$ PW_{12} %$ O_{40} $-catalyzed styrene oxidations showed the oxidation product was benzaldehyde as the only product. 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Oxidation of styrene to benzaldehyde with hydrogen peroxide in the presence of catalysts obtained by the immobilization of $ H_{3} %$ PW_{12} %$ O_{40} $ on SBA-15 mesoporous material

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