The processes of benzene alkylation with n-alkenes on the sulfocation exchangers
Abstract The processes of benzene alkylation with n-alkenes $ C_{2} $–$ C_{3} $ on sulfocation exchangers are developed. The processes are deprived of the strong corrosion aggressiveness, characteristic of the industrial processes with use of $ AlCl_{3} $ or $ BF_{3} $, and do not need the periodic...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Pavlov, O. S. [verfasserIn] Chistyakova, T. A. [verfasserIn] Pavlov, S. Yu. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2009 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Russian journal of applied chemistry - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1996, 82(2009), 4 vom: Apr., Seite 706-710 |
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| Übergeordnetes Werk: |
volume:82 ; year:2009 ; number:4 ; month:04 ; pages:706-710 |
| Links: |
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| DOI / URN: |
10.1134/S1070427209040338 |
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| Katalog-ID: |
SPR01721792X |
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| 245 | 1 | 4 | |a The processes of benzene alkylation with n-alkenes on the sulfocation exchangers |
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| 520 | |a Abstract The processes of benzene alkylation with n-alkenes $ C_{2} $–$ C_{3} $ on sulfocation exchangers are developed. The processes are deprived of the strong corrosion aggressiveness, characteristic of the industrial processes with use of $ AlCl_{3} $ or $ BF_{3} $, and do not need the periodic burning out of the formed contaminants, that is characteristic of the processes with application of zeolites. Alkylation proceeds in the liquid phase at moderate temperatures: 70–90°C in the case of alkylation with propene and n-butenes, and 130°C for the alkylation with ethylene. With the use of alkane-alkene fractions $ C_{2} $–$ C_{3} $ the conversion of alkenes process exceeds 99%, the alkylbenzene to dialkylbenzenes ratio reaches 20–25%. Peralkylation of dialkylbenzenes it not required. | ||
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| 650 | 4 | |a Benzene Alkylation |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a EtPh |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Chistyakova, T. A. |e verfasserin |4 aut | |
| 700 | 1 | |a Pavlov, S. Yu. |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Russian journal of applied chemistry |d Dordrecht [u.a.] : Springer Science + Business Media B.V, 1996 |g 82(2009), 4 vom: Apr., Seite 706-710 |w (DE-627)336798393 |w (DE-600)2061899-2 |x 1608-3296 |7 nnns |
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10.1134/S1070427209040338 doi (DE-627)SPR01721792X (SPR)S1070427209040338-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl 58.10 bkl 58.00 bkl Pavlov, O. S. verfasserin aut The processes of benzene alkylation with n-alkenes on the sulfocation exchangers 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The processes of benzene alkylation with n-alkenes $ C_{2} $–$ C_{3} $ on sulfocation exchangers are developed. The processes are deprived of the strong corrosion aggressiveness, characteristic of the industrial processes with use of $ AlCl_{3} $ or $ BF_{3} $, and do not need the periodic burning out of the formed contaminants, that is characteristic of the processes with application of zeolites. Alkylation proceeds in the liquid phase at moderate temperatures: 70–90°C in the case of alkylation with propene and n-butenes, and 130°C for the alkylation with ethylene. With the use of alkane-alkene fractions $ C_{2} $–$ C_{3} $ the conversion of alkenes process exceeds 99%, the alkylbenzene to dialkylbenzenes ratio reaches 20–25%. Peralkylation of dialkylbenzenes it not required. Zeolite (dpeaa)DE-He213 Reaction Zone (dpeaa)DE-He213 Ethylbenzene (dpeaa)DE-He213 Benzene Alkylation (dpeaa)DE-He213 EtPh (dpeaa)DE-He213 Chistyakova, T. A. verfasserin aut Pavlov, S. Yu. verfasserin aut Enthalten in Russian journal of applied chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1996 82(2009), 4 vom: Apr., Seite 706-710 (DE-627)336798393 (DE-600)2061899-2 1608-3296 nnns volume:82 year:2009 number:4 month:04 pages:706-710 https://dx.doi.org/10.1134/S1070427209040338 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE 58.10 ASE 58.00 ASE AR 82 2009 4 04 706-710 |
| spelling |
10.1134/S1070427209040338 doi (DE-627)SPR01721792X (SPR)S1070427209040338-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl 58.10 bkl 58.00 bkl Pavlov, O. S. verfasserin aut The processes of benzene alkylation with n-alkenes on the sulfocation exchangers 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The processes of benzene alkylation with n-alkenes $ C_{2} $–$ C_{3} $ on sulfocation exchangers are developed. The processes are deprived of the strong corrosion aggressiveness, characteristic of the industrial processes with use of $ AlCl_{3} $ or $ BF_{3} $, and do not need the periodic burning out of the formed contaminants, that is characteristic of the processes with application of zeolites. Alkylation proceeds in the liquid phase at moderate temperatures: 70–90°C in the case of alkylation with propene and n-butenes, and 130°C for the alkylation with ethylene. With the use of alkane-alkene fractions $ C_{2} $–$ C_{3} $ the conversion of alkenes process exceeds 99%, the alkylbenzene to dialkylbenzenes ratio reaches 20–25%. Peralkylation of dialkylbenzenes it not required. Zeolite (dpeaa)DE-He213 Reaction Zone (dpeaa)DE-He213 Ethylbenzene (dpeaa)DE-He213 Benzene Alkylation (dpeaa)DE-He213 EtPh (dpeaa)DE-He213 Chistyakova, T. A. verfasserin aut Pavlov, S. Yu. verfasserin aut Enthalten in Russian journal of applied chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1996 82(2009), 4 vom: Apr., Seite 706-710 (DE-627)336798393 (DE-600)2061899-2 1608-3296 nnns volume:82 year:2009 number:4 month:04 pages:706-710 https://dx.doi.org/10.1134/S1070427209040338 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE 58.10 ASE 58.00 ASE AR 82 2009 4 04 706-710 |
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10.1134/S1070427209040338 doi (DE-627)SPR01721792X (SPR)S1070427209040338-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl 58.10 bkl 58.00 bkl Pavlov, O. S. verfasserin aut The processes of benzene alkylation with n-alkenes on the sulfocation exchangers 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The processes of benzene alkylation with n-alkenes $ C_{2} $–$ C_{3} $ on sulfocation exchangers are developed. The processes are deprived of the strong corrosion aggressiveness, characteristic of the industrial processes with use of $ AlCl_{3} $ or $ BF_{3} $, and do not need the periodic burning out of the formed contaminants, that is characteristic of the processes with application of zeolites. Alkylation proceeds in the liquid phase at moderate temperatures: 70–90°C in the case of alkylation with propene and n-butenes, and 130°C for the alkylation with ethylene. With the use of alkane-alkene fractions $ C_{2} $–$ C_{3} $ the conversion of alkenes process exceeds 99%, the alkylbenzene to dialkylbenzenes ratio reaches 20–25%. Peralkylation of dialkylbenzenes it not required. Zeolite (dpeaa)DE-He213 Reaction Zone (dpeaa)DE-He213 Ethylbenzene (dpeaa)DE-He213 Benzene Alkylation (dpeaa)DE-He213 EtPh (dpeaa)DE-He213 Chistyakova, T. A. verfasserin aut Pavlov, S. Yu. verfasserin aut Enthalten in Russian journal of applied chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1996 82(2009), 4 vom: Apr., Seite 706-710 (DE-627)336798393 (DE-600)2061899-2 1608-3296 nnns volume:82 year:2009 number:4 month:04 pages:706-710 https://dx.doi.org/10.1134/S1070427209040338 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE 58.10 ASE 58.00 ASE AR 82 2009 4 04 706-710 |
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10.1134/S1070427209040338 doi (DE-627)SPR01721792X (SPR)S1070427209040338-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl 58.10 bkl 58.00 bkl Pavlov, O. S. verfasserin aut The processes of benzene alkylation with n-alkenes on the sulfocation exchangers 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The processes of benzene alkylation with n-alkenes $ C_{2} $–$ C_{3} $ on sulfocation exchangers are developed. The processes are deprived of the strong corrosion aggressiveness, characteristic of the industrial processes with use of $ AlCl_{3} $ or $ BF_{3} $, and do not need the periodic burning out of the formed contaminants, that is characteristic of the processes with application of zeolites. Alkylation proceeds in the liquid phase at moderate temperatures: 70–90°C in the case of alkylation with propene and n-butenes, and 130°C for the alkylation with ethylene. With the use of alkane-alkene fractions $ C_{2} $–$ C_{3} $ the conversion of alkenes process exceeds 99%, the alkylbenzene to dialkylbenzenes ratio reaches 20–25%. Peralkylation of dialkylbenzenes it not required. Zeolite (dpeaa)DE-He213 Reaction Zone (dpeaa)DE-He213 Ethylbenzene (dpeaa)DE-He213 Benzene Alkylation (dpeaa)DE-He213 EtPh (dpeaa)DE-He213 Chistyakova, T. A. verfasserin aut Pavlov, S. Yu. verfasserin aut Enthalten in Russian journal of applied chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1996 82(2009), 4 vom: Apr., Seite 706-710 (DE-627)336798393 (DE-600)2061899-2 1608-3296 nnns volume:82 year:2009 number:4 month:04 pages:706-710 https://dx.doi.org/10.1134/S1070427209040338 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE 58.10 ASE 58.00 ASE AR 82 2009 4 04 706-710 |
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10.1134/S1070427209040338 doi (DE-627)SPR01721792X (SPR)S1070427209040338-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl 58.10 bkl 58.00 bkl Pavlov, O. S. verfasserin aut The processes of benzene alkylation with n-alkenes on the sulfocation exchangers 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The processes of benzene alkylation with n-alkenes $ C_{2} $–$ C_{3} $ on sulfocation exchangers are developed. The processes are deprived of the strong corrosion aggressiveness, characteristic of the industrial processes with use of $ AlCl_{3} $ or $ BF_{3} $, and do not need the periodic burning out of the formed contaminants, that is characteristic of the processes with application of zeolites. Alkylation proceeds in the liquid phase at moderate temperatures: 70–90°C in the case of alkylation with propene and n-butenes, and 130°C for the alkylation with ethylene. With the use of alkane-alkene fractions $ C_{2} $–$ C_{3} $ the conversion of alkenes process exceeds 99%, the alkylbenzene to dialkylbenzenes ratio reaches 20–25%. Peralkylation of dialkylbenzenes it not required. Zeolite (dpeaa)DE-He213 Reaction Zone (dpeaa)DE-He213 Ethylbenzene (dpeaa)DE-He213 Benzene Alkylation (dpeaa)DE-He213 EtPh (dpeaa)DE-He213 Chistyakova, T. A. verfasserin aut Pavlov, S. Yu. verfasserin aut Enthalten in Russian journal of applied chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1996 82(2009), 4 vom: Apr., Seite 706-710 (DE-627)336798393 (DE-600)2061899-2 1608-3296 nnns volume:82 year:2009 number:4 month:04 pages:706-710 https://dx.doi.org/10.1134/S1070427209040338 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE 58.10 ASE 58.00 ASE AR 82 2009 4 04 706-710 |
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Enthalten in Russian journal of applied chemistry 82(2009), 4 vom: Apr., Seite 706-710 volume:82 year:2009 number:4 month:04 pages:706-710 |
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Zeolite Reaction Zone Ethylbenzene Benzene Alkylation EtPh |
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Russian journal of applied chemistry |
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Pavlov, O. S. @@aut@@ Chistyakova, T. A. @@aut@@ Pavlov, S. Yu. @@aut@@ |
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| author |
Pavlov, O. S. |
| spellingShingle |
Pavlov, O. S. ddc 540 bkl 35.00 bkl 58.10 bkl 58.00 misc Zeolite misc Reaction Zone misc Ethylbenzene misc Benzene Alkylation misc EtPh The processes of benzene alkylation with n-alkenes on the sulfocation exchangers |
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540 ASE 35.00 bkl 58.10 bkl 58.00 bkl The processes of benzene alkylation with n-alkenes on the sulfocation exchangers Zeolite (dpeaa)DE-He213 Reaction Zone (dpeaa)DE-He213 Ethylbenzene (dpeaa)DE-He213 Benzene Alkylation (dpeaa)DE-He213 EtPh (dpeaa)DE-He213 |
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ddc 540 bkl 35.00 bkl 58.10 bkl 58.00 misc Zeolite misc Reaction Zone misc Ethylbenzene misc Benzene Alkylation misc EtPh |
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ddc 540 bkl 35.00 bkl 58.10 bkl 58.00 misc Zeolite misc Reaction Zone misc Ethylbenzene misc Benzene Alkylation misc EtPh |
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ddc 540 bkl 35.00 bkl 58.10 bkl 58.00 misc Zeolite misc Reaction Zone misc Ethylbenzene misc Benzene Alkylation misc EtPh |
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Elektronische Aufsätze Aufsätze Elektronische Ressource |
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Russian journal of applied chemistry |
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The processes of benzene alkylation with n-alkenes on the sulfocation exchangers |
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The processes of benzene alkylation with n-alkenes on the sulfocation exchangers |
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Pavlov, O. S. |
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Russian journal of applied chemistry |
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Pavlov, O. S. Chistyakova, T. A. Pavlov, S. Yu. |
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540 ASE 35.00 bkl 58.10 bkl 58.00 bkl |
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Elektronische Aufsätze |
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Pavlov, O. S. |
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10.1134/S1070427209040338 |
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540 |
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verfasserin |
| title_sort |
processes of benzene alkylation with n-alkenes on the sulfocation exchangers |
| title_auth |
The processes of benzene alkylation with n-alkenes on the sulfocation exchangers |
| abstract |
Abstract The processes of benzene alkylation with n-alkenes $ C_{2} $–$ C_{3} $ on sulfocation exchangers are developed. The processes are deprived of the strong corrosion aggressiveness, characteristic of the industrial processes with use of $ AlCl_{3} $ or $ BF_{3} $, and do not need the periodic burning out of the formed contaminants, that is characteristic of the processes with application of zeolites. Alkylation proceeds in the liquid phase at moderate temperatures: 70–90°C in the case of alkylation with propene and n-butenes, and 130°C for the alkylation with ethylene. With the use of alkane-alkene fractions $ C_{2} $–$ C_{3} $ the conversion of alkenes process exceeds 99%, the alkylbenzene to dialkylbenzenes ratio reaches 20–25%. Peralkylation of dialkylbenzenes it not required. |
| abstractGer |
Abstract The processes of benzene alkylation with n-alkenes $ C_{2} $–$ C_{3} $ on sulfocation exchangers are developed. The processes are deprived of the strong corrosion aggressiveness, characteristic of the industrial processes with use of $ AlCl_{3} $ or $ BF_{3} $, and do not need the periodic burning out of the formed contaminants, that is characteristic of the processes with application of zeolites. Alkylation proceeds in the liquid phase at moderate temperatures: 70–90°C in the case of alkylation with propene and n-butenes, and 130°C for the alkylation with ethylene. With the use of alkane-alkene fractions $ C_{2} $–$ C_{3} $ the conversion of alkenes process exceeds 99%, the alkylbenzene to dialkylbenzenes ratio reaches 20–25%. Peralkylation of dialkylbenzenes it not required. |
| abstract_unstemmed |
Abstract The processes of benzene alkylation with n-alkenes $ C_{2} $–$ C_{3} $ on sulfocation exchangers are developed. The processes are deprived of the strong corrosion aggressiveness, characteristic of the industrial processes with use of $ AlCl_{3} $ or $ BF_{3} $, and do not need the periodic burning out of the formed contaminants, that is characteristic of the processes with application of zeolites. Alkylation proceeds in the liquid phase at moderate temperatures: 70–90°C in the case of alkylation with propene and n-butenes, and 130°C for the alkylation with ethylene. With the use of alkane-alkene fractions $ C_{2} $–$ C_{3} $ the conversion of alkenes process exceeds 99%, the alkylbenzene to dialkylbenzenes ratio reaches 20–25%. Peralkylation of dialkylbenzenes it not required. |
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4 |
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The processes of benzene alkylation with n-alkenes on the sulfocation exchangers |
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https://dx.doi.org/10.1134/S1070427209040338 |
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Chistyakova, T. A. Pavlov, S. Yu |
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Chistyakova, T. A. Pavlov, S. Yu |
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| doi_str |
10.1134/S1070427209040338 |
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2024-07-04T02:37:13.948Z |
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|
| score |
7.400526 |