Synthesis and crystal structure of cadmium(II) complex with 2-pyrimidinecarboxamide

Abstract The complex [Cd($ N_{2} %$ H_{3} %$ C_{5} %$ ONH_{2} $)2($ CH_{3} $COO)2] (I) was synthesized and its structure was determined. The crystals are monoclinic: space group C2/c, a = 14/416(1), b = 9.410(1), c = 13.708(1) Å, β = 113.82(1)°, V = 1701.0(1) $ Å^{3} $, ρ(calcd.) = 1.862 g/$ cm^{3}...
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Autor*in:	Kokunov, Yu. V. [verfasserIn] Gorbunova, Yu. E. [verfasserIn] Kovalev, V. V. [verfasserIn] Ivanov, S. V. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2008

Schlagwörter:	Coordination Chemistry Coordination Polyhedron Acetate Group Cadmium Acetate Hydrogen Bonding System

Übergeordnetes Werk:	Enthalten in: Russian journal of coordination chemistry - Moscow : MAIK Nauka/Interperiodica Publ., 2000, 34(2008), 11 vom: 31. Okt., Seite 795-798
Übergeordnetes Werk:	volume:34 ; year:2008 ; number:11 ; day:31 ; month:10 ; pages:795-798

Links:	Volltext

DOI / URN:	10.1134/S1070328408110018

Katalog-ID:	SPR017350514

Internformat


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245	1	0	\|a Synthesis and crystal structure of cadmium(II) complex with 2-pyrimidinecarboxamide
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520			\|a Abstract The complex [Cd($ N_{2} %$ H_{3} %$ C_{5} %$ ONH_{2} $)2($ CH_{3} $COO)2] (I) was synthesized and its structure was determined. The crystals are monoclinic: space group C2/c, a = 14/416(1), b = 9.410(1), c = 13.708(1) Å, β = 113.82(1)°, V = 1701.0(1) $ Å^{3} $, ρ(calcd.) = 1.862 g/$ cm^{3} $, Z = 4. The structure consists of individual complexes I united by the N-H…O hydrogen bonding system into supramolecular framework. The coordination sphere of the cadmium atom (on axis 2) involves two chelate pyrimidinecarboxamide ligands, which form five-membered chelate rings CdOCCN(Cd-N(2) 2.432(4), Cd-O(3) 2.388(4) Å), and two monodentate $ CH_{3} %$ COO^{−} $ ions (Cd-O(1) 2.280(3) Å). The second O atom of the acetate group is involved in a weak contact with the $ Cd^{2+} $ ion (Cd-O 2.670(4) Å). With account for the latter two contacts, the coordination polyhedron of Cd is irregular octahedron.
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700	1		\|a Gorbunova, Yu. E. \|e verfasserin \|4 aut
700	1		\|a Kovalev, V. V. \|e verfasserin \|4 aut
700	1		\|a Ivanov, S. V. \|e verfasserin \|4 aut
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912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
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912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
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912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2116
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2119
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
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912			\|a GBV_ILN_4334
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allfields	10.1134/S1070328408110018 doi (DE-627)SPR017350514 (SPR)S1070328408110018-e DE-627 ger DE-627 rakwb eng 540 ASE 35.43 bkl Kokunov, Yu. V. verfasserin aut Synthesis and crystal structure of cadmium(II) complex with 2-pyrimidinecarboxamide 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The complex [Cd($ N_{2} %$ H_{3} %$ C_{5} %$ ONH_{2} $)2($ CH_{3} $COO)2] (I) was synthesized and its structure was determined. The crystals are monoclinic: space group C2/c, a = 14/416(1), b = 9.410(1), c = 13.708(1) Å, β = 113.82(1)°, V = 1701.0(1) $ Å^{3} $, ρ(calcd.) = 1.862 g/$ cm^{3} $, Z = 4. The structure consists of individual complexes I united by the N-H…O hydrogen bonding system into supramolecular framework. The coordination sphere of the cadmium atom (on axis 2) involves two chelate pyrimidinecarboxamide ligands, which form five-membered chelate rings CdOCCN(Cd-N(2) 2.432(4), Cd-O(3) 2.388(4) Å), and two monodentate $ CH_{3} %$ COO^{−} $ ions (Cd-O(1) 2.280(3) Å). The second O atom of the acetate group is involved in a weak contact with the $ Cd^{2+} $ ion (Cd-O 2.670(4) Å). With account for the latter two contacts, the coordination polyhedron of Cd is irregular octahedron. Coordination Chemistry (dpeaa)DE-He213 Coordination Polyhedron (dpeaa)DE-He213 Acetate Group (dpeaa)DE-He213 Cadmium Acetate (dpeaa)DE-He213 Hydrogen Bonding System (dpeaa)DE-He213 Gorbunova, Yu. E. verfasserin aut Kovalev, V. V. verfasserin aut Ivanov, S. V. verfasserin aut Enthalten in Russian journal of coordination chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2000 34(2008), 11 vom: 31. Okt., Seite 795-798 (DE-627)334712939 (DE-600)2058157-9 1608-3318 nnns volume:34 year:2008 number:11 day:31 month:10 pages:795-798 https://dx.doi.org/10.1134/S1070328408110018 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.43 ASE AR 34 2008 11 31 10 795-798
spelling	10.1134/S1070328408110018 doi (DE-627)SPR017350514 (SPR)S1070328408110018-e DE-627 ger DE-627 rakwb eng 540 ASE 35.43 bkl Kokunov, Yu. V. verfasserin aut Synthesis and crystal structure of cadmium(II) complex with 2-pyrimidinecarboxamide 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The complex [Cd($ N_{2} %$ H_{3} %$ C_{5} %$ ONH_{2} $)2($ CH_{3} $COO)2] (I) was synthesized and its structure was determined. The crystals are monoclinic: space group C2/c, a = 14/416(1), b = 9.410(1), c = 13.708(1) Å, β = 113.82(1)°, V = 1701.0(1) $ Å^{3} $, ρ(calcd.) = 1.862 g/$ cm^{3} $, Z = 4. The structure consists of individual complexes I united by the N-H…O hydrogen bonding system into supramolecular framework. The coordination sphere of the cadmium atom (on axis 2) involves two chelate pyrimidinecarboxamide ligands, which form five-membered chelate rings CdOCCN(Cd-N(2) 2.432(4), Cd-O(3) 2.388(4) Å), and two monodentate $ CH_{3} %$ COO^{−} $ ions (Cd-O(1) 2.280(3) Å). The second O atom of the acetate group is involved in a weak contact with the $ Cd^{2+} $ ion (Cd-O 2.670(4) Å). With account for the latter two contacts, the coordination polyhedron of Cd is irregular octahedron. Coordination Chemistry (dpeaa)DE-He213 Coordination Polyhedron (dpeaa)DE-He213 Acetate Group (dpeaa)DE-He213 Cadmium Acetate (dpeaa)DE-He213 Hydrogen Bonding System (dpeaa)DE-He213 Gorbunova, Yu. E. verfasserin aut Kovalev, V. V. verfasserin aut Ivanov, S. V. verfasserin aut Enthalten in Russian journal of coordination chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2000 34(2008), 11 vom: 31. Okt., Seite 795-798 (DE-627)334712939 (DE-600)2058157-9 1608-3318 nnns volume:34 year:2008 number:11 day:31 month:10 pages:795-798 https://dx.doi.org/10.1134/S1070328408110018 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.43 ASE AR 34 2008 11 31 10 795-798
allfields_unstemmed	10.1134/S1070328408110018 doi (DE-627)SPR017350514 (SPR)S1070328408110018-e DE-627 ger DE-627 rakwb eng 540 ASE 35.43 bkl Kokunov, Yu. V. verfasserin aut Synthesis and crystal structure of cadmium(II) complex with 2-pyrimidinecarboxamide 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The complex [Cd($ N_{2} %$ H_{3} %$ C_{5} %$ ONH_{2} $)2($ CH_{3} $COO)2] (I) was synthesized and its structure was determined. The crystals are monoclinic: space group C2/c, a = 14/416(1), b = 9.410(1), c = 13.708(1) Å, β = 113.82(1)°, V = 1701.0(1) $ Å^{3} $, ρ(calcd.) = 1.862 g/$ cm^{3} $, Z = 4. The structure consists of individual complexes I united by the N-H…O hydrogen bonding system into supramolecular framework. The coordination sphere of the cadmium atom (on axis 2) involves two chelate pyrimidinecarboxamide ligands, which form five-membered chelate rings CdOCCN(Cd-N(2) 2.432(4), Cd-O(3) 2.388(4) Å), and two monodentate $ CH_{3} %$ COO^{−} $ ions (Cd-O(1) 2.280(3) Å). The second O atom of the acetate group is involved in a weak contact with the $ Cd^{2+} $ ion (Cd-O 2.670(4) Å). With account for the latter two contacts, the coordination polyhedron of Cd is irregular octahedron. Coordination Chemistry (dpeaa)DE-He213 Coordination Polyhedron (dpeaa)DE-He213 Acetate Group (dpeaa)DE-He213 Cadmium Acetate (dpeaa)DE-He213 Hydrogen Bonding System (dpeaa)DE-He213 Gorbunova, Yu. E. verfasserin aut Kovalev, V. V. verfasserin aut Ivanov, S. V. verfasserin aut Enthalten in Russian journal of coordination chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2000 34(2008), 11 vom: 31. Okt., Seite 795-798 (DE-627)334712939 (DE-600)2058157-9 1608-3318 nnns volume:34 year:2008 number:11 day:31 month:10 pages:795-798 https://dx.doi.org/10.1134/S1070328408110018 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.43 ASE AR 34 2008 11 31 10 795-798
allfieldsGer	10.1134/S1070328408110018 doi (DE-627)SPR017350514 (SPR)S1070328408110018-e DE-627 ger DE-627 rakwb eng 540 ASE 35.43 bkl Kokunov, Yu. V. verfasserin aut Synthesis and crystal structure of cadmium(II) complex with 2-pyrimidinecarboxamide 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The complex [Cd($ N_{2} %$ H_{3} %$ C_{5} %$ ONH_{2} $)2($ CH_{3} $COO)2] (I) was synthesized and its structure was determined. The crystals are monoclinic: space group C2/c, a = 14/416(1), b = 9.410(1), c = 13.708(1) Å, β = 113.82(1)°, V = 1701.0(1) $ Å^{3} $, ρ(calcd.) = 1.862 g/$ cm^{3} $, Z = 4. The structure consists of individual complexes I united by the N-H…O hydrogen bonding system into supramolecular framework. The coordination sphere of the cadmium atom (on axis 2) involves two chelate pyrimidinecarboxamide ligands, which form five-membered chelate rings CdOCCN(Cd-N(2) 2.432(4), Cd-O(3) 2.388(4) Å), and two monodentate $ CH_{3} %$ COO^{−} $ ions (Cd-O(1) 2.280(3) Å). The second O atom of the acetate group is involved in a weak contact with the $ Cd^{2+} $ ion (Cd-O 2.670(4) Å). With account for the latter two contacts, the coordination polyhedron of Cd is irregular octahedron. Coordination Chemistry (dpeaa)DE-He213 Coordination Polyhedron (dpeaa)DE-He213 Acetate Group (dpeaa)DE-He213 Cadmium Acetate (dpeaa)DE-He213 Hydrogen Bonding System (dpeaa)DE-He213 Gorbunova, Yu. E. verfasserin aut Kovalev, V. V. verfasserin aut Ivanov, S. V. verfasserin aut Enthalten in Russian journal of coordination chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2000 34(2008), 11 vom: 31. Okt., Seite 795-798 (DE-627)334712939 (DE-600)2058157-9 1608-3318 nnns volume:34 year:2008 number:11 day:31 month:10 pages:795-798 https://dx.doi.org/10.1134/S1070328408110018 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.43 ASE AR 34 2008 11 31 10 795-798
allfieldsSound	10.1134/S1070328408110018 doi (DE-627)SPR017350514 (SPR)S1070328408110018-e DE-627 ger DE-627 rakwb eng 540 ASE 35.43 bkl Kokunov, Yu. V. verfasserin aut Synthesis and crystal structure of cadmium(II) complex with 2-pyrimidinecarboxamide 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The complex [Cd($ N_{2} %$ H_{3} %$ C_{5} %$ ONH_{2} $)2($ CH_{3} $COO)2] (I) was synthesized and its structure was determined. The crystals are monoclinic: space group C2/c, a = 14/416(1), b = 9.410(1), c = 13.708(1) Å, β = 113.82(1)°, V = 1701.0(1) $ Å^{3} $, ρ(calcd.) = 1.862 g/$ cm^{3} $, Z = 4. The structure consists of individual complexes I united by the N-H…O hydrogen bonding system into supramolecular framework. The coordination sphere of the cadmium atom (on axis 2) involves two chelate pyrimidinecarboxamide ligands, which form five-membered chelate rings CdOCCN(Cd-N(2) 2.432(4), Cd-O(3) 2.388(4) Å), and two monodentate $ CH_{3} %$ COO^{−} $ ions (Cd-O(1) 2.280(3) Å). The second O atom of the acetate group is involved in a weak contact with the $ Cd^{2+} $ ion (Cd-O 2.670(4) Å). With account for the latter two contacts, the coordination polyhedron of Cd is irregular octahedron. Coordination Chemistry (dpeaa)DE-He213 Coordination Polyhedron (dpeaa)DE-He213 Acetate Group (dpeaa)DE-He213 Cadmium Acetate (dpeaa)DE-He213 Hydrogen Bonding System (dpeaa)DE-He213 Gorbunova, Yu. E. verfasserin aut Kovalev, V. V. verfasserin aut Ivanov, S. V. verfasserin aut Enthalten in Russian journal of coordination chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2000 34(2008), 11 vom: 31. Okt., Seite 795-798 (DE-627)334712939 (DE-600)2058157-9 1608-3318 nnns volume:34 year:2008 number:11 day:31 month:10 pages:795-798 https://dx.doi.org/10.1134/S1070328408110018 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.43 ASE AR 34 2008 11 31 10 795-798
language	English
source	Enthalten in Russian journal of coordination chemistry 34(2008), 11 vom: 31. Okt., Seite 795-798 volume:34 year:2008 number:11 day:31 month:10 pages:795-798
sourceStr	Enthalten in Russian journal of coordination chemistry 34(2008), 11 vom: 31. Okt., Seite 795-798 volume:34 year:2008 number:11 day:31 month:10 pages:795-798
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Coordination Chemistry Coordination Polyhedron Acetate Group Cadmium Acetate Hydrogen Bonding System
dewey-raw	540
isfreeaccess_bool	false
container_title	Russian journal of coordination chemistry
authorswithroles_txt_mv	Kokunov, Yu. V. @@aut@@ Gorbunova, Yu. E. @@aut@@ Kovalev, V. V. @@aut@@ Ivanov, S. V. @@aut@@
publishDateDaySort_date	2008-10-31T00:00:00Z
hierarchy_top_id	334712939
dewey-sort	3540
id	SPR017350514
language_de	englisch
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The crystals are monoclinic: space group C2/c, a = 14/416(1), b = 9.410(1), c = 13.708(1) Å, β = 113.82(1)°, V = 1701.0(1) $ Å^{3} $, ρ(calcd.) = 1.862 g/$ cm^{3} $, Z = 4. The structure consists of individual complexes I united by the N-H…O hydrogen bonding system into supramolecular framework. The coordination sphere of the cadmium atom (on axis 2) involves two chelate pyrimidinecarboxamide ligands, which form five-membered chelate rings CdOCCN(Cd-N(2) 2.432(4), Cd-O(3) 2.388(4) Å), and two monodentate $ CH_{3} %$ COO^{−} $ ions (Cd-O(1) 2.280(3) Å). The second O atom of the acetate group is involved in a weak contact with the $ Cd^{2+} $ ion (Cd-O 2.670(4) Å). 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author	Kokunov, Yu. V.
spellingShingle	Kokunov, Yu. V. ddc 540 bkl 35.43 misc Coordination Chemistry misc Coordination Polyhedron misc Acetate Group misc Cadmium Acetate misc Hydrogen Bonding System Synthesis and crystal structure of cadmium(II) complex with 2-pyrimidinecarboxamide
authorStr	Kokunov, Yu. V.
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topic_title	540 ASE 35.43 bkl Synthesis and crystal structure of cadmium(II) complex with 2-pyrimidinecarboxamide Coordination Chemistry (dpeaa)DE-He213 Coordination Polyhedron (dpeaa)DE-He213 Acetate Group (dpeaa)DE-He213 Cadmium Acetate (dpeaa)DE-He213 Hydrogen Bonding System (dpeaa)DE-He213
topic	ddc 540 bkl 35.43 misc Coordination Chemistry misc Coordination Polyhedron misc Acetate Group misc Cadmium Acetate misc Hydrogen Bonding System
topic_unstemmed	ddc 540 bkl 35.43 misc Coordination Chemistry misc Coordination Polyhedron misc Acetate Group misc Cadmium Acetate misc Hydrogen Bonding System
topic_browse	ddc 540 bkl 35.43 misc Coordination Chemistry misc Coordination Polyhedron misc Acetate Group misc Cadmium Acetate misc Hydrogen Bonding System
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title	Synthesis and crystal structure of cadmium(II) complex with 2-pyrimidinecarboxamide
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title_full	Synthesis and crystal structure of cadmium(II) complex with 2-pyrimidinecarboxamide
author_sort	Kokunov, Yu. V.
journal	Russian journal of coordination chemistry
journalStr	Russian journal of coordination chemistry
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title_sort	synthesis and crystal structure of cadmium(ii) complex with 2-pyrimidinecarboxamide
title_auth	Synthesis and crystal structure of cadmium(II) complex with 2-pyrimidinecarboxamide
abstract	Abstract The complex [Cd($ N_{2} %$ H_{3} %$ C_{5} %$ ONH_{2} $)2($ CH_{3} $COO)2] (I) was synthesized and its structure was determined. The crystals are monoclinic: space group C2/c, a = 14/416(1), b = 9.410(1), c = 13.708(1) Å, β = 113.82(1)°, V = 1701.0(1) $ Å^{3} $, ρ(calcd.) = 1.862 g/$ cm^{3} $, Z = 4. The structure consists of individual complexes I united by the N-H…O hydrogen bonding system into supramolecular framework. The coordination sphere of the cadmium atom (on axis 2) involves two chelate pyrimidinecarboxamide ligands, which form five-membered chelate rings CdOCCN(Cd-N(2) 2.432(4), Cd-O(3) 2.388(4) Å), and two monodentate $ CH_{3} %$ COO^{−} $ ions (Cd-O(1) 2.280(3) Å). The second O atom of the acetate group is involved in a weak contact with the $ Cd^{2+} $ ion (Cd-O 2.670(4) Å). With account for the latter two contacts, the coordination polyhedron of Cd is irregular octahedron.
abstractGer	Abstract The complex [Cd($ N_{2} %$ H_{3} %$ C_{5} %$ ONH_{2} $)2($ CH_{3} $COO)2] (I) was synthesized and its structure was determined. The crystals are monoclinic: space group C2/c, a = 14/416(1), b = 9.410(1), c = 13.708(1) Å, β = 113.82(1)°, V = 1701.0(1) $ Å^{3} $, ρ(calcd.) = 1.862 g/$ cm^{3} $, Z = 4. The structure consists of individual complexes I united by the N-H…O hydrogen bonding system into supramolecular framework. The coordination sphere of the cadmium atom (on axis 2) involves two chelate pyrimidinecarboxamide ligands, which form five-membered chelate rings CdOCCN(Cd-N(2) 2.432(4), Cd-O(3) 2.388(4) Å), and two monodentate $ CH_{3} %$ COO^{−} $ ions (Cd-O(1) 2.280(3) Å). The second O atom of the acetate group is involved in a weak contact with the $ Cd^{2+} $ ion (Cd-O 2.670(4) Å). With account for the latter two contacts, the coordination polyhedron of Cd is irregular octahedron.
abstract_unstemmed	Abstract The complex [Cd($ N_{2} %$ H_{3} %$ C_{5} %$ ONH_{2} $)2($ CH_{3} $COO)2] (I) was synthesized and its structure was determined. The crystals are monoclinic: space group C2/c, a = 14/416(1), b = 9.410(1), c = 13.708(1) Å, β = 113.82(1)°, V = 1701.0(1) $ Å^{3} $, ρ(calcd.) = 1.862 g/$ cm^{3} $, Z = 4. The structure consists of individual complexes I united by the N-H…O hydrogen bonding system into supramolecular framework. The coordination sphere of the cadmium atom (on axis 2) involves two chelate pyrimidinecarboxamide ligands, which form five-membered chelate rings CdOCCN(Cd-N(2) 2.432(4), Cd-O(3) 2.388(4) Å), and two monodentate $ CH_{3} %$ COO^{−} $ ions (Cd-O(1) 2.280(3) Å). The second O atom of the acetate group is involved in a weak contact with the $ Cd^{2+} $ ion (Cd-O 2.670(4) Å). With account for the latter two contacts, the coordination polyhedron of Cd is irregular octahedron.
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container_issue	11
title_short	Synthesis and crystal structure of cadmium(II) complex with 2-pyrimidinecarboxamide
url	https://dx.doi.org/10.1134/S1070328408110018
remote_bool	true
author2	Gorbunova, Yu. E. Kovalev, V. V. Ivanov, S. V.
author2Str	Gorbunova, Yu. E. Kovalev, V. V. Ivanov, S. V.
ppnlink	334712939
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doi_str	10.1134/S1070328408110018
up_date	2024-07-04T03:04:35.426Z
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Synthesis and crystal structure of cadmium(II) complex with 2-pyrimidinecarboxamide

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