Considering the polynuclear complexes in the ionic equilibria of the $ Pb^{2+} $-$ H_{2} $O system
Abstract Analysis of conditions of the lead hydroxide and sulfide formation in the $ Pb^{2+} $-$ H_{2} $O system was carried out with accounting for the formation of polynuclear hydroxo-complexes. This allows predicting a possibility of the lead hydroxide formation in the solution before the beginni...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Kozhevnikova, N. S. [verfasserIn] Sadovnikov, S. I. [verfasserIn] Uritskaya, A. A. [verfasserIn] Gusev, A. I. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2012 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Russian journal of general chemistry - Dordrecht : Springer Science + Business Media B.V., 1996, 82(2012), 4 vom: Apr., Seite 626-634 |
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| Übergeordnetes Werk: |
volume:82 ; year:2012 ; number:4 ; month:04 ; pages:626-634 |
| Links: |
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| DOI / URN: |
10.1134/S1070363212040020 |
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| Katalog-ID: |
SPR017418429 |
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| 245 | 1 | 0 | |a Considering the polynuclear complexes in the ionic equilibria of the $ Pb^{2+} $-$ H_{2} $O system |
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| 520 | |a Abstract Analysis of conditions of the lead hydroxide and sulfide formation in the $ Pb^{2+} $-$ H_{2} $O system was carried out with accounting for the formation of polynuclear hydroxo-complexes. This allows predicting a possibility of the lead hydroxide formation in the solution before the beginning of the synthesis of lead sulfide. The domains of the stable formation of Pb(OH)2 and PbS were calculated for the systems containing lead citrate complexes and hydroxo-complexes. The proposed calculation method can be used for the quantitative determination of the reaction mixture composition and development of the chemical deposition technology of lead chalcogenides in different morphological forms: nanocrystalline powders (hydrophobic sol), quantum dots, heterostructures of the coreshell type or films. The proposed calculation method is applicable to other chalcogenide systems containing metal ions forming mononuclear and polynuclear hydroxo-complexes. | ||
| 650 | 4 | |a General Chemistry |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Metal Sulfide |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Metal Hydroxide |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Lead Sulfide |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Thiocarbamide |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Sadovnikov, S. I. |e verfasserin |4 aut | |
| 700 | 1 | |a Uritskaya, A. A. |e verfasserin |4 aut | |
| 700 | 1 | |a Gusev, A. I. |e verfasserin |4 aut | |
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10.1134/S1070363212040020 doi (DE-627)SPR017418429 (SPR)S1070363212040020-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Kozhevnikova, N. S. verfasserin aut Considering the polynuclear complexes in the ionic equilibria of the $ Pb^{2+} $-$ H_{2} $O system 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Analysis of conditions of the lead hydroxide and sulfide formation in the $ Pb^{2+} $-$ H_{2} $O system was carried out with accounting for the formation of polynuclear hydroxo-complexes. This allows predicting a possibility of the lead hydroxide formation in the solution before the beginning of the synthesis of lead sulfide. The domains of the stable formation of Pb(OH)2 and PbS were calculated for the systems containing lead citrate complexes and hydroxo-complexes. The proposed calculation method can be used for the quantitative determination of the reaction mixture composition and development of the chemical deposition technology of lead chalcogenides in different morphological forms: nanocrystalline powders (hydrophobic sol), quantum dots, heterostructures of the coreshell type or films. The proposed calculation method is applicable to other chalcogenide systems containing metal ions forming mononuclear and polynuclear hydroxo-complexes. General Chemistry (dpeaa)DE-He213 Metal Sulfide (dpeaa)DE-He213 Metal Hydroxide (dpeaa)DE-He213 Lead Sulfide (dpeaa)DE-He213 Thiocarbamide (dpeaa)DE-He213 Sadovnikov, S. I. verfasserin aut Uritskaya, A. A. verfasserin aut Gusev, A. I. verfasserin aut Enthalten in Russian journal of general chemistry Dordrecht : Springer Science + Business Media B.V., 1996 82(2012), 4 vom: Apr., Seite 626-634 (DE-627)340146834 (DE-600)2065665-8 1608-3350 nnns volume:82 year:2012 number:4 month:04 pages:626-634 https://dx.doi.org/10.1134/S1070363212040020 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 82 2012 4 04 626-634 |
| spelling |
10.1134/S1070363212040020 doi (DE-627)SPR017418429 (SPR)S1070363212040020-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Kozhevnikova, N. S. verfasserin aut Considering the polynuclear complexes in the ionic equilibria of the $ Pb^{2+} $-$ H_{2} $O system 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Analysis of conditions of the lead hydroxide and sulfide formation in the $ Pb^{2+} $-$ H_{2} $O system was carried out with accounting for the formation of polynuclear hydroxo-complexes. This allows predicting a possibility of the lead hydroxide formation in the solution before the beginning of the synthesis of lead sulfide. The domains of the stable formation of Pb(OH)2 and PbS were calculated for the systems containing lead citrate complexes and hydroxo-complexes. The proposed calculation method can be used for the quantitative determination of the reaction mixture composition and development of the chemical deposition technology of lead chalcogenides in different morphological forms: nanocrystalline powders (hydrophobic sol), quantum dots, heterostructures of the coreshell type or films. The proposed calculation method is applicable to other chalcogenide systems containing metal ions forming mononuclear and polynuclear hydroxo-complexes. General Chemistry (dpeaa)DE-He213 Metal Sulfide (dpeaa)DE-He213 Metal Hydroxide (dpeaa)DE-He213 Lead Sulfide (dpeaa)DE-He213 Thiocarbamide (dpeaa)DE-He213 Sadovnikov, S. I. verfasserin aut Uritskaya, A. A. verfasserin aut Gusev, A. I. verfasserin aut Enthalten in Russian journal of general chemistry Dordrecht : Springer Science + Business Media B.V., 1996 82(2012), 4 vom: Apr., Seite 626-634 (DE-627)340146834 (DE-600)2065665-8 1608-3350 nnns volume:82 year:2012 number:4 month:04 pages:626-634 https://dx.doi.org/10.1134/S1070363212040020 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 82 2012 4 04 626-634 |
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10.1134/S1070363212040020 doi (DE-627)SPR017418429 (SPR)S1070363212040020-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Kozhevnikova, N. S. verfasserin aut Considering the polynuclear complexes in the ionic equilibria of the $ Pb^{2+} $-$ H_{2} $O system 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Analysis of conditions of the lead hydroxide and sulfide formation in the $ Pb^{2+} $-$ H_{2} $O system was carried out with accounting for the formation of polynuclear hydroxo-complexes. This allows predicting a possibility of the lead hydroxide formation in the solution before the beginning of the synthesis of lead sulfide. The domains of the stable formation of Pb(OH)2 and PbS were calculated for the systems containing lead citrate complexes and hydroxo-complexes. The proposed calculation method can be used for the quantitative determination of the reaction mixture composition and development of the chemical deposition technology of lead chalcogenides in different morphological forms: nanocrystalline powders (hydrophobic sol), quantum dots, heterostructures of the coreshell type or films. The proposed calculation method is applicable to other chalcogenide systems containing metal ions forming mononuclear and polynuclear hydroxo-complexes. General Chemistry (dpeaa)DE-He213 Metal Sulfide (dpeaa)DE-He213 Metal Hydroxide (dpeaa)DE-He213 Lead Sulfide (dpeaa)DE-He213 Thiocarbamide (dpeaa)DE-He213 Sadovnikov, S. I. verfasserin aut Uritskaya, A. A. verfasserin aut Gusev, A. I. verfasserin aut Enthalten in Russian journal of general chemistry Dordrecht : Springer Science + Business Media B.V., 1996 82(2012), 4 vom: Apr., Seite 626-634 (DE-627)340146834 (DE-600)2065665-8 1608-3350 nnns volume:82 year:2012 number:4 month:04 pages:626-634 https://dx.doi.org/10.1134/S1070363212040020 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 82 2012 4 04 626-634 |
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10.1134/S1070363212040020 doi (DE-627)SPR017418429 (SPR)S1070363212040020-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Kozhevnikova, N. S. verfasserin aut Considering the polynuclear complexes in the ionic equilibria of the $ Pb^{2+} $-$ H_{2} $O system 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Analysis of conditions of the lead hydroxide and sulfide formation in the $ Pb^{2+} $-$ H_{2} $O system was carried out with accounting for the formation of polynuclear hydroxo-complexes. This allows predicting a possibility of the lead hydroxide formation in the solution before the beginning of the synthesis of lead sulfide. The domains of the stable formation of Pb(OH)2 and PbS were calculated for the systems containing lead citrate complexes and hydroxo-complexes. The proposed calculation method can be used for the quantitative determination of the reaction mixture composition and development of the chemical deposition technology of lead chalcogenides in different morphological forms: nanocrystalline powders (hydrophobic sol), quantum dots, heterostructures of the coreshell type or films. The proposed calculation method is applicable to other chalcogenide systems containing metal ions forming mononuclear and polynuclear hydroxo-complexes. General Chemistry (dpeaa)DE-He213 Metal Sulfide (dpeaa)DE-He213 Metal Hydroxide (dpeaa)DE-He213 Lead Sulfide (dpeaa)DE-He213 Thiocarbamide (dpeaa)DE-He213 Sadovnikov, S. I. verfasserin aut Uritskaya, A. A. verfasserin aut Gusev, A. I. verfasserin aut Enthalten in Russian journal of general chemistry Dordrecht : Springer Science + Business Media B.V., 1996 82(2012), 4 vom: Apr., Seite 626-634 (DE-627)340146834 (DE-600)2065665-8 1608-3350 nnns volume:82 year:2012 number:4 month:04 pages:626-634 https://dx.doi.org/10.1134/S1070363212040020 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 82 2012 4 04 626-634 |
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10.1134/S1070363212040020 doi (DE-627)SPR017418429 (SPR)S1070363212040020-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Kozhevnikova, N. S. verfasserin aut Considering the polynuclear complexes in the ionic equilibria of the $ Pb^{2+} $-$ H_{2} $O system 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Analysis of conditions of the lead hydroxide and sulfide formation in the $ Pb^{2+} $-$ H_{2} $O system was carried out with accounting for the formation of polynuclear hydroxo-complexes. This allows predicting a possibility of the lead hydroxide formation in the solution before the beginning of the synthesis of lead sulfide. The domains of the stable formation of Pb(OH)2 and PbS were calculated for the systems containing lead citrate complexes and hydroxo-complexes. The proposed calculation method can be used for the quantitative determination of the reaction mixture composition and development of the chemical deposition technology of lead chalcogenides in different morphological forms: nanocrystalline powders (hydrophobic sol), quantum dots, heterostructures of the coreshell type or films. The proposed calculation method is applicable to other chalcogenide systems containing metal ions forming mononuclear and polynuclear hydroxo-complexes. General Chemistry (dpeaa)DE-He213 Metal Sulfide (dpeaa)DE-He213 Metal Hydroxide (dpeaa)DE-He213 Lead Sulfide (dpeaa)DE-He213 Thiocarbamide (dpeaa)DE-He213 Sadovnikov, S. I. verfasserin aut Uritskaya, A. A. verfasserin aut Gusev, A. I. verfasserin aut Enthalten in Russian journal of general chemistry Dordrecht : Springer Science + Business Media B.V., 1996 82(2012), 4 vom: Apr., Seite 626-634 (DE-627)340146834 (DE-600)2065665-8 1608-3350 nnns volume:82 year:2012 number:4 month:04 pages:626-634 https://dx.doi.org/10.1134/S1070363212040020 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 82 2012 4 04 626-634 |
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Enthalten in Russian journal of general chemistry 82(2012), 4 vom: Apr., Seite 626-634 volume:82 year:2012 number:4 month:04 pages:626-634 |
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General Chemistry Metal Sulfide Metal Hydroxide Lead Sulfide Thiocarbamide |
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Russian journal of general chemistry |
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Kozhevnikova, N. S. @@aut@@ Sadovnikov, S. I. @@aut@@ Uritskaya, A. A. @@aut@@ Gusev, A. I. @@aut@@ |
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| author |
Kozhevnikova, N. S. |
| spellingShingle |
Kozhevnikova, N. S. ddc 540 bkl 35.00 misc General Chemistry misc Metal Sulfide misc Metal Hydroxide misc Lead Sulfide misc Thiocarbamide Considering the polynuclear complexes in the ionic equilibria of the $ Pb^{2+} $-$ H_{2} $O system |
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1608-3350 |
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540 ASE 35.00 bkl Considering the polynuclear complexes in the ionic equilibria of the $ Pb^{2+} $-$ H_{2} $O system General Chemistry (dpeaa)DE-He213 Metal Sulfide (dpeaa)DE-He213 Metal Hydroxide (dpeaa)DE-He213 Lead Sulfide (dpeaa)DE-He213 Thiocarbamide (dpeaa)DE-He213 |
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ddc 540 bkl 35.00 misc General Chemistry misc Metal Sulfide misc Metal Hydroxide misc Lead Sulfide misc Thiocarbamide |
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ddc 540 bkl 35.00 misc General Chemistry misc Metal Sulfide misc Metal Hydroxide misc Lead Sulfide misc Thiocarbamide |
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ddc 540 bkl 35.00 misc General Chemistry misc Metal Sulfide misc Metal Hydroxide misc Lead Sulfide misc Thiocarbamide |
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Elektronische Aufsätze Aufsätze Elektronische Ressource |
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Considering the polynuclear complexes in the ionic equilibria of the $ Pb^{2+} $-$ H_{2} $O system |
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(DE-627)SPR017418429 (SPR)S1070363212040020-e |
| title_full |
Considering the polynuclear complexes in the ionic equilibria of the $ Pb^{2+} $-$ H_{2} $O system |
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Kozhevnikova, N. S. |
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Russian journal of general chemistry |
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2012 |
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626 |
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Kozhevnikova, N. S. Sadovnikov, S. I. Uritskaya, A. A. Gusev, A. I. |
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82 |
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540 ASE 35.00 bkl |
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Elektronische Aufsätze |
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Kozhevnikova, N. S. |
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10.1134/S1070363212040020 |
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540 |
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verfasserin |
| title_sort |
considering the polynuclear complexes in the ionic equilibria of the $ pb^{2+} $-$ h_{2} $o system |
| title_auth |
Considering the polynuclear complexes in the ionic equilibria of the $ Pb^{2+} $-$ H_{2} $O system |
| abstract |
Abstract Analysis of conditions of the lead hydroxide and sulfide formation in the $ Pb^{2+} $-$ H_{2} $O system was carried out with accounting for the formation of polynuclear hydroxo-complexes. This allows predicting a possibility of the lead hydroxide formation in the solution before the beginning of the synthesis of lead sulfide. The domains of the stable formation of Pb(OH)2 and PbS were calculated for the systems containing lead citrate complexes and hydroxo-complexes. The proposed calculation method can be used for the quantitative determination of the reaction mixture composition and development of the chemical deposition technology of lead chalcogenides in different morphological forms: nanocrystalline powders (hydrophobic sol), quantum dots, heterostructures of the coreshell type or films. The proposed calculation method is applicable to other chalcogenide systems containing metal ions forming mononuclear and polynuclear hydroxo-complexes. |
| abstractGer |
Abstract Analysis of conditions of the lead hydroxide and sulfide formation in the $ Pb^{2+} $-$ H_{2} $O system was carried out with accounting for the formation of polynuclear hydroxo-complexes. This allows predicting a possibility of the lead hydroxide formation in the solution before the beginning of the synthesis of lead sulfide. The domains of the stable formation of Pb(OH)2 and PbS were calculated for the systems containing lead citrate complexes and hydroxo-complexes. The proposed calculation method can be used for the quantitative determination of the reaction mixture composition and development of the chemical deposition technology of lead chalcogenides in different morphological forms: nanocrystalline powders (hydrophobic sol), quantum dots, heterostructures of the coreshell type or films. The proposed calculation method is applicable to other chalcogenide systems containing metal ions forming mononuclear and polynuclear hydroxo-complexes. |
| abstract_unstemmed |
Abstract Analysis of conditions of the lead hydroxide and sulfide formation in the $ Pb^{2+} $-$ H_{2} $O system was carried out with accounting for the formation of polynuclear hydroxo-complexes. This allows predicting a possibility of the lead hydroxide formation in the solution before the beginning of the synthesis of lead sulfide. The domains of the stable formation of Pb(OH)2 and PbS were calculated for the systems containing lead citrate complexes and hydroxo-complexes. The proposed calculation method can be used for the quantitative determination of the reaction mixture composition and development of the chemical deposition technology of lead chalcogenides in different morphological forms: nanocrystalline powders (hydrophobic sol), quantum dots, heterostructures of the coreshell type or films. The proposed calculation method is applicable to other chalcogenide systems containing metal ions forming mononuclear and polynuclear hydroxo-complexes. |
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| title_short |
Considering the polynuclear complexes in the ionic equilibria of the $ Pb^{2+} $-$ H_{2} $O system |
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https://dx.doi.org/10.1134/S1070363212040020 |
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Sadovnikov, S. I. Uritskaya, A. A. Gusev, A. I. |
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Sadovnikov, S. I. Uritskaya, A. A. Gusev, A. I. |
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| doi_str |
10.1134/S1070363212040020 |
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2024-07-04T03:18:09.256Z |
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| score |
7.3998165 |