Thermal decomposition of ammonia borane at 357 K
Abstract The heat effect of ammonia borane decomposition at 357 K under atmospheric pressure in glass and copper cells has been determined by calorimetry. The enthalpy of $ BH_{3} %$ NH_{3} $ heat-induced decomposition in glass ampoules is of–24.8±2.3 kJ/mol; this value includes the structural reorg...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Butlak, A. V. [verfasserIn] Kondrat’ev, Yu. V. [verfasserIn] Mazur, A. S. [verfasserIn] Timoshkin, A. Yu. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2015 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Russian journal of general chemistry - Dordrecht : Springer Science + Business Media B.V., 1996, 85(2015), 11 vom: Nov., Seite 2505-2508 |
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| Übergeordnetes Werk: |
volume:85 ; year:2015 ; number:11 ; month:11 ; pages:2505-2508 |
| Links: |
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| DOI / URN: |
10.1134/S1070363215110018 |
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| Katalog-ID: |
SPR017430925 |
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| 520 | |a Abstract The heat effect of ammonia borane decomposition at 357 K under atmospheric pressure in glass and copper cells has been determined by calorimetry. The enthalpy of $ BH_{3} %$ NH_{3} $ heat-induced decomposition in glass ampoules is of–24.8±2.3 kJ/mol; this value includes the structural reorganization into diammoniate of diborane of–4.0±2.8 kJ/mol and the thermal effect of decomposition into polyamidoborane of–20.8±1.6 kJ/mol. In the case of experiments in copper cells a much higher (–47.6±8.3 kJ/mol) heat evolution is observed. The solidstate 15N and 11B NMR analysis of samples after the calorimetric experiment has shown that partial oxidation of the sample into boric acid occurs in copper cells. | ||
| 650 | 4 | |a ammonia borane |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a thermal decomposition |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a calorimetry |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a solid-state NMR |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Kondrat’ev, Yu. V. |e verfasserin |4 aut | |
| 700 | 1 | |a Mazur, A. S. |e verfasserin |4 aut | |
| 700 | 1 | |a Timoshkin, A. Yu. |e verfasserin |4 aut | |
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10.1134/S1070363215110018 doi (DE-627)SPR017430925 (SPR)S1070363215110018-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Butlak, A. V. verfasserin aut Thermal decomposition of ammonia borane at 357 K 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The heat effect of ammonia borane decomposition at 357 K under atmospheric pressure in glass and copper cells has been determined by calorimetry. The enthalpy of $ BH_{3} %$ NH_{3} $ heat-induced decomposition in glass ampoules is of–24.8±2.3 kJ/mol; this value includes the structural reorganization into diammoniate of diborane of–4.0±2.8 kJ/mol and the thermal effect of decomposition into polyamidoborane of–20.8±1.6 kJ/mol. In the case of experiments in copper cells a much higher (–47.6±8.3 kJ/mol) heat evolution is observed. The solidstate 15N and 11B NMR analysis of samples after the calorimetric experiment has shown that partial oxidation of the sample into boric acid occurs in copper cells. ammonia borane (dpeaa)DE-He213 thermal decomposition (dpeaa)DE-He213 calorimetry (dpeaa)DE-He213 solid-state NMR (dpeaa)DE-He213 Kondrat’ev, Yu. V. verfasserin aut Mazur, A. S. verfasserin aut Timoshkin, A. Yu. verfasserin aut Enthalten in Russian journal of general chemistry Dordrecht : Springer Science + Business Media B.V., 1996 85(2015), 11 vom: Nov., Seite 2505-2508 (DE-627)340146834 (DE-600)2065665-8 1608-3350 nnns volume:85 year:2015 number:11 month:11 pages:2505-2508 https://dx.doi.org/10.1134/S1070363215110018 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 85 2015 11 11 2505-2508 |
| spelling |
10.1134/S1070363215110018 doi (DE-627)SPR017430925 (SPR)S1070363215110018-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Butlak, A. V. verfasserin aut Thermal decomposition of ammonia borane at 357 K 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The heat effect of ammonia borane decomposition at 357 K under atmospheric pressure in glass and copper cells has been determined by calorimetry. The enthalpy of $ BH_{3} %$ NH_{3} $ heat-induced decomposition in glass ampoules is of–24.8±2.3 kJ/mol; this value includes the structural reorganization into diammoniate of diborane of–4.0±2.8 kJ/mol and the thermal effect of decomposition into polyamidoborane of–20.8±1.6 kJ/mol. In the case of experiments in copper cells a much higher (–47.6±8.3 kJ/mol) heat evolution is observed. The solidstate 15N and 11B NMR analysis of samples after the calorimetric experiment has shown that partial oxidation of the sample into boric acid occurs in copper cells. ammonia borane (dpeaa)DE-He213 thermal decomposition (dpeaa)DE-He213 calorimetry (dpeaa)DE-He213 solid-state NMR (dpeaa)DE-He213 Kondrat’ev, Yu. V. verfasserin aut Mazur, A. S. verfasserin aut Timoshkin, A. Yu. verfasserin aut Enthalten in Russian journal of general chemistry Dordrecht : Springer Science + Business Media B.V., 1996 85(2015), 11 vom: Nov., Seite 2505-2508 (DE-627)340146834 (DE-600)2065665-8 1608-3350 nnns volume:85 year:2015 number:11 month:11 pages:2505-2508 https://dx.doi.org/10.1134/S1070363215110018 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 85 2015 11 11 2505-2508 |
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10.1134/S1070363215110018 doi (DE-627)SPR017430925 (SPR)S1070363215110018-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Butlak, A. V. verfasserin aut Thermal decomposition of ammonia borane at 357 K 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The heat effect of ammonia borane decomposition at 357 K under atmospheric pressure in glass and copper cells has been determined by calorimetry. The enthalpy of $ BH_{3} %$ NH_{3} $ heat-induced decomposition in glass ampoules is of–24.8±2.3 kJ/mol; this value includes the structural reorganization into diammoniate of diborane of–4.0±2.8 kJ/mol and the thermal effect of decomposition into polyamidoborane of–20.8±1.6 kJ/mol. In the case of experiments in copper cells a much higher (–47.6±8.3 kJ/mol) heat evolution is observed. The solidstate 15N and 11B NMR analysis of samples after the calorimetric experiment has shown that partial oxidation of the sample into boric acid occurs in copper cells. ammonia borane (dpeaa)DE-He213 thermal decomposition (dpeaa)DE-He213 calorimetry (dpeaa)DE-He213 solid-state NMR (dpeaa)DE-He213 Kondrat’ev, Yu. V. verfasserin aut Mazur, A. S. verfasserin aut Timoshkin, A. Yu. verfasserin aut Enthalten in Russian journal of general chemistry Dordrecht : Springer Science + Business Media B.V., 1996 85(2015), 11 vom: Nov., Seite 2505-2508 (DE-627)340146834 (DE-600)2065665-8 1608-3350 nnns volume:85 year:2015 number:11 month:11 pages:2505-2508 https://dx.doi.org/10.1134/S1070363215110018 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 85 2015 11 11 2505-2508 |
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10.1134/S1070363215110018 doi (DE-627)SPR017430925 (SPR)S1070363215110018-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Butlak, A. V. verfasserin aut Thermal decomposition of ammonia borane at 357 K 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The heat effect of ammonia borane decomposition at 357 K under atmospheric pressure in glass and copper cells has been determined by calorimetry. The enthalpy of $ BH_{3} %$ NH_{3} $ heat-induced decomposition in glass ampoules is of–24.8±2.3 kJ/mol; this value includes the structural reorganization into diammoniate of diborane of–4.0±2.8 kJ/mol and the thermal effect of decomposition into polyamidoborane of–20.8±1.6 kJ/mol. In the case of experiments in copper cells a much higher (–47.6±8.3 kJ/mol) heat evolution is observed. The solidstate 15N and 11B NMR analysis of samples after the calorimetric experiment has shown that partial oxidation of the sample into boric acid occurs in copper cells. ammonia borane (dpeaa)DE-He213 thermal decomposition (dpeaa)DE-He213 calorimetry (dpeaa)DE-He213 solid-state NMR (dpeaa)DE-He213 Kondrat’ev, Yu. V. verfasserin aut Mazur, A. S. verfasserin aut Timoshkin, A. Yu. verfasserin aut Enthalten in Russian journal of general chemistry Dordrecht : Springer Science + Business Media B.V., 1996 85(2015), 11 vom: Nov., Seite 2505-2508 (DE-627)340146834 (DE-600)2065665-8 1608-3350 nnns volume:85 year:2015 number:11 month:11 pages:2505-2508 https://dx.doi.org/10.1134/S1070363215110018 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 85 2015 11 11 2505-2508 |
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10.1134/S1070363215110018 doi (DE-627)SPR017430925 (SPR)S1070363215110018-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Butlak, A. V. verfasserin aut Thermal decomposition of ammonia borane at 357 K 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The heat effect of ammonia borane decomposition at 357 K under atmospheric pressure in glass and copper cells has been determined by calorimetry. The enthalpy of $ BH_{3} %$ NH_{3} $ heat-induced decomposition in glass ampoules is of–24.8±2.3 kJ/mol; this value includes the structural reorganization into diammoniate of diborane of–4.0±2.8 kJ/mol and the thermal effect of decomposition into polyamidoborane of–20.8±1.6 kJ/mol. In the case of experiments in copper cells a much higher (–47.6±8.3 kJ/mol) heat evolution is observed. The solidstate 15N and 11B NMR analysis of samples after the calorimetric experiment has shown that partial oxidation of the sample into boric acid occurs in copper cells. ammonia borane (dpeaa)DE-He213 thermal decomposition (dpeaa)DE-He213 calorimetry (dpeaa)DE-He213 solid-state NMR (dpeaa)DE-He213 Kondrat’ev, Yu. V. verfasserin aut Mazur, A. S. verfasserin aut Timoshkin, A. Yu. verfasserin aut Enthalten in Russian journal of general chemistry Dordrecht : Springer Science + Business Media B.V., 1996 85(2015), 11 vom: Nov., Seite 2505-2508 (DE-627)340146834 (DE-600)2065665-8 1608-3350 nnns volume:85 year:2015 number:11 month:11 pages:2505-2508 https://dx.doi.org/10.1134/S1070363215110018 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 85 2015 11 11 2505-2508 |
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Butlak, A. V. @@aut@@ Kondrat’ev, Yu. V. @@aut@@ Mazur, A. S. @@aut@@ Timoshkin, A. Yu. @@aut@@ |
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| author |
Butlak, A. V. |
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Butlak, A. V. ddc 540 bkl 35.00 misc ammonia borane misc thermal decomposition misc calorimetry misc solid-state NMR Thermal decomposition of ammonia borane at 357 K |
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540 ASE 35.00 bkl Thermal decomposition of ammonia borane at 357 K ammonia borane (dpeaa)DE-He213 thermal decomposition (dpeaa)DE-He213 calorimetry (dpeaa)DE-He213 solid-state NMR (dpeaa)DE-He213 |
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ddc 540 bkl 35.00 misc ammonia borane misc thermal decomposition misc calorimetry misc solid-state NMR |
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ddc 540 bkl 35.00 misc ammonia borane misc thermal decomposition misc calorimetry misc solid-state NMR |
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ddc 540 bkl 35.00 misc ammonia borane misc thermal decomposition misc calorimetry misc solid-state NMR |
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Elektronische Aufsätze Aufsätze Elektronische Ressource |
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Thermal decomposition of ammonia borane at 357 K |
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Thermal decomposition of ammonia borane at 357 K |
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Butlak, A. V. |
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Butlak, A. V. Kondrat’ev, Yu. V. Mazur, A. S. Timoshkin, A. Yu. |
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thermal decomposition of ammonia borane at 357 k |
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Thermal decomposition of ammonia borane at 357 K |
| abstract |
Abstract The heat effect of ammonia borane decomposition at 357 K under atmospheric pressure in glass and copper cells has been determined by calorimetry. The enthalpy of $ BH_{3} %$ NH_{3} $ heat-induced decomposition in glass ampoules is of–24.8±2.3 kJ/mol; this value includes the structural reorganization into diammoniate of diborane of–4.0±2.8 kJ/mol and the thermal effect of decomposition into polyamidoborane of–20.8±1.6 kJ/mol. In the case of experiments in copper cells a much higher (–47.6±8.3 kJ/mol) heat evolution is observed. The solidstate 15N and 11B NMR analysis of samples after the calorimetric experiment has shown that partial oxidation of the sample into boric acid occurs in copper cells. |
| abstractGer |
Abstract The heat effect of ammonia borane decomposition at 357 K under atmospheric pressure in glass and copper cells has been determined by calorimetry. The enthalpy of $ BH_{3} %$ NH_{3} $ heat-induced decomposition in glass ampoules is of–24.8±2.3 kJ/mol; this value includes the structural reorganization into diammoniate of diborane of–4.0±2.8 kJ/mol and the thermal effect of decomposition into polyamidoborane of–20.8±1.6 kJ/mol. In the case of experiments in copper cells a much higher (–47.6±8.3 kJ/mol) heat evolution is observed. The solidstate 15N and 11B NMR analysis of samples after the calorimetric experiment has shown that partial oxidation of the sample into boric acid occurs in copper cells. |
| abstract_unstemmed |
Abstract The heat effect of ammonia borane decomposition at 357 K under atmospheric pressure in glass and copper cells has been determined by calorimetry. The enthalpy of $ BH_{3} %$ NH_{3} $ heat-induced decomposition in glass ampoules is of–24.8±2.3 kJ/mol; this value includes the structural reorganization into diammoniate of diborane of–4.0±2.8 kJ/mol and the thermal effect of decomposition into polyamidoborane of–20.8±1.6 kJ/mol. In the case of experiments in copper cells a much higher (–47.6±8.3 kJ/mol) heat evolution is observed. The solidstate 15N and 11B NMR analysis of samples after the calorimetric experiment has shown that partial oxidation of the sample into boric acid occurs in copper cells. |
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Thermal decomposition of ammonia borane at 357 K |
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https://dx.doi.org/10.1134/S1070363215110018 |
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Kondrat’ev, Yu. V. Mazur, A. S. Timoshkin, A. Yu |
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Kondrat’ev, Yu. V. Mazur, A. S. Timoshkin, A. Yu |
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10.1134/S1070363215110018 |
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2024-07-04T03:20:33.210Z |
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| score |
7.4002647 |