On the possibility of homolytic addition of N-bromohexamethyldisilazane to the triple carbon–carbon bond

Abstract By an example of a reaction of N-bromohexamethyldisilazane with phenylacetylene the possibility of its homolytic addition to the triple carbon-carbon bond with the formation of a mixture of the corresponding E- and Z-isomers in the ratio of 1.2 : 1 was shown.

Gespeichert in:
Autor*in:

Rakhlin, V. I. [verfasserIn]

Tsyrendorzhieva, I. P. [verfasserIn]

Albanov, A. I. [verfasserIn]

Format:

E-Artikel

Sprache:

Englisch

Erschienen:

2017

Schlagwörter:

homolytic addition

-bromohexamethyldisilazane

phenylacetylene

Übergeordnetes Werk:

Enthalten in: Russian journal of general chemistry - Dordrecht : Springer Science + Business Media B.V., 1996, 87(2017), 4 vom: Apr., Seite 880-881

Übergeordnetes Werk:

volume:87 ; year:2017 ; number:4 ; month:04 ; pages:880-881

Links:

Volltext

DOI / URN:

10.1134/S1070363217040351

Katalog-ID:

SPR017443245

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