Features of the Formation of the [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] Complex in the Malic Acid Oxidation Process
Abstract Complex [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] was obtained on the basis of $ V_{2} %$ O_{5} $ and malic acid in the presence of concentrated $ HNO_{3} $ and phenanthroline. Its structure was determined by the X-ray structural analysis; its magnetic susceptibility was measure...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Panina, N. S. [verfasserIn] Nikandrov, E. M. [verfasserIn] Laptenkova, A. V. [verfasserIn] Selyutin, A. A. [verfasserIn] Ruzanov, D. O. [verfasserIn] Belyaev, A. N. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2019 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Russian journal of general chemistry - Dordrecht : Springer Science + Business Media B.V., 1996, 89(2019), 4 vom: Apr., Seite 741-746 |
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| Übergeordnetes Werk: |
volume:89 ; year:2019 ; number:4 ; month:04 ; pages:741-746 |
| Links: |
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| DOI / URN: |
10.1134/S1070363219040170 |
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| Katalog-ID: |
SPR017452856 |
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| 245 | 1 | 0 | |a Features of the Formation of the [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] Complex in the Malic Acid Oxidation Process |
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| 520 | |a Abstract Complex [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] was obtained on the basis of $ V_{2} %$ O_{5} $ and malic acid in the presence of concentrated $ HNO_{3} $ and phenanthroline. Its structure was determined by the X-ray structural analysis; its magnetic susceptibility was measured. The role of the %$\rm{VO}^+_2%$ and $ VO^{2+} $ cations in the oxidation and complex-formation processes was considered. A method for the conversion of malic acid to oxalate anions through the formation of oxaloacetic acid and the intermediate products of its decarboxylation reactions was proposed. It was shown by the DFT M06/6-31G(d,p) method that the transition state energy decreases in the way of the HOC(O)C(0)$ CH_{2} $-COOH bond breakage during decarboxylation compared with the free acid in the intermediate of its anion with $ VO^{2+} $. | ||
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| 650 | 4 | |a carboxylic acids |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a decarboxylation |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a DFT modeling |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Nikandrov, E. M. |e verfasserin |4 aut | |
| 700 | 1 | |a Laptenkova, A. V. |e verfasserin |4 aut | |
| 700 | 1 | |a Selyutin, A. A. |e verfasserin |4 aut | |
| 700 | 1 | |a Ruzanov, D. O. |e verfasserin |4 aut | |
| 700 | 1 | |a Belyaev, A. N. |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Russian journal of general chemistry |d Dordrecht : Springer Science + Business Media B.V., 1996 |g 89(2019), 4 vom: Apr., Seite 741-746 |w (DE-627)340146834 |w (DE-600)2065665-8 |x 1608-3350 |7 nnns |
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10.1134/S1070363219040170 doi (DE-627)SPR017452856 (SPR)S1070363219040170-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Panina, N. S. verfasserin aut Features of the Formation of the [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] Complex in the Malic Acid Oxidation Process 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Complex [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] was obtained on the basis of $ V_{2} %$ O_{5} $ and malic acid in the presence of concentrated $ HNO_{3} $ and phenanthroline. Its structure was determined by the X-ray structural analysis; its magnetic susceptibility was measured. The role of the %$\rm{VO}^+_2%$ and $ VO^{2+} $ cations in the oxidation and complex-formation processes was considered. A method for the conversion of malic acid to oxalate anions through the formation of oxaloacetic acid and the intermediate products of its decarboxylation reactions was proposed. It was shown by the DFT M06/6-31G(d,p) method that the transition state energy decreases in the way of the HOC(O)C(0)$ CH_{2} $-COOH bond breakage during decarboxylation compared with the free acid in the intermediate of its anion with $ VO^{2+} $. vanadium (dpeaa)DE-He213 carboxylic acids (dpeaa)DE-He213 decarboxylation (dpeaa)DE-He213 DFT modeling (dpeaa)DE-He213 Nikandrov, E. M. verfasserin aut Laptenkova, A. V. verfasserin aut Selyutin, A. A. verfasserin aut Ruzanov, D. O. verfasserin aut Belyaev, A. N. verfasserin aut Enthalten in Russian journal of general chemistry Dordrecht : Springer Science + Business Media B.V., 1996 89(2019), 4 vom: Apr., Seite 741-746 (DE-627)340146834 (DE-600)2065665-8 1608-3350 nnns volume:89 year:2019 number:4 month:04 pages:741-746 https://dx.doi.org/10.1134/S1070363219040170 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 89 2019 4 04 741-746 |
| spelling |
10.1134/S1070363219040170 doi (DE-627)SPR017452856 (SPR)S1070363219040170-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Panina, N. S. verfasserin aut Features of the Formation of the [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] Complex in the Malic Acid Oxidation Process 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Complex [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] was obtained on the basis of $ V_{2} %$ O_{5} $ and malic acid in the presence of concentrated $ HNO_{3} $ and phenanthroline. Its structure was determined by the X-ray structural analysis; its magnetic susceptibility was measured. The role of the %$\rm{VO}^+_2%$ and $ VO^{2+} $ cations in the oxidation and complex-formation processes was considered. A method for the conversion of malic acid to oxalate anions through the formation of oxaloacetic acid and the intermediate products of its decarboxylation reactions was proposed. It was shown by the DFT M06/6-31G(d,p) method that the transition state energy decreases in the way of the HOC(O)C(0)$ CH_{2} $-COOH bond breakage during decarboxylation compared with the free acid in the intermediate of its anion with $ VO^{2+} $. vanadium (dpeaa)DE-He213 carboxylic acids (dpeaa)DE-He213 decarboxylation (dpeaa)DE-He213 DFT modeling (dpeaa)DE-He213 Nikandrov, E. M. verfasserin aut Laptenkova, A. V. verfasserin aut Selyutin, A. A. verfasserin aut Ruzanov, D. O. verfasserin aut Belyaev, A. N. verfasserin aut Enthalten in Russian journal of general chemistry Dordrecht : Springer Science + Business Media B.V., 1996 89(2019), 4 vom: Apr., Seite 741-746 (DE-627)340146834 (DE-600)2065665-8 1608-3350 nnns volume:89 year:2019 number:4 month:04 pages:741-746 https://dx.doi.org/10.1134/S1070363219040170 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 89 2019 4 04 741-746 |
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10.1134/S1070363219040170 doi (DE-627)SPR017452856 (SPR)S1070363219040170-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Panina, N. S. verfasserin aut Features of the Formation of the [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] Complex in the Malic Acid Oxidation Process 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Complex [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] was obtained on the basis of $ V_{2} %$ O_{5} $ and malic acid in the presence of concentrated $ HNO_{3} $ and phenanthroline. Its structure was determined by the X-ray structural analysis; its magnetic susceptibility was measured. The role of the %$\rm{VO}^+_2%$ and $ VO^{2+} $ cations in the oxidation and complex-formation processes was considered. A method for the conversion of malic acid to oxalate anions through the formation of oxaloacetic acid and the intermediate products of its decarboxylation reactions was proposed. It was shown by the DFT M06/6-31G(d,p) method that the transition state energy decreases in the way of the HOC(O)C(0)$ CH_{2} $-COOH bond breakage during decarboxylation compared with the free acid in the intermediate of its anion with $ VO^{2+} $. vanadium (dpeaa)DE-He213 carboxylic acids (dpeaa)DE-He213 decarboxylation (dpeaa)DE-He213 DFT modeling (dpeaa)DE-He213 Nikandrov, E. M. verfasserin aut Laptenkova, A. V. verfasserin aut Selyutin, A. A. verfasserin aut Ruzanov, D. O. verfasserin aut Belyaev, A. N. verfasserin aut Enthalten in Russian journal of general chemistry Dordrecht : Springer Science + Business Media B.V., 1996 89(2019), 4 vom: Apr., Seite 741-746 (DE-627)340146834 (DE-600)2065665-8 1608-3350 nnns volume:89 year:2019 number:4 month:04 pages:741-746 https://dx.doi.org/10.1134/S1070363219040170 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 89 2019 4 04 741-746 |
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10.1134/S1070363219040170 doi (DE-627)SPR017452856 (SPR)S1070363219040170-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Panina, N. S. verfasserin aut Features of the Formation of the [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] Complex in the Malic Acid Oxidation Process 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Complex [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] was obtained on the basis of $ V_{2} %$ O_{5} $ and malic acid in the presence of concentrated $ HNO_{3} $ and phenanthroline. Its structure was determined by the X-ray structural analysis; its magnetic susceptibility was measured. The role of the %$\rm{VO}^+_2%$ and $ VO^{2+} $ cations in the oxidation and complex-formation processes was considered. A method for the conversion of malic acid to oxalate anions through the formation of oxaloacetic acid and the intermediate products of its decarboxylation reactions was proposed. It was shown by the DFT M06/6-31G(d,p) method that the transition state energy decreases in the way of the HOC(O)C(0)$ CH_{2} $-COOH bond breakage during decarboxylation compared with the free acid in the intermediate of its anion with $ VO^{2+} $. vanadium (dpeaa)DE-He213 carboxylic acids (dpeaa)DE-He213 decarboxylation (dpeaa)DE-He213 DFT modeling (dpeaa)DE-He213 Nikandrov, E. M. verfasserin aut Laptenkova, A. V. verfasserin aut Selyutin, A. A. verfasserin aut Ruzanov, D. O. verfasserin aut Belyaev, A. N. verfasserin aut Enthalten in Russian journal of general chemistry Dordrecht : Springer Science + Business Media B.V., 1996 89(2019), 4 vom: Apr., Seite 741-746 (DE-627)340146834 (DE-600)2065665-8 1608-3350 nnns volume:89 year:2019 number:4 month:04 pages:741-746 https://dx.doi.org/10.1134/S1070363219040170 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 89 2019 4 04 741-746 |
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10.1134/S1070363219040170 doi (DE-627)SPR017452856 (SPR)S1070363219040170-e DE-627 ger DE-627 rakwb eng 540 ASE 35.00 bkl Panina, N. S. verfasserin aut Features of the Formation of the [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] Complex in the Malic Acid Oxidation Process 2019 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Complex [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] was obtained on the basis of $ V_{2} %$ O_{5} $ and malic acid in the presence of concentrated $ HNO_{3} $ and phenanthroline. Its structure was determined by the X-ray structural analysis; its magnetic susceptibility was measured. The role of the %$\rm{VO}^+_2%$ and $ VO^{2+} $ cations in the oxidation and complex-formation processes was considered. A method for the conversion of malic acid to oxalate anions through the formation of oxaloacetic acid and the intermediate products of its decarboxylation reactions was proposed. It was shown by the DFT M06/6-31G(d,p) method that the transition state energy decreases in the way of the HOC(O)C(0)$ CH_{2} $-COOH bond breakage during decarboxylation compared with the free acid in the intermediate of its anion with $ VO^{2+} $. vanadium (dpeaa)DE-He213 carboxylic acids (dpeaa)DE-He213 decarboxylation (dpeaa)DE-He213 DFT modeling (dpeaa)DE-He213 Nikandrov, E. M. verfasserin aut Laptenkova, A. V. verfasserin aut Selyutin, A. A. verfasserin aut Ruzanov, D. O. verfasserin aut Belyaev, A. N. verfasserin aut Enthalten in Russian journal of general chemistry Dordrecht : Springer Science + Business Media B.V., 1996 89(2019), 4 vom: Apr., Seite 741-746 (DE-627)340146834 (DE-600)2065665-8 1608-3350 nnns volume:89 year:2019 number:4 month:04 pages:741-746 https://dx.doi.org/10.1134/S1070363219040170 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 89 2019 4 04 741-746 |
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vanadium carboxylic acids decarboxylation DFT modeling |
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Panina, N. S. @@aut@@ Nikandrov, E. M. @@aut@@ Laptenkova, A. V. @@aut@@ Selyutin, A. A. @@aut@@ Ruzanov, D. O. @@aut@@ Belyaev, A. N. @@aut@@ |
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S.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Features of the Formation of the [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] Complex in the Malic Acid Oxidation Process</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2019</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Complex [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] was obtained on the basis of $ V_{2} %$ O_{5} $ and malic acid in the presence of concentrated $ HNO_{3} $ and phenanthroline. Its structure was determined by the X-ray structural analysis; its magnetic susceptibility was measured. The role of the %$\rm{VO}^+_2%$ and $ VO^{2+} $ cations in the oxidation and complex-formation processes was considered. A method for the conversion of malic acid to oxalate anions through the formation of oxaloacetic acid and the intermediate products of its decarboxylation reactions was proposed. It was shown by the DFT M06/6-31G(d,p) method that the transition state energy decreases in the way of the HOC(O)C(0)$ CH_{2} $-COOH bond breakage during decarboxylation compared with the free acid in the intermediate of its anion with $ VO^{2+} $.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">vanadium</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">carboxylic acids</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">decarboxylation</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">DFT modeling</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Nikandrov, E. 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|
| author |
Panina, N. S. |
| spellingShingle |
Panina, N. S. ddc 540 bkl 35.00 misc vanadium misc carboxylic acids misc decarboxylation misc DFT modeling Features of the Formation of the [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] Complex in the Malic Acid Oxidation Process |
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Panina, N. S. |
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1608-3350 |
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540 ASE 35.00 bkl Features of the Formation of the [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] Complex in the Malic Acid Oxidation Process vanadium (dpeaa)DE-He213 carboxylic acids (dpeaa)DE-He213 decarboxylation (dpeaa)DE-He213 DFT modeling (dpeaa)DE-He213 |
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ddc 540 bkl 35.00 misc vanadium misc carboxylic acids misc decarboxylation misc DFT modeling |
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ddc 540 bkl 35.00 misc vanadium misc carboxylic acids misc decarboxylation misc DFT modeling |
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ddc 540 bkl 35.00 misc vanadium misc carboxylic acids misc decarboxylation misc DFT modeling |
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Russian journal of general chemistry |
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Features of the Formation of the [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] Complex in the Malic Acid Oxidation Process |
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(DE-627)SPR017452856 (SPR)S1070363219040170-e |
| title_full |
Features of the Formation of the [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] Complex in the Malic Acid Oxidation Process |
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Panina, N. S. |
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Russian journal of general chemistry |
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Russian journal of general chemistry |
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eng |
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500 - Science |
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2019 |
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741 |
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Panina, N. S. Nikandrov, E. M. Laptenkova, A. V. Selyutin, A. A. Ruzanov, D. O. Belyaev, A. N. |
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540 ASE 35.00 bkl |
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Elektronische Aufsätze |
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Panina, N. S. |
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10.1134/S1070363219040170 |
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540 |
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verfasserin |
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features of the formation of the [(o)$ v^{iv} $($ c_{2} %$ o_{4} $)(phen)($ h_{2} $o)] complex in the malic acid oxidation process |
| title_auth |
Features of the Formation of the [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] Complex in the Malic Acid Oxidation Process |
| abstract |
Abstract Complex [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] was obtained on the basis of $ V_{2} %$ O_{5} $ and malic acid in the presence of concentrated $ HNO_{3} $ and phenanthroline. Its structure was determined by the X-ray structural analysis; its magnetic susceptibility was measured. The role of the %$\rm{VO}^+_2%$ and $ VO^{2+} $ cations in the oxidation and complex-formation processes was considered. A method for the conversion of malic acid to oxalate anions through the formation of oxaloacetic acid and the intermediate products of its decarboxylation reactions was proposed. It was shown by the DFT M06/6-31G(d,p) method that the transition state energy decreases in the way of the HOC(O)C(0)$ CH_{2} $-COOH bond breakage during decarboxylation compared with the free acid in the intermediate of its anion with $ VO^{2+} $. |
| abstractGer |
Abstract Complex [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] was obtained on the basis of $ V_{2} %$ O_{5} $ and malic acid in the presence of concentrated $ HNO_{3} $ and phenanthroline. Its structure was determined by the X-ray structural analysis; its magnetic susceptibility was measured. The role of the %$\rm{VO}^+_2%$ and $ VO^{2+} $ cations in the oxidation and complex-formation processes was considered. A method for the conversion of malic acid to oxalate anions through the formation of oxaloacetic acid and the intermediate products of its decarboxylation reactions was proposed. It was shown by the DFT M06/6-31G(d,p) method that the transition state energy decreases in the way of the HOC(O)C(0)$ CH_{2} $-COOH bond breakage during decarboxylation compared with the free acid in the intermediate of its anion with $ VO^{2+} $. |
| abstract_unstemmed |
Abstract Complex [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] was obtained on the basis of $ V_{2} %$ O_{5} $ and malic acid in the presence of concentrated $ HNO_{3} $ and phenanthroline. Its structure was determined by the X-ray structural analysis; its magnetic susceptibility was measured. The role of the %$\rm{VO}^+_2%$ and $ VO^{2+} $ cations in the oxidation and complex-formation processes was considered. A method for the conversion of malic acid to oxalate anions through the formation of oxaloacetic acid and the intermediate products of its decarboxylation reactions was proposed. It was shown by the DFT M06/6-31G(d,p) method that the transition state energy decreases in the way of the HOC(O)C(0)$ CH_{2} $-COOH bond breakage during decarboxylation compared with the free acid in the intermediate of its anion with $ VO^{2+} $. |
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4 |
| title_short |
Features of the Formation of the [(O)$ V^{IV} $($ C_{2} %$ O_{4} $)(Phen)($ H_{2} $O)] Complex in the Malic Acid Oxidation Process |
| url |
https://dx.doi.org/10.1134/S1070363219040170 |
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| author2 |
Nikandrov, E. M. Laptenkova, A. V. Selyutin, A. A. Ruzanov, D. O. Belyaev, A. N. |
| author2Str |
Nikandrov, E. M. Laptenkova, A. V. Selyutin, A. A. Ruzanov, D. O. Belyaev, A. N. |
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340146834 |
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| doi_str |
10.1134/S1070363219040170 |
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2024-07-04T03:24:53.235Z |
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1803617297487626240 |
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| score |
7.401127 |