Properties of the Triplet State of Coumarin Substituted Compounds
The absorption spectra of the triplet excited state of coumarin sensitizers are investigated both theoretically and experimentally. The most intense triplet-triplet (TT) absorption bands are determined. The experimental spectra of the T-T absorption are compared with the theoretical T-T transitions....
Ausführliche Beschreibung
Autor*in: |
Bryantseva, N. G. [verfasserIn] Gadirov, R. M. [verfasserIn] Nikonov, S. Yu. [verfasserIn] Sokolova, I. V. [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2015 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Russian physics journal - New York, NY [u.a.] : Consultants Bureau, 1965, 57(2015), 11 vom: März, Seite 1532-1538 |
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Übergeordnetes Werk: |
volume:57 ; year:2015 ; number:11 ; month:03 ; pages:1532-1538 |
Links: |
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DOI / URN: |
10.1007/s11182-015-0415-y |
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Katalog-ID: |
SPR017631661 |
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520 | |a The absorption spectra of the triplet excited state of coumarin sensitizers are investigated both theoretically and experimentally. The most intense triplet-triplet (TT) absorption bands are determined. The experimental spectra of the T-T absorption are compared with the theoretical T-T transitions. The phosphorescence spectra of five compounds are measured at a temperature of 77 K. The quantum phosphorescence yield is determined by the method of comparison with an etalon (8-methoxypsoralen). The phosphorescence lifetime is determined for the examined molecules at a temperature of 77 K. For 3,4-phenyl-4',5'-cyclohexylpsoralen, 4'-methyl-3,4-cycloheptylpsoralen, and 4'5'-dimethyl-3,4-cyclohexylpsoralen compounds, this time is equal to 1.1, 1.25, and 2.5 s, respectively. The main energy deactivation channel for all examined compounds is the phosphorescence. The positions of the lower excited triplet states, calculated by the quantum-chemical method of intermediate neglect of differential overlap with spectroscopic parameterization (INDO/S), are confirmed by the available experimental data. | ||
650 | 4 | |a substituted coumarin (psoralen) |7 (dpeaa)DE-He213 | |
650 | 4 | |a triplet-triplet absorption |7 (dpeaa)DE-He213 | |
650 | 4 | |a phosphorescence |7 (dpeaa)DE-He213 | |
650 | 4 | |a phosphorescence quantum yield |7 (dpeaa)DE-He213 | |
650 | 4 | |a phosphorescence lifetime |7 (dpeaa)DE-He213 | |
700 | 1 | |a Gadirov, R. M. |e verfasserin |4 aut | |
700 | 1 | |a Nikonov, S. Yu. |e verfasserin |4 aut | |
700 | 1 | |a Sokolova, I. V. |e verfasserin |4 aut | |
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10.1007/s11182-015-0415-y doi (DE-627)SPR017631661 (SPR)s11182-015-0415-y-e DE-627 ger DE-627 rakwb eng 370 530 ASE 33.00 bkl Bryantseva, N. G. verfasserin aut Properties of the Triplet State of Coumarin Substituted Compounds 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The absorption spectra of the triplet excited state of coumarin sensitizers are investigated both theoretically and experimentally. The most intense triplet-triplet (TT) absorption bands are determined. The experimental spectra of the T-T absorption are compared with the theoretical T-T transitions. The phosphorescence spectra of five compounds are measured at a temperature of 77 K. The quantum phosphorescence yield is determined by the method of comparison with an etalon (8-methoxypsoralen). The phosphorescence lifetime is determined for the examined molecules at a temperature of 77 K. For 3,4-phenyl-4',5'-cyclohexylpsoralen, 4'-methyl-3,4-cycloheptylpsoralen, and 4'5'-dimethyl-3,4-cyclohexylpsoralen compounds, this time is equal to 1.1, 1.25, and 2.5 s, respectively. The main energy deactivation channel for all examined compounds is the phosphorescence. The positions of the lower excited triplet states, calculated by the quantum-chemical method of intermediate neglect of differential overlap with spectroscopic parameterization (INDO/S), are confirmed by the available experimental data. substituted coumarin (psoralen) (dpeaa)DE-He213 triplet-triplet absorption (dpeaa)DE-He213 phosphorescence (dpeaa)DE-He213 phosphorescence quantum yield (dpeaa)DE-He213 phosphorescence lifetime (dpeaa)DE-He213 Gadirov, R. M. verfasserin aut Nikonov, S. Yu. verfasserin aut Sokolova, I. V. verfasserin aut Enthalten in Russian physics journal New York, NY [u.a.] : Consultants Bureau, 1965 57(2015), 11 vom: März, Seite 1532-1538 (DE-627)325572518 (DE-600)2037572-4 1573-9228 nnns volume:57 year:2015 number:11 month:03 pages:1532-1538 https://dx.doi.org/10.1007/s11182-015-0415-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 57 2015 11 03 1532-1538 |
spelling |
10.1007/s11182-015-0415-y doi (DE-627)SPR017631661 (SPR)s11182-015-0415-y-e DE-627 ger DE-627 rakwb eng 370 530 ASE 33.00 bkl Bryantseva, N. G. verfasserin aut Properties of the Triplet State of Coumarin Substituted Compounds 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The absorption spectra of the triplet excited state of coumarin sensitizers are investigated both theoretically and experimentally. The most intense triplet-triplet (TT) absorption bands are determined. The experimental spectra of the T-T absorption are compared with the theoretical T-T transitions. The phosphorescence spectra of five compounds are measured at a temperature of 77 K. The quantum phosphorescence yield is determined by the method of comparison with an etalon (8-methoxypsoralen). The phosphorescence lifetime is determined for the examined molecules at a temperature of 77 K. For 3,4-phenyl-4',5'-cyclohexylpsoralen, 4'-methyl-3,4-cycloheptylpsoralen, and 4'5'-dimethyl-3,4-cyclohexylpsoralen compounds, this time is equal to 1.1, 1.25, and 2.5 s, respectively. The main energy deactivation channel for all examined compounds is the phosphorescence. The positions of the lower excited triplet states, calculated by the quantum-chemical method of intermediate neglect of differential overlap with spectroscopic parameterization (INDO/S), are confirmed by the available experimental data. substituted coumarin (psoralen) (dpeaa)DE-He213 triplet-triplet absorption (dpeaa)DE-He213 phosphorescence (dpeaa)DE-He213 phosphorescence quantum yield (dpeaa)DE-He213 phosphorescence lifetime (dpeaa)DE-He213 Gadirov, R. M. verfasserin aut Nikonov, S. Yu. verfasserin aut Sokolova, I. V. verfasserin aut Enthalten in Russian physics journal New York, NY [u.a.] : Consultants Bureau, 1965 57(2015), 11 vom: März, Seite 1532-1538 (DE-627)325572518 (DE-600)2037572-4 1573-9228 nnns volume:57 year:2015 number:11 month:03 pages:1532-1538 https://dx.doi.org/10.1007/s11182-015-0415-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 57 2015 11 03 1532-1538 |
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10.1007/s11182-015-0415-y doi (DE-627)SPR017631661 (SPR)s11182-015-0415-y-e DE-627 ger DE-627 rakwb eng 370 530 ASE 33.00 bkl Bryantseva, N. G. verfasserin aut Properties of the Triplet State of Coumarin Substituted Compounds 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The absorption spectra of the triplet excited state of coumarin sensitizers are investigated both theoretically and experimentally. The most intense triplet-triplet (TT) absorption bands are determined. The experimental spectra of the T-T absorption are compared with the theoretical T-T transitions. The phosphorescence spectra of five compounds are measured at a temperature of 77 K. The quantum phosphorescence yield is determined by the method of comparison with an etalon (8-methoxypsoralen). The phosphorescence lifetime is determined for the examined molecules at a temperature of 77 K. For 3,4-phenyl-4',5'-cyclohexylpsoralen, 4'-methyl-3,4-cycloheptylpsoralen, and 4'5'-dimethyl-3,4-cyclohexylpsoralen compounds, this time is equal to 1.1, 1.25, and 2.5 s, respectively. The main energy deactivation channel for all examined compounds is the phosphorescence. The positions of the lower excited triplet states, calculated by the quantum-chemical method of intermediate neglect of differential overlap with spectroscopic parameterization (INDO/S), are confirmed by the available experimental data. substituted coumarin (psoralen) (dpeaa)DE-He213 triplet-triplet absorption (dpeaa)DE-He213 phosphorescence (dpeaa)DE-He213 phosphorescence quantum yield (dpeaa)DE-He213 phosphorescence lifetime (dpeaa)DE-He213 Gadirov, R. M. verfasserin aut Nikonov, S. Yu. verfasserin aut Sokolova, I. V. verfasserin aut Enthalten in Russian physics journal New York, NY [u.a.] : Consultants Bureau, 1965 57(2015), 11 vom: März, Seite 1532-1538 (DE-627)325572518 (DE-600)2037572-4 1573-9228 nnns volume:57 year:2015 number:11 month:03 pages:1532-1538 https://dx.doi.org/10.1007/s11182-015-0415-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 57 2015 11 03 1532-1538 |
allfieldsGer |
10.1007/s11182-015-0415-y doi (DE-627)SPR017631661 (SPR)s11182-015-0415-y-e DE-627 ger DE-627 rakwb eng 370 530 ASE 33.00 bkl Bryantseva, N. G. verfasserin aut Properties of the Triplet State of Coumarin Substituted Compounds 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The absorption spectra of the triplet excited state of coumarin sensitizers are investigated both theoretically and experimentally. The most intense triplet-triplet (TT) absorption bands are determined. The experimental spectra of the T-T absorption are compared with the theoretical T-T transitions. The phosphorescence spectra of five compounds are measured at a temperature of 77 K. The quantum phosphorescence yield is determined by the method of comparison with an etalon (8-methoxypsoralen). The phosphorescence lifetime is determined for the examined molecules at a temperature of 77 K. For 3,4-phenyl-4',5'-cyclohexylpsoralen, 4'-methyl-3,4-cycloheptylpsoralen, and 4'5'-dimethyl-3,4-cyclohexylpsoralen compounds, this time is equal to 1.1, 1.25, and 2.5 s, respectively. The main energy deactivation channel for all examined compounds is the phosphorescence. The positions of the lower excited triplet states, calculated by the quantum-chemical method of intermediate neglect of differential overlap with spectroscopic parameterization (INDO/S), are confirmed by the available experimental data. substituted coumarin (psoralen) (dpeaa)DE-He213 triplet-triplet absorption (dpeaa)DE-He213 phosphorescence (dpeaa)DE-He213 phosphorescence quantum yield (dpeaa)DE-He213 phosphorescence lifetime (dpeaa)DE-He213 Gadirov, R. M. verfasserin aut Nikonov, S. Yu. verfasserin aut Sokolova, I. V. verfasserin aut Enthalten in Russian physics journal New York, NY [u.a.] : Consultants Bureau, 1965 57(2015), 11 vom: März, Seite 1532-1538 (DE-627)325572518 (DE-600)2037572-4 1573-9228 nnns volume:57 year:2015 number:11 month:03 pages:1532-1538 https://dx.doi.org/10.1007/s11182-015-0415-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 57 2015 11 03 1532-1538 |
allfieldsSound |
10.1007/s11182-015-0415-y doi (DE-627)SPR017631661 (SPR)s11182-015-0415-y-e DE-627 ger DE-627 rakwb eng 370 530 ASE 33.00 bkl Bryantseva, N. G. verfasserin aut Properties of the Triplet State of Coumarin Substituted Compounds 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The absorption spectra of the triplet excited state of coumarin sensitizers are investigated both theoretically and experimentally. The most intense triplet-triplet (TT) absorption bands are determined. The experimental spectra of the T-T absorption are compared with the theoretical T-T transitions. The phosphorescence spectra of five compounds are measured at a temperature of 77 K. The quantum phosphorescence yield is determined by the method of comparison with an etalon (8-methoxypsoralen). The phosphorescence lifetime is determined for the examined molecules at a temperature of 77 K. For 3,4-phenyl-4',5'-cyclohexylpsoralen, 4'-methyl-3,4-cycloheptylpsoralen, and 4'5'-dimethyl-3,4-cyclohexylpsoralen compounds, this time is equal to 1.1, 1.25, and 2.5 s, respectively. The main energy deactivation channel for all examined compounds is the phosphorescence. The positions of the lower excited triplet states, calculated by the quantum-chemical method of intermediate neglect of differential overlap with spectroscopic parameterization (INDO/S), are confirmed by the available experimental data. substituted coumarin (psoralen) (dpeaa)DE-He213 triplet-triplet absorption (dpeaa)DE-He213 phosphorescence (dpeaa)DE-He213 phosphorescence quantum yield (dpeaa)DE-He213 phosphorescence lifetime (dpeaa)DE-He213 Gadirov, R. M. verfasserin aut Nikonov, S. Yu. verfasserin aut Sokolova, I. V. verfasserin aut Enthalten in Russian physics journal New York, NY [u.a.] : Consultants Bureau, 1965 57(2015), 11 vom: März, Seite 1532-1538 (DE-627)325572518 (DE-600)2037572-4 1573-9228 nnns volume:57 year:2015 number:11 month:03 pages:1532-1538 https://dx.doi.org/10.1007/s11182-015-0415-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 ASE AR 57 2015 11 03 1532-1538 |
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Enthalten in Russian physics journal 57(2015), 11 vom: März, Seite 1532-1538 volume:57 year:2015 number:11 month:03 pages:1532-1538 |
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Enthalten in Russian physics journal 57(2015), 11 vom: März, Seite 1532-1538 volume:57 year:2015 number:11 month:03 pages:1532-1538 |
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substituted coumarin (psoralen) triplet-triplet absorption phosphorescence phosphorescence quantum yield phosphorescence lifetime |
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Bryantseva, N. G. @@aut@@ Gadirov, R. M. @@aut@@ Nikonov, S. Yu. @@aut@@ Sokolova, I. V. @@aut@@ |
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The most intense triplet-triplet (TT) absorption bands are determined. The experimental spectra of the T-T absorption are compared with the theoretical T-T transitions. The phosphorescence spectra of five compounds are measured at a temperature of 77 K. The quantum phosphorescence yield is determined by the method of comparison with an etalon (8-methoxypsoralen). The phosphorescence lifetime is determined for the examined molecules at a temperature of 77 K. For 3,4-phenyl-4',5'-cyclohexylpsoralen, 4'-methyl-3,4-cycloheptylpsoralen, and 4'5'-dimethyl-3,4-cyclohexylpsoralen compounds, this time is equal to 1.1, 1.25, and 2.5 s, respectively. The main energy deactivation channel for all examined compounds is the phosphorescence. 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author |
Bryantseva, N. G. |
spellingShingle |
Bryantseva, N. G. ddc 370 bkl 33.00 misc substituted coumarin (psoralen) misc triplet-triplet absorption misc phosphorescence misc phosphorescence quantum yield misc phosphorescence lifetime Properties of the Triplet State of Coumarin Substituted Compounds |
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370 530 ASE 33.00 bkl Properties of the Triplet State of Coumarin Substituted Compounds substituted coumarin (psoralen) (dpeaa)DE-He213 triplet-triplet absorption (dpeaa)DE-He213 phosphorescence (dpeaa)DE-He213 phosphorescence quantum yield (dpeaa)DE-He213 phosphorescence lifetime (dpeaa)DE-He213 |
topic |
ddc 370 bkl 33.00 misc substituted coumarin (psoralen) misc triplet-triplet absorption misc phosphorescence misc phosphorescence quantum yield misc phosphorescence lifetime |
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ddc 370 bkl 33.00 misc substituted coumarin (psoralen) misc triplet-triplet absorption misc phosphorescence misc phosphorescence quantum yield misc phosphorescence lifetime |
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Properties of the Triplet State of Coumarin Substituted Compounds |
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Properties of the Triplet State of Coumarin Substituted Compounds |
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Bryantseva, N. G. Gadirov, R. M. Nikonov, S. Yu. Sokolova, I. V. |
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properties of the triplet state of coumarin substituted compounds |
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Properties of the Triplet State of Coumarin Substituted Compounds |
abstract |
The absorption spectra of the triplet excited state of coumarin sensitizers are investigated both theoretically and experimentally. The most intense triplet-triplet (TT) absorption bands are determined. The experimental spectra of the T-T absorption are compared with the theoretical T-T transitions. The phosphorescence spectra of five compounds are measured at a temperature of 77 K. The quantum phosphorescence yield is determined by the method of comparison with an etalon (8-methoxypsoralen). The phosphorescence lifetime is determined for the examined molecules at a temperature of 77 K. For 3,4-phenyl-4',5'-cyclohexylpsoralen, 4'-methyl-3,4-cycloheptylpsoralen, and 4'5'-dimethyl-3,4-cyclohexylpsoralen compounds, this time is equal to 1.1, 1.25, and 2.5 s, respectively. The main energy deactivation channel for all examined compounds is the phosphorescence. The positions of the lower excited triplet states, calculated by the quantum-chemical method of intermediate neglect of differential overlap with spectroscopic parameterization (INDO/S), are confirmed by the available experimental data. |
abstractGer |
The absorption spectra of the triplet excited state of coumarin sensitizers are investigated both theoretically and experimentally. The most intense triplet-triplet (TT) absorption bands are determined. The experimental spectra of the T-T absorption are compared with the theoretical T-T transitions. The phosphorescence spectra of five compounds are measured at a temperature of 77 K. The quantum phosphorescence yield is determined by the method of comparison with an etalon (8-methoxypsoralen). The phosphorescence lifetime is determined for the examined molecules at a temperature of 77 K. For 3,4-phenyl-4',5'-cyclohexylpsoralen, 4'-methyl-3,4-cycloheptylpsoralen, and 4'5'-dimethyl-3,4-cyclohexylpsoralen compounds, this time is equal to 1.1, 1.25, and 2.5 s, respectively. The main energy deactivation channel for all examined compounds is the phosphorescence. The positions of the lower excited triplet states, calculated by the quantum-chemical method of intermediate neglect of differential overlap with spectroscopic parameterization (INDO/S), are confirmed by the available experimental data. |
abstract_unstemmed |
The absorption spectra of the triplet excited state of coumarin sensitizers are investigated both theoretically and experimentally. The most intense triplet-triplet (TT) absorption bands are determined. The experimental spectra of the T-T absorption are compared with the theoretical T-T transitions. The phosphorescence spectra of five compounds are measured at a temperature of 77 K. The quantum phosphorescence yield is determined by the method of comparison with an etalon (8-methoxypsoralen). The phosphorescence lifetime is determined for the examined molecules at a temperature of 77 K. For 3,4-phenyl-4',5'-cyclohexylpsoralen, 4'-methyl-3,4-cycloheptylpsoralen, and 4'5'-dimethyl-3,4-cyclohexylpsoralen compounds, this time is equal to 1.1, 1.25, and 2.5 s, respectively. The main energy deactivation channel for all examined compounds is the phosphorescence. The positions of the lower excited triplet states, calculated by the quantum-chemical method of intermediate neglect of differential overlap with spectroscopic parameterization (INDO/S), are confirmed by the available experimental data. |
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container_issue |
11 |
title_short |
Properties of the Triplet State of Coumarin Substituted Compounds |
url |
https://dx.doi.org/10.1007/s11182-015-0415-y |
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author2 |
Gadirov, R. M. Nikonov, S. Yu Sokolova, I. V. |
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Gadirov, R. M. Nikonov, S. Yu Sokolova, I. V. |
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10.1007/s11182-015-0415-y |
up_date |
2024-07-03T14:09:44.716Z |
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score |
7.3994884 |