Synthesis, characterization and thermal properties of novel PMDA-PAPD/silica hybrid network polymers
Abstract Novel PMDA-PAPD/silica hybrid polymers were synthesized by the sol-gel process. Fourier transform infrared spectroscopy and 29Si nuclear magnetic resonance spectroscopy were used to characterize the structure of the hybrids, (condensed siloxane bonds designated as $ Q^{1} $, $ Q^{2} $, $ Q^...
Ausführliche Beschreibung
Autor*in: |
Qiu, Fengxian [verfasserIn] Jiang, Yan [verfasserIn] Zhou, Yuming [verfasserIn] Liu, Juzheng [verfasserIn] |
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Sprache: |
Englisch |
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2006 |
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Übergeordnetes Werk: |
Enthalten in: Silicon chemistry - Dordrecht : Springer Science + Business Media B.V., 2002, 3(2006), 1-2 vom: 08. Feb., Seite 65-73 |
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Übergeordnetes Werk: |
volume:3 ; year:2006 ; number:1-2 ; day:08 ; month:02 ; pages:65-73 |
Links: |
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DOI / URN: |
10.1007/s11201-005-9003-2 |
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Katalog-ID: |
SPR017675111 |
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520 | |a Abstract Novel PMDA-PAPD/silica hybrid polymers were synthesized by the sol-gel process. Fourier transform infrared spectroscopy and 29Si nuclear magnetic resonance spectroscopy were used to characterize the structure of the hybrids, (condensed siloxane bonds designated as $ Q^{1} $, $ Q^{2} $, $ Q^{3} $, $ Q^{4} $, wth 3-aminopropyltriethoxysilane having mono-, di-, tri-, tetra-substituted siloxane bonds is designated as $ T^{1} $, $ T^{2} $ and $ T^{3} $). The results revealed that $ Q^{3} $, $ Q^{4} $ and $ T^{3} $ are the major microstructure elements in forming a network structure. The surface morphology, particle size, crystallinity and the thermal stability of the hybrids were investigated using Scanning electron microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray diffraction (XRD), Thermogravimetric analysis (TGA) and Differential Scanning Calorimetry (DSC). SEM and TEM revealed that the hybrids were nanocomposites. The XRD indicated that covalent bonding (Si-O-Si) between the organic and inorganic components enhanced miscibility. DSC and TGA results showed that these hybrid materials had excellent thermal stability. The heat capacities of some materials were reported for the temperature range 273 K and 363 K as no thermal anomaly was found in this temperature range. | ||
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700 | 1 | |a Jiang, Yan |e verfasserin |4 aut | |
700 | 1 | |a Zhou, Yuming |e verfasserin |4 aut | |
700 | 1 | |a Liu, Juzheng |e verfasserin |4 aut | |
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10.1007/s11201-005-9003-2 doi (DE-627)SPR017675111 (SPR)s11201-005-9003-2-e DE-627 ger DE-627 rakwb eng 540 ASE 35.48 bkl Qiu, Fengxian verfasserin aut Synthesis, characterization and thermal properties of novel PMDA-PAPD/silica hybrid network polymers 2006 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Novel PMDA-PAPD/silica hybrid polymers were synthesized by the sol-gel process. Fourier transform infrared spectroscopy and 29Si nuclear magnetic resonance spectroscopy were used to characterize the structure of the hybrids, (condensed siloxane bonds designated as $ Q^{1} $, $ Q^{2} $, $ Q^{3} $, $ Q^{4} $, wth 3-aminopropyltriethoxysilane having mono-, di-, tri-, tetra-substituted siloxane bonds is designated as $ T^{1} $, $ T^{2} $ and $ T^{3} $). The results revealed that $ Q^{3} $, $ Q^{4} $ and $ T^{3} $ are the major microstructure elements in forming a network structure. The surface morphology, particle size, crystallinity and the thermal stability of the hybrids were investigated using Scanning electron microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray diffraction (XRD), Thermogravimetric analysis (TGA) and Differential Scanning Calorimetry (DSC). SEM and TEM revealed that the hybrids were nanocomposites. The XRD indicated that covalent bonding (Si-O-Si) between the organic and inorganic components enhanced miscibility. DSC and TGA results showed that these hybrid materials had excellent thermal stability. The heat capacities of some materials were reported for the temperature range 273 K and 363 K as no thermal anomaly was found in this temperature range. heat capacity (dpeaa)DE-He213 organic-inorganic hybrid (dpeaa)DE-He213 silica (dpeaa)DE-He213 sol-gel process (dpeaa)DE-He213 thermal property (dpeaa)DE-He213 Jiang, Yan verfasserin aut Zhou, Yuming verfasserin aut Liu, Juzheng verfasserin aut Enthalten in Silicon chemistry Dordrecht : Springer Science + Business Media B.V., 2002 3(2006), 1-2 vom: 08. Feb., Seite 65-73 (DE-627)340872586 (DE-600)2065666-X 1572-8994 nnns volume:3 year:2006 number:1-2 day:08 month:02 pages:65-73 https://dx.doi.org/10.1007/s11201-005-9003-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_24 GBV_ILN_40 GBV_ILN_63 GBV_ILN_70 GBV_ILN_100 GBV_ILN_101 GBV_ILN_702 GBV_ILN_2048 GBV_ILN_2190 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4333 GBV_ILN_4338 35.48 ASE AR 3 2006 1-2 08 02 65-73 |
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10.1007/s11201-005-9003-2 doi (DE-627)SPR017675111 (SPR)s11201-005-9003-2-e DE-627 ger DE-627 rakwb eng 540 ASE 35.48 bkl Qiu, Fengxian verfasserin aut Synthesis, characterization and thermal properties of novel PMDA-PAPD/silica hybrid network polymers 2006 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Novel PMDA-PAPD/silica hybrid polymers were synthesized by the sol-gel process. Fourier transform infrared spectroscopy and 29Si nuclear magnetic resonance spectroscopy were used to characterize the structure of the hybrids, (condensed siloxane bonds designated as $ Q^{1} $, $ Q^{2} $, $ Q^{3} $, $ Q^{4} $, wth 3-aminopropyltriethoxysilane having mono-, di-, tri-, tetra-substituted siloxane bonds is designated as $ T^{1} $, $ T^{2} $ and $ T^{3} $). The results revealed that $ Q^{3} $, $ Q^{4} $ and $ T^{3} $ are the major microstructure elements in forming a network structure. The surface morphology, particle size, crystallinity and the thermal stability of the hybrids were investigated using Scanning electron microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray diffraction (XRD), Thermogravimetric analysis (TGA) and Differential Scanning Calorimetry (DSC). SEM and TEM revealed that the hybrids were nanocomposites. The XRD indicated that covalent bonding (Si-O-Si) between the organic and inorganic components enhanced miscibility. DSC and TGA results showed that these hybrid materials had excellent thermal stability. The heat capacities of some materials were reported for the temperature range 273 K and 363 K as no thermal anomaly was found in this temperature range. heat capacity (dpeaa)DE-He213 organic-inorganic hybrid (dpeaa)DE-He213 silica (dpeaa)DE-He213 sol-gel process (dpeaa)DE-He213 thermal property (dpeaa)DE-He213 Jiang, Yan verfasserin aut Zhou, Yuming verfasserin aut Liu, Juzheng verfasserin aut Enthalten in Silicon chemistry Dordrecht : Springer Science + Business Media B.V., 2002 3(2006), 1-2 vom: 08. Feb., Seite 65-73 (DE-627)340872586 (DE-600)2065666-X 1572-8994 nnns volume:3 year:2006 number:1-2 day:08 month:02 pages:65-73 https://dx.doi.org/10.1007/s11201-005-9003-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_24 GBV_ILN_40 GBV_ILN_63 GBV_ILN_70 GBV_ILN_100 GBV_ILN_101 GBV_ILN_702 GBV_ILN_2048 GBV_ILN_2190 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4333 GBV_ILN_4338 35.48 ASE AR 3 2006 1-2 08 02 65-73 |
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10.1007/s11201-005-9003-2 doi (DE-627)SPR017675111 (SPR)s11201-005-9003-2-e DE-627 ger DE-627 rakwb eng 540 ASE 35.48 bkl Qiu, Fengxian verfasserin aut Synthesis, characterization and thermal properties of novel PMDA-PAPD/silica hybrid network polymers 2006 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Novel PMDA-PAPD/silica hybrid polymers were synthesized by the sol-gel process. Fourier transform infrared spectroscopy and 29Si nuclear magnetic resonance spectroscopy were used to characterize the structure of the hybrids, (condensed siloxane bonds designated as $ Q^{1} $, $ Q^{2} $, $ Q^{3} $, $ Q^{4} $, wth 3-aminopropyltriethoxysilane having mono-, di-, tri-, tetra-substituted siloxane bonds is designated as $ T^{1} $, $ T^{2} $ and $ T^{3} $). The results revealed that $ Q^{3} $, $ Q^{4} $ and $ T^{3} $ are the major microstructure elements in forming a network structure. The surface morphology, particle size, crystallinity and the thermal stability of the hybrids were investigated using Scanning electron microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray diffraction (XRD), Thermogravimetric analysis (TGA) and Differential Scanning Calorimetry (DSC). SEM and TEM revealed that the hybrids were nanocomposites. The XRD indicated that covalent bonding (Si-O-Si) between the organic and inorganic components enhanced miscibility. DSC and TGA results showed that these hybrid materials had excellent thermal stability. The heat capacities of some materials were reported for the temperature range 273 K and 363 K as no thermal anomaly was found in this temperature range. heat capacity (dpeaa)DE-He213 organic-inorganic hybrid (dpeaa)DE-He213 silica (dpeaa)DE-He213 sol-gel process (dpeaa)DE-He213 thermal property (dpeaa)DE-He213 Jiang, Yan verfasserin aut Zhou, Yuming verfasserin aut Liu, Juzheng verfasserin aut Enthalten in Silicon chemistry Dordrecht : Springer Science + Business Media B.V., 2002 3(2006), 1-2 vom: 08. Feb., Seite 65-73 (DE-627)340872586 (DE-600)2065666-X 1572-8994 nnns volume:3 year:2006 number:1-2 day:08 month:02 pages:65-73 https://dx.doi.org/10.1007/s11201-005-9003-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_24 GBV_ILN_40 GBV_ILN_63 GBV_ILN_70 GBV_ILN_100 GBV_ILN_101 GBV_ILN_702 GBV_ILN_2048 GBV_ILN_2190 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4333 GBV_ILN_4338 35.48 ASE AR 3 2006 1-2 08 02 65-73 |
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10.1007/s11201-005-9003-2 doi (DE-627)SPR017675111 (SPR)s11201-005-9003-2-e DE-627 ger DE-627 rakwb eng 540 ASE 35.48 bkl Qiu, Fengxian verfasserin aut Synthesis, characterization and thermal properties of novel PMDA-PAPD/silica hybrid network polymers 2006 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Novel PMDA-PAPD/silica hybrid polymers were synthesized by the sol-gel process. Fourier transform infrared spectroscopy and 29Si nuclear magnetic resonance spectroscopy were used to characterize the structure of the hybrids, (condensed siloxane bonds designated as $ Q^{1} $, $ Q^{2} $, $ Q^{3} $, $ Q^{4} $, wth 3-aminopropyltriethoxysilane having mono-, di-, tri-, tetra-substituted siloxane bonds is designated as $ T^{1} $, $ T^{2} $ and $ T^{3} $). The results revealed that $ Q^{3} $, $ Q^{4} $ and $ T^{3} $ are the major microstructure elements in forming a network structure. The surface morphology, particle size, crystallinity and the thermal stability of the hybrids were investigated using Scanning electron microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray diffraction (XRD), Thermogravimetric analysis (TGA) and Differential Scanning Calorimetry (DSC). SEM and TEM revealed that the hybrids were nanocomposites. The XRD indicated that covalent bonding (Si-O-Si) between the organic and inorganic components enhanced miscibility. DSC and TGA results showed that these hybrid materials had excellent thermal stability. The heat capacities of some materials were reported for the temperature range 273 K and 363 K as no thermal anomaly was found in this temperature range. heat capacity (dpeaa)DE-He213 organic-inorganic hybrid (dpeaa)DE-He213 silica (dpeaa)DE-He213 sol-gel process (dpeaa)DE-He213 thermal property (dpeaa)DE-He213 Jiang, Yan verfasserin aut Zhou, Yuming verfasserin aut Liu, Juzheng verfasserin aut Enthalten in Silicon chemistry Dordrecht : Springer Science + Business Media B.V., 2002 3(2006), 1-2 vom: 08. Feb., Seite 65-73 (DE-627)340872586 (DE-600)2065666-X 1572-8994 nnns volume:3 year:2006 number:1-2 day:08 month:02 pages:65-73 https://dx.doi.org/10.1007/s11201-005-9003-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_24 GBV_ILN_40 GBV_ILN_63 GBV_ILN_70 GBV_ILN_100 GBV_ILN_101 GBV_ILN_702 GBV_ILN_2048 GBV_ILN_2190 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4333 GBV_ILN_4338 35.48 ASE AR 3 2006 1-2 08 02 65-73 |
allfieldsSound |
10.1007/s11201-005-9003-2 doi (DE-627)SPR017675111 (SPR)s11201-005-9003-2-e DE-627 ger DE-627 rakwb eng 540 ASE 35.48 bkl Qiu, Fengxian verfasserin aut Synthesis, characterization and thermal properties of novel PMDA-PAPD/silica hybrid network polymers 2006 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Novel PMDA-PAPD/silica hybrid polymers were synthesized by the sol-gel process. Fourier transform infrared spectroscopy and 29Si nuclear magnetic resonance spectroscopy were used to characterize the structure of the hybrids, (condensed siloxane bonds designated as $ Q^{1} $, $ Q^{2} $, $ Q^{3} $, $ Q^{4} $, wth 3-aminopropyltriethoxysilane having mono-, di-, tri-, tetra-substituted siloxane bonds is designated as $ T^{1} $, $ T^{2} $ and $ T^{3} $). The results revealed that $ Q^{3} $, $ Q^{4} $ and $ T^{3} $ are the major microstructure elements in forming a network structure. The surface morphology, particle size, crystallinity and the thermal stability of the hybrids were investigated using Scanning electron microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray diffraction (XRD), Thermogravimetric analysis (TGA) and Differential Scanning Calorimetry (DSC). SEM and TEM revealed that the hybrids were nanocomposites. The XRD indicated that covalent bonding (Si-O-Si) between the organic and inorganic components enhanced miscibility. DSC and TGA results showed that these hybrid materials had excellent thermal stability. The heat capacities of some materials were reported for the temperature range 273 K and 363 K as no thermal anomaly was found in this temperature range. heat capacity (dpeaa)DE-He213 organic-inorganic hybrid (dpeaa)DE-He213 silica (dpeaa)DE-He213 sol-gel process (dpeaa)DE-He213 thermal property (dpeaa)DE-He213 Jiang, Yan verfasserin aut Zhou, Yuming verfasserin aut Liu, Juzheng verfasserin aut Enthalten in Silicon chemistry Dordrecht : Springer Science + Business Media B.V., 2002 3(2006), 1-2 vom: 08. Feb., Seite 65-73 (DE-627)340872586 (DE-600)2065666-X 1572-8994 nnns volume:3 year:2006 number:1-2 day:08 month:02 pages:65-73 https://dx.doi.org/10.1007/s11201-005-9003-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_24 GBV_ILN_40 GBV_ILN_63 GBV_ILN_70 GBV_ILN_100 GBV_ILN_101 GBV_ILN_702 GBV_ILN_2048 GBV_ILN_2190 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4333 GBV_ILN_4338 35.48 ASE AR 3 2006 1-2 08 02 65-73 |
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Fourier transform infrared spectroscopy and 29Si nuclear magnetic resonance spectroscopy were used to characterize the structure of the hybrids, (condensed siloxane bonds designated as $ Q^{1} $, $ Q^{2} $, $ Q^{3} $, $ Q^{4} $, wth 3-aminopropyltriethoxysilane having mono-, di-, tri-, tetra-substituted siloxane bonds is designated as $ T^{1} $, $ T^{2} $ and $ T^{3} $). The results revealed that $ Q^{3} $, $ Q^{4} $ and $ T^{3} $ are the major microstructure elements in forming a network structure. The surface morphology, particle size, crystallinity and the thermal stability of the hybrids were investigated using Scanning electron microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray diffraction (XRD), Thermogravimetric analysis (TGA) and Differential Scanning Calorimetry (DSC). SEM and TEM revealed that the hybrids were nanocomposites. The XRD indicated that covalent bonding (Si-O-Si) between the organic and inorganic components enhanced miscibility. DSC and TGA results showed that these hybrid materials had excellent thermal stability. 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Qiu, Fengxian |
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Qiu, Fengxian ddc 540 bkl 35.48 misc heat capacity misc organic-inorganic hybrid misc silica misc sol-gel process misc thermal property Synthesis, characterization and thermal properties of novel PMDA-PAPD/silica hybrid network polymers |
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540 ASE 35.48 bkl Synthesis, characterization and thermal properties of novel PMDA-PAPD/silica hybrid network polymers heat capacity (dpeaa)DE-He213 organic-inorganic hybrid (dpeaa)DE-He213 silica (dpeaa)DE-He213 sol-gel process (dpeaa)DE-He213 thermal property (dpeaa)DE-He213 |
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Synthesis, characterization and thermal properties of novel PMDA-PAPD/silica hybrid network polymers |
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Qiu, Fengxian Jiang, Yan Zhou, Yuming Liu, Juzheng |
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synthesis, characterization and thermal properties of novel pmda-papd/silica hybrid network polymers |
title_auth |
Synthesis, characterization and thermal properties of novel PMDA-PAPD/silica hybrid network polymers |
abstract |
Abstract Novel PMDA-PAPD/silica hybrid polymers were synthesized by the sol-gel process. Fourier transform infrared spectroscopy and 29Si nuclear magnetic resonance spectroscopy were used to characterize the structure of the hybrids, (condensed siloxane bonds designated as $ Q^{1} $, $ Q^{2} $, $ Q^{3} $, $ Q^{4} $, wth 3-aminopropyltriethoxysilane having mono-, di-, tri-, tetra-substituted siloxane bonds is designated as $ T^{1} $, $ T^{2} $ and $ T^{3} $). The results revealed that $ Q^{3} $, $ Q^{4} $ and $ T^{3} $ are the major microstructure elements in forming a network structure. The surface morphology, particle size, crystallinity and the thermal stability of the hybrids were investigated using Scanning electron microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray diffraction (XRD), Thermogravimetric analysis (TGA) and Differential Scanning Calorimetry (DSC). SEM and TEM revealed that the hybrids were nanocomposites. The XRD indicated that covalent bonding (Si-O-Si) between the organic and inorganic components enhanced miscibility. DSC and TGA results showed that these hybrid materials had excellent thermal stability. The heat capacities of some materials were reported for the temperature range 273 K and 363 K as no thermal anomaly was found in this temperature range. |
abstractGer |
Abstract Novel PMDA-PAPD/silica hybrid polymers were synthesized by the sol-gel process. Fourier transform infrared spectroscopy and 29Si nuclear magnetic resonance spectroscopy were used to characterize the structure of the hybrids, (condensed siloxane bonds designated as $ Q^{1} $, $ Q^{2} $, $ Q^{3} $, $ Q^{4} $, wth 3-aminopropyltriethoxysilane having mono-, di-, tri-, tetra-substituted siloxane bonds is designated as $ T^{1} $, $ T^{2} $ and $ T^{3} $). The results revealed that $ Q^{3} $, $ Q^{4} $ and $ T^{3} $ are the major microstructure elements in forming a network structure. The surface morphology, particle size, crystallinity and the thermal stability of the hybrids were investigated using Scanning electron microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray diffraction (XRD), Thermogravimetric analysis (TGA) and Differential Scanning Calorimetry (DSC). SEM and TEM revealed that the hybrids were nanocomposites. The XRD indicated that covalent bonding (Si-O-Si) between the organic and inorganic components enhanced miscibility. DSC and TGA results showed that these hybrid materials had excellent thermal stability. The heat capacities of some materials were reported for the temperature range 273 K and 363 K as no thermal anomaly was found in this temperature range. |
abstract_unstemmed |
Abstract Novel PMDA-PAPD/silica hybrid polymers were synthesized by the sol-gel process. Fourier transform infrared spectroscopy and 29Si nuclear magnetic resonance spectroscopy were used to characterize the structure of the hybrids, (condensed siloxane bonds designated as $ Q^{1} $, $ Q^{2} $, $ Q^{3} $, $ Q^{4} $, wth 3-aminopropyltriethoxysilane having mono-, di-, tri-, tetra-substituted siloxane bonds is designated as $ T^{1} $, $ T^{2} $ and $ T^{3} $). The results revealed that $ Q^{3} $, $ Q^{4} $ and $ T^{3} $ are the major microstructure elements in forming a network structure. The surface morphology, particle size, crystallinity and the thermal stability of the hybrids were investigated using Scanning electron microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray diffraction (XRD), Thermogravimetric analysis (TGA) and Differential Scanning Calorimetry (DSC). SEM and TEM revealed that the hybrids were nanocomposites. The XRD indicated that covalent bonding (Si-O-Si) between the organic and inorganic components enhanced miscibility. DSC and TGA results showed that these hybrid materials had excellent thermal stability. The heat capacities of some materials were reported for the temperature range 273 K and 363 K as no thermal anomaly was found in this temperature range. |
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Synthesis, characterization and thermal properties of novel PMDA-PAPD/silica hybrid network polymers |
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