Solvolysis–hydrolysis of N-bearing alkoxysilanes: Reactions studied with 29Si NMR

Abstract The hydrolysis reactions of 8 different N-bearing alkoxy-silane coupling agents, namely: 3-cyanopropyl triethoxy silane (CPES), triethoxy-3-(2-imidazolin-1-yl) propyl silane (IZPES), and amino silanes, 3-aminopropyl triethoxy silane (APES), 3-aminopropyl trimethoxy silane (APMS), 3-(2-amino...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Brochier Salon, Marie-Christine [verfasserIn] Bardet, Michel [verfasserIn] Belgacem, Mohamed Naceur [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2008

Schlagwörter:	Silane coupling agents Hydrolysis Solvolysis Alkoxysilanes

Übergeordnetes Werk:	Enthalten in: Silicon chemistry - Dordrecht : Springer Science + Business Media B.V., 2002, 3(2008), 6 vom: 05. Juli, Seite 335-350
Übergeordnetes Werk:	volume:3 ; year:2008 ; number:6 ; day:05 ; month:07 ; pages:335-350

Links:	Volltext

DOI / URN:	10.1007/s11201-008-9036-4

Katalog-ID:	SPR017675464

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520			\|a Abstract The hydrolysis reactions of 8 different N-bearing alkoxy-silane coupling agents, namely: 3-cyanopropyl triethoxy silane (CPES), triethoxy-3-(2-imidazolin-1-yl) propyl silane (IZPES), and amino silanes, 3-aminopropyl triethoxy silane (APES), 3-aminopropyl trimethoxy silane (APMS), 3-(2-aminoethylamino)propyl trimethoxysilane (DAMS), 3-[2-(2-aminoethylamino)ethylamino] propyl trimethoxysilane (TAMS), 4-amino-3,3-dibutyl trimethoxy silane (ADBMS) and trimethoxy [3-(phenylamino)propyl] silane (PAPMS) were carried out in ethanol/water 80/20 (w/w) solutions in acidic media and followed in situ by 1H-, 13C- and 29Si-NMR spectroscopy. Acidic conditions were selected in order to enhance the formation of silanol and to slow down the self condensation reactions of the hydrolyzed functions. 29Si NMR spectroscopy revealed the formation of intermediate species, particularly the solvolysis of γ-amino silanes by reaction exchange with the alcoholic solvent.
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allfields	10.1007/s11201-008-9036-4 doi (DE-627)SPR017675464 (SPR)s11201-008-9036-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.48 bkl Brochier Salon, Marie-Christine verfasserin aut Solvolysis–hydrolysis of N-bearing alkoxysilanes: Reactions studied with 29Si NMR 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The hydrolysis reactions of 8 different N-bearing alkoxy-silane coupling agents, namely: 3-cyanopropyl triethoxy silane (CPES), triethoxy-3-(2-imidazolin-1-yl) propyl silane (IZPES), and amino silanes, 3-aminopropyl triethoxy silane (APES), 3-aminopropyl trimethoxy silane (APMS), 3-(2-aminoethylamino)propyl trimethoxysilane (DAMS), 3-[2-(2-aminoethylamino)ethylamino] propyl trimethoxysilane (TAMS), 4-amino-3,3-dibutyl trimethoxy silane (ADBMS) and trimethoxy [3-(phenylamino)propyl] silane (PAPMS) were carried out in ethanol/water 80/20 (w/w) solutions in acidic media and followed in situ by 1H-, 13C- and 29Si-NMR spectroscopy. Acidic conditions were selected in order to enhance the formation of silanol and to slow down the self condensation reactions of the hydrolyzed functions. 29Si NMR spectroscopy revealed the formation of intermediate species, particularly the solvolysis of γ-amino silanes by reaction exchange with the alcoholic solvent. Silane coupling agents (dpeaa)DE-He213 Hydrolysis (dpeaa)DE-He213 Solvolysis (dpeaa)DE-He213 Alkoxysilanes (dpeaa)DE-He213 Bardet, Michel verfasserin aut Belgacem, Mohamed Naceur verfasserin aut Enthalten in Silicon chemistry Dordrecht : Springer Science + Business Media B.V., 2002 3(2008), 6 vom: 05. Juli, Seite 335-350 (DE-627)340872586 (DE-600)2065666-X 1572-8994 nnns volume:3 year:2008 number:6 day:05 month:07 pages:335-350 https://dx.doi.org/10.1007/s11201-008-9036-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_24 GBV_ILN_40 GBV_ILN_63 GBV_ILN_70 GBV_ILN_100 GBV_ILN_101 GBV_ILN_702 GBV_ILN_2048 GBV_ILN_2190 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4333 GBV_ILN_4338 35.48 ASE AR 3 2008 6 05 07 335-350
spelling	10.1007/s11201-008-9036-4 doi (DE-627)SPR017675464 (SPR)s11201-008-9036-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.48 bkl Brochier Salon, Marie-Christine verfasserin aut Solvolysis–hydrolysis of N-bearing alkoxysilanes: Reactions studied with 29Si NMR 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The hydrolysis reactions of 8 different N-bearing alkoxy-silane coupling agents, namely: 3-cyanopropyl triethoxy silane (CPES), triethoxy-3-(2-imidazolin-1-yl) propyl silane (IZPES), and amino silanes, 3-aminopropyl triethoxy silane (APES), 3-aminopropyl trimethoxy silane (APMS), 3-(2-aminoethylamino)propyl trimethoxysilane (DAMS), 3-[2-(2-aminoethylamino)ethylamino] propyl trimethoxysilane (TAMS), 4-amino-3,3-dibutyl trimethoxy silane (ADBMS) and trimethoxy [3-(phenylamino)propyl] silane (PAPMS) were carried out in ethanol/water 80/20 (w/w) solutions in acidic media and followed in situ by 1H-, 13C- and 29Si-NMR spectroscopy. Acidic conditions were selected in order to enhance the formation of silanol and to slow down the self condensation reactions of the hydrolyzed functions. 29Si NMR spectroscopy revealed the formation of intermediate species, particularly the solvolysis of γ-amino silanes by reaction exchange with the alcoholic solvent. Silane coupling agents (dpeaa)DE-He213 Hydrolysis (dpeaa)DE-He213 Solvolysis (dpeaa)DE-He213 Alkoxysilanes (dpeaa)DE-He213 Bardet, Michel verfasserin aut Belgacem, Mohamed Naceur verfasserin aut Enthalten in Silicon chemistry Dordrecht : Springer Science + Business Media B.V., 2002 3(2008), 6 vom: 05. Juli, Seite 335-350 (DE-627)340872586 (DE-600)2065666-X 1572-8994 nnns volume:3 year:2008 number:6 day:05 month:07 pages:335-350 https://dx.doi.org/10.1007/s11201-008-9036-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_24 GBV_ILN_40 GBV_ILN_63 GBV_ILN_70 GBV_ILN_100 GBV_ILN_101 GBV_ILN_702 GBV_ILN_2048 GBV_ILN_2190 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4333 GBV_ILN_4338 35.48 ASE AR 3 2008 6 05 07 335-350
allfields_unstemmed	10.1007/s11201-008-9036-4 doi (DE-627)SPR017675464 (SPR)s11201-008-9036-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.48 bkl Brochier Salon, Marie-Christine verfasserin aut Solvolysis–hydrolysis of N-bearing alkoxysilanes: Reactions studied with 29Si NMR 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The hydrolysis reactions of 8 different N-bearing alkoxy-silane coupling agents, namely: 3-cyanopropyl triethoxy silane (CPES), triethoxy-3-(2-imidazolin-1-yl) propyl silane (IZPES), and amino silanes, 3-aminopropyl triethoxy silane (APES), 3-aminopropyl trimethoxy silane (APMS), 3-(2-aminoethylamino)propyl trimethoxysilane (DAMS), 3-[2-(2-aminoethylamino)ethylamino] propyl trimethoxysilane (TAMS), 4-amino-3,3-dibutyl trimethoxy silane (ADBMS) and trimethoxy [3-(phenylamino)propyl] silane (PAPMS) were carried out in ethanol/water 80/20 (w/w) solutions in acidic media and followed in situ by 1H-, 13C- and 29Si-NMR spectroscopy. Acidic conditions were selected in order to enhance the formation of silanol and to slow down the self condensation reactions of the hydrolyzed functions. 29Si NMR spectroscopy revealed the formation of intermediate species, particularly the solvolysis of γ-amino silanes by reaction exchange with the alcoholic solvent. Silane coupling agents (dpeaa)DE-He213 Hydrolysis (dpeaa)DE-He213 Solvolysis (dpeaa)DE-He213 Alkoxysilanes (dpeaa)DE-He213 Bardet, Michel verfasserin aut Belgacem, Mohamed Naceur verfasserin aut Enthalten in Silicon chemistry Dordrecht : Springer Science + Business Media B.V., 2002 3(2008), 6 vom: 05. Juli, Seite 335-350 (DE-627)340872586 (DE-600)2065666-X 1572-8994 nnns volume:3 year:2008 number:6 day:05 month:07 pages:335-350 https://dx.doi.org/10.1007/s11201-008-9036-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_24 GBV_ILN_40 GBV_ILN_63 GBV_ILN_70 GBV_ILN_100 GBV_ILN_101 GBV_ILN_702 GBV_ILN_2048 GBV_ILN_2190 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4333 GBV_ILN_4338 35.48 ASE AR 3 2008 6 05 07 335-350
allfieldsGer	10.1007/s11201-008-9036-4 doi (DE-627)SPR017675464 (SPR)s11201-008-9036-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.48 bkl Brochier Salon, Marie-Christine verfasserin aut Solvolysis–hydrolysis of N-bearing alkoxysilanes: Reactions studied with 29Si NMR 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The hydrolysis reactions of 8 different N-bearing alkoxy-silane coupling agents, namely: 3-cyanopropyl triethoxy silane (CPES), triethoxy-3-(2-imidazolin-1-yl) propyl silane (IZPES), and amino silanes, 3-aminopropyl triethoxy silane (APES), 3-aminopropyl trimethoxy silane (APMS), 3-(2-aminoethylamino)propyl trimethoxysilane (DAMS), 3-[2-(2-aminoethylamino)ethylamino] propyl trimethoxysilane (TAMS), 4-amino-3,3-dibutyl trimethoxy silane (ADBMS) and trimethoxy [3-(phenylamino)propyl] silane (PAPMS) were carried out in ethanol/water 80/20 (w/w) solutions in acidic media and followed in situ by 1H-, 13C- and 29Si-NMR spectroscopy. Acidic conditions were selected in order to enhance the formation of silanol and to slow down the self condensation reactions of the hydrolyzed functions. 29Si NMR spectroscopy revealed the formation of intermediate species, particularly the solvolysis of γ-amino silanes by reaction exchange with the alcoholic solvent. Silane coupling agents (dpeaa)DE-He213 Hydrolysis (dpeaa)DE-He213 Solvolysis (dpeaa)DE-He213 Alkoxysilanes (dpeaa)DE-He213 Bardet, Michel verfasserin aut Belgacem, Mohamed Naceur verfasserin aut Enthalten in Silicon chemistry Dordrecht : Springer Science + Business Media B.V., 2002 3(2008), 6 vom: 05. Juli, Seite 335-350 (DE-627)340872586 (DE-600)2065666-X 1572-8994 nnns volume:3 year:2008 number:6 day:05 month:07 pages:335-350 https://dx.doi.org/10.1007/s11201-008-9036-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_24 GBV_ILN_40 GBV_ILN_63 GBV_ILN_70 GBV_ILN_100 GBV_ILN_101 GBV_ILN_702 GBV_ILN_2048 GBV_ILN_2190 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4333 GBV_ILN_4338 35.48 ASE AR 3 2008 6 05 07 335-350
allfieldsSound	10.1007/s11201-008-9036-4 doi (DE-627)SPR017675464 (SPR)s11201-008-9036-4-e DE-627 ger DE-627 rakwb eng 540 ASE 35.48 bkl Brochier Salon, Marie-Christine verfasserin aut Solvolysis–hydrolysis of N-bearing alkoxysilanes: Reactions studied with 29Si NMR 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The hydrolysis reactions of 8 different N-bearing alkoxy-silane coupling agents, namely: 3-cyanopropyl triethoxy silane (CPES), triethoxy-3-(2-imidazolin-1-yl) propyl silane (IZPES), and amino silanes, 3-aminopropyl triethoxy silane (APES), 3-aminopropyl trimethoxy silane (APMS), 3-(2-aminoethylamino)propyl trimethoxysilane (DAMS), 3-[2-(2-aminoethylamino)ethylamino] propyl trimethoxysilane (TAMS), 4-amino-3,3-dibutyl trimethoxy silane (ADBMS) and trimethoxy [3-(phenylamino)propyl] silane (PAPMS) were carried out in ethanol/water 80/20 (w/w) solutions in acidic media and followed in situ by 1H-, 13C- and 29Si-NMR spectroscopy. Acidic conditions were selected in order to enhance the formation of silanol and to slow down the self condensation reactions of the hydrolyzed functions. 29Si NMR spectroscopy revealed the formation of intermediate species, particularly the solvolysis of γ-amino silanes by reaction exchange with the alcoholic solvent. Silane coupling agents (dpeaa)DE-He213 Hydrolysis (dpeaa)DE-He213 Solvolysis (dpeaa)DE-He213 Alkoxysilanes (dpeaa)DE-He213 Bardet, Michel verfasserin aut Belgacem, Mohamed Naceur verfasserin aut Enthalten in Silicon chemistry Dordrecht : Springer Science + Business Media B.V., 2002 3(2008), 6 vom: 05. Juli, Seite 335-350 (DE-627)340872586 (DE-600)2065666-X 1572-8994 nnns volume:3 year:2008 number:6 day:05 month:07 pages:335-350 https://dx.doi.org/10.1007/s11201-008-9036-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_24 GBV_ILN_40 GBV_ILN_63 GBV_ILN_70 GBV_ILN_100 GBV_ILN_101 GBV_ILN_702 GBV_ILN_2048 GBV_ILN_2190 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4333 GBV_ILN_4338 35.48 ASE AR 3 2008 6 05 07 335-350
language	English
source	Enthalten in Silicon chemistry 3(2008), 6 vom: 05. Juli, Seite 335-350 volume:3 year:2008 number:6 day:05 month:07 pages:335-350
sourceStr	Enthalten in Silicon chemistry 3(2008), 6 vom: 05. Juli, Seite 335-350 volume:3 year:2008 number:6 day:05 month:07 pages:335-350
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Silane coupling agents Hydrolysis Solvolysis Alkoxysilanes
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container_title	Silicon chemistry
authorswithroles_txt_mv	Brochier Salon, Marie-Christine @@aut@@ Bardet, Michel @@aut@@ Belgacem, Mohamed Naceur @@aut@@
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author	Brochier Salon, Marie-Christine
spellingShingle	Brochier Salon, Marie-Christine ddc 540 bkl 35.48 misc Silane coupling agents misc Hydrolysis misc Solvolysis misc Alkoxysilanes Solvolysis–hydrolysis of N-bearing alkoxysilanes: Reactions studied with 29Si NMR
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topic_title	540 ASE 35.48 bkl Solvolysis–hydrolysis of N-bearing alkoxysilanes: Reactions studied with 29Si NMR Silane coupling agents (dpeaa)DE-He213 Hydrolysis (dpeaa)DE-He213 Solvolysis (dpeaa)DE-He213 Alkoxysilanes (dpeaa)DE-He213
topic	ddc 540 bkl 35.48 misc Silane coupling agents misc Hydrolysis misc Solvolysis misc Alkoxysilanes
topic_unstemmed	ddc 540 bkl 35.48 misc Silane coupling agents misc Hydrolysis misc Solvolysis misc Alkoxysilanes
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title	Solvolysis–hydrolysis of N-bearing alkoxysilanes: Reactions studied with 29Si NMR
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title_full	Solvolysis–hydrolysis of N-bearing alkoxysilanes: Reactions studied with 29Si NMR
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author_browse	Brochier Salon, Marie-Christine Bardet, Michel Belgacem, Mohamed Naceur
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author-letter	Brochier Salon, Marie-Christine
doi_str_mv	10.1007/s11201-008-9036-4
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title_sort	solvolysis–hydrolysis of n-bearing alkoxysilanes: reactions studied with 29si nmr
title_auth	Solvolysis–hydrolysis of N-bearing alkoxysilanes: Reactions studied with 29Si NMR
abstract	Abstract The hydrolysis reactions of 8 different N-bearing alkoxy-silane coupling agents, namely: 3-cyanopropyl triethoxy silane (CPES), triethoxy-3-(2-imidazolin-1-yl) propyl silane (IZPES), and amino silanes, 3-aminopropyl triethoxy silane (APES), 3-aminopropyl trimethoxy silane (APMS), 3-(2-aminoethylamino)propyl trimethoxysilane (DAMS), 3-[2-(2-aminoethylamino)ethylamino] propyl trimethoxysilane (TAMS), 4-amino-3,3-dibutyl trimethoxy silane (ADBMS) and trimethoxy [3-(phenylamino)propyl] silane (PAPMS) were carried out in ethanol/water 80/20 (w/w) solutions in acidic media and followed in situ by 1H-, 13C- and 29Si-NMR spectroscopy. Acidic conditions were selected in order to enhance the formation of silanol and to slow down the self condensation reactions of the hydrolyzed functions. 29Si NMR spectroscopy revealed the formation of intermediate species, particularly the solvolysis of γ-amino silanes by reaction exchange with the alcoholic solvent.
abstractGer	Abstract The hydrolysis reactions of 8 different N-bearing alkoxy-silane coupling agents, namely: 3-cyanopropyl triethoxy silane (CPES), triethoxy-3-(2-imidazolin-1-yl) propyl silane (IZPES), and amino silanes, 3-aminopropyl triethoxy silane (APES), 3-aminopropyl trimethoxy silane (APMS), 3-(2-aminoethylamino)propyl trimethoxysilane (DAMS), 3-[2-(2-aminoethylamino)ethylamino] propyl trimethoxysilane (TAMS), 4-amino-3,3-dibutyl trimethoxy silane (ADBMS) and trimethoxy [3-(phenylamino)propyl] silane (PAPMS) were carried out in ethanol/water 80/20 (w/w) solutions in acidic media and followed in situ by 1H-, 13C- and 29Si-NMR spectroscopy. Acidic conditions were selected in order to enhance the formation of silanol and to slow down the self condensation reactions of the hydrolyzed functions. 29Si NMR spectroscopy revealed the formation of intermediate species, particularly the solvolysis of γ-amino silanes by reaction exchange with the alcoholic solvent.
abstract_unstemmed	Abstract The hydrolysis reactions of 8 different N-bearing alkoxy-silane coupling agents, namely: 3-cyanopropyl triethoxy silane (CPES), triethoxy-3-(2-imidazolin-1-yl) propyl silane (IZPES), and amino silanes, 3-aminopropyl triethoxy silane (APES), 3-aminopropyl trimethoxy silane (APMS), 3-(2-aminoethylamino)propyl trimethoxysilane (DAMS), 3-[2-(2-aminoethylamino)ethylamino] propyl trimethoxysilane (TAMS), 4-amino-3,3-dibutyl trimethoxy silane (ADBMS) and trimethoxy [3-(phenylamino)propyl] silane (PAPMS) were carried out in ethanol/water 80/20 (w/w) solutions in acidic media and followed in situ by 1H-, 13C- and 29Si-NMR spectroscopy. Acidic conditions were selected in order to enhance the formation of silanol and to slow down the self condensation reactions of the hydrolyzed functions. 29Si NMR spectroscopy revealed the formation of intermediate species, particularly the solvolysis of γ-amino silanes by reaction exchange with the alcoholic solvent.
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title_short	Solvolysis–hydrolysis of N-bearing alkoxysilanes: Reactions studied with 29Si NMR
url	https://dx.doi.org/10.1007/s11201-008-9036-4
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author2	Bardet, Michel Belgacem, Mohamed Naceur
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Solvolysis–hydrolysis of N-bearing alkoxysilanes: Reactions studied with 29Si NMR

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