Complexes built with a scorpion-type tripodal ligand and metal ions: syntheses, structural features, electrochemical properties and magnetic properties

Abstract The complexes [Fe(bpz*mpy)2]($ ClO_{4} $)2 (1a), [Cu(bpz*mpy)2]($ ClO_{4} $)2 (1b) and [Ag(bpz*mpy)($ Ph_{3} $P)]($ ClO_{4} $) · $ H_{2} $O (2) (bpz*mpy = pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane) have been synthesized and characterized by physicochemical and spectroscopic methods....
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Xiao, Chao-Hu [verfasserIn] Liu, Jia-Cheng [verfasserIn] Song, Xue-Yan [verfasserIn] Yang, Yun-Xia [verfasserIn] Hu, Dong-Cheng [verfasserIn] Si, Chang-Dai [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2013

Schlagwörter:	Ph3P Spin Crossover Magnetic Susceptibility Data Distorted Octahedral Coordination Distorted Tetrahedral Geometry

Übergeordnetes Werk:	Enthalten in: Transition metal chemistry - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1975, 38(2013), 3 vom: 20. Jan., Seite 307-311
Übergeordnetes Werk:	volume:38 ; year:2013 ; number:3 ; day:20 ; month:01 ; pages:307-311

Links:	Volltext

DOI / URN:	10.1007/s11243-013-9693-9

Katalog-ID:	SPR018096220

Internformat


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520			\|a Abstract The complexes [Fe(bpzmpy)2]($ ClO_{4} $)2 (1a), [Cu(bpzmpy)2]($ ClO_{4} $)2 (1b) and [Ag(bpzmpy)($ Ph_{3} $P)]($ ClO_{4} $) · $ H_{2} $O (2) (bpzmpy = pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane) have been synthesized and characterized by physicochemical and spectroscopic methods. X-ray crystallographic analysis reveals that the central $ Fe^{II} $ and $ Cu^{II} $ ions in complexes 1a and 1b are located on a twofold rotation axis and have a distorted octahedral coordination sphere, while the $ Ag^{I} $ center in complex 2 is tetrahedrally coordinated. The electrochemical properties of complex 1b have been investigated. Furthermore, a variable temperature magnetic susceptibility study of complex 1a has also been performed over the measured temperature range 2–300 K.
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912			\|a GBV_ILN_161
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912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
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912			\|a GBV_ILN_230
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912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
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912			\|a GBV_ILN_602
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912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
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912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
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912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2119
912			\|a GBV_ILN_2122
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Indexfelder

author_variant	c h x chx j c l jcl x y s xys y x y yxy d c h dch c d s cds
matchkey_str	article:1572901X:2013----::opeebitihsopotptioalgnadeainsnhsstutrletrslcrcei
hierarchy_sort_str	2013
bklnumber	58.00
publishDate	2013
allfields	10.1007/s11243-013-9693-9 doi (DE-627)SPR018096220 (SPR)s11243-013-9693-9-e DE-627 ger DE-627 rakwb eng 660 ASE 58.00 bkl Xiao, Chao-Hu verfasserin aut Complexes built with a scorpion-type tripodal ligand and metal ions: syntheses, structural features, electrochemical properties and magnetic properties 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The complexes [Fe(bpzmpy)2]($ ClO_{4} $)2 (1a), [Cu(bpzmpy)2]($ ClO_{4} $)2 (1b) and [Ag(bpzmpy)($ Ph_{3} $P)]($ ClO_{4} $) · $ H_{2} $O (2) (bpzmpy = pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane) have been synthesized and characterized by physicochemical and spectroscopic methods. X-ray crystallographic analysis reveals that the central $ Fe^{II} $ and $ Cu^{II} $ ions in complexes 1a and 1b are located on a twofold rotation axis and have a distorted octahedral coordination sphere, while the $ Ag^{I} $ center in complex 2 is tetrahedrally coordinated. The electrochemical properties of complex 1b have been investigated. Furthermore, a variable temperature magnetic susceptibility study of complex 1a has also been performed over the measured temperature range 2–300 K. Ph3P (dpeaa)DE-He213 Spin Crossover (dpeaa)DE-He213 Magnetic Susceptibility Data (dpeaa)DE-He213 Distorted Octahedral Coordination (dpeaa)DE-He213 Distorted Tetrahedral Geometry (dpeaa)DE-He213 Liu, Jia-Cheng verfasserin aut Song, Xue-Yan verfasserin aut Yang, Yun-Xia verfasserin aut Hu, Dong-Cheng verfasserin aut Si, Chang-Dai verfasserin aut Enthalten in Transition metal chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1975 38(2013), 3 vom: 20. Jan., Seite 307-311 (DE-627)306713632 (DE-600)1501083-1 1572-901X nnns volume:38 year:2013 number:3 day:20 month:01 pages:307-311 https://dx.doi.org/10.1007/s11243-013-9693-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.00 ASE AR 38 2013 3 20 01 307-311
spelling	10.1007/s11243-013-9693-9 doi (DE-627)SPR018096220 (SPR)s11243-013-9693-9-e DE-627 ger DE-627 rakwb eng 660 ASE 58.00 bkl Xiao, Chao-Hu verfasserin aut Complexes built with a scorpion-type tripodal ligand and metal ions: syntheses, structural features, electrochemical properties and magnetic properties 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The complexes [Fe(bpzmpy)2]($ ClO_{4} $)2 (1a), [Cu(bpzmpy)2]($ ClO_{4} $)2 (1b) and [Ag(bpzmpy)($ Ph_{3} $P)]($ ClO_{4} $) · $ H_{2} $O (2) (bpzmpy = pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane) have been synthesized and characterized by physicochemical and spectroscopic methods. X-ray crystallographic analysis reveals that the central $ Fe^{II} $ and $ Cu^{II} $ ions in complexes 1a and 1b are located on a twofold rotation axis and have a distorted octahedral coordination sphere, while the $ Ag^{I} $ center in complex 2 is tetrahedrally coordinated. The electrochemical properties of complex 1b have been investigated. Furthermore, a variable temperature magnetic susceptibility study of complex 1a has also been performed over the measured temperature range 2–300 K. Ph3P (dpeaa)DE-He213 Spin Crossover (dpeaa)DE-He213 Magnetic Susceptibility Data (dpeaa)DE-He213 Distorted Octahedral Coordination (dpeaa)DE-He213 Distorted Tetrahedral Geometry (dpeaa)DE-He213 Liu, Jia-Cheng verfasserin aut Song, Xue-Yan verfasserin aut Yang, Yun-Xia verfasserin aut Hu, Dong-Cheng verfasserin aut Si, Chang-Dai verfasserin aut Enthalten in Transition metal chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1975 38(2013), 3 vom: 20. Jan., Seite 307-311 (DE-627)306713632 (DE-600)1501083-1 1572-901X nnns volume:38 year:2013 number:3 day:20 month:01 pages:307-311 https://dx.doi.org/10.1007/s11243-013-9693-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.00 ASE AR 38 2013 3 20 01 307-311
allfields_unstemmed	10.1007/s11243-013-9693-9 doi (DE-627)SPR018096220 (SPR)s11243-013-9693-9-e DE-627 ger DE-627 rakwb eng 660 ASE 58.00 bkl Xiao, Chao-Hu verfasserin aut Complexes built with a scorpion-type tripodal ligand and metal ions: syntheses, structural features, electrochemical properties and magnetic properties 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The complexes [Fe(bpzmpy)2]($ ClO_{4} $)2 (1a), [Cu(bpzmpy)2]($ ClO_{4} $)2 (1b) and [Ag(bpzmpy)($ Ph_{3} $P)]($ ClO_{4} $) · $ H_{2} $O (2) (bpzmpy = pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane) have been synthesized and characterized by physicochemical and spectroscopic methods. X-ray crystallographic analysis reveals that the central $ Fe^{II} $ and $ Cu^{II} $ ions in complexes 1a and 1b are located on a twofold rotation axis and have a distorted octahedral coordination sphere, while the $ Ag^{I} $ center in complex 2 is tetrahedrally coordinated. The electrochemical properties of complex 1b have been investigated. Furthermore, a variable temperature magnetic susceptibility study of complex 1a has also been performed over the measured temperature range 2–300 K. Ph3P (dpeaa)DE-He213 Spin Crossover (dpeaa)DE-He213 Magnetic Susceptibility Data (dpeaa)DE-He213 Distorted Octahedral Coordination (dpeaa)DE-He213 Distorted Tetrahedral Geometry (dpeaa)DE-He213 Liu, Jia-Cheng verfasserin aut Song, Xue-Yan verfasserin aut Yang, Yun-Xia verfasserin aut Hu, Dong-Cheng verfasserin aut Si, Chang-Dai verfasserin aut Enthalten in Transition metal chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1975 38(2013), 3 vom: 20. Jan., Seite 307-311 (DE-627)306713632 (DE-600)1501083-1 1572-901X nnns volume:38 year:2013 number:3 day:20 month:01 pages:307-311 https://dx.doi.org/10.1007/s11243-013-9693-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.00 ASE AR 38 2013 3 20 01 307-311
allfieldsGer	10.1007/s11243-013-9693-9 doi (DE-627)SPR018096220 (SPR)s11243-013-9693-9-e DE-627 ger DE-627 rakwb eng 660 ASE 58.00 bkl Xiao, Chao-Hu verfasserin aut Complexes built with a scorpion-type tripodal ligand and metal ions: syntheses, structural features, electrochemical properties and magnetic properties 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The complexes [Fe(bpzmpy)2]($ ClO_{4} $)2 (1a), [Cu(bpzmpy)2]($ ClO_{4} $)2 (1b) and [Ag(bpzmpy)($ Ph_{3} $P)]($ ClO_{4} $) · $ H_{2} $O (2) (bpzmpy = pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane) have been synthesized and characterized by physicochemical and spectroscopic methods. X-ray crystallographic analysis reveals that the central $ Fe^{II} $ and $ Cu^{II} $ ions in complexes 1a and 1b are located on a twofold rotation axis and have a distorted octahedral coordination sphere, while the $ Ag^{I} $ center in complex 2 is tetrahedrally coordinated. The electrochemical properties of complex 1b have been investigated. Furthermore, a variable temperature magnetic susceptibility study of complex 1a has also been performed over the measured temperature range 2–300 K. Ph3P (dpeaa)DE-He213 Spin Crossover (dpeaa)DE-He213 Magnetic Susceptibility Data (dpeaa)DE-He213 Distorted Octahedral Coordination (dpeaa)DE-He213 Distorted Tetrahedral Geometry (dpeaa)DE-He213 Liu, Jia-Cheng verfasserin aut Song, Xue-Yan verfasserin aut Yang, Yun-Xia verfasserin aut Hu, Dong-Cheng verfasserin aut Si, Chang-Dai verfasserin aut Enthalten in Transition metal chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1975 38(2013), 3 vom: 20. Jan., Seite 307-311 (DE-627)306713632 (DE-600)1501083-1 1572-901X nnns volume:38 year:2013 number:3 day:20 month:01 pages:307-311 https://dx.doi.org/10.1007/s11243-013-9693-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.00 ASE AR 38 2013 3 20 01 307-311
allfieldsSound	10.1007/s11243-013-9693-9 doi (DE-627)SPR018096220 (SPR)s11243-013-9693-9-e DE-627 ger DE-627 rakwb eng 660 ASE 58.00 bkl Xiao, Chao-Hu verfasserin aut Complexes built with a scorpion-type tripodal ligand and metal ions: syntheses, structural features, electrochemical properties and magnetic properties 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract The complexes [Fe(bpzmpy)2]($ ClO_{4} $)2 (1a), [Cu(bpzmpy)2]($ ClO_{4} $)2 (1b) and [Ag(bpzmpy)($ Ph_{3} $P)]($ ClO_{4} $) · $ H_{2} $O (2) (bpzmpy = pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane) have been synthesized and characterized by physicochemical and spectroscopic methods. X-ray crystallographic analysis reveals that the central $ Fe^{II} $ and $ Cu^{II} $ ions in complexes 1a and 1b are located on a twofold rotation axis and have a distorted octahedral coordination sphere, while the $ Ag^{I} $ center in complex 2 is tetrahedrally coordinated. The electrochemical properties of complex 1b have been investigated. Furthermore, a variable temperature magnetic susceptibility study of complex 1a has also been performed over the measured temperature range 2–300 K. Ph3P (dpeaa)DE-He213 Spin Crossover (dpeaa)DE-He213 Magnetic Susceptibility Data (dpeaa)DE-He213 Distorted Octahedral Coordination (dpeaa)DE-He213 Distorted Tetrahedral Geometry (dpeaa)DE-He213 Liu, Jia-Cheng verfasserin aut Song, Xue-Yan verfasserin aut Yang, Yun-Xia verfasserin aut Hu, Dong-Cheng verfasserin aut Si, Chang-Dai verfasserin aut Enthalten in Transition metal chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1975 38(2013), 3 vom: 20. Jan., Seite 307-311 (DE-627)306713632 (DE-600)1501083-1 1572-901X nnns volume:38 year:2013 number:3 day:20 month:01 pages:307-311 https://dx.doi.org/10.1007/s11243-013-9693-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.00 ASE AR 38 2013 3 20 01 307-311
language	English
source	Enthalten in Transition metal chemistry 38(2013), 3 vom: 20. Jan., Seite 307-311 volume:38 year:2013 number:3 day:20 month:01 pages:307-311
sourceStr	Enthalten in Transition metal chemistry 38(2013), 3 vom: 20. Jan., Seite 307-311 volume:38 year:2013 number:3 day:20 month:01 pages:307-311
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Ph3P Spin Crossover Magnetic Susceptibility Data Distorted Octahedral Coordination Distorted Tetrahedral Geometry
dewey-raw	660
isfreeaccess_bool	false
container_title	Transition metal chemistry
authorswithroles_txt_mv	Xiao, Chao-Hu @@aut@@ Liu, Jia-Cheng @@aut@@ Song, Xue-Yan @@aut@@ Yang, Yun-Xia @@aut@@ Hu, Dong-Cheng @@aut@@ Si, Chang-Dai @@aut@@
publishDateDaySort_date	2013-01-20T00:00:00Z
hierarchy_top_id	306713632
dewey-sort	3660
id	SPR018096220
language_de	englisch
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X-ray crystallographic analysis reveals that the central $ Fe^{II} $ and $ Cu^{II} $ ions in complexes 1a and 1b are located on a twofold rotation axis and have a distorted octahedral coordination sphere, while the $ Ag^{I} $ center in complex 2 is tetrahedrally coordinated. The electrochemical properties of complex 1b have been investigated. 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author	Xiao, Chao-Hu
spellingShingle	Xiao, Chao-Hu ddc 660 bkl 58.00 misc Ph3P misc Spin Crossover misc Magnetic Susceptibility Data misc Distorted Octahedral Coordination misc Distorted Tetrahedral Geometry Complexes built with a scorpion-type tripodal ligand and metal ions: syntheses, structural features, electrochemical properties and magnetic properties
authorStr	Xiao, Chao-Hu
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topic_title	660 ASE 58.00 bkl Complexes built with a scorpion-type tripodal ligand and metal ions: syntheses, structural features, electrochemical properties and magnetic properties Ph3P (dpeaa)DE-He213 Spin Crossover (dpeaa)DE-He213 Magnetic Susceptibility Data (dpeaa)DE-He213 Distorted Octahedral Coordination (dpeaa)DE-He213 Distorted Tetrahedral Geometry (dpeaa)DE-He213
topic	ddc 660 bkl 58.00 misc Ph3P misc Spin Crossover misc Magnetic Susceptibility Data misc Distorted Octahedral Coordination misc Distorted Tetrahedral Geometry
topic_unstemmed	ddc 660 bkl 58.00 misc Ph3P misc Spin Crossover misc Magnetic Susceptibility Data misc Distorted Octahedral Coordination misc Distorted Tetrahedral Geometry
topic_browse	ddc 660 bkl 58.00 misc Ph3P misc Spin Crossover misc Magnetic Susceptibility Data misc Distorted Octahedral Coordination misc Distorted Tetrahedral Geometry
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
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title	Complexes built with a scorpion-type tripodal ligand and metal ions: syntheses, structural features, electrochemical properties and magnetic properties
ctrlnum	(DE-627)SPR018096220 (SPR)s11243-013-9693-9-e
title_full	Complexes built with a scorpion-type tripodal ligand and metal ions: syntheses, structural features, electrochemical properties and magnetic properties
author_sort	Xiao, Chao-Hu
journal	Transition metal chemistry
journalStr	Transition metal chemistry
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author_browse	Xiao, Chao-Hu Liu, Jia-Cheng Song, Xue-Yan Yang, Yun-Xia Hu, Dong-Cheng Si, Chang-Dai
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class	660 ASE 58.00 bkl
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author-letter	Xiao, Chao-Hu
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title_sort	complexes built with a scorpion-type tripodal ligand and metal ions: syntheses, structural features, electrochemical properties and magnetic properties
title_auth	Complexes built with a scorpion-type tripodal ligand and metal ions: syntheses, structural features, electrochemical properties and magnetic properties
abstract	Abstract The complexes [Fe(bpzmpy)2]($ ClO_{4} $)2 (1a), [Cu(bpzmpy)2]($ ClO_{4} $)2 (1b) and [Ag(bpzmpy)($ Ph_{3} $P)]($ ClO_{4} $) · $ H_{2} $O (2) (bpzmpy = pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane) have been synthesized and characterized by physicochemical and spectroscopic methods. X-ray crystallographic analysis reveals that the central $ Fe^{II} $ and $ Cu^{II} $ ions in complexes 1a and 1b are located on a twofold rotation axis and have a distorted octahedral coordination sphere, while the $ Ag^{I} $ center in complex 2 is tetrahedrally coordinated. The electrochemical properties of complex 1b have been investigated. Furthermore, a variable temperature magnetic susceptibility study of complex 1a has also been performed over the measured temperature range 2–300 K.
abstractGer	Abstract The complexes [Fe(bpzmpy)2]($ ClO_{4} $)2 (1a), [Cu(bpzmpy)2]($ ClO_{4} $)2 (1b) and [Ag(bpzmpy)($ Ph_{3} $P)]($ ClO_{4} $) · $ H_{2} $O (2) (bpzmpy = pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane) have been synthesized and characterized by physicochemical and spectroscopic methods. X-ray crystallographic analysis reveals that the central $ Fe^{II} $ and $ Cu^{II} $ ions in complexes 1a and 1b are located on a twofold rotation axis and have a distorted octahedral coordination sphere, while the $ Ag^{I} $ center in complex 2 is tetrahedrally coordinated. The electrochemical properties of complex 1b have been investigated. Furthermore, a variable temperature magnetic susceptibility study of complex 1a has also been performed over the measured temperature range 2–300 K.
abstract_unstemmed	Abstract The complexes [Fe(bpzmpy)2]($ ClO_{4} $)2 (1a), [Cu(bpzmpy)2]($ ClO_{4} $)2 (1b) and [Ag(bpzmpy)($ Ph_{3} $P)]($ ClO_{4} $) · $ H_{2} $O (2) (bpzmpy = pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane) have been synthesized and characterized by physicochemical and spectroscopic methods. X-ray crystallographic analysis reveals that the central $ Fe^{II} $ and $ Cu^{II} $ ions in complexes 1a and 1b are located on a twofold rotation axis and have a distorted octahedral coordination sphere, while the $ Ag^{I} $ center in complex 2 is tetrahedrally coordinated. The electrochemical properties of complex 1b have been investigated. Furthermore, a variable temperature magnetic susceptibility study of complex 1a has also been performed over the measured temperature range 2–300 K.
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container_issue	3
title_short	Complexes built with a scorpion-type tripodal ligand and metal ions: syntheses, structural features, electrochemical properties and magnetic properties
url	https://dx.doi.org/10.1007/s11243-013-9693-9
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author2	Liu, Jia-Cheng Song, Xue-Yan Yang, Yun-Xia Hu, Dong-Cheng Si, Chang-Dai
author2Str	Liu, Jia-Cheng Song, Xue-Yan Yang, Yun-Xia Hu, Dong-Cheng Si, Chang-Dai
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doi_str	10.1007/s11243-013-9693-9
up_date	2024-07-03T17:20:01.380Z
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fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR018096220</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519220304.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2013 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11243-013-9693-9</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR018096220</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s11243-013-9693-9-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.00</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Xiao, Chao-Hu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Complexes built with a scorpion-type tripodal ligand and metal ions: syntheses, structural features, electrochemical properties and magnetic properties</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2013</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The complexes [Fe(bpzmpy)2]($ ClO_{4} $)2 (1a), [Cu(bpzmpy)2]($ ClO_{4} $)2 (1b) and [Ag(bpzmpy)($ Ph_{3} $P)]($ ClO_{4} $) · $ H_{2} $O (2) (bpzmpy = pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane) have been synthesized and characterized by physicochemical and spectroscopic methods. X-ray crystallographic analysis reveals that the central $ Fe^{II} $ and $ Cu^{II} $ ions in complexes 1a and 1b are located on a twofold rotation axis and have a distorted octahedral coordination sphere, while the $ Ag^{I} $ center in complex 2 is tetrahedrally coordinated. The electrochemical properties of complex 1b have been investigated. 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