Synthesis, structure, and magnetic properties of heterotrimetallic tetranuclear complexes
Abstract Two novel heterotrimetallic tetranuclear complexes [Cu($ H_{2} $L)($ CH_{3} $OH)]2Gd(DMF)Fe(CN)6·$ 2H_{2} $O·DMF (1) and [Cu($ H_{2} $L)($ CH_{3} $OH)]2Tb($ H_{2} $O)0.57(DMF)0.43Fe(CN)6·5.$ 5H_{2} $O (2) are reported ($ H_{4} $L = N,N′-ethylenebis(3-hydroxysalicylidene)). The central Ln(II...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Hu, Kong-Qiu [verfasserIn] Wu, Shu-Qi [verfasserIn] Cui, Ai-Li [verfasserIn] Kou, Hui-Zhong [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Transition metal chemistry - Dordrecht [u.a.] : Springer Science + Business Media B.V, 1975, 39(2014), 6 vom: 05. Juli, Seite 713-718 |
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| Übergeordnetes Werk: |
volume:39 ; year:2014 ; number:6 ; day:05 ; month:07 ; pages:713-718 |
| Links: |
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| DOI / URN: |
10.1007/s11243-014-9854-5 |
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| Katalog-ID: |
SPR018097839 |
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| 520 | |a Abstract Two novel heterotrimetallic tetranuclear complexes [Cu($ H_{2} $L)($ CH_{3} $OH)]2Gd(DMF)Fe(CN)6·$ 2H_{2} $O·DMF (1) and [Cu($ H_{2} $L)($ CH_{3} $OH)]2Tb($ H_{2} $O)0.57(DMF)0.43Fe(CN)6·5.$ 5H_{2} $O (2) are reported ($ H_{4} $L = N,N′-ethylenebis(3-hydroxysalicylidene)). The central Ln(III) ion is surrounded by two neutral [Cu($ H_{2} $L)($ CH_{3} $OH)] moieties, forming a $ Cu_{2} $Ln trinuclear unit. The [Fe(CN)6]3− anion is weakly coordinated to one Cu(II) ion of [Cu($ H_{2} $L)($ CH_{3} $OH)] through a cyanide nitrogen atom with the N–Cu distance of ca. 3.2 Å. Magnetic susceptibility measurements indicate the presence of overall ferromagnetic interactions in complexes 1 and 2. The magnetic coupling constant in complex 1 is JCu1Gd1 = 4.54 $ cm^{−1} $ and JCu2Gd1 = 7.97 $ cm^{−1} $ based on %$ \hat{H} = - 2J_{\text{Cu1Gd1}} \hat{S}_{\text{Cu1Gd1}} - 2J_{\text{Cu2Gd1}} \hat{S}_{\text{Cu2Gd1}} %$. Dynamic AC magnetic susceptibility studies reveal that complex 2 shows frequency-dependent out-of-phase signals, typical of single molecule magnet behavior. The energy barrier for complex 2 under a 2 kOe applied DC magnetic field is 13 K. | ||
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10.1007/s11243-014-9854-5 doi (DE-627)SPR018097839 (SPR)s11243-014-9854-5-e DE-627 ger DE-627 rakwb eng 660 ASE 58.00 bkl Hu, Kong-Qiu verfasserin aut Synthesis, structure, and magnetic properties of heterotrimetallic tetranuclear complexes 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Two novel heterotrimetallic tetranuclear complexes [Cu($ H_{2} $L)($ CH_{3} $OH)]2Gd(DMF)Fe(CN)6·$ 2H_{2} $O·DMF (1) and [Cu($ H_{2} $L)($ CH_{3} $OH)]2Tb($ H_{2} $O)0.57(DMF)0.43Fe(CN)6·5.$ 5H_{2} $O (2) are reported ($ H_{4} $L = N,N′-ethylenebis(3-hydroxysalicylidene)). The central Ln(III) ion is surrounded by two neutral [Cu($ H_{2} $L)($ CH_{3} $OH)] moieties, forming a $ Cu_{2} $Ln trinuclear unit. The [Fe(CN)6]3− anion is weakly coordinated to one Cu(II) ion of [Cu($ H_{2} $L)($ CH_{3} $OH)] through a cyanide nitrogen atom with the N–Cu distance of ca. 3.2 Å. Magnetic susceptibility measurements indicate the presence of overall ferromagnetic interactions in complexes 1 and 2. The magnetic coupling constant in complex 1 is JCu1Gd1 = 4.54 $ cm^{−1} $ and JCu2Gd1 = 7.97 $ cm^{−1} $ based on %$ \hat{H} = - 2J_{\text{Cu1Gd1}} \hat{S}_{\text{Cu1Gd1}} - 2J_{\text{Cu2Gd1}} \hat{S}_{\text{Cu2Gd1}} %$. Dynamic AC magnetic susceptibility studies reveal that complex 2 shows frequency-dependent out-of-phase signals, typical of single molecule magnet behavior. The energy barrier for complex 2 under a 2 kOe applied DC magnetic field is 13 K. Bond Distance (dpeaa)DE-He213 Ferromagnetic Interaction (dpeaa)DE-He213 Heterometallic Complex (dpeaa)DE-He213 Single Molecule Magnet (dpeaa)DE-He213 CuGd (dpeaa)DE-He213 Wu, Shu-Qi verfasserin aut Cui, Ai-Li verfasserin aut Kou, Hui-Zhong verfasserin aut Enthalten in Transition metal chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1975 39(2014), 6 vom: 05. Juli, Seite 713-718 (DE-627)306713632 (DE-600)1501083-1 1572-901X nnns volume:39 year:2014 number:6 day:05 month:07 pages:713-718 https://dx.doi.org/10.1007/s11243-014-9854-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.00 ASE AR 39 2014 6 05 07 713-718 |
| spelling |
10.1007/s11243-014-9854-5 doi (DE-627)SPR018097839 (SPR)s11243-014-9854-5-e DE-627 ger DE-627 rakwb eng 660 ASE 58.00 bkl Hu, Kong-Qiu verfasserin aut Synthesis, structure, and magnetic properties of heterotrimetallic tetranuclear complexes 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Two novel heterotrimetallic tetranuclear complexes [Cu($ H_{2} $L)($ CH_{3} $OH)]2Gd(DMF)Fe(CN)6·$ 2H_{2} $O·DMF (1) and [Cu($ H_{2} $L)($ CH_{3} $OH)]2Tb($ H_{2} $O)0.57(DMF)0.43Fe(CN)6·5.$ 5H_{2} $O (2) are reported ($ H_{4} $L = N,N′-ethylenebis(3-hydroxysalicylidene)). The central Ln(III) ion is surrounded by two neutral [Cu($ H_{2} $L)($ CH_{3} $OH)] moieties, forming a $ Cu_{2} $Ln trinuclear unit. The [Fe(CN)6]3− anion is weakly coordinated to one Cu(II) ion of [Cu($ H_{2} $L)($ CH_{3} $OH)] through a cyanide nitrogen atom with the N–Cu distance of ca. 3.2 Å. Magnetic susceptibility measurements indicate the presence of overall ferromagnetic interactions in complexes 1 and 2. The magnetic coupling constant in complex 1 is JCu1Gd1 = 4.54 $ cm^{−1} $ and JCu2Gd1 = 7.97 $ cm^{−1} $ based on %$ \hat{H} = - 2J_{\text{Cu1Gd1}} \hat{S}_{\text{Cu1Gd1}} - 2J_{\text{Cu2Gd1}} \hat{S}_{\text{Cu2Gd1}} %$. Dynamic AC magnetic susceptibility studies reveal that complex 2 shows frequency-dependent out-of-phase signals, typical of single molecule magnet behavior. The energy barrier for complex 2 under a 2 kOe applied DC magnetic field is 13 K. Bond Distance (dpeaa)DE-He213 Ferromagnetic Interaction (dpeaa)DE-He213 Heterometallic Complex (dpeaa)DE-He213 Single Molecule Magnet (dpeaa)DE-He213 CuGd (dpeaa)DE-He213 Wu, Shu-Qi verfasserin aut Cui, Ai-Li verfasserin aut Kou, Hui-Zhong verfasserin aut Enthalten in Transition metal chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1975 39(2014), 6 vom: 05. Juli, Seite 713-718 (DE-627)306713632 (DE-600)1501083-1 1572-901X nnns volume:39 year:2014 number:6 day:05 month:07 pages:713-718 https://dx.doi.org/10.1007/s11243-014-9854-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.00 ASE AR 39 2014 6 05 07 713-718 |
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10.1007/s11243-014-9854-5 doi (DE-627)SPR018097839 (SPR)s11243-014-9854-5-e DE-627 ger DE-627 rakwb eng 660 ASE 58.00 bkl Hu, Kong-Qiu verfasserin aut Synthesis, structure, and magnetic properties of heterotrimetallic tetranuclear complexes 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Two novel heterotrimetallic tetranuclear complexes [Cu($ H_{2} $L)($ CH_{3} $OH)]2Gd(DMF)Fe(CN)6·$ 2H_{2} $O·DMF (1) and [Cu($ H_{2} $L)($ CH_{3} $OH)]2Tb($ H_{2} $O)0.57(DMF)0.43Fe(CN)6·5.$ 5H_{2} $O (2) are reported ($ H_{4} $L = N,N′-ethylenebis(3-hydroxysalicylidene)). The central Ln(III) ion is surrounded by two neutral [Cu($ H_{2} $L)($ CH_{3} $OH)] moieties, forming a $ Cu_{2} $Ln trinuclear unit. The [Fe(CN)6]3− anion is weakly coordinated to one Cu(II) ion of [Cu($ H_{2} $L)($ CH_{3} $OH)] through a cyanide nitrogen atom with the N–Cu distance of ca. 3.2 Å. Magnetic susceptibility measurements indicate the presence of overall ferromagnetic interactions in complexes 1 and 2. The magnetic coupling constant in complex 1 is JCu1Gd1 = 4.54 $ cm^{−1} $ and JCu2Gd1 = 7.97 $ cm^{−1} $ based on %$ \hat{H} = - 2J_{\text{Cu1Gd1}} \hat{S}_{\text{Cu1Gd1}} - 2J_{\text{Cu2Gd1}} \hat{S}_{\text{Cu2Gd1}} %$. Dynamic AC magnetic susceptibility studies reveal that complex 2 shows frequency-dependent out-of-phase signals, typical of single molecule magnet behavior. The energy barrier for complex 2 under a 2 kOe applied DC magnetic field is 13 K. Bond Distance (dpeaa)DE-He213 Ferromagnetic Interaction (dpeaa)DE-He213 Heterometallic Complex (dpeaa)DE-He213 Single Molecule Magnet (dpeaa)DE-He213 CuGd (dpeaa)DE-He213 Wu, Shu-Qi verfasserin aut Cui, Ai-Li verfasserin aut Kou, Hui-Zhong verfasserin aut Enthalten in Transition metal chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1975 39(2014), 6 vom: 05. Juli, Seite 713-718 (DE-627)306713632 (DE-600)1501083-1 1572-901X nnns volume:39 year:2014 number:6 day:05 month:07 pages:713-718 https://dx.doi.org/10.1007/s11243-014-9854-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.00 ASE AR 39 2014 6 05 07 713-718 |
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10.1007/s11243-014-9854-5 doi (DE-627)SPR018097839 (SPR)s11243-014-9854-5-e DE-627 ger DE-627 rakwb eng 660 ASE 58.00 bkl Hu, Kong-Qiu verfasserin aut Synthesis, structure, and magnetic properties of heterotrimetallic tetranuclear complexes 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Two novel heterotrimetallic tetranuclear complexes [Cu($ H_{2} $L)($ CH_{3} $OH)]2Gd(DMF)Fe(CN)6·$ 2H_{2} $O·DMF (1) and [Cu($ H_{2} $L)($ CH_{3} $OH)]2Tb($ H_{2} $O)0.57(DMF)0.43Fe(CN)6·5.$ 5H_{2} $O (2) are reported ($ H_{4} $L = N,N′-ethylenebis(3-hydroxysalicylidene)). The central Ln(III) ion is surrounded by two neutral [Cu($ H_{2} $L)($ CH_{3} $OH)] moieties, forming a $ Cu_{2} $Ln trinuclear unit. The [Fe(CN)6]3− anion is weakly coordinated to one Cu(II) ion of [Cu($ H_{2} $L)($ CH_{3} $OH)] through a cyanide nitrogen atom with the N–Cu distance of ca. 3.2 Å. Magnetic susceptibility measurements indicate the presence of overall ferromagnetic interactions in complexes 1 and 2. The magnetic coupling constant in complex 1 is JCu1Gd1 = 4.54 $ cm^{−1} $ and JCu2Gd1 = 7.97 $ cm^{−1} $ based on %$ \hat{H} = - 2J_{\text{Cu1Gd1}} \hat{S}_{\text{Cu1Gd1}} - 2J_{\text{Cu2Gd1}} \hat{S}_{\text{Cu2Gd1}} %$. Dynamic AC magnetic susceptibility studies reveal that complex 2 shows frequency-dependent out-of-phase signals, typical of single molecule magnet behavior. The energy barrier for complex 2 under a 2 kOe applied DC magnetic field is 13 K. Bond Distance (dpeaa)DE-He213 Ferromagnetic Interaction (dpeaa)DE-He213 Heterometallic Complex (dpeaa)DE-He213 Single Molecule Magnet (dpeaa)DE-He213 CuGd (dpeaa)DE-He213 Wu, Shu-Qi verfasserin aut Cui, Ai-Li verfasserin aut Kou, Hui-Zhong verfasserin aut Enthalten in Transition metal chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1975 39(2014), 6 vom: 05. Juli, Seite 713-718 (DE-627)306713632 (DE-600)1501083-1 1572-901X nnns volume:39 year:2014 number:6 day:05 month:07 pages:713-718 https://dx.doi.org/10.1007/s11243-014-9854-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.00 ASE AR 39 2014 6 05 07 713-718 |
| allfieldsSound |
10.1007/s11243-014-9854-5 doi (DE-627)SPR018097839 (SPR)s11243-014-9854-5-e DE-627 ger DE-627 rakwb eng 660 ASE 58.00 bkl Hu, Kong-Qiu verfasserin aut Synthesis, structure, and magnetic properties of heterotrimetallic tetranuclear complexes 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Two novel heterotrimetallic tetranuclear complexes [Cu($ H_{2} $L)($ CH_{3} $OH)]2Gd(DMF)Fe(CN)6·$ 2H_{2} $O·DMF (1) and [Cu($ H_{2} $L)($ CH_{3} $OH)]2Tb($ H_{2} $O)0.57(DMF)0.43Fe(CN)6·5.$ 5H_{2} $O (2) are reported ($ H_{4} $L = N,N′-ethylenebis(3-hydroxysalicylidene)). The central Ln(III) ion is surrounded by two neutral [Cu($ H_{2} $L)($ CH_{3} $OH)] moieties, forming a $ Cu_{2} $Ln trinuclear unit. The [Fe(CN)6]3− anion is weakly coordinated to one Cu(II) ion of [Cu($ H_{2} $L)($ CH_{3} $OH)] through a cyanide nitrogen atom with the N–Cu distance of ca. 3.2 Å. Magnetic susceptibility measurements indicate the presence of overall ferromagnetic interactions in complexes 1 and 2. The magnetic coupling constant in complex 1 is JCu1Gd1 = 4.54 $ cm^{−1} $ and JCu2Gd1 = 7.97 $ cm^{−1} $ based on %$ \hat{H} = - 2J_{\text{Cu1Gd1}} \hat{S}_{\text{Cu1Gd1}} - 2J_{\text{Cu2Gd1}} \hat{S}_{\text{Cu2Gd1}} %$. Dynamic AC magnetic susceptibility studies reveal that complex 2 shows frequency-dependent out-of-phase signals, typical of single molecule magnet behavior. The energy barrier for complex 2 under a 2 kOe applied DC magnetic field is 13 K. Bond Distance (dpeaa)DE-He213 Ferromagnetic Interaction (dpeaa)DE-He213 Heterometallic Complex (dpeaa)DE-He213 Single Molecule Magnet (dpeaa)DE-He213 CuGd (dpeaa)DE-He213 Wu, Shu-Qi verfasserin aut Cui, Ai-Li verfasserin aut Kou, Hui-Zhong verfasserin aut Enthalten in Transition metal chemistry Dordrecht [u.a.] : Springer Science + Business Media B.V, 1975 39(2014), 6 vom: 05. Juli, Seite 713-718 (DE-627)306713632 (DE-600)1501083-1 1572-901X nnns volume:39 year:2014 number:6 day:05 month:07 pages:713-718 https://dx.doi.org/10.1007/s11243-014-9854-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.00 ASE AR 39 2014 6 05 07 713-718 |
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English |
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Enthalten in Transition metal chemistry 39(2014), 6 vom: 05. Juli, Seite 713-718 volume:39 year:2014 number:6 day:05 month:07 pages:713-718 |
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Enthalten in Transition metal chemistry 39(2014), 6 vom: 05. Juli, Seite 713-718 volume:39 year:2014 number:6 day:05 month:07 pages:713-718 |
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Bond Distance Ferromagnetic Interaction Heterometallic Complex Single Molecule Magnet CuGd |
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Transition metal chemistry |
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Hu, Kong-Qiu @@aut@@ Wu, Shu-Qi @@aut@@ Cui, Ai-Li @@aut@@ Kou, Hui-Zhong @@aut@@ |
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2014-07-05T00:00:00Z |
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The central Ln(III) ion is surrounded by two neutral [Cu($ H_{2} $L)($ CH_{3} $OH)] moieties, forming a $ Cu_{2} $Ln trinuclear unit. The [Fe(CN)6]3− anion is weakly coordinated to one Cu(II) ion of [Cu($ H_{2} $L)($ CH_{3} $OH)] through a cyanide nitrogen atom with the N–Cu distance of ca. 3.2 Å. Magnetic susceptibility measurements indicate the presence of overall ferromagnetic interactions in complexes 1 and 2. The magnetic coupling constant in complex 1 is JCu1Gd1 = 4.54 $ cm^{−1} $ and JCu2Gd1 = 7.97 $ cm^{−1} $ based on %$ \hat{H} = - 2J_{\text{Cu1Gd1}} \hat{S}_{\text{Cu1Gd1}} - 2J_{\text{Cu2Gd1}} \hat{S}_{\text{Cu2Gd1}} %$. Dynamic AC magnetic susceptibility studies reveal that complex 2 shows frequency-dependent out-of-phase signals, typical of single molecule magnet behavior. 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Hu, Kong-Qiu |
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Hu, Kong-Qiu ddc 660 bkl 58.00 misc Bond Distance misc Ferromagnetic Interaction misc Heterometallic Complex misc Single Molecule Magnet misc CuGd Synthesis, structure, and magnetic properties of heterotrimetallic tetranuclear complexes |
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660 ASE 58.00 bkl Synthesis, structure, and magnetic properties of heterotrimetallic tetranuclear complexes Bond Distance (dpeaa)DE-He213 Ferromagnetic Interaction (dpeaa)DE-He213 Heterometallic Complex (dpeaa)DE-He213 Single Molecule Magnet (dpeaa)DE-He213 CuGd (dpeaa)DE-He213 |
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synthesis, structure, and magnetic properties of heterotrimetallic tetranuclear complexes |
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Synthesis, structure, and magnetic properties of heterotrimetallic tetranuclear complexes |
| abstract |
Abstract Two novel heterotrimetallic tetranuclear complexes [Cu($ H_{2} $L)($ CH_{3} $OH)]2Gd(DMF)Fe(CN)6·$ 2H_{2} $O·DMF (1) and [Cu($ H_{2} $L)($ CH_{3} $OH)]2Tb($ H_{2} $O)0.57(DMF)0.43Fe(CN)6·5.$ 5H_{2} $O (2) are reported ($ H_{4} $L = N,N′-ethylenebis(3-hydroxysalicylidene)). The central Ln(III) ion is surrounded by two neutral [Cu($ H_{2} $L)($ CH_{3} $OH)] moieties, forming a $ Cu_{2} $Ln trinuclear unit. The [Fe(CN)6]3− anion is weakly coordinated to one Cu(II) ion of [Cu($ H_{2} $L)($ CH_{3} $OH)] through a cyanide nitrogen atom with the N–Cu distance of ca. 3.2 Å. Magnetic susceptibility measurements indicate the presence of overall ferromagnetic interactions in complexes 1 and 2. The magnetic coupling constant in complex 1 is JCu1Gd1 = 4.54 $ cm^{−1} $ and JCu2Gd1 = 7.97 $ cm^{−1} $ based on %$ \hat{H} = - 2J_{\text{Cu1Gd1}} \hat{S}_{\text{Cu1Gd1}} - 2J_{\text{Cu2Gd1}} \hat{S}_{\text{Cu2Gd1}} %$. Dynamic AC magnetic susceptibility studies reveal that complex 2 shows frequency-dependent out-of-phase signals, typical of single molecule magnet behavior. The energy barrier for complex 2 under a 2 kOe applied DC magnetic field is 13 K. |
| abstractGer |
Abstract Two novel heterotrimetallic tetranuclear complexes [Cu($ H_{2} $L)($ CH_{3} $OH)]2Gd(DMF)Fe(CN)6·$ 2H_{2} $O·DMF (1) and [Cu($ H_{2} $L)($ CH_{3} $OH)]2Tb($ H_{2} $O)0.57(DMF)0.43Fe(CN)6·5.$ 5H_{2} $O (2) are reported ($ H_{4} $L = N,N′-ethylenebis(3-hydroxysalicylidene)). The central Ln(III) ion is surrounded by two neutral [Cu($ H_{2} $L)($ CH_{3} $OH)] moieties, forming a $ Cu_{2} $Ln trinuclear unit. The [Fe(CN)6]3− anion is weakly coordinated to one Cu(II) ion of [Cu($ H_{2} $L)($ CH_{3} $OH)] through a cyanide nitrogen atom with the N–Cu distance of ca. 3.2 Å. Magnetic susceptibility measurements indicate the presence of overall ferromagnetic interactions in complexes 1 and 2. The magnetic coupling constant in complex 1 is JCu1Gd1 = 4.54 $ cm^{−1} $ and JCu2Gd1 = 7.97 $ cm^{−1} $ based on %$ \hat{H} = - 2J_{\text{Cu1Gd1}} \hat{S}_{\text{Cu1Gd1}} - 2J_{\text{Cu2Gd1}} \hat{S}_{\text{Cu2Gd1}} %$. Dynamic AC magnetic susceptibility studies reveal that complex 2 shows frequency-dependent out-of-phase signals, typical of single molecule magnet behavior. The energy barrier for complex 2 under a 2 kOe applied DC magnetic field is 13 K. |
| abstract_unstemmed |
Abstract Two novel heterotrimetallic tetranuclear complexes [Cu($ H_{2} $L)($ CH_{3} $OH)]2Gd(DMF)Fe(CN)6·$ 2H_{2} $O·DMF (1) and [Cu($ H_{2} $L)($ CH_{3} $OH)]2Tb($ H_{2} $O)0.57(DMF)0.43Fe(CN)6·5.$ 5H_{2} $O (2) are reported ($ H_{4} $L = N,N′-ethylenebis(3-hydroxysalicylidene)). The central Ln(III) ion is surrounded by two neutral [Cu($ H_{2} $L)($ CH_{3} $OH)] moieties, forming a $ Cu_{2} $Ln trinuclear unit. The [Fe(CN)6]3− anion is weakly coordinated to one Cu(II) ion of [Cu($ H_{2} $L)($ CH_{3} $OH)] through a cyanide nitrogen atom with the N–Cu distance of ca. 3.2 Å. Magnetic susceptibility measurements indicate the presence of overall ferromagnetic interactions in complexes 1 and 2. The magnetic coupling constant in complex 1 is JCu1Gd1 = 4.54 $ cm^{−1} $ and JCu2Gd1 = 7.97 $ cm^{−1} $ based on %$ \hat{H} = - 2J_{\text{Cu1Gd1}} \hat{S}_{\text{Cu1Gd1}} - 2J_{\text{Cu2Gd1}} \hat{S}_{\text{Cu2Gd1}} %$. Dynamic AC magnetic susceptibility studies reveal that complex 2 shows frequency-dependent out-of-phase signals, typical of single molecule magnet behavior. The energy barrier for complex 2 under a 2 kOe applied DC magnetic field is 13 K. |
| collection_details |
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| container_issue |
6 |
| title_short |
Synthesis, structure, and magnetic properties of heterotrimetallic tetranuclear complexes |
| url |
https://dx.doi.org/10.1007/s11243-014-9854-5 |
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| author2 |
Wu, Shu-Qi Cui, Ai-Li Kou, Hui-Zhong |
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Wu, Shu-Qi Cui, Ai-Li Kou, Hui-Zhong |
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| doi_str |
10.1007/s11243-014-9854-5 |
| up_date |
2024-07-03T17:20:44.790Z |
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| score |
7.3996077 |