Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes
Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-met...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Ni, ZhongHai [verfasserIn] Zhang, LiFang [verfasserIn] Cui, AiLi [verfasserIn] Kou, HuiZhong [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2009 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Science in China - Asheville, NC : Science in China Press, 1995, 52(2009), 9 vom: Sept., Seite 1444-1450 |
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| Übergeordnetes Werk: |
volume:52 ; year:2009 ; number:9 ; month:09 ; pages:1444-1450 |
| Links: |
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| DOI / URN: |
10.1007/s11426-009-0162-4 |
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| Katalog-ID: |
SPR019154186 |
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| 520 | |a Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian %$. | ||
| 650 | 4 | |a polynuclear complex |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a crystal structure |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a magnetic property |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a cyanide |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a chromium |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a manganese |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Zhang, LiFang |e verfasserin |4 aut | |
| 700 | 1 | |a Cui, AiLi |e verfasserin |4 aut | |
| 700 | 1 | |a Kou, HuiZhong |e verfasserin |4 aut | |
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| 773 | 1 | 8 | |g volume:52 |g year:2009 |g number:9 |g month:09 |g pages:1444-1450 |
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10.1007/s11426-009-0162-4 doi (DE-627)SPR019154186 (SPR)s11426-009-0162-4-e DE-627 ger DE-627 rakwb eng 540 550 570 ASE 35.00 bkl Ni, ZhongHai verfasserin aut Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian %$. polynuclear complex (dpeaa)DE-He213 crystal structure (dpeaa)DE-He213 magnetic property (dpeaa)DE-He213 cyanide (dpeaa)DE-He213 chromium (dpeaa)DE-He213 manganese (dpeaa)DE-He213 Zhang, LiFang verfasserin aut Cui, AiLi verfasserin aut Kou, HuiZhong verfasserin aut Enthalten in Science in China Asheville, NC : Science in China Press, 1995 52(2009), 9 vom: Sept., Seite 1444-1450 (DE-627)327310405 (DE-600)2043454-6 1862-2771 nnns volume:52 year:2009 number:9 month:09 pages:1444-1450 https://dx.doi.org/10.1007/s11426-009-0162-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 52 2009 9 09 1444-1450 |
| spelling |
10.1007/s11426-009-0162-4 doi (DE-627)SPR019154186 (SPR)s11426-009-0162-4-e DE-627 ger DE-627 rakwb eng 540 550 570 ASE 35.00 bkl Ni, ZhongHai verfasserin aut Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian %$. polynuclear complex (dpeaa)DE-He213 crystal structure (dpeaa)DE-He213 magnetic property (dpeaa)DE-He213 cyanide (dpeaa)DE-He213 chromium (dpeaa)DE-He213 manganese (dpeaa)DE-He213 Zhang, LiFang verfasserin aut Cui, AiLi verfasserin aut Kou, HuiZhong verfasserin aut Enthalten in Science in China Asheville, NC : Science in China Press, 1995 52(2009), 9 vom: Sept., Seite 1444-1450 (DE-627)327310405 (DE-600)2043454-6 1862-2771 nnns volume:52 year:2009 number:9 month:09 pages:1444-1450 https://dx.doi.org/10.1007/s11426-009-0162-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 52 2009 9 09 1444-1450 |
| allfields_unstemmed |
10.1007/s11426-009-0162-4 doi (DE-627)SPR019154186 (SPR)s11426-009-0162-4-e DE-627 ger DE-627 rakwb eng 540 550 570 ASE 35.00 bkl Ni, ZhongHai verfasserin aut Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian %$. polynuclear complex (dpeaa)DE-He213 crystal structure (dpeaa)DE-He213 magnetic property (dpeaa)DE-He213 cyanide (dpeaa)DE-He213 chromium (dpeaa)DE-He213 manganese (dpeaa)DE-He213 Zhang, LiFang verfasserin aut Cui, AiLi verfasserin aut Kou, HuiZhong verfasserin aut Enthalten in Science in China Asheville, NC : Science in China Press, 1995 52(2009), 9 vom: Sept., Seite 1444-1450 (DE-627)327310405 (DE-600)2043454-6 1862-2771 nnns volume:52 year:2009 number:9 month:09 pages:1444-1450 https://dx.doi.org/10.1007/s11426-009-0162-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 52 2009 9 09 1444-1450 |
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10.1007/s11426-009-0162-4 doi (DE-627)SPR019154186 (SPR)s11426-009-0162-4-e DE-627 ger DE-627 rakwb eng 540 550 570 ASE 35.00 bkl Ni, ZhongHai verfasserin aut Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian %$. polynuclear complex (dpeaa)DE-He213 crystal structure (dpeaa)DE-He213 magnetic property (dpeaa)DE-He213 cyanide (dpeaa)DE-He213 chromium (dpeaa)DE-He213 manganese (dpeaa)DE-He213 Zhang, LiFang verfasserin aut Cui, AiLi verfasserin aut Kou, HuiZhong verfasserin aut Enthalten in Science in China Asheville, NC : Science in China Press, 1995 52(2009), 9 vom: Sept., Seite 1444-1450 (DE-627)327310405 (DE-600)2043454-6 1862-2771 nnns volume:52 year:2009 number:9 month:09 pages:1444-1450 https://dx.doi.org/10.1007/s11426-009-0162-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 52 2009 9 09 1444-1450 |
| allfieldsSound |
10.1007/s11426-009-0162-4 doi (DE-627)SPR019154186 (SPR)s11426-009-0162-4-e DE-627 ger DE-627 rakwb eng 540 550 570 ASE 35.00 bkl Ni, ZhongHai verfasserin aut Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian %$. polynuclear complex (dpeaa)DE-He213 crystal structure (dpeaa)DE-He213 magnetic property (dpeaa)DE-He213 cyanide (dpeaa)DE-He213 chromium (dpeaa)DE-He213 manganese (dpeaa)DE-He213 Zhang, LiFang verfasserin aut Cui, AiLi verfasserin aut Kou, HuiZhong verfasserin aut Enthalten in Science in China Asheville, NC : Science in China Press, 1995 52(2009), 9 vom: Sept., Seite 1444-1450 (DE-627)327310405 (DE-600)2043454-6 1862-2771 nnns volume:52 year:2009 number:9 month:09 pages:1444-1450 https://dx.doi.org/10.1007/s11426-009-0162-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 ASE AR 52 2009 9 09 1444-1450 |
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English |
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Enthalten in Science in China 52(2009), 9 vom: Sept., Seite 1444-1450 volume:52 year:2009 number:9 month:09 pages:1444-1450 |
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Enthalten in Science in China 52(2009), 9 vom: Sept., Seite 1444-1450 volume:52 year:2009 number:9 month:09 pages:1444-1450 |
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polynuclear complex crystal structure magnetic property cyanide chromium manganese |
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Science in China |
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Ni, ZhongHai @@aut@@ Zhang, LiFang @@aut@@ Cui, AiLi @@aut@@ Kou, HuiZhong @@aut@@ |
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2009-09-01T00:00:00Z |
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The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. 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Ni, ZhongHai |
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Ni, ZhongHai ddc 540 bkl 35.00 misc polynuclear complex misc crystal structure misc magnetic property misc cyanide misc chromium misc manganese Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes |
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540 550 570 ASE 35.00 bkl Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes polynuclear complex (dpeaa)DE-He213 crystal structure (dpeaa)DE-He213 magnetic property (dpeaa)DE-He213 cyanide (dpeaa)DE-He213 chromium (dpeaa)DE-He213 manganese (dpeaa)DE-He213 |
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Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes |
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Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes |
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synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes |
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Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes |
| abstract |
Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian %$. |
| abstractGer |
Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian %$. |
| abstract_unstemmed |
Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian %$. |
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| container_issue |
9 |
| title_short |
Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes |
| url |
https://dx.doi.org/10.1007/s11426-009-0162-4 |
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Zhang, LiFang Cui, AiLi Kou, HuiZhong |
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| doi_str |
10.1007/s11426-009-0162-4 |
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2024-07-04T00:23:54.648Z |
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| score |
7.401311 |