X-ray scintillation in lead-free double perovskite crystals

Abstract Metal halide perovskites have shown great performance for various applications, including solar cells, light emitting diodes, and radiation detectors, but they still suffer from the toxicity of lead and instability. Here we report the use of lanthanide series as trivalent metals to obtain l...
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Autor*in:	Hu, Qingsong [verfasserIn] Deng, Zhenzhou [verfasserIn] Hu, Manchen [verfasserIn] Zhao, Anjiang [verfasserIn] Zhang, Yaqi [verfasserIn] Tan, Zhifang [verfasserIn] Niu, Guangda [verfasserIn] Wu, Haodi [verfasserIn] Tang, Jiang [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2018

Schlagwörter:	low toxic scintillation light yield lanthanide double perovskites

Übergeordnetes Werk:	Enthalten in: Science in China - Asheville, NC : Science in China Press, 1995, 61(2018), 12 vom: 02. Aug., Seite 1581-1586
Übergeordnetes Werk:	volume:61 ; year:2018 ; number:12 ; day:02 ; month:08 ; pages:1581-1586

Links:	Volltext

DOI / URN:	10.1007/s11426-018-9308-2

Katalog-ID:	SPR019178247

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allfields	10.1007/s11426-018-9308-2 doi (DE-627)SPR019178247 (SPR)s11426-018-9308-2-e DE-627 ger DE-627 rakwb eng 540 550 570 ASE 35.00 bkl Hu, Qingsong verfasserin aut X-ray scintillation in lead-free double perovskite crystals 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Metal halide perovskites have shown great performance for various applications, including solar cells, light emitting diodes, and radiation detectors, but they still suffer from the toxicity of lead and instability. Here we report the use of lanthanide series as trivalent metals to obtain low toxicity and highly stable double perovskites ($ Cs_{2} %$ NaLnCl_{6} $, Ln=Tb or Eu) with high scintillation light yield. The crystals exhibit typical f-f transitions of lanthanide cations, while $ Cs_{2} %$ NaTbCl_{6} $ exhibits strong green photoluminescence, and $ Cs_{2} %$ NaEuCl_{6} $ exhibits red photoluminescence. Under X-ray radiations, the light yield of $ Cs_{2} %$ NaTbCl_{6} $ reaches 46600 photons $ MeV^{−1} $, much higher than that of the commercially used (Lu,Y)2$ SiO_{5} $:$ Ce^{3+} $ crystals (LYSO, 28500 photons $ MeV^{−1} $), and previously reported lead-based perovskites (14000 photons $ MeV^{−1} $). As a new member of lead-free perovskites, lanthanide-based double perovskites open up a new route toward radiation detections and potential medical imaging. low toxic (dpeaa)DE-He213 scintillation (dpeaa)DE-He213 light yield (dpeaa)DE-He213 lanthanide (dpeaa)DE-He213 double perovskites (dpeaa)DE-He213 Deng, Zhenzhou verfasserin aut Hu, Manchen verfasserin aut Zhao, Anjiang verfasserin aut Zhang, Yaqi verfasserin aut Tan, Zhifang verfasserin aut Niu, Guangda verfasserin aut Wu, Haodi verfasserin aut Tang, Jiang verfasserin aut Enthalten in Science in China Asheville, NC : Science in China Press, 1995 61(2018), 12 vom: 02. Aug., Seite 1581-1586 (DE-627)327310405 (DE-600)2043454-6 1862-2771 nnns volume:61 year:2018 number:12 day:02 month:08 pages:1581-1586 https://dx.doi.org/10.1007/s11426-018-9308-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.00 ASE AR 61 2018 12 02 08 1581-1586
spelling	10.1007/s11426-018-9308-2 doi (DE-627)SPR019178247 (SPR)s11426-018-9308-2-e DE-627 ger DE-627 rakwb eng 540 550 570 ASE 35.00 bkl Hu, Qingsong verfasserin aut X-ray scintillation in lead-free double perovskite crystals 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Metal halide perovskites have shown great performance for various applications, including solar cells, light emitting diodes, and radiation detectors, but they still suffer from the toxicity of lead and instability. Here we report the use of lanthanide series as trivalent metals to obtain low toxicity and highly stable double perovskites ($ Cs_{2} %$ NaLnCl_{6} $, Ln=Tb or Eu) with high scintillation light yield. The crystals exhibit typical f-f transitions of lanthanide cations, while $ Cs_{2} %$ NaTbCl_{6} $ exhibits strong green photoluminescence, and $ Cs_{2} %$ NaEuCl_{6} $ exhibits red photoluminescence. Under X-ray radiations, the light yield of $ Cs_{2} %$ NaTbCl_{6} $ reaches 46600 photons $ MeV^{−1} $, much higher than that of the commercially used (Lu,Y)2$ SiO_{5} $:$ Ce^{3+} $ crystals (LYSO, 28500 photons $ MeV^{−1} $), and previously reported lead-based perovskites (14000 photons $ MeV^{−1} $). As a new member of lead-free perovskites, lanthanide-based double perovskites open up a new route toward radiation detections and potential medical imaging. low toxic (dpeaa)DE-He213 scintillation (dpeaa)DE-He213 light yield (dpeaa)DE-He213 lanthanide (dpeaa)DE-He213 double perovskites (dpeaa)DE-He213 Deng, Zhenzhou verfasserin aut Hu, Manchen verfasserin aut Zhao, Anjiang verfasserin aut Zhang, Yaqi verfasserin aut Tan, Zhifang verfasserin aut Niu, Guangda verfasserin aut Wu, Haodi verfasserin aut Tang, Jiang verfasserin aut Enthalten in Science in China Asheville, NC : Science in China Press, 1995 61(2018), 12 vom: 02. Aug., Seite 1581-1586 (DE-627)327310405 (DE-600)2043454-6 1862-2771 nnns volume:61 year:2018 number:12 day:02 month:08 pages:1581-1586 https://dx.doi.org/10.1007/s11426-018-9308-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.00 ASE AR 61 2018 12 02 08 1581-1586
allfields_unstemmed	10.1007/s11426-018-9308-2 doi (DE-627)SPR019178247 (SPR)s11426-018-9308-2-e DE-627 ger DE-627 rakwb eng 540 550 570 ASE 35.00 bkl Hu, Qingsong verfasserin aut X-ray scintillation in lead-free double perovskite crystals 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Metal halide perovskites have shown great performance for various applications, including solar cells, light emitting diodes, and radiation detectors, but they still suffer from the toxicity of lead and instability. Here we report the use of lanthanide series as trivalent metals to obtain low toxicity and highly stable double perovskites ($ Cs_{2} %$ NaLnCl_{6} $, Ln=Tb or Eu) with high scintillation light yield. The crystals exhibit typical f-f transitions of lanthanide cations, while $ Cs_{2} %$ NaTbCl_{6} $ exhibits strong green photoluminescence, and $ Cs_{2} %$ NaEuCl_{6} $ exhibits red photoluminescence. Under X-ray radiations, the light yield of $ Cs_{2} %$ NaTbCl_{6} $ reaches 46600 photons $ MeV^{−1} $, much higher than that of the commercially used (Lu,Y)2$ SiO_{5} $:$ Ce^{3+} $ crystals (LYSO, 28500 photons $ MeV^{−1} $), and previously reported lead-based perovskites (14000 photons $ MeV^{−1} $). As a new member of lead-free perovskites, lanthanide-based double perovskites open up a new route toward radiation detections and potential medical imaging. low toxic (dpeaa)DE-He213 scintillation (dpeaa)DE-He213 light yield (dpeaa)DE-He213 lanthanide (dpeaa)DE-He213 double perovskites (dpeaa)DE-He213 Deng, Zhenzhou verfasserin aut Hu, Manchen verfasserin aut Zhao, Anjiang verfasserin aut Zhang, Yaqi verfasserin aut Tan, Zhifang verfasserin aut Niu, Guangda verfasserin aut Wu, Haodi verfasserin aut Tang, Jiang verfasserin aut Enthalten in Science in China Asheville, NC : Science in China Press, 1995 61(2018), 12 vom: 02. Aug., Seite 1581-1586 (DE-627)327310405 (DE-600)2043454-6 1862-2771 nnns volume:61 year:2018 number:12 day:02 month:08 pages:1581-1586 https://dx.doi.org/10.1007/s11426-018-9308-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.00 ASE AR 61 2018 12 02 08 1581-1586
allfieldsGer	10.1007/s11426-018-9308-2 doi (DE-627)SPR019178247 (SPR)s11426-018-9308-2-e DE-627 ger DE-627 rakwb eng 540 550 570 ASE 35.00 bkl Hu, Qingsong verfasserin aut X-ray scintillation in lead-free double perovskite crystals 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Metal halide perovskites have shown great performance for various applications, including solar cells, light emitting diodes, and radiation detectors, but they still suffer from the toxicity of lead and instability. Here we report the use of lanthanide series as trivalent metals to obtain low toxicity and highly stable double perovskites ($ Cs_{2} %$ NaLnCl_{6} $, Ln=Tb or Eu) with high scintillation light yield. The crystals exhibit typical f-f transitions of lanthanide cations, while $ Cs_{2} %$ NaTbCl_{6} $ exhibits strong green photoluminescence, and $ Cs_{2} %$ NaEuCl_{6} $ exhibits red photoluminescence. Under X-ray radiations, the light yield of $ Cs_{2} %$ NaTbCl_{6} $ reaches 46600 photons $ MeV^{−1} $, much higher than that of the commercially used (Lu,Y)2$ SiO_{5} $:$ Ce^{3+} $ crystals (LYSO, 28500 photons $ MeV^{−1} $), and previously reported lead-based perovskites (14000 photons $ MeV^{−1} $). As a new member of lead-free perovskites, lanthanide-based double perovskites open up a new route toward radiation detections and potential medical imaging. low toxic (dpeaa)DE-He213 scintillation (dpeaa)DE-He213 light yield (dpeaa)DE-He213 lanthanide (dpeaa)DE-He213 double perovskites (dpeaa)DE-He213 Deng, Zhenzhou verfasserin aut Hu, Manchen verfasserin aut Zhao, Anjiang verfasserin aut Zhang, Yaqi verfasserin aut Tan, Zhifang verfasserin aut Niu, Guangda verfasserin aut Wu, Haodi verfasserin aut Tang, Jiang verfasserin aut Enthalten in Science in China Asheville, NC : Science in China Press, 1995 61(2018), 12 vom: 02. Aug., Seite 1581-1586 (DE-627)327310405 (DE-600)2043454-6 1862-2771 nnns volume:61 year:2018 number:12 day:02 month:08 pages:1581-1586 https://dx.doi.org/10.1007/s11426-018-9308-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.00 ASE AR 61 2018 12 02 08 1581-1586
allfieldsSound	10.1007/s11426-018-9308-2 doi (DE-627)SPR019178247 (SPR)s11426-018-9308-2-e DE-627 ger DE-627 rakwb eng 540 550 570 ASE 35.00 bkl Hu, Qingsong verfasserin aut X-ray scintillation in lead-free double perovskite crystals 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Metal halide perovskites have shown great performance for various applications, including solar cells, light emitting diodes, and radiation detectors, but they still suffer from the toxicity of lead and instability. Here we report the use of lanthanide series as trivalent metals to obtain low toxicity and highly stable double perovskites ($ Cs_{2} %$ NaLnCl_{6} $, Ln=Tb or Eu) with high scintillation light yield. The crystals exhibit typical f-f transitions of lanthanide cations, while $ Cs_{2} %$ NaTbCl_{6} $ exhibits strong green photoluminescence, and $ Cs_{2} %$ NaEuCl_{6} $ exhibits red photoluminescence. Under X-ray radiations, the light yield of $ Cs_{2} %$ NaTbCl_{6} $ reaches 46600 photons $ MeV^{−1} $, much higher than that of the commercially used (Lu,Y)2$ SiO_{5} $:$ Ce^{3+} $ crystals (LYSO, 28500 photons $ MeV^{−1} $), and previously reported lead-based perovskites (14000 photons $ MeV^{−1} $). As a new member of lead-free perovskites, lanthanide-based double perovskites open up a new route toward radiation detections and potential medical imaging. low toxic (dpeaa)DE-He213 scintillation (dpeaa)DE-He213 light yield (dpeaa)DE-He213 lanthanide (dpeaa)DE-He213 double perovskites (dpeaa)DE-He213 Deng, Zhenzhou verfasserin aut Hu, Manchen verfasserin aut Zhao, Anjiang verfasserin aut Zhang, Yaqi verfasserin aut Tan, Zhifang verfasserin aut Niu, Guangda verfasserin aut Wu, Haodi verfasserin aut Tang, Jiang verfasserin aut Enthalten in Science in China Asheville, NC : Science in China Press, 1995 61(2018), 12 vom: 02. Aug., Seite 1581-1586 (DE-627)327310405 (DE-600)2043454-6 1862-2771 nnns volume:61 year:2018 number:12 day:02 month:08 pages:1581-1586 https://dx.doi.org/10.1007/s11426-018-9308-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 35.00 ASE AR 61 2018 12 02 08 1581-1586
language	English
source	Enthalten in Science in China 61(2018), 12 vom: 02. Aug., Seite 1581-1586 volume:61 year:2018 number:12 day:02 month:08 pages:1581-1586
sourceStr	Enthalten in Science in China 61(2018), 12 vom: 02. Aug., Seite 1581-1586 volume:61 year:2018 number:12 day:02 month:08 pages:1581-1586
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institution	findex.gbv.de
topic_facet	low toxic scintillation light yield lanthanide double perovskites
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container_title	Science in China
authorswithroles_txt_mv	Hu, Qingsong @@aut@@ Deng, Zhenzhou @@aut@@ Hu, Manchen @@aut@@ Zhao, Anjiang @@aut@@ Zhang, Yaqi @@aut@@ Tan, Zhifang @@aut@@ Niu, Guangda @@aut@@ Wu, Haodi @@aut@@ Tang, Jiang @@aut@@
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author	Hu, Qingsong
spellingShingle	Hu, Qingsong ddc 540 bkl 35.00 misc low toxic misc scintillation misc light yield misc lanthanide misc double perovskites X-ray scintillation in lead-free double perovskite crystals
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topic_title	540 550 570 ASE 35.00 bkl X-ray scintillation in lead-free double perovskite crystals low toxic (dpeaa)DE-He213 scintillation (dpeaa)DE-He213 light yield (dpeaa)DE-He213 lanthanide (dpeaa)DE-He213 double perovskites (dpeaa)DE-He213
topic	ddc 540 bkl 35.00 misc low toxic misc scintillation misc light yield misc lanthanide misc double perovskites
topic_unstemmed	ddc 540 bkl 35.00 misc low toxic misc scintillation misc light yield misc lanthanide misc double perovskites
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title	X-ray scintillation in lead-free double perovskite crystals
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title_full	X-ray scintillation in lead-free double perovskite crystals
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author_browse	Hu, Qingsong Deng, Zhenzhou Hu, Manchen Zhao, Anjiang Zhang, Yaqi Tan, Zhifang Niu, Guangda Wu, Haodi Tang, Jiang
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title_sort	x-ray scintillation in lead-free double perovskite crystals
title_auth	X-ray scintillation in lead-free double perovskite crystals
abstract	Abstract Metal halide perovskites have shown great performance for various applications, including solar cells, light emitting diodes, and radiation detectors, but they still suffer from the toxicity of lead and instability. Here we report the use of lanthanide series as trivalent metals to obtain low toxicity and highly stable double perovskites ($ Cs_{2} %$ NaLnCl_{6} $, Ln=Tb or Eu) with high scintillation light yield. The crystals exhibit typical f-f transitions of lanthanide cations, while $ Cs_{2} %$ NaTbCl_{6} $ exhibits strong green photoluminescence, and $ Cs_{2} %$ NaEuCl_{6} $ exhibits red photoluminescence. Under X-ray radiations, the light yield of $ Cs_{2} %$ NaTbCl_{6} $ reaches 46600 photons $ MeV^{−1} $, much higher than that of the commercially used (Lu,Y)2$ SiO_{5} $:$ Ce^{3+} $ crystals (LYSO, 28500 photons $ MeV^{−1} $), and previously reported lead-based perovskites (14000 photons $ MeV^{−1} $). As a new member of lead-free perovskites, lanthanide-based double perovskites open up a new route toward radiation detections and potential medical imaging.
abstractGer	Abstract Metal halide perovskites have shown great performance for various applications, including solar cells, light emitting diodes, and radiation detectors, but they still suffer from the toxicity of lead and instability. Here we report the use of lanthanide series as trivalent metals to obtain low toxicity and highly stable double perovskites ($ Cs_{2} %$ NaLnCl_{6} $, Ln=Tb or Eu) with high scintillation light yield. The crystals exhibit typical f-f transitions of lanthanide cations, while $ Cs_{2} %$ NaTbCl_{6} $ exhibits strong green photoluminescence, and $ Cs_{2} %$ NaEuCl_{6} $ exhibits red photoluminescence. Under X-ray radiations, the light yield of $ Cs_{2} %$ NaTbCl_{6} $ reaches 46600 photons $ MeV^{−1} $, much higher than that of the commercially used (Lu,Y)2$ SiO_{5} $:$ Ce^{3+} $ crystals (LYSO, 28500 photons $ MeV^{−1} $), and previously reported lead-based perovskites (14000 photons $ MeV^{−1} $). As a new member of lead-free perovskites, lanthanide-based double perovskites open up a new route toward radiation detections and potential medical imaging.
abstract_unstemmed	Abstract Metal halide perovskites have shown great performance for various applications, including solar cells, light emitting diodes, and radiation detectors, but they still suffer from the toxicity of lead and instability. Here we report the use of lanthanide series as trivalent metals to obtain low toxicity and highly stable double perovskites ($ Cs_{2} %$ NaLnCl_{6} $, Ln=Tb or Eu) with high scintillation light yield. The crystals exhibit typical f-f transitions of lanthanide cations, while $ Cs_{2} %$ NaTbCl_{6} $ exhibits strong green photoluminescence, and $ Cs_{2} %$ NaEuCl_{6} $ exhibits red photoluminescence. Under X-ray radiations, the light yield of $ Cs_{2} %$ NaTbCl_{6} $ reaches 46600 photons $ MeV^{−1} $, much higher than that of the commercially used (Lu,Y)2$ SiO_{5} $:$ Ce^{3+} $ crystals (LYSO, 28500 photons $ MeV^{−1} $), and previously reported lead-based perovskites (14000 photons $ MeV^{−1} $). As a new member of lead-free perovskites, lanthanide-based double perovskites open up a new route toward radiation detections and potential medical imaging.
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702
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title_short	X-ray scintillation in lead-free double perovskite crystals
url	https://dx.doi.org/10.1007/s11426-018-9308-2
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author2	Deng, Zhenzhou Hu, Manchen Zhao, Anjiang Zhang, Yaqi Tan, Zhifang Niu, Guangda Wu, Haodi Tang, Jiang
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up_date	2024-07-04T00:29:39.430Z
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Here we report the use of lanthanide series as trivalent metals to obtain low toxicity and highly stable double perovskites ($ Cs_{2} %$ NaLnCl_{6} $, Ln=Tb or Eu) with high scintillation light yield. The crystals exhibit typical f-f transitions of lanthanide cations, while $ Cs_{2} %$ NaTbCl_{6} $ exhibits strong green photoluminescence, and $ Cs_{2} %$ NaEuCl_{6} $ exhibits red photoluminescence. Under X-ray radiations, the light yield of $ Cs_{2} %$ NaTbCl_{6} $ reaches 46600 photons $ MeV^{−1} $, much higher than that of the commercially used (Lu,Y)2$ SiO_{5} $:$ Ce^{3+} $ crystals (LYSO, 28500 photons $ MeV^{−1} $), and previously reported lead-based perovskites (14000 photons $ MeV^{−1} $). 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Aug., Seite 1581-1586</subfield><subfield code="w">(DE-627)327310405</subfield><subfield code="w">(DE-600)2043454-6</subfield><subfield code="x">1862-2771</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:61</subfield><subfield code="g">year:2018</subfield><subfield code="g">number:12</subfield><subfield code="g">day:02</subfield><subfield code="g">month:08</subfield><subfield code="g">pages:1581-1586</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s11426-018-9308-2</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_101</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_120</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_138</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_171</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_250</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_281</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.00</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">61</subfield><subfield code="j">2018</subfield><subfield code="e">12</subfield><subfield code="b">02</subfield><subfield code="c">08</subfield><subfield code="h">1581-1586</subfield></datafield></record></collection>
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X-ray scintillation in lead-free double perovskite crystals

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