Effect of feeding ratios on the structure and electrochemical performance of graphite oxide/polypyrrole nanocomposites
Abstract Graphite oxide (GO)/polypyrrole (PPy) nanocomposites (GPYs) were synthesized using in situ polymerization. The effect of the feeding ratios of pyrrole and GO on the structure and electrochemical performances of GPYs was investigated. The structure was characterized via Fourier-transform inf...
Ausführliche Beschreibung
Autor*in: |
Han, YongQin [verfasserIn] Ding, Bing [verfasserIn] Zhang, XiaoGang [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2011 |
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Übergeordnetes Werk: |
Enthalten in: Chinese science bulletin - Beijing, China : Chinese Acad. of Sciences, 1997, 56(2011), 26 vom: 24. Aug. |
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Übergeordnetes Werk: |
volume:56 ; year:2011 ; number:26 ; day:24 ; month:08 |
Links: |
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DOI / URN: |
10.1007/s11434-011-4646-1 |
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Katalog-ID: |
SPR019941102 |
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520 | |a Abstract Graphite oxide (GO)/polypyrrole (PPy) nanocomposites (GPYs) were synthesized using in situ polymerization. The effect of the feeding ratios of pyrrole and GO on the structure and electrochemical performances of GPYs was investigated. The structure was characterized via Fourier-transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The electrochemical performance was characterized via cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy. The results indicate that the more pyrrole is added to GO (with GO concentrations of 20% and 50%), the more agglomeration of both PPy and GO layers occurs. This is detrimental to the capacitance utilization of PPy. When the feeding ratio of GO:pyrrole is 80:20, PPys with nanofibrils are dispersed homogenously in/on the exfoliated layer of GO and the conductivity is enhanced. The capacitance utilization of PPy in a composite with a GO concentration of 80% (383 F/g) is higher than that of pure PPy (201 F/g), which indicates the presence of a synergistic effect between GO and PPy. | ||
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10.1007/s11434-011-4646-1 doi (DE-627)SPR019941102 (SPR)s11434-011-4646-1-e DE-627 ger DE-627 rakwb eng 500 ASE 30.00 bkl Han, YongQin verfasserin aut Effect of feeding ratios on the structure and electrochemical performance of graphite oxide/polypyrrole nanocomposites 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Graphite oxide (GO)/polypyrrole (PPy) nanocomposites (GPYs) were synthesized using in situ polymerization. The effect of the feeding ratios of pyrrole and GO on the structure and electrochemical performances of GPYs was investigated. The structure was characterized via Fourier-transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The electrochemical performance was characterized via cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy. The results indicate that the more pyrrole is added to GO (with GO concentrations of 20% and 50%), the more agglomeration of both PPy and GO layers occurs. This is detrimental to the capacitance utilization of PPy. When the feeding ratio of GO:pyrrole is 80:20, PPys with nanofibrils are dispersed homogenously in/on the exfoliated layer of GO and the conductivity is enhanced. The capacitance utilization of PPy in a composite with a GO concentration of 80% (383 F/g) is higher than that of pure PPy (201 F/g), which indicates the presence of a synergistic effect between GO and PPy. graphite oxide (dpeaa)DE-He213 polypyrrole (dpeaa)DE-He213 nanocomposites (dpeaa)DE-He213 electrochemical performance (dpeaa)DE-He213 Ding, Bing verfasserin aut Zhang, XiaoGang verfasserin aut Enthalten in Chinese science bulletin Beijing, China : Chinese Acad. of Sciences, 1997 56(2011), 26 vom: 24. Aug. (DE-627)341897809 (DE-600)2069521-4 1861-9541 nnns volume:56 year:2011 number:26 day:24 month:08 https://dx.doi.org/10.1007/s11434-011-4646-1 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_213 GBV_ILN_230 GBV_ILN_266 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2055 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 30.00 ASE AR 56 2011 26 24 08 |
spelling |
10.1007/s11434-011-4646-1 doi (DE-627)SPR019941102 (SPR)s11434-011-4646-1-e DE-627 ger DE-627 rakwb eng 500 ASE 30.00 bkl Han, YongQin verfasserin aut Effect of feeding ratios on the structure and electrochemical performance of graphite oxide/polypyrrole nanocomposites 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Graphite oxide (GO)/polypyrrole (PPy) nanocomposites (GPYs) were synthesized using in situ polymerization. The effect of the feeding ratios of pyrrole and GO on the structure and electrochemical performances of GPYs was investigated. The structure was characterized via Fourier-transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The electrochemical performance was characterized via cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy. The results indicate that the more pyrrole is added to GO (with GO concentrations of 20% and 50%), the more agglomeration of both PPy and GO layers occurs. This is detrimental to the capacitance utilization of PPy. When the feeding ratio of GO:pyrrole is 80:20, PPys with nanofibrils are dispersed homogenously in/on the exfoliated layer of GO and the conductivity is enhanced. The capacitance utilization of PPy in a composite with a GO concentration of 80% (383 F/g) is higher than that of pure PPy (201 F/g), which indicates the presence of a synergistic effect between GO and PPy. graphite oxide (dpeaa)DE-He213 polypyrrole (dpeaa)DE-He213 nanocomposites (dpeaa)DE-He213 electrochemical performance (dpeaa)DE-He213 Ding, Bing verfasserin aut Zhang, XiaoGang verfasserin aut Enthalten in Chinese science bulletin Beijing, China : Chinese Acad. of Sciences, 1997 56(2011), 26 vom: 24. Aug. (DE-627)341897809 (DE-600)2069521-4 1861-9541 nnns volume:56 year:2011 number:26 day:24 month:08 https://dx.doi.org/10.1007/s11434-011-4646-1 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_213 GBV_ILN_230 GBV_ILN_266 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2055 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 30.00 ASE AR 56 2011 26 24 08 |
allfields_unstemmed |
10.1007/s11434-011-4646-1 doi (DE-627)SPR019941102 (SPR)s11434-011-4646-1-e DE-627 ger DE-627 rakwb eng 500 ASE 30.00 bkl Han, YongQin verfasserin aut Effect of feeding ratios on the structure and electrochemical performance of graphite oxide/polypyrrole nanocomposites 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Graphite oxide (GO)/polypyrrole (PPy) nanocomposites (GPYs) were synthesized using in situ polymerization. The effect of the feeding ratios of pyrrole and GO on the structure and electrochemical performances of GPYs was investigated. The structure was characterized via Fourier-transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The electrochemical performance was characterized via cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy. The results indicate that the more pyrrole is added to GO (with GO concentrations of 20% and 50%), the more agglomeration of both PPy and GO layers occurs. This is detrimental to the capacitance utilization of PPy. When the feeding ratio of GO:pyrrole is 80:20, PPys with nanofibrils are dispersed homogenously in/on the exfoliated layer of GO and the conductivity is enhanced. The capacitance utilization of PPy in a composite with a GO concentration of 80% (383 F/g) is higher than that of pure PPy (201 F/g), which indicates the presence of a synergistic effect between GO and PPy. graphite oxide (dpeaa)DE-He213 polypyrrole (dpeaa)DE-He213 nanocomposites (dpeaa)DE-He213 electrochemical performance (dpeaa)DE-He213 Ding, Bing verfasserin aut Zhang, XiaoGang verfasserin aut Enthalten in Chinese science bulletin Beijing, China : Chinese Acad. of Sciences, 1997 56(2011), 26 vom: 24. Aug. (DE-627)341897809 (DE-600)2069521-4 1861-9541 nnns volume:56 year:2011 number:26 day:24 month:08 https://dx.doi.org/10.1007/s11434-011-4646-1 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_213 GBV_ILN_230 GBV_ILN_266 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2055 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 30.00 ASE AR 56 2011 26 24 08 |
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10.1007/s11434-011-4646-1 doi (DE-627)SPR019941102 (SPR)s11434-011-4646-1-e DE-627 ger DE-627 rakwb eng 500 ASE 30.00 bkl Han, YongQin verfasserin aut Effect of feeding ratios on the structure and electrochemical performance of graphite oxide/polypyrrole nanocomposites 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Graphite oxide (GO)/polypyrrole (PPy) nanocomposites (GPYs) were synthesized using in situ polymerization. The effect of the feeding ratios of pyrrole and GO on the structure and electrochemical performances of GPYs was investigated. The structure was characterized via Fourier-transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The electrochemical performance was characterized via cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy. The results indicate that the more pyrrole is added to GO (with GO concentrations of 20% and 50%), the more agglomeration of both PPy and GO layers occurs. This is detrimental to the capacitance utilization of PPy. When the feeding ratio of GO:pyrrole is 80:20, PPys with nanofibrils are dispersed homogenously in/on the exfoliated layer of GO and the conductivity is enhanced. The capacitance utilization of PPy in a composite with a GO concentration of 80% (383 F/g) is higher than that of pure PPy (201 F/g), which indicates the presence of a synergistic effect between GO and PPy. graphite oxide (dpeaa)DE-He213 polypyrrole (dpeaa)DE-He213 nanocomposites (dpeaa)DE-He213 electrochemical performance (dpeaa)DE-He213 Ding, Bing verfasserin aut Zhang, XiaoGang verfasserin aut Enthalten in Chinese science bulletin Beijing, China : Chinese Acad. of Sciences, 1997 56(2011), 26 vom: 24. Aug. (DE-627)341897809 (DE-600)2069521-4 1861-9541 nnns volume:56 year:2011 number:26 day:24 month:08 https://dx.doi.org/10.1007/s11434-011-4646-1 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_213 GBV_ILN_230 GBV_ILN_266 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2055 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 30.00 ASE AR 56 2011 26 24 08 |
allfieldsSound |
10.1007/s11434-011-4646-1 doi (DE-627)SPR019941102 (SPR)s11434-011-4646-1-e DE-627 ger DE-627 rakwb eng 500 ASE 30.00 bkl Han, YongQin verfasserin aut Effect of feeding ratios on the structure and electrochemical performance of graphite oxide/polypyrrole nanocomposites 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract Graphite oxide (GO)/polypyrrole (PPy) nanocomposites (GPYs) were synthesized using in situ polymerization. The effect of the feeding ratios of pyrrole and GO on the structure and electrochemical performances of GPYs was investigated. The structure was characterized via Fourier-transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The electrochemical performance was characterized via cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy. The results indicate that the more pyrrole is added to GO (with GO concentrations of 20% and 50%), the more agglomeration of both PPy and GO layers occurs. This is detrimental to the capacitance utilization of PPy. When the feeding ratio of GO:pyrrole is 80:20, PPys with nanofibrils are dispersed homogenously in/on the exfoliated layer of GO and the conductivity is enhanced. The capacitance utilization of PPy in a composite with a GO concentration of 80% (383 F/g) is higher than that of pure PPy (201 F/g), which indicates the presence of a synergistic effect between GO and PPy. graphite oxide (dpeaa)DE-He213 polypyrrole (dpeaa)DE-He213 nanocomposites (dpeaa)DE-He213 electrochemical performance (dpeaa)DE-He213 Ding, Bing verfasserin aut Zhang, XiaoGang verfasserin aut Enthalten in Chinese science bulletin Beijing, China : Chinese Acad. of Sciences, 1997 56(2011), 26 vom: 24. Aug. (DE-627)341897809 (DE-600)2069521-4 1861-9541 nnns volume:56 year:2011 number:26 day:24 month:08 https://dx.doi.org/10.1007/s11434-011-4646-1 kostenfrei Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_95 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_213 GBV_ILN_230 GBV_ILN_266 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2055 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2522 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4367 GBV_ILN_4700 30.00 ASE AR 56 2011 26 24 08 |
language |
English |
source |
Enthalten in Chinese science bulletin 56(2011), 26 vom: 24. Aug. volume:56 year:2011 number:26 day:24 month:08 |
sourceStr |
Enthalten in Chinese science bulletin 56(2011), 26 vom: 24. Aug. volume:56 year:2011 number:26 day:24 month:08 |
format_phy_str_mv |
Article |
institution |
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topic_facet |
graphite oxide polypyrrole nanocomposites electrochemical performance |
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500 |
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Chinese science bulletin |
authorswithroles_txt_mv |
Han, YongQin @@aut@@ Ding, Bing @@aut@@ Zhang, XiaoGang @@aut@@ |
publishDateDaySort_date |
2011-08-24T00:00:00Z |
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Han, YongQin |
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Han, YongQin ddc 500 bkl 30.00 misc graphite oxide misc polypyrrole misc nanocomposites misc electrochemical performance Effect of feeding ratios on the structure and electrochemical performance of graphite oxide/polypyrrole nanocomposites |
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500 ASE 30.00 bkl Effect of feeding ratios on the structure and electrochemical performance of graphite oxide/polypyrrole nanocomposites graphite oxide (dpeaa)DE-He213 polypyrrole (dpeaa)DE-He213 nanocomposites (dpeaa)DE-He213 electrochemical performance (dpeaa)DE-He213 |
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Effect of feeding ratios on the structure and electrochemical performance of graphite oxide/polypyrrole nanocomposites |
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effect of feeding ratios on the structure and electrochemical performance of graphite oxide/polypyrrole nanocomposites |
title_auth |
Effect of feeding ratios on the structure and electrochemical performance of graphite oxide/polypyrrole nanocomposites |
abstract |
Abstract Graphite oxide (GO)/polypyrrole (PPy) nanocomposites (GPYs) were synthesized using in situ polymerization. The effect of the feeding ratios of pyrrole and GO on the structure and electrochemical performances of GPYs was investigated. The structure was characterized via Fourier-transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The electrochemical performance was characterized via cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy. The results indicate that the more pyrrole is added to GO (with GO concentrations of 20% and 50%), the more agglomeration of both PPy and GO layers occurs. This is detrimental to the capacitance utilization of PPy. When the feeding ratio of GO:pyrrole is 80:20, PPys with nanofibrils are dispersed homogenously in/on the exfoliated layer of GO and the conductivity is enhanced. The capacitance utilization of PPy in a composite with a GO concentration of 80% (383 F/g) is higher than that of pure PPy (201 F/g), which indicates the presence of a synergistic effect between GO and PPy. |
abstractGer |
Abstract Graphite oxide (GO)/polypyrrole (PPy) nanocomposites (GPYs) were synthesized using in situ polymerization. The effect of the feeding ratios of pyrrole and GO on the structure and electrochemical performances of GPYs was investigated. The structure was characterized via Fourier-transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The electrochemical performance was characterized via cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy. The results indicate that the more pyrrole is added to GO (with GO concentrations of 20% and 50%), the more agglomeration of both PPy and GO layers occurs. This is detrimental to the capacitance utilization of PPy. When the feeding ratio of GO:pyrrole is 80:20, PPys with nanofibrils are dispersed homogenously in/on the exfoliated layer of GO and the conductivity is enhanced. The capacitance utilization of PPy in a composite with a GO concentration of 80% (383 F/g) is higher than that of pure PPy (201 F/g), which indicates the presence of a synergistic effect between GO and PPy. |
abstract_unstemmed |
Abstract Graphite oxide (GO)/polypyrrole (PPy) nanocomposites (GPYs) were synthesized using in situ polymerization. The effect of the feeding ratios of pyrrole and GO on the structure and electrochemical performances of GPYs was investigated. The structure was characterized via Fourier-transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The electrochemical performance was characterized via cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy. The results indicate that the more pyrrole is added to GO (with GO concentrations of 20% and 50%), the more agglomeration of both PPy and GO layers occurs. This is detrimental to the capacitance utilization of PPy. When the feeding ratio of GO:pyrrole is 80:20, PPys with nanofibrils are dispersed homogenously in/on the exfoliated layer of GO and the conductivity is enhanced. The capacitance utilization of PPy in a composite with a GO concentration of 80% (383 F/g) is higher than that of pure PPy (201 F/g), which indicates the presence of a synergistic effect between GO and PPy. |
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Effect of feeding ratios on the structure and electrochemical performance of graphite oxide/polypyrrole nanocomposites |
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|
score |
7.398695 |