Lignin phenols in soils as biomarkers of paleovegetation
Abstract It has been shown by the methods of biochemistry, nuclear magnetic resonance, and isotope geochemistry that the proportions of lignin phenols may be used as molecular traces of paleovegetation due to their biochemical and physiological specificity and high resistance to decomposition. Ligni...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Kovaleva, N. O. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2015 |
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| Schlagwörter: |
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| Anmerkung: |
© Pleiades Publishing, Ltd. 2015 |
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| Übergeordnetes Werk: |
Enthalten in: Eurasian soil science - Moscow : MAIK Nauka/Interperiodica Publ., 1996, 48(2015), 9 vom: Sept., Seite 946-958 |
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| Übergeordnetes Werk: |
volume:48 ; year:2015 ; number:9 ; month:09 ; pages:946-958 |
| Links: |
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| DOI / URN: |
10.1134/S1064229315090057 |
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| Katalog-ID: |
SPR01996028X |
|---|
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| 100 | 1 | |a Kovaleva, N. O. |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Lignin phenols in soils as biomarkers of paleovegetation |
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| 520 | |a Abstract It has been shown by the methods of biochemistry, nuclear magnetic resonance, and isotope geochemistry that the proportions of lignin phenols may be used as molecular traces of paleovegetation due to their biochemical and physiological specificity and high resistance to decomposition. Lignin structures have been detected in iron–manganese concretions. The comparison of the 13 NMR spectra of native lignin preparations isolated from different woody and herbaceous species with those of soil humic acids makes it possible to identify many characteristic shifts of lignin nature in humic acids at 56, 102, 115, 119, 131, 147, 151–152, 160, and 166 ppm. The information role of biomarker has been tested at the reconstruction of paleovegetation in the uplands of the Russian Plain: an upward shift of the forest boundary has been recorded on the Northern Caucasus; the hypothesis about the steppe period of landscape development in the Tien Shan mountain valleys during the middle Holocene has been confirmed, and molecular traces of tropical flora have been revealed in the buried soils of Pleistocene age. The representativeness of information has been increased using the isotope analysis ($ δ^{13} $C); a new parameter—the composition of lignin phenols—has been introduced in the existed system of biomarkers. | ||
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| 650 | 4 | |a second humus horizons |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Holocene |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Pleistocene |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Kovalev, I. V. |4 aut | |
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10.1134/S1064229315090057 doi (DE-627)SPR01996028X (SPR)S1064229315090057-e DE-627 ger DE-627 rakwb eng Kovaleva, N. O. verfasserin aut Lignin phenols in soils as biomarkers of paleovegetation 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2015 Abstract It has been shown by the methods of biochemistry, nuclear magnetic resonance, and isotope geochemistry that the proportions of lignin phenols may be used as molecular traces of paleovegetation due to their biochemical and physiological specificity and high resistance to decomposition. Lignin structures have been detected in iron–manganese concretions. The comparison of the 13 NMR spectra of native lignin preparations isolated from different woody and herbaceous species with those of soil humic acids makes it possible to identify many characteristic shifts of lignin nature in humic acids at 56, 102, 115, 119, 131, 147, 151–152, 160, and 166 ppm. The information role of biomarker has been tested at the reconstruction of paleovegetation in the uplands of the Russian Plain: an upward shift of the forest boundary has been recorded on the Northern Caucasus; the hypothesis about the steppe period of landscape development in the Tien Shan mountain valleys during the middle Holocene has been confirmed, and molecular traces of tropical flora have been revealed in the buried soils of Pleistocene age. The representativeness of information has been increased using the isotope analysis ($ δ^{13} $C); a new parameter—the composition of lignin phenols—has been introduced in the existed system of biomarkers. lignin phenols (dpeaa)DE-He213 biomarkers (dpeaa)DE-He213 humic acids (dpeaa)DE-He213 NMR spectra (dpeaa)DE-He213 δ (dpeaa)DE-He213 C isotopes (dpeaa)DE-He213 second humus horizons (dpeaa)DE-He213 Holocene (dpeaa)DE-He213 Pleistocene (dpeaa)DE-He213 Kovalev, I. V. aut Enthalten in Eurasian soil science Moscow : MAIK Nauka/Interperiodica Publ., 1996 48(2015), 9 vom: Sept., Seite 946-958 (DE-627)341913227 (DE-600)2071129-3 1556-195X nnns volume:48 year:2015 number:9 month:09 pages:946-958 https://dx.doi.org/10.1134/S1064229315090057 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 48 2015 9 09 946-958 |
| spelling |
10.1134/S1064229315090057 doi (DE-627)SPR01996028X (SPR)S1064229315090057-e DE-627 ger DE-627 rakwb eng Kovaleva, N. O. verfasserin aut Lignin phenols in soils as biomarkers of paleovegetation 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2015 Abstract It has been shown by the methods of biochemistry, nuclear magnetic resonance, and isotope geochemistry that the proportions of lignin phenols may be used as molecular traces of paleovegetation due to their biochemical and physiological specificity and high resistance to decomposition. Lignin structures have been detected in iron–manganese concretions. The comparison of the 13 NMR spectra of native lignin preparations isolated from different woody and herbaceous species with those of soil humic acids makes it possible to identify many characteristic shifts of lignin nature in humic acids at 56, 102, 115, 119, 131, 147, 151–152, 160, and 166 ppm. The information role of biomarker has been tested at the reconstruction of paleovegetation in the uplands of the Russian Plain: an upward shift of the forest boundary has been recorded on the Northern Caucasus; the hypothesis about the steppe period of landscape development in the Tien Shan mountain valleys during the middle Holocene has been confirmed, and molecular traces of tropical flora have been revealed in the buried soils of Pleistocene age. The representativeness of information has been increased using the isotope analysis ($ δ^{13} $C); a new parameter—the composition of lignin phenols—has been introduced in the existed system of biomarkers. lignin phenols (dpeaa)DE-He213 biomarkers (dpeaa)DE-He213 humic acids (dpeaa)DE-He213 NMR spectra (dpeaa)DE-He213 δ (dpeaa)DE-He213 C isotopes (dpeaa)DE-He213 second humus horizons (dpeaa)DE-He213 Holocene (dpeaa)DE-He213 Pleistocene (dpeaa)DE-He213 Kovalev, I. V. aut Enthalten in Eurasian soil science Moscow : MAIK Nauka/Interperiodica Publ., 1996 48(2015), 9 vom: Sept., Seite 946-958 (DE-627)341913227 (DE-600)2071129-3 1556-195X nnns volume:48 year:2015 number:9 month:09 pages:946-958 https://dx.doi.org/10.1134/S1064229315090057 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 48 2015 9 09 946-958 |
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10.1134/S1064229315090057 doi (DE-627)SPR01996028X (SPR)S1064229315090057-e DE-627 ger DE-627 rakwb eng Kovaleva, N. O. verfasserin aut Lignin phenols in soils as biomarkers of paleovegetation 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2015 Abstract It has been shown by the methods of biochemistry, nuclear magnetic resonance, and isotope geochemistry that the proportions of lignin phenols may be used as molecular traces of paleovegetation due to their biochemical and physiological specificity and high resistance to decomposition. Lignin structures have been detected in iron–manganese concretions. The comparison of the 13 NMR spectra of native lignin preparations isolated from different woody and herbaceous species with those of soil humic acids makes it possible to identify many characteristic shifts of lignin nature in humic acids at 56, 102, 115, 119, 131, 147, 151–152, 160, and 166 ppm. The information role of biomarker has been tested at the reconstruction of paleovegetation in the uplands of the Russian Plain: an upward shift of the forest boundary has been recorded on the Northern Caucasus; the hypothesis about the steppe period of landscape development in the Tien Shan mountain valleys during the middle Holocene has been confirmed, and molecular traces of tropical flora have been revealed in the buried soils of Pleistocene age. The representativeness of information has been increased using the isotope analysis ($ δ^{13} $C); a new parameter—the composition of lignin phenols—has been introduced in the existed system of biomarkers. lignin phenols (dpeaa)DE-He213 biomarkers (dpeaa)DE-He213 humic acids (dpeaa)DE-He213 NMR spectra (dpeaa)DE-He213 δ (dpeaa)DE-He213 C isotopes (dpeaa)DE-He213 second humus horizons (dpeaa)DE-He213 Holocene (dpeaa)DE-He213 Pleistocene (dpeaa)DE-He213 Kovalev, I. V. aut Enthalten in Eurasian soil science Moscow : MAIK Nauka/Interperiodica Publ., 1996 48(2015), 9 vom: Sept., Seite 946-958 (DE-627)341913227 (DE-600)2071129-3 1556-195X nnns volume:48 year:2015 number:9 month:09 pages:946-958 https://dx.doi.org/10.1134/S1064229315090057 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 48 2015 9 09 946-958 |
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10.1134/S1064229315090057 doi (DE-627)SPR01996028X (SPR)S1064229315090057-e DE-627 ger DE-627 rakwb eng Kovaleva, N. O. verfasserin aut Lignin phenols in soils as biomarkers of paleovegetation 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2015 Abstract It has been shown by the methods of biochemistry, nuclear magnetic resonance, and isotope geochemistry that the proportions of lignin phenols may be used as molecular traces of paleovegetation due to their biochemical and physiological specificity and high resistance to decomposition. Lignin structures have been detected in iron–manganese concretions. The comparison of the 13 NMR spectra of native lignin preparations isolated from different woody and herbaceous species with those of soil humic acids makes it possible to identify many characteristic shifts of lignin nature in humic acids at 56, 102, 115, 119, 131, 147, 151–152, 160, and 166 ppm. The information role of biomarker has been tested at the reconstruction of paleovegetation in the uplands of the Russian Plain: an upward shift of the forest boundary has been recorded on the Northern Caucasus; the hypothesis about the steppe period of landscape development in the Tien Shan mountain valleys during the middle Holocene has been confirmed, and molecular traces of tropical flora have been revealed in the buried soils of Pleistocene age. The representativeness of information has been increased using the isotope analysis ($ δ^{13} $C); a new parameter—the composition of lignin phenols—has been introduced in the existed system of biomarkers. lignin phenols (dpeaa)DE-He213 biomarkers (dpeaa)DE-He213 humic acids (dpeaa)DE-He213 NMR spectra (dpeaa)DE-He213 δ (dpeaa)DE-He213 C isotopes (dpeaa)DE-He213 second humus horizons (dpeaa)DE-He213 Holocene (dpeaa)DE-He213 Pleistocene (dpeaa)DE-He213 Kovalev, I. V. aut Enthalten in Eurasian soil science Moscow : MAIK Nauka/Interperiodica Publ., 1996 48(2015), 9 vom: Sept., Seite 946-958 (DE-627)341913227 (DE-600)2071129-3 1556-195X nnns volume:48 year:2015 number:9 month:09 pages:946-958 https://dx.doi.org/10.1134/S1064229315090057 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 48 2015 9 09 946-958 |
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10.1134/S1064229315090057 doi (DE-627)SPR01996028X (SPR)S1064229315090057-e DE-627 ger DE-627 rakwb eng Kovaleva, N. O. verfasserin aut Lignin phenols in soils as biomarkers of paleovegetation 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2015 Abstract It has been shown by the methods of biochemistry, nuclear magnetic resonance, and isotope geochemistry that the proportions of lignin phenols may be used as molecular traces of paleovegetation due to their biochemical and physiological specificity and high resistance to decomposition. Lignin structures have been detected in iron–manganese concretions. The comparison of the 13 NMR spectra of native lignin preparations isolated from different woody and herbaceous species with those of soil humic acids makes it possible to identify many characteristic shifts of lignin nature in humic acids at 56, 102, 115, 119, 131, 147, 151–152, 160, and 166 ppm. The information role of biomarker has been tested at the reconstruction of paleovegetation in the uplands of the Russian Plain: an upward shift of the forest boundary has been recorded on the Northern Caucasus; the hypothesis about the steppe period of landscape development in the Tien Shan mountain valleys during the middle Holocene has been confirmed, and molecular traces of tropical flora have been revealed in the buried soils of Pleistocene age. The representativeness of information has been increased using the isotope analysis ($ δ^{13} $C); a new parameter—the composition of lignin phenols—has been introduced in the existed system of biomarkers. lignin phenols (dpeaa)DE-He213 biomarkers (dpeaa)DE-He213 humic acids (dpeaa)DE-He213 NMR spectra (dpeaa)DE-He213 δ (dpeaa)DE-He213 C isotopes (dpeaa)DE-He213 second humus horizons (dpeaa)DE-He213 Holocene (dpeaa)DE-He213 Pleistocene (dpeaa)DE-He213 Kovalev, I. V. aut Enthalten in Eurasian soil science Moscow : MAIK Nauka/Interperiodica Publ., 1996 48(2015), 9 vom: Sept., Seite 946-958 (DE-627)341913227 (DE-600)2071129-3 1556-195X nnns volume:48 year:2015 number:9 month:09 pages:946-958 https://dx.doi.org/10.1134/S1064229315090057 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 48 2015 9 09 946-958 |
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Lignin structures have been detected in iron–manganese concretions. The comparison of the 13 NMR spectra of native lignin preparations isolated from different woody and herbaceous species with those of soil humic acids makes it possible to identify many characteristic shifts of lignin nature in humic acids at 56, 102, 115, 119, 131, 147, 151–152, 160, and 166 ppm. The information role of biomarker has been tested at the reconstruction of paleovegetation in the uplands of the Russian Plain: an upward shift of the forest boundary has been recorded on the Northern Caucasus; the hypothesis about the steppe period of landscape development in the Tien Shan mountain valleys during the middle Holocene has been confirmed, and molecular traces of tropical flora have been revealed in the buried soils of Pleistocene age. 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Kovaleva, N. O. |
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Kovaleva, N. O. misc lignin phenols misc biomarkers misc humic acids misc NMR spectra misc δ misc C isotopes misc second humus horizons misc Holocene misc Pleistocene Lignin phenols in soils as biomarkers of paleovegetation |
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Lignin phenols in soils as biomarkers of paleovegetation lignin phenols (dpeaa)DE-He213 biomarkers (dpeaa)DE-He213 humic acids (dpeaa)DE-He213 NMR spectra (dpeaa)DE-He213 δ (dpeaa)DE-He213 C isotopes (dpeaa)DE-He213 second humus horizons (dpeaa)DE-He213 Holocene (dpeaa)DE-He213 Pleistocene (dpeaa)DE-He213 |
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lignin phenols in soils as biomarkers of paleovegetation |
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Lignin phenols in soils as biomarkers of paleovegetation |
| abstract |
Abstract It has been shown by the methods of biochemistry, nuclear magnetic resonance, and isotope geochemistry that the proportions of lignin phenols may be used as molecular traces of paleovegetation due to their biochemical and physiological specificity and high resistance to decomposition. Lignin structures have been detected in iron–manganese concretions. The comparison of the 13 NMR spectra of native lignin preparations isolated from different woody and herbaceous species with those of soil humic acids makes it possible to identify many characteristic shifts of lignin nature in humic acids at 56, 102, 115, 119, 131, 147, 151–152, 160, and 166 ppm. The information role of biomarker has been tested at the reconstruction of paleovegetation in the uplands of the Russian Plain: an upward shift of the forest boundary has been recorded on the Northern Caucasus; the hypothesis about the steppe period of landscape development in the Tien Shan mountain valleys during the middle Holocene has been confirmed, and molecular traces of tropical flora have been revealed in the buried soils of Pleistocene age. The representativeness of information has been increased using the isotope analysis ($ δ^{13} $C); a new parameter—the composition of lignin phenols—has been introduced in the existed system of biomarkers. © Pleiades Publishing, Ltd. 2015 |
| abstractGer |
Abstract It has been shown by the methods of biochemistry, nuclear magnetic resonance, and isotope geochemistry that the proportions of lignin phenols may be used as molecular traces of paleovegetation due to their biochemical and physiological specificity and high resistance to decomposition. Lignin structures have been detected in iron–manganese concretions. The comparison of the 13 NMR spectra of native lignin preparations isolated from different woody and herbaceous species with those of soil humic acids makes it possible to identify many characteristic shifts of lignin nature in humic acids at 56, 102, 115, 119, 131, 147, 151–152, 160, and 166 ppm. The information role of biomarker has been tested at the reconstruction of paleovegetation in the uplands of the Russian Plain: an upward shift of the forest boundary has been recorded on the Northern Caucasus; the hypothesis about the steppe period of landscape development in the Tien Shan mountain valleys during the middle Holocene has been confirmed, and molecular traces of tropical flora have been revealed in the buried soils of Pleistocene age. The representativeness of information has been increased using the isotope analysis ($ δ^{13} $C); a new parameter—the composition of lignin phenols—has been introduced in the existed system of biomarkers. © Pleiades Publishing, Ltd. 2015 |
| abstract_unstemmed |
Abstract It has been shown by the methods of biochemistry, nuclear magnetic resonance, and isotope geochemistry that the proportions of lignin phenols may be used as molecular traces of paleovegetation due to their biochemical and physiological specificity and high resistance to decomposition. Lignin structures have been detected in iron–manganese concretions. The comparison of the 13 NMR spectra of native lignin preparations isolated from different woody and herbaceous species with those of soil humic acids makes it possible to identify many characteristic shifts of lignin nature in humic acids at 56, 102, 115, 119, 131, 147, 151–152, 160, and 166 ppm. The information role of biomarker has been tested at the reconstruction of paleovegetation in the uplands of the Russian Plain: an upward shift of the forest boundary has been recorded on the Northern Caucasus; the hypothesis about the steppe period of landscape development in the Tien Shan mountain valleys during the middle Holocene has been confirmed, and molecular traces of tropical flora have been revealed in the buried soils of Pleistocene age. The representativeness of information has been increased using the isotope analysis ($ δ^{13} $C); a new parameter—the composition of lignin phenols—has been introduced in the existed system of biomarkers. © Pleiades Publishing, Ltd. 2015 |
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| title_short |
Lignin phenols in soils as biomarkers of paleovegetation |
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https://dx.doi.org/10.1134/S1064229315090057 |
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Kovalev, I. V. |
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|
| score |
7.401121 |