Aktashite $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $ from the Aktash deposit, Altai, Russia: Refinement and crystal chemical analysis of the structure
Abstract The composition and structure of aktashite from the Aktash deposit, Gorny Altai, Russia, have been studied by electron microprobe and X-ray structural analysis. On the basis of close compositions and crystal structures, the identity of aktashite from the Gal-Khaya and Aktash deposits has be...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Vasil’ev, V. I. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2010 |
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| Schlagwörter: |
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| Anmerkung: |
© Pleiades Publishing, Ltd. 2010 |
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| Übergeordnetes Werk: |
Enthalten in: Geology of ore deposits - Berlin : Springer Science + Business Media B.V., 2006, 52(2010), 7 vom: Dez., Seite 656-661 |
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| Übergeordnetes Werk: |
volume:52 ; year:2010 ; number:7 ; month:12 ; pages:656-661 |
| Links: |
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| DOI / URN: |
10.1134/S1075701510070184 |
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| Katalog-ID: |
SPR01998359X |
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| 100 | 1 | |a Vasil’ev, V. I. |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Aktashite $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $ from the Aktash deposit, Altai, Russia: Refinement and crystal chemical analysis of the structure |
| 264 | 1 | |c 2010 | |
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| 520 | |a Abstract The composition and structure of aktashite from the Aktash deposit, Gorny Altai, Russia, have been studied by electron microprobe and X-ray structural analysis. On the basis of close compositions and crystal structures, the identity of aktashite from the Gal-Khaya and Aktash deposits has been demonstrated. Crystals of aktashite are of trigonal symmetry; the unit-cell dimensions are: a = 13.7500(4), c = 9.3600(3) Å, V = 532.54(8) $ Å^{3} $, space group R3, Z = 3 for the composition of $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $, R = 0.043. The structure of aktashite as a framework of vertex-shared $ HgS_{4−} $ and $ CuS_{4−} $ tetrahedrons of the same orientation is intimately related to the sphalerite-type structure. The earlier identified uncommon cluster group [$ As_{4} $] has been verified and its parameters have been refined. It is shown that the structure may be represented as construction blocks ($ As_{4} %$ S_{12} $)12− packed according to the law of the distorted cubic I-cell. | ||
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| 700 | 1 | |a Pervukhina, N. V. |4 aut | |
| 700 | 1 | |a Borisov, S. V. |4 aut | |
| 700 | 1 | |a Magarill, S. A. |4 aut | |
| 700 | 1 | |a Naumov, D. Yu. |4 aut | |
| 700 | 1 | |a Kurat’eva, N. V. |4 aut | |
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10.1134/S1075701510070184 doi (DE-627)SPR01998359X (SPR)S1075701510070184-e DE-627 ger DE-627 rakwb eng Vasil’ev, V. I. verfasserin aut Aktashite $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $ from the Aktash deposit, Altai, Russia: Refinement and crystal chemical analysis of the structure 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2010 Abstract The composition and structure of aktashite from the Aktash deposit, Gorny Altai, Russia, have been studied by electron microprobe and X-ray structural analysis. On the basis of close compositions and crystal structures, the identity of aktashite from the Gal-Khaya and Aktash deposits has been demonstrated. Crystals of aktashite are of trigonal symmetry; the unit-cell dimensions are: a = 13.7500(4), c = 9.3600(3) Å, V = 532.54(8) $ Å^{3} $, space group R3, Z = 3 for the composition of $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $, R = 0.043. The structure of aktashite as a framework of vertex-shared $ HgS_{4−} $ and $ CuS_{4−} $ tetrahedrons of the same orientation is intimately related to the sphalerite-type structure. The earlier identified uncommon cluster group [$ As_{4} $] has been verified and its parameters have been refined. It is shown that the structure may be represented as construction blocks ($ As_{4} %$ S_{12} $)12− packed according to the law of the distorted cubic I-cell. Vasil (dpeaa)DE-He213 Electron Microprobe (dpeaa)DE-He213 Polysulfide (dpeaa)DE-He213 Unit Cell Dimension (dpeaa)DE-He213 Trigonal Symmetry (dpeaa)DE-He213 Pervukhina, N. V. aut Borisov, S. V. aut Magarill, S. A. aut Naumov, D. Yu. aut Kurat’eva, N. V. aut Enthalten in Geology of ore deposits Berlin : Springer Science + Business Media B.V., 2006 52(2010), 7 vom: Dez., Seite 656-661 (DE-627)510462294 (DE-600)2230159-8 1555-6476 nnns volume:52 year:2010 number:7 month:12 pages:656-661 https://dx.doi.org/10.1134/S1075701510070184 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 52 2010 7 12 656-661 |
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10.1134/S1075701510070184 doi (DE-627)SPR01998359X (SPR)S1075701510070184-e DE-627 ger DE-627 rakwb eng Vasil’ev, V. I. verfasserin aut Aktashite $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $ from the Aktash deposit, Altai, Russia: Refinement and crystal chemical analysis of the structure 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2010 Abstract The composition and structure of aktashite from the Aktash deposit, Gorny Altai, Russia, have been studied by electron microprobe and X-ray structural analysis. On the basis of close compositions and crystal structures, the identity of aktashite from the Gal-Khaya and Aktash deposits has been demonstrated. Crystals of aktashite are of trigonal symmetry; the unit-cell dimensions are: a = 13.7500(4), c = 9.3600(3) Å, V = 532.54(8) $ Å^{3} $, space group R3, Z = 3 for the composition of $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $, R = 0.043. The structure of aktashite as a framework of vertex-shared $ HgS_{4−} $ and $ CuS_{4−} $ tetrahedrons of the same orientation is intimately related to the sphalerite-type structure. The earlier identified uncommon cluster group [$ As_{4} $] has been verified and its parameters have been refined. It is shown that the structure may be represented as construction blocks ($ As_{4} %$ S_{12} $)12− packed according to the law of the distorted cubic I-cell. Vasil (dpeaa)DE-He213 Electron Microprobe (dpeaa)DE-He213 Polysulfide (dpeaa)DE-He213 Unit Cell Dimension (dpeaa)DE-He213 Trigonal Symmetry (dpeaa)DE-He213 Pervukhina, N. V. aut Borisov, S. V. aut Magarill, S. A. aut Naumov, D. Yu. aut Kurat’eva, N. V. aut Enthalten in Geology of ore deposits Berlin : Springer Science + Business Media B.V., 2006 52(2010), 7 vom: Dez., Seite 656-661 (DE-627)510462294 (DE-600)2230159-8 1555-6476 nnns volume:52 year:2010 number:7 month:12 pages:656-661 https://dx.doi.org/10.1134/S1075701510070184 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 52 2010 7 12 656-661 |
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10.1134/S1075701510070184 doi (DE-627)SPR01998359X (SPR)S1075701510070184-e DE-627 ger DE-627 rakwb eng Vasil’ev, V. I. verfasserin aut Aktashite $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $ from the Aktash deposit, Altai, Russia: Refinement and crystal chemical analysis of the structure 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2010 Abstract The composition and structure of aktashite from the Aktash deposit, Gorny Altai, Russia, have been studied by electron microprobe and X-ray structural analysis. On the basis of close compositions and crystal structures, the identity of aktashite from the Gal-Khaya and Aktash deposits has been demonstrated. Crystals of aktashite are of trigonal symmetry; the unit-cell dimensions are: a = 13.7500(4), c = 9.3600(3) Å, V = 532.54(8) $ Å^{3} $, space group R3, Z = 3 for the composition of $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $, R = 0.043. The structure of aktashite as a framework of vertex-shared $ HgS_{4−} $ and $ CuS_{4−} $ tetrahedrons of the same orientation is intimately related to the sphalerite-type structure. The earlier identified uncommon cluster group [$ As_{4} $] has been verified and its parameters have been refined. It is shown that the structure may be represented as construction blocks ($ As_{4} %$ S_{12} $)12− packed according to the law of the distorted cubic I-cell. Vasil (dpeaa)DE-He213 Electron Microprobe (dpeaa)DE-He213 Polysulfide (dpeaa)DE-He213 Unit Cell Dimension (dpeaa)DE-He213 Trigonal Symmetry (dpeaa)DE-He213 Pervukhina, N. V. aut Borisov, S. V. aut Magarill, S. A. aut Naumov, D. Yu. aut Kurat’eva, N. V. aut Enthalten in Geology of ore deposits Berlin : Springer Science + Business Media B.V., 2006 52(2010), 7 vom: Dez., Seite 656-661 (DE-627)510462294 (DE-600)2230159-8 1555-6476 nnns volume:52 year:2010 number:7 month:12 pages:656-661 https://dx.doi.org/10.1134/S1075701510070184 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 52 2010 7 12 656-661 |
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10.1134/S1075701510070184 doi (DE-627)SPR01998359X (SPR)S1075701510070184-e DE-627 ger DE-627 rakwb eng Vasil’ev, V. I. verfasserin aut Aktashite $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $ from the Aktash deposit, Altai, Russia: Refinement and crystal chemical analysis of the structure 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2010 Abstract The composition and structure of aktashite from the Aktash deposit, Gorny Altai, Russia, have been studied by electron microprobe and X-ray structural analysis. On the basis of close compositions and crystal structures, the identity of aktashite from the Gal-Khaya and Aktash deposits has been demonstrated. Crystals of aktashite are of trigonal symmetry; the unit-cell dimensions are: a = 13.7500(4), c = 9.3600(3) Å, V = 532.54(8) $ Å^{3} $, space group R3, Z = 3 for the composition of $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $, R = 0.043. The structure of aktashite as a framework of vertex-shared $ HgS_{4−} $ and $ CuS_{4−} $ tetrahedrons of the same orientation is intimately related to the sphalerite-type structure. The earlier identified uncommon cluster group [$ As_{4} $] has been verified and its parameters have been refined. It is shown that the structure may be represented as construction blocks ($ As_{4} %$ S_{12} $)12− packed according to the law of the distorted cubic I-cell. Vasil (dpeaa)DE-He213 Electron Microprobe (dpeaa)DE-He213 Polysulfide (dpeaa)DE-He213 Unit Cell Dimension (dpeaa)DE-He213 Trigonal Symmetry (dpeaa)DE-He213 Pervukhina, N. V. aut Borisov, S. V. aut Magarill, S. A. aut Naumov, D. Yu. aut Kurat’eva, N. V. aut Enthalten in Geology of ore deposits Berlin : Springer Science + Business Media B.V., 2006 52(2010), 7 vom: Dez., Seite 656-661 (DE-627)510462294 (DE-600)2230159-8 1555-6476 nnns volume:52 year:2010 number:7 month:12 pages:656-661 https://dx.doi.org/10.1134/S1075701510070184 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 52 2010 7 12 656-661 |
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10.1134/S1075701510070184 doi (DE-627)SPR01998359X (SPR)S1075701510070184-e DE-627 ger DE-627 rakwb eng Vasil’ev, V. I. verfasserin aut Aktashite $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $ from the Aktash deposit, Altai, Russia: Refinement and crystal chemical analysis of the structure 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2010 Abstract The composition and structure of aktashite from the Aktash deposit, Gorny Altai, Russia, have been studied by electron microprobe and X-ray structural analysis. On the basis of close compositions and crystal structures, the identity of aktashite from the Gal-Khaya and Aktash deposits has been demonstrated. Crystals of aktashite are of trigonal symmetry; the unit-cell dimensions are: a = 13.7500(4), c = 9.3600(3) Å, V = 532.54(8) $ Å^{3} $, space group R3, Z = 3 for the composition of $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $, R = 0.043. The structure of aktashite as a framework of vertex-shared $ HgS_{4−} $ and $ CuS_{4−} $ tetrahedrons of the same orientation is intimately related to the sphalerite-type structure. The earlier identified uncommon cluster group [$ As_{4} $] has been verified and its parameters have been refined. It is shown that the structure may be represented as construction blocks ($ As_{4} %$ S_{12} $)12− packed according to the law of the distorted cubic I-cell. Vasil (dpeaa)DE-He213 Electron Microprobe (dpeaa)DE-He213 Polysulfide (dpeaa)DE-He213 Unit Cell Dimension (dpeaa)DE-He213 Trigonal Symmetry (dpeaa)DE-He213 Pervukhina, N. V. aut Borisov, S. V. aut Magarill, S. A. aut Naumov, D. Yu. aut Kurat’eva, N. V. aut Enthalten in Geology of ore deposits Berlin : Springer Science + Business Media B.V., 2006 52(2010), 7 vom: Dez., Seite 656-661 (DE-627)510462294 (DE-600)2230159-8 1555-6476 nnns volume:52 year:2010 number:7 month:12 pages:656-661 https://dx.doi.org/10.1134/S1075701510070184 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 52 2010 7 12 656-661 |
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Enthalten in Geology of ore deposits 52(2010), 7 vom: Dez., Seite 656-661 volume:52 year:2010 number:7 month:12 pages:656-661 |
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Vasil’ev, V. I. @@aut@@ Pervukhina, N. V. @@aut@@ Borisov, S. V. @@aut@@ Magarill, S. A. @@aut@@ Naumov, D. Yu. @@aut@@ Kurat’eva, N. V. @@aut@@ |
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I.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Aktashite $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $ from the Aktash deposit, Altai, Russia: Refinement and crystal chemical analysis of the structure</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2010</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Pleiades Publishing, Ltd. 2010</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The composition and structure of aktashite from the Aktash deposit, Gorny Altai, Russia, have been studied by electron microprobe and X-ray structural analysis. On the basis of close compositions and crystal structures, the identity of aktashite from the Gal-Khaya and Aktash deposits has been demonstrated. Crystals of aktashite are of trigonal symmetry; the unit-cell dimensions are: a = 13.7500(4), c = 9.3600(3) Å, V = 532.54(8) $ Å^{3} $, space group R3, Z = 3 for the composition of $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $, R = 0.043. The structure of aktashite as a framework of vertex-shared $ HgS_{4−} $ and $ CuS_{4−} $ tetrahedrons of the same orientation is intimately related to the sphalerite-type structure. The earlier identified uncommon cluster group [$ As_{4} $] has been verified and its parameters have been refined. 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Vasil’ev, V. I. |
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Vasil’ev, V. I. misc Vasil misc Electron Microprobe misc Polysulfide misc Unit Cell Dimension misc Trigonal Symmetry Aktashite $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $ from the Aktash deposit, Altai, Russia: Refinement and crystal chemical analysis of the structure |
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Aktashite $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $ from the Aktash deposit, Altai, Russia: Refinement and crystal chemical analysis of the structure Vasil (dpeaa)DE-He213 Electron Microprobe (dpeaa)DE-He213 Polysulfide (dpeaa)DE-He213 Unit Cell Dimension (dpeaa)DE-He213 Trigonal Symmetry (dpeaa)DE-He213 |
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Aktashite $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $ from the Aktash deposit, Altai, Russia: Refinement and crystal chemical analysis of the structure |
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Aktashite $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $ from the Aktash deposit, Altai, Russia: Refinement and crystal chemical analysis of the structure |
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Vasil’ev, V. I. Pervukhina, N. V. Borisov, S. V. Magarill, S. A. Naumov, D. Yu. Kurat’eva, N. V. |
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aktashite $ cu_{6} %$ hg_{3} %$ as_{4} %$ s_{12} $ from the aktash deposit, altai, russia: refinement and crystal chemical analysis of the structure |
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Aktashite $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $ from the Aktash deposit, Altai, Russia: Refinement and crystal chemical analysis of the structure |
| abstract |
Abstract The composition and structure of aktashite from the Aktash deposit, Gorny Altai, Russia, have been studied by electron microprobe and X-ray structural analysis. On the basis of close compositions and crystal structures, the identity of aktashite from the Gal-Khaya and Aktash deposits has been demonstrated. Crystals of aktashite are of trigonal symmetry; the unit-cell dimensions are: a = 13.7500(4), c = 9.3600(3) Å, V = 532.54(8) $ Å^{3} $, space group R3, Z = 3 for the composition of $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $, R = 0.043. The structure of aktashite as a framework of vertex-shared $ HgS_{4−} $ and $ CuS_{4−} $ tetrahedrons of the same orientation is intimately related to the sphalerite-type structure. The earlier identified uncommon cluster group [$ As_{4} $] has been verified and its parameters have been refined. It is shown that the structure may be represented as construction blocks ($ As_{4} %$ S_{12} $)12− packed according to the law of the distorted cubic I-cell. © Pleiades Publishing, Ltd. 2010 |
| abstractGer |
Abstract The composition and structure of aktashite from the Aktash deposit, Gorny Altai, Russia, have been studied by electron microprobe and X-ray structural analysis. On the basis of close compositions and crystal structures, the identity of aktashite from the Gal-Khaya and Aktash deposits has been demonstrated. Crystals of aktashite are of trigonal symmetry; the unit-cell dimensions are: a = 13.7500(4), c = 9.3600(3) Å, V = 532.54(8) $ Å^{3} $, space group R3, Z = 3 for the composition of $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $, R = 0.043. The structure of aktashite as a framework of vertex-shared $ HgS_{4−} $ and $ CuS_{4−} $ tetrahedrons of the same orientation is intimately related to the sphalerite-type structure. The earlier identified uncommon cluster group [$ As_{4} $] has been verified and its parameters have been refined. It is shown that the structure may be represented as construction blocks ($ As_{4} %$ S_{12} $)12− packed according to the law of the distorted cubic I-cell. © Pleiades Publishing, Ltd. 2010 |
| abstract_unstemmed |
Abstract The composition and structure of aktashite from the Aktash deposit, Gorny Altai, Russia, have been studied by electron microprobe and X-ray structural analysis. On the basis of close compositions and crystal structures, the identity of aktashite from the Gal-Khaya and Aktash deposits has been demonstrated. Crystals of aktashite are of trigonal symmetry; the unit-cell dimensions are: a = 13.7500(4), c = 9.3600(3) Å, V = 532.54(8) $ Å^{3} $, space group R3, Z = 3 for the composition of $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $, R = 0.043. The structure of aktashite as a framework of vertex-shared $ HgS_{4−} $ and $ CuS_{4−} $ tetrahedrons of the same orientation is intimately related to the sphalerite-type structure. The earlier identified uncommon cluster group [$ As_{4} $] has been verified and its parameters have been refined. It is shown that the structure may be represented as construction blocks ($ As_{4} %$ S_{12} $)12− packed according to the law of the distorted cubic I-cell. © Pleiades Publishing, Ltd. 2010 |
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7 |
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Aktashite $ Cu_{6} %$ Hg_{3} %$ As_{4} %$ S_{12} $ from the Aktash deposit, Altai, Russia: Refinement and crystal chemical analysis of the structure |
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https://dx.doi.org/10.1134/S1075701510070184 |
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Pervukhina, N. V. Borisov, S. V. Magarill, S. A. Naumov, D. Yu Kurat’eva, N. V. |
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Pervukhina, N. V. Borisov, S. V. Magarill, S. A. Naumov, D. Yu Kurat’eva, N. V. |
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2024-07-04T03:33:12.190Z |
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|
| score |
7.40236 |