The possibility of applying a titanium-magnesium nanocatalyst in the polymerization filling of polyolefins and some properties of the obtained composites

Abstract The possibility of applying a titanium-magnesium nanocatalyst during in situ polymerization of ethylene and propylene in the presence of organomodified aluminum silicates and diatomite under mild conditions is investigated. How the substantial (2- to 3-fold) increase in the catalytic activi...
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Autor*in:	Khar’kova, E. M. [verfasserIn] Mendeleev, D. I. Smetannikov, O. V. Chinova, M. S. Ivanyuk, A. V. Antipov, E. M.

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2014

Schlagwörter:	Polymer Science Series Diatomite TIBA Olefin Polymerization Polymerization Filling

Anmerkung:	© Pleiades Publishing, Ltd. 2014

Übergeordnetes Werk:	Enthalten in: Polymer science - Moscow : MAIK Nauka/Interperiodics Publ., 2006, 56(2014), 5 vom: Sept., Seite 664-674
Übergeordnetes Werk:	volume:56 ; year:2014 ; number:5 ; month:09 ; pages:664-674

Links:	Volltext

DOI / URN:	10.1134/S1560090414050066

Katalog-ID:	SPR02025606X

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245	1	4	\|a The possibility of applying a titanium-magnesium nanocatalyst in the polymerization filling of polyolefins and some properties of the obtained composites
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520			\|a Abstract The possibility of applying a titanium-magnesium nanocatalyst during in situ polymerization of ethylene and propylene in the presence of organomodified aluminum silicates and diatomite under mild conditions is investigated. How the substantial (2- to 3-fold) increase in the catalytic activity of the system depends on the type and amount of filler is shown. The activity of the titanium-magnesium nanocatalyst-filler system during polymerization of propylene is 3–4 times higher than that during the polymerization of ethylene. Composites based on ultrahigh-molecular-mass polyethylene (M = (1.4–1.7) × $ 10^{6} $) with 3.5–13.0 wt % filler are obtained. According to DSC and X-ray structural-analysis data, the polyethylene matrix differs by its high crystallinity and a Tm of 143–144°C. The physicochemical characteristics of the composites are 1.5–2.0 times greater than those of unfilled polyethylene; the nanocomposite containing 11 wt % mont-morillonite modified with vinyltrimethoxysilane has the best properties. It is shown that during the propylene polymerization, the effect of the type of filler affects not only the catalytic activity of the system, increasing it three times in the case of diatomite, but also the stereospecificity of the effect. Isotactic high-molecularmass (up to 390 × $ 10^{3} $) polypropylene is obtained in the presence of montmorillonite containing vinyltrimethoxysilane, while a low-molecular-mass ((65–75) × $ 10^{3} $) polymer with lower isotacticity is formed on diatomite. The deformation-strength characteristics of composites based on polypropylene testify the formation of an elastomeric material with Tm = 156–158°C.
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650		4	\|a Diatomite \|7 (dpeaa)DE-He213
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650		4	\|a Olefin Polymerization \|7 (dpeaa)DE-He213
650		4	\|a Polymerization Filling \|7 (dpeaa)DE-He213
700	1		\|a Mendeleev, D. I. \|4 aut
700	1		\|a Smetannikov, O. V. \|4 aut
700	1		\|a Chinova, M. S. \|4 aut
700	1		\|a Ivanyuk, A. V. \|4 aut
700	1		\|a Antipov, E. M. \|4 aut
773	0	8	\|i Enthalten in \|t Polymer science \|d Moscow : MAIK Nauka/Interperiodics Publ., 2006 \|g 56(2014), 5 vom: Sept., Seite 664-674 \|w (DE-627)513506896 \|w (DE-600)2239942-2 \|x 1555-6123 \|7 nnns
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856	4	0	\|u https://dx.doi.org/10.1134/S1560090414050066 \|z lizenzpflichtig \|3 Volltext
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912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
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912			\|a GBV_ILN_702
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912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
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912			\|a GBV_ILN_2044
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912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
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912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
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Indexfelder

author_variant	e m k em emk d i m di dim o v s ov ovs m s c ms msc a v i av avi e m a em ema
matchkey_str	article:15556123:2014----::hpsiiiyfpligttnumgeimaoaaytnhplmrztofligfoylfnado
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publishDate	2014
allfields	10.1134/S1560090414050066 doi (DE-627)SPR02025606X (SPR)S1560090414050066-e DE-627 ger DE-627 rakwb eng Khar’kova, E. M. verfasserin aut The possibility of applying a titanium-magnesium nanocatalyst in the polymerization filling of polyolefins and some properties of the obtained composites 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract The possibility of applying a titanium-magnesium nanocatalyst during in situ polymerization of ethylene and propylene in the presence of organomodified aluminum silicates and diatomite under mild conditions is investigated. How the substantial (2- to 3-fold) increase in the catalytic activity of the system depends on the type and amount of filler is shown. The activity of the titanium-magnesium nanocatalyst-filler system during polymerization of propylene is 3–4 times higher than that during the polymerization of ethylene. Composites based on ultrahigh-molecular-mass polyethylene (M = (1.4–1.7) × $ 10^{6} $) with 3.5–13.0 wt % filler are obtained. According to DSC and X-ray structural-analysis data, the polyethylene matrix differs by its high crystallinity and a Tm of 143–144°C. The physicochemical characteristics of the composites are 1.5–2.0 times greater than those of unfilled polyethylene; the nanocomposite containing 11 wt % mont-morillonite modified with vinyltrimethoxysilane has the best properties. It is shown that during the propylene polymerization, the effect of the type of filler affects not only the catalytic activity of the system, increasing it three times in the case of diatomite, but also the stereospecificity of the effect. Isotactic high-molecularmass (up to 390 × $ 10^{3} $) polypropylene is obtained in the presence of montmorillonite containing vinyltrimethoxysilane, while a low-molecular-mass ((65–75) × $ 10^{3} $) polymer with lower isotacticity is formed on diatomite. The deformation-strength characteristics of composites based on polypropylene testify the formation of an elastomeric material with Tm = 156–158°C. Polymer Science Series (dpeaa)DE-He213 Diatomite (dpeaa)DE-He213 TIBA (dpeaa)DE-He213 Olefin Polymerization (dpeaa)DE-He213 Polymerization Filling (dpeaa)DE-He213 Mendeleev, D. I. aut Smetannikov, O. V. aut Chinova, M. S. aut Ivanyuk, A. V. aut Antipov, E. M. aut Enthalten in Polymer science Moscow : MAIK Nauka/Interperiodics Publ., 2006 56(2014), 5 vom: Sept., Seite 664-674 (DE-627)513506896 (DE-600)2239942-2 1555-6123 nnns volume:56 year:2014 number:5 month:09 pages:664-674 https://dx.doi.org/10.1134/S1560090414050066 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 56 2014 5 09 664-674
spelling	10.1134/S1560090414050066 doi (DE-627)SPR02025606X (SPR)S1560090414050066-e DE-627 ger DE-627 rakwb eng Khar’kova, E. M. verfasserin aut The possibility of applying a titanium-magnesium nanocatalyst in the polymerization filling of polyolefins and some properties of the obtained composites 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract The possibility of applying a titanium-magnesium nanocatalyst during in situ polymerization of ethylene and propylene in the presence of organomodified aluminum silicates and diatomite under mild conditions is investigated. How the substantial (2- to 3-fold) increase in the catalytic activity of the system depends on the type and amount of filler is shown. The activity of the titanium-magnesium nanocatalyst-filler system during polymerization of propylene is 3–4 times higher than that during the polymerization of ethylene. Composites based on ultrahigh-molecular-mass polyethylene (M = (1.4–1.7) × $ 10^{6} $) with 3.5–13.0 wt % filler are obtained. According to DSC and X-ray structural-analysis data, the polyethylene matrix differs by its high crystallinity and a Tm of 143–144°C. The physicochemical characteristics of the composites are 1.5–2.0 times greater than those of unfilled polyethylene; the nanocomposite containing 11 wt % mont-morillonite modified with vinyltrimethoxysilane has the best properties. It is shown that during the propylene polymerization, the effect of the type of filler affects not only the catalytic activity of the system, increasing it three times in the case of diatomite, but also the stereospecificity of the effect. Isotactic high-molecularmass (up to 390 × $ 10^{3} $) polypropylene is obtained in the presence of montmorillonite containing vinyltrimethoxysilane, while a low-molecular-mass ((65–75) × $ 10^{3} $) polymer with lower isotacticity is formed on diatomite. The deformation-strength characteristics of composites based on polypropylene testify the formation of an elastomeric material with Tm = 156–158°C. Polymer Science Series (dpeaa)DE-He213 Diatomite (dpeaa)DE-He213 TIBA (dpeaa)DE-He213 Olefin Polymerization (dpeaa)DE-He213 Polymerization Filling (dpeaa)DE-He213 Mendeleev, D. I. aut Smetannikov, O. V. aut Chinova, M. S. aut Ivanyuk, A. V. aut Antipov, E. M. aut Enthalten in Polymer science Moscow : MAIK Nauka/Interperiodics Publ., 2006 56(2014), 5 vom: Sept., Seite 664-674 (DE-627)513506896 (DE-600)2239942-2 1555-6123 nnns volume:56 year:2014 number:5 month:09 pages:664-674 https://dx.doi.org/10.1134/S1560090414050066 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 56 2014 5 09 664-674
allfields_unstemmed	10.1134/S1560090414050066 doi (DE-627)SPR02025606X (SPR)S1560090414050066-e DE-627 ger DE-627 rakwb eng Khar’kova, E. M. verfasserin aut The possibility of applying a titanium-magnesium nanocatalyst in the polymerization filling of polyolefins and some properties of the obtained composites 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract The possibility of applying a titanium-magnesium nanocatalyst during in situ polymerization of ethylene and propylene in the presence of organomodified aluminum silicates and diatomite under mild conditions is investigated. How the substantial (2- to 3-fold) increase in the catalytic activity of the system depends on the type and amount of filler is shown. The activity of the titanium-magnesium nanocatalyst-filler system during polymerization of propylene is 3–4 times higher than that during the polymerization of ethylene. Composites based on ultrahigh-molecular-mass polyethylene (M = (1.4–1.7) × $ 10^{6} $) with 3.5–13.0 wt % filler are obtained. According to DSC and X-ray structural-analysis data, the polyethylene matrix differs by its high crystallinity and a Tm of 143–144°C. The physicochemical characteristics of the composites are 1.5–2.0 times greater than those of unfilled polyethylene; the nanocomposite containing 11 wt % mont-morillonite modified with vinyltrimethoxysilane has the best properties. It is shown that during the propylene polymerization, the effect of the type of filler affects not only the catalytic activity of the system, increasing it three times in the case of diatomite, but also the stereospecificity of the effect. Isotactic high-molecularmass (up to 390 × $ 10^{3} $) polypropylene is obtained in the presence of montmorillonite containing vinyltrimethoxysilane, while a low-molecular-mass ((65–75) × $ 10^{3} $) polymer with lower isotacticity is formed on diatomite. The deformation-strength characteristics of composites based on polypropylene testify the formation of an elastomeric material with Tm = 156–158°C. Polymer Science Series (dpeaa)DE-He213 Diatomite (dpeaa)DE-He213 TIBA (dpeaa)DE-He213 Olefin Polymerization (dpeaa)DE-He213 Polymerization Filling (dpeaa)DE-He213 Mendeleev, D. I. aut Smetannikov, O. V. aut Chinova, M. S. aut Ivanyuk, A. V. aut Antipov, E. M. aut Enthalten in Polymer science Moscow : MAIK Nauka/Interperiodics Publ., 2006 56(2014), 5 vom: Sept., Seite 664-674 (DE-627)513506896 (DE-600)2239942-2 1555-6123 nnns volume:56 year:2014 number:5 month:09 pages:664-674 https://dx.doi.org/10.1134/S1560090414050066 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 56 2014 5 09 664-674
allfieldsGer	10.1134/S1560090414050066 doi (DE-627)SPR02025606X (SPR)S1560090414050066-e DE-627 ger DE-627 rakwb eng Khar’kova, E. M. verfasserin aut The possibility of applying a titanium-magnesium nanocatalyst in the polymerization filling of polyolefins and some properties of the obtained composites 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract The possibility of applying a titanium-magnesium nanocatalyst during in situ polymerization of ethylene and propylene in the presence of organomodified aluminum silicates and diatomite under mild conditions is investigated. How the substantial (2- to 3-fold) increase in the catalytic activity of the system depends on the type and amount of filler is shown. The activity of the titanium-magnesium nanocatalyst-filler system during polymerization of propylene is 3–4 times higher than that during the polymerization of ethylene. Composites based on ultrahigh-molecular-mass polyethylene (M = (1.4–1.7) × $ 10^{6} $) with 3.5–13.0 wt % filler are obtained. According to DSC and X-ray structural-analysis data, the polyethylene matrix differs by its high crystallinity and a Tm of 143–144°C. The physicochemical characteristics of the composites are 1.5–2.0 times greater than those of unfilled polyethylene; the nanocomposite containing 11 wt % mont-morillonite modified with vinyltrimethoxysilane has the best properties. It is shown that during the propylene polymerization, the effect of the type of filler affects not only the catalytic activity of the system, increasing it three times in the case of diatomite, but also the stereospecificity of the effect. Isotactic high-molecularmass (up to 390 × $ 10^{3} $) polypropylene is obtained in the presence of montmorillonite containing vinyltrimethoxysilane, while a low-molecular-mass ((65–75) × $ 10^{3} $) polymer with lower isotacticity is formed on diatomite. The deformation-strength characteristics of composites based on polypropylene testify the formation of an elastomeric material with Tm = 156–158°C. Polymer Science Series (dpeaa)DE-He213 Diatomite (dpeaa)DE-He213 TIBA (dpeaa)DE-He213 Olefin Polymerization (dpeaa)DE-He213 Polymerization Filling (dpeaa)DE-He213 Mendeleev, D. I. aut Smetannikov, O. V. aut Chinova, M. S. aut Ivanyuk, A. V. aut Antipov, E. M. aut Enthalten in Polymer science Moscow : MAIK Nauka/Interperiodics Publ., 2006 56(2014), 5 vom: Sept., Seite 664-674 (DE-627)513506896 (DE-600)2239942-2 1555-6123 nnns volume:56 year:2014 number:5 month:09 pages:664-674 https://dx.doi.org/10.1134/S1560090414050066 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 56 2014 5 09 664-674
allfieldsSound	10.1134/S1560090414050066 doi (DE-627)SPR02025606X (SPR)S1560090414050066-e DE-627 ger DE-627 rakwb eng Khar’kova, E. M. verfasserin aut The possibility of applying a titanium-magnesium nanocatalyst in the polymerization filling of polyolefins and some properties of the obtained composites 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract The possibility of applying a titanium-magnesium nanocatalyst during in situ polymerization of ethylene and propylene in the presence of organomodified aluminum silicates and diatomite under mild conditions is investigated. How the substantial (2- to 3-fold) increase in the catalytic activity of the system depends on the type and amount of filler is shown. The activity of the titanium-magnesium nanocatalyst-filler system during polymerization of propylene is 3–4 times higher than that during the polymerization of ethylene. Composites based on ultrahigh-molecular-mass polyethylene (M = (1.4–1.7) × $ 10^{6} $) with 3.5–13.0 wt % filler are obtained. According to DSC and X-ray structural-analysis data, the polyethylene matrix differs by its high crystallinity and a Tm of 143–144°C. The physicochemical characteristics of the composites are 1.5–2.0 times greater than those of unfilled polyethylene; the nanocomposite containing 11 wt % mont-morillonite modified with vinyltrimethoxysilane has the best properties. It is shown that during the propylene polymerization, the effect of the type of filler affects not only the catalytic activity of the system, increasing it three times in the case of diatomite, but also the stereospecificity of the effect. Isotactic high-molecularmass (up to 390 × $ 10^{3} $) polypropylene is obtained in the presence of montmorillonite containing vinyltrimethoxysilane, while a low-molecular-mass ((65–75) × $ 10^{3} $) polymer with lower isotacticity is formed on diatomite. The deformation-strength characteristics of composites based on polypropylene testify the formation of an elastomeric material with Tm = 156–158°C. Polymer Science Series (dpeaa)DE-He213 Diatomite (dpeaa)DE-He213 TIBA (dpeaa)DE-He213 Olefin Polymerization (dpeaa)DE-He213 Polymerization Filling (dpeaa)DE-He213 Mendeleev, D. I. aut Smetannikov, O. V. aut Chinova, M. S. aut Ivanyuk, A. V. aut Antipov, E. M. aut Enthalten in Polymer science Moscow : MAIK Nauka/Interperiodics Publ., 2006 56(2014), 5 vom: Sept., Seite 664-674 (DE-627)513506896 (DE-600)2239942-2 1555-6123 nnns volume:56 year:2014 number:5 month:09 pages:664-674 https://dx.doi.org/10.1134/S1560090414050066 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 56 2014 5 09 664-674
language	English
source	Enthalten in Polymer science 56(2014), 5 vom: Sept., Seite 664-674 volume:56 year:2014 number:5 month:09 pages:664-674
sourceStr	Enthalten in Polymer science 56(2014), 5 vom: Sept., Seite 664-674 volume:56 year:2014 number:5 month:09 pages:664-674
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Polymer Science Series Diatomite TIBA Olefin Polymerization Polymerization Filling
isfreeaccess_bool	false
container_title	Polymer science
authorswithroles_txt_mv	Khar’kova, E. M. @@aut@@ Mendeleev, D. I. @@aut@@ Smetannikov, O. V. @@aut@@ Chinova, M. S. @@aut@@ Ivanyuk, A. V. @@aut@@ Antipov, E. M. @@aut@@
publishDateDaySort_date	2014-09-01T00:00:00Z
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author	Khar’kova, E. M.
spellingShingle	Khar’kova, E. M. misc Polymer Science Series misc Diatomite misc TIBA misc Olefin Polymerization misc Polymerization Filling The possibility of applying a titanium-magnesium nanocatalyst in the polymerization filling of polyolefins and some properties of the obtained composites
authorStr	Khar’kova, E. M.
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topic_title	The possibility of applying a titanium-magnesium nanocatalyst in the polymerization filling of polyolefins and some properties of the obtained composites Polymer Science Series (dpeaa)DE-He213 Diatomite (dpeaa)DE-He213 TIBA (dpeaa)DE-He213 Olefin Polymerization (dpeaa)DE-He213 Polymerization Filling (dpeaa)DE-He213
topic	misc Polymer Science Series misc Diatomite misc TIBA misc Olefin Polymerization misc Polymerization Filling
topic_unstemmed	misc Polymer Science Series misc Diatomite misc TIBA misc Olefin Polymerization misc Polymerization Filling
topic_browse	misc Polymer Science Series misc Diatomite misc TIBA misc Olefin Polymerization misc Polymerization Filling
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title	The possibility of applying a titanium-magnesium nanocatalyst in the polymerization filling of polyolefins and some properties of the obtained composites
ctrlnum	(DE-627)SPR02025606X (SPR)S1560090414050066-e
title_full	The possibility of applying a titanium-magnesium nanocatalyst in the polymerization filling of polyolefins and some properties of the obtained composites
author_sort	Khar’kova, E. M.
journal	Polymer science
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container_start_page	664
author_browse	Khar’kova, E. M. Mendeleev, D. I. Smetannikov, O. V. Chinova, M. S. Ivanyuk, A. V. Antipov, E. M.
container_volume	56
format_se	Elektronische Aufsätze
author-letter	Khar’kova, E. M.
doi_str_mv	10.1134/S1560090414050066
title_sort	possibility of applying a titanium-magnesium nanocatalyst in the polymerization filling of polyolefins and some properties of the obtained composites
title_auth	The possibility of applying a titanium-magnesium nanocatalyst in the polymerization filling of polyolefins and some properties of the obtained composites
abstract	Abstract The possibility of applying a titanium-magnesium nanocatalyst during in situ polymerization of ethylene and propylene in the presence of organomodified aluminum silicates and diatomite under mild conditions is investigated. How the substantial (2- to 3-fold) increase in the catalytic activity of the system depends on the type and amount of filler is shown. The activity of the titanium-magnesium nanocatalyst-filler system during polymerization of propylene is 3–4 times higher than that during the polymerization of ethylene. Composites based on ultrahigh-molecular-mass polyethylene (M = (1.4–1.7) × $ 10^{6} $) with 3.5–13.0 wt % filler are obtained. According to DSC and X-ray structural-analysis data, the polyethylene matrix differs by its high crystallinity and a Tm of 143–144°C. The physicochemical characteristics of the composites are 1.5–2.0 times greater than those of unfilled polyethylene; the nanocomposite containing 11 wt % mont-morillonite modified with vinyltrimethoxysilane has the best properties. It is shown that during the propylene polymerization, the effect of the type of filler affects not only the catalytic activity of the system, increasing it three times in the case of diatomite, but also the stereospecificity of the effect. Isotactic high-molecularmass (up to 390 × $ 10^{3} $) polypropylene is obtained in the presence of montmorillonite containing vinyltrimethoxysilane, while a low-molecular-mass ((65–75) × $ 10^{3} $) polymer with lower isotacticity is formed on diatomite. The deformation-strength characteristics of composites based on polypropylene testify the formation of an elastomeric material with Tm = 156–158°C. © Pleiades Publishing, Ltd. 2014
abstractGer	Abstract The possibility of applying a titanium-magnesium nanocatalyst during in situ polymerization of ethylene and propylene in the presence of organomodified aluminum silicates and diatomite under mild conditions is investigated. How the substantial (2- to 3-fold) increase in the catalytic activity of the system depends on the type and amount of filler is shown. The activity of the titanium-magnesium nanocatalyst-filler system during polymerization of propylene is 3–4 times higher than that during the polymerization of ethylene. Composites based on ultrahigh-molecular-mass polyethylene (M = (1.4–1.7) × $ 10^{6} $) with 3.5–13.0 wt % filler are obtained. According to DSC and X-ray structural-analysis data, the polyethylene matrix differs by its high crystallinity and a Tm of 143–144°C. The physicochemical characteristics of the composites are 1.5–2.0 times greater than those of unfilled polyethylene; the nanocomposite containing 11 wt % mont-morillonite modified with vinyltrimethoxysilane has the best properties. It is shown that during the propylene polymerization, the effect of the type of filler affects not only the catalytic activity of the system, increasing it three times in the case of diatomite, but also the stereospecificity of the effect. Isotactic high-molecularmass (up to 390 × $ 10^{3} $) polypropylene is obtained in the presence of montmorillonite containing vinyltrimethoxysilane, while a low-molecular-mass ((65–75) × $ 10^{3} $) polymer with lower isotacticity is formed on diatomite. The deformation-strength characteristics of composites based on polypropylene testify the formation of an elastomeric material with Tm = 156–158°C. © Pleiades Publishing, Ltd. 2014
abstract_unstemmed	Abstract The possibility of applying a titanium-magnesium nanocatalyst during in situ polymerization of ethylene and propylene in the presence of organomodified aluminum silicates and diatomite under mild conditions is investigated. How the substantial (2- to 3-fold) increase in the catalytic activity of the system depends on the type and amount of filler is shown. The activity of the titanium-magnesium nanocatalyst-filler system during polymerization of propylene is 3–4 times higher than that during the polymerization of ethylene. Composites based on ultrahigh-molecular-mass polyethylene (M = (1.4–1.7) × $ 10^{6} $) with 3.5–13.0 wt % filler are obtained. According to DSC and X-ray structural-analysis data, the polyethylene matrix differs by its high crystallinity and a Tm of 143–144°C. The physicochemical characteristics of the composites are 1.5–2.0 times greater than those of unfilled polyethylene; the nanocomposite containing 11 wt % mont-morillonite modified with vinyltrimethoxysilane has the best properties. It is shown that during the propylene polymerization, the effect of the type of filler affects not only the catalytic activity of the system, increasing it three times in the case of diatomite, but also the stereospecificity of the effect. Isotactic high-molecularmass (up to 390 × $ 10^{3} $) polypropylene is obtained in the presence of montmorillonite containing vinyltrimethoxysilane, while a low-molecular-mass ((65–75) × $ 10^{3} $) polymer with lower isotacticity is formed on diatomite. The deformation-strength characteristics of composites based on polypropylene testify the formation of an elastomeric material with Tm = 156–158°C. © Pleiades Publishing, Ltd. 2014
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container_issue	5
title_short	The possibility of applying a titanium-magnesium nanocatalyst in the polymerization filling of polyolefins and some properties of the obtained composites
url	https://dx.doi.org/10.1134/S1560090414050066
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author2	Mendeleev, D. I. Smetannikov, O. V. Chinova, M. S. Ivanyuk, A. V. Antipov, E. M.
author2Str	Mendeleev, D. I. Smetannikov, O. V. Chinova, M. S. Ivanyuk, A. V. Antipov, E. M.
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doi_str	10.1134/S1560090414050066
up_date	2024-07-03T14:54:18.923Z
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The possibility of applying a titanium-magnesium nanocatalyst in the polymerization filling of polyolefins and some properties of the obtained composites

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