Solid-phase modification of the natural polysaccharide arabinogalactan by poorly soluble pesticides

Abstract The modification of arabinogalactan by poorly soluble pesticides (chlorsulfuron, carbendasim, and thiram) is studied via an impact–deformation action method. It is found that the mechanochemical action on arabinogalactan leads to change in its macromolecular structure owing to the polymer c...
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Autor*in:	Mudarisova, R. Kh. [verfasserIn] Koptyaeva, E. I. Badykova, L. A.

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2015

Schlagwörter:	Inclusion Complex Polymer Science Series Thiram Mechanochemical Action Chlorsulfuron

Anmerkung:	© Pleiades Publishing, Ltd. 2015

Übergeordnetes Werk:	Enthalten in: Polymer science - Moscow : MAIK Nauka/Interperiodics Publ., 2006, 57(2015), 6 vom: Nov., Seite 616-622
Übergeordnetes Werk:	volume:57 ; year:2015 ; number:6 ; month:11 ; pages:616-622

Links:	Volltext

DOI / URN:	10.1134/S1560090415060147

Katalog-ID:	SPR020257228

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520			\|a Abstract The modification of arabinogalactan by poorly soluble pesticides (chlorsulfuron, carbendasim, and thiram) is studied via an impact–deformation action method. It is found that the mechanochemical action on arabinogalactan leads to change in its macromolecular structure owing to the polymer chain breakage, splitting of the side fragments, and the appearance of new functional (carboxyl) groups. The impact–shear action on pesticides leads to disordering of the crystalline structure with the breakage of the intermolecular hydrogen bonds. NMR relaxation, UV, IR, and 13C NMR spectroscopic methods are used to demonstrate the formation of the inclusion complexes with the participation of the nitrogen-containing groups of a herbicide and hydroxyl and ester groups of the polymer. The complex formation results in increases in the characteristic viscosities of the composition solutions relative to those of the components activated individually and an increase in the pesticide content going into solution (from 1.5 to 5.0 times). The investigation of the thermal characteristics of the compositions via TGA and DTA methods shows that, first, the sample decomposition is more intense than that of the initial components and, second, the crystalline phase of the herbicide in the modified compositions almost completely disappears. The formation of new properties provides high stability and biological activity to the compositions with a simultaneous possibility to decrease the pesticide consumption norm 10-fold.
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700	1		\|a Badykova, L. A. \|4 aut
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912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2116
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2119
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author_variant	r k m rk rkm e i k ei eik l a b la lab
matchkey_str	article:15556123:2015----::oipaeoiiainfhntrloyacaierbnglcabp
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publishDate	2015
allfields	10.1134/S1560090415060147 doi (DE-627)SPR020257228 (SPR)S1560090415060147-e DE-627 ger DE-627 rakwb eng Mudarisova, R. Kh. verfasserin aut Solid-phase modification of the natural polysaccharide arabinogalactan by poorly soluble pesticides 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2015 Abstract The modification of arabinogalactan by poorly soluble pesticides (chlorsulfuron, carbendasim, and thiram) is studied via an impact–deformation action method. It is found that the mechanochemical action on arabinogalactan leads to change in its macromolecular structure owing to the polymer chain breakage, splitting of the side fragments, and the appearance of new functional (carboxyl) groups. The impact–shear action on pesticides leads to disordering of the crystalline structure with the breakage of the intermolecular hydrogen bonds. NMR relaxation, UV, IR, and 13C NMR spectroscopic methods are used to demonstrate the formation of the inclusion complexes with the participation of the nitrogen-containing groups of a herbicide and hydroxyl and ester groups of the polymer. The complex formation results in increases in the characteristic viscosities of the composition solutions relative to those of the components activated individually and an increase in the pesticide content going into solution (from 1.5 to 5.0 times). The investigation of the thermal characteristics of the compositions via TGA and DTA methods shows that, first, the sample decomposition is more intense than that of the initial components and, second, the crystalline phase of the herbicide in the modified compositions almost completely disappears. The formation of new properties provides high stability and biological activity to the compositions with a simultaneous possibility to decrease the pesticide consumption norm 10-fold. Inclusion Complex (dpeaa)DE-He213 Polymer Science Series (dpeaa)DE-He213 Thiram (dpeaa)DE-He213 Mechanochemical Action (dpeaa)DE-He213 Chlorsulfuron (dpeaa)DE-He213 Koptyaeva, E. I. aut Badykova, L. A. aut Enthalten in Polymer science Moscow : MAIK Nauka/Interperiodics Publ., 2006 57(2015), 6 vom: Nov., Seite 616-622 (DE-627)513506896 (DE-600)2239942-2 1555-6123 nnns volume:57 year:2015 number:6 month:11 pages:616-622 https://dx.doi.org/10.1134/S1560090415060147 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 57 2015 6 11 616-622
spelling	10.1134/S1560090415060147 doi (DE-627)SPR020257228 (SPR)S1560090415060147-e DE-627 ger DE-627 rakwb eng Mudarisova, R. Kh. verfasserin aut Solid-phase modification of the natural polysaccharide arabinogalactan by poorly soluble pesticides 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2015 Abstract The modification of arabinogalactan by poorly soluble pesticides (chlorsulfuron, carbendasim, and thiram) is studied via an impact–deformation action method. It is found that the mechanochemical action on arabinogalactan leads to change in its macromolecular structure owing to the polymer chain breakage, splitting of the side fragments, and the appearance of new functional (carboxyl) groups. The impact–shear action on pesticides leads to disordering of the crystalline structure with the breakage of the intermolecular hydrogen bonds. NMR relaxation, UV, IR, and 13C NMR spectroscopic methods are used to demonstrate the formation of the inclusion complexes with the participation of the nitrogen-containing groups of a herbicide and hydroxyl and ester groups of the polymer. The complex formation results in increases in the characteristic viscosities of the composition solutions relative to those of the components activated individually and an increase in the pesticide content going into solution (from 1.5 to 5.0 times). The investigation of the thermal characteristics of the compositions via TGA and DTA methods shows that, first, the sample decomposition is more intense than that of the initial components and, second, the crystalline phase of the herbicide in the modified compositions almost completely disappears. The formation of new properties provides high stability and biological activity to the compositions with a simultaneous possibility to decrease the pesticide consumption norm 10-fold. Inclusion Complex (dpeaa)DE-He213 Polymer Science Series (dpeaa)DE-He213 Thiram (dpeaa)DE-He213 Mechanochemical Action (dpeaa)DE-He213 Chlorsulfuron (dpeaa)DE-He213 Koptyaeva, E. I. aut Badykova, L. A. aut Enthalten in Polymer science Moscow : MAIK Nauka/Interperiodics Publ., 2006 57(2015), 6 vom: Nov., Seite 616-622 (DE-627)513506896 (DE-600)2239942-2 1555-6123 nnns volume:57 year:2015 number:6 month:11 pages:616-622 https://dx.doi.org/10.1134/S1560090415060147 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 57 2015 6 11 616-622
allfields_unstemmed	10.1134/S1560090415060147 doi (DE-627)SPR020257228 (SPR)S1560090415060147-e DE-627 ger DE-627 rakwb eng Mudarisova, R. Kh. verfasserin aut Solid-phase modification of the natural polysaccharide arabinogalactan by poorly soluble pesticides 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2015 Abstract The modification of arabinogalactan by poorly soluble pesticides (chlorsulfuron, carbendasim, and thiram) is studied via an impact–deformation action method. It is found that the mechanochemical action on arabinogalactan leads to change in its macromolecular structure owing to the polymer chain breakage, splitting of the side fragments, and the appearance of new functional (carboxyl) groups. The impact–shear action on pesticides leads to disordering of the crystalline structure with the breakage of the intermolecular hydrogen bonds. NMR relaxation, UV, IR, and 13C NMR spectroscopic methods are used to demonstrate the formation of the inclusion complexes with the participation of the nitrogen-containing groups of a herbicide and hydroxyl and ester groups of the polymer. The complex formation results in increases in the characteristic viscosities of the composition solutions relative to those of the components activated individually and an increase in the pesticide content going into solution (from 1.5 to 5.0 times). The investigation of the thermal characteristics of the compositions via TGA and DTA methods shows that, first, the sample decomposition is more intense than that of the initial components and, second, the crystalline phase of the herbicide in the modified compositions almost completely disappears. The formation of new properties provides high stability and biological activity to the compositions with a simultaneous possibility to decrease the pesticide consumption norm 10-fold. Inclusion Complex (dpeaa)DE-He213 Polymer Science Series (dpeaa)DE-He213 Thiram (dpeaa)DE-He213 Mechanochemical Action (dpeaa)DE-He213 Chlorsulfuron (dpeaa)DE-He213 Koptyaeva, E. I. aut Badykova, L. A. aut Enthalten in Polymer science Moscow : MAIK Nauka/Interperiodics Publ., 2006 57(2015), 6 vom: Nov., Seite 616-622 (DE-627)513506896 (DE-600)2239942-2 1555-6123 nnns volume:57 year:2015 number:6 month:11 pages:616-622 https://dx.doi.org/10.1134/S1560090415060147 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 57 2015 6 11 616-622
allfieldsGer	10.1134/S1560090415060147 doi (DE-627)SPR020257228 (SPR)S1560090415060147-e DE-627 ger DE-627 rakwb eng Mudarisova, R. Kh. verfasserin aut Solid-phase modification of the natural polysaccharide arabinogalactan by poorly soluble pesticides 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2015 Abstract The modification of arabinogalactan by poorly soluble pesticides (chlorsulfuron, carbendasim, and thiram) is studied via an impact–deformation action method. It is found that the mechanochemical action on arabinogalactan leads to change in its macromolecular structure owing to the polymer chain breakage, splitting of the side fragments, and the appearance of new functional (carboxyl) groups. The impact–shear action on pesticides leads to disordering of the crystalline structure with the breakage of the intermolecular hydrogen bonds. NMR relaxation, UV, IR, and 13C NMR spectroscopic methods are used to demonstrate the formation of the inclusion complexes with the participation of the nitrogen-containing groups of a herbicide and hydroxyl and ester groups of the polymer. The complex formation results in increases in the characteristic viscosities of the composition solutions relative to those of the components activated individually and an increase in the pesticide content going into solution (from 1.5 to 5.0 times). The investigation of the thermal characteristics of the compositions via TGA and DTA methods shows that, first, the sample decomposition is more intense than that of the initial components and, second, the crystalline phase of the herbicide in the modified compositions almost completely disappears. The formation of new properties provides high stability and biological activity to the compositions with a simultaneous possibility to decrease the pesticide consumption norm 10-fold. Inclusion Complex (dpeaa)DE-He213 Polymer Science Series (dpeaa)DE-He213 Thiram (dpeaa)DE-He213 Mechanochemical Action (dpeaa)DE-He213 Chlorsulfuron (dpeaa)DE-He213 Koptyaeva, E. I. aut Badykova, L. A. aut Enthalten in Polymer science Moscow : MAIK Nauka/Interperiodics Publ., 2006 57(2015), 6 vom: Nov., Seite 616-622 (DE-627)513506896 (DE-600)2239942-2 1555-6123 nnns volume:57 year:2015 number:6 month:11 pages:616-622 https://dx.doi.org/10.1134/S1560090415060147 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 57 2015 6 11 616-622
allfieldsSound	10.1134/S1560090415060147 doi (DE-627)SPR020257228 (SPR)S1560090415060147-e DE-627 ger DE-627 rakwb eng Mudarisova, R. Kh. verfasserin aut Solid-phase modification of the natural polysaccharide arabinogalactan by poorly soluble pesticides 2015 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2015 Abstract The modification of arabinogalactan by poorly soluble pesticides (chlorsulfuron, carbendasim, and thiram) is studied via an impact–deformation action method. It is found that the mechanochemical action on arabinogalactan leads to change in its macromolecular structure owing to the polymer chain breakage, splitting of the side fragments, and the appearance of new functional (carboxyl) groups. The impact–shear action on pesticides leads to disordering of the crystalline structure with the breakage of the intermolecular hydrogen bonds. NMR relaxation, UV, IR, and 13C NMR spectroscopic methods are used to demonstrate the formation of the inclusion complexes with the participation of the nitrogen-containing groups of a herbicide and hydroxyl and ester groups of the polymer. The complex formation results in increases in the characteristic viscosities of the composition solutions relative to those of the components activated individually and an increase in the pesticide content going into solution (from 1.5 to 5.0 times). The investigation of the thermal characteristics of the compositions via TGA and DTA methods shows that, first, the sample decomposition is more intense than that of the initial components and, second, the crystalline phase of the herbicide in the modified compositions almost completely disappears. The formation of new properties provides high stability and biological activity to the compositions with a simultaneous possibility to decrease the pesticide consumption norm 10-fold. Inclusion Complex (dpeaa)DE-He213 Polymer Science Series (dpeaa)DE-He213 Thiram (dpeaa)DE-He213 Mechanochemical Action (dpeaa)DE-He213 Chlorsulfuron (dpeaa)DE-He213 Koptyaeva, E. I. aut Badykova, L. A. aut Enthalten in Polymer science Moscow : MAIK Nauka/Interperiodics Publ., 2006 57(2015), 6 vom: Nov., Seite 616-622 (DE-627)513506896 (DE-600)2239942-2 1555-6123 nnns volume:57 year:2015 number:6 month:11 pages:616-622 https://dx.doi.org/10.1134/S1560090415060147 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 57 2015 6 11 616-622
language	English
source	Enthalten in Polymer science 57(2015), 6 vom: Nov., Seite 616-622 volume:57 year:2015 number:6 month:11 pages:616-622
sourceStr	Enthalten in Polymer science 57(2015), 6 vom: Nov., Seite 616-622 volume:57 year:2015 number:6 month:11 pages:616-622
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Inclusion Complex Polymer Science Series Thiram Mechanochemical Action Chlorsulfuron
isfreeaccess_bool	false
container_title	Polymer science
authorswithroles_txt_mv	Mudarisova, R. Kh. @@aut@@ Koptyaeva, E. I. @@aut@@ Badykova, L. A. @@aut@@
publishDateDaySort_date	2015-11-01T00:00:00Z
hierarchy_top_id	513506896
id	SPR020257228
language_de	englisch
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author	Mudarisova, R. Kh.
spellingShingle	Mudarisova, R. Kh. misc Inclusion Complex misc Polymer Science Series misc Thiram misc Mechanochemical Action misc Chlorsulfuron Solid-phase modification of the natural polysaccharide arabinogalactan by poorly soluble pesticides
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topic_title	Solid-phase modification of the natural polysaccharide arabinogalactan by poorly soluble pesticides Inclusion Complex (dpeaa)DE-He213 Polymer Science Series (dpeaa)DE-He213 Thiram (dpeaa)DE-He213 Mechanochemical Action (dpeaa)DE-He213 Chlorsulfuron (dpeaa)DE-He213
topic	misc Inclusion Complex misc Polymer Science Series misc Thiram misc Mechanochemical Action misc Chlorsulfuron
topic_unstemmed	misc Inclusion Complex misc Polymer Science Series misc Thiram misc Mechanochemical Action misc Chlorsulfuron
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title	Solid-phase modification of the natural polysaccharide arabinogalactan by poorly soluble pesticides
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title_full	Solid-phase modification of the natural polysaccharide arabinogalactan by poorly soluble pesticides
author_sort	Mudarisova, R. Kh.
journal	Polymer science
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container_start_page	616
author_browse	Mudarisova, R. Kh. Koptyaeva, E. I. Badykova, L. A.
container_volume	57
format_se	Elektronische Aufsätze
author-letter	Mudarisova, R. Kh.
doi_str_mv	10.1134/S1560090415060147
title_sort	solid-phase modification of the natural polysaccharide arabinogalactan by poorly soluble pesticides
title_auth	Solid-phase modification of the natural polysaccharide arabinogalactan by poorly soluble pesticides
abstract	Abstract The modification of arabinogalactan by poorly soluble pesticides (chlorsulfuron, carbendasim, and thiram) is studied via an impact–deformation action method. It is found that the mechanochemical action on arabinogalactan leads to change in its macromolecular structure owing to the polymer chain breakage, splitting of the side fragments, and the appearance of new functional (carboxyl) groups. The impact–shear action on pesticides leads to disordering of the crystalline structure with the breakage of the intermolecular hydrogen bonds. NMR relaxation, UV, IR, and 13C NMR spectroscopic methods are used to demonstrate the formation of the inclusion complexes with the participation of the nitrogen-containing groups of a herbicide and hydroxyl and ester groups of the polymer. The complex formation results in increases in the characteristic viscosities of the composition solutions relative to those of the components activated individually and an increase in the pesticide content going into solution (from 1.5 to 5.0 times). The investigation of the thermal characteristics of the compositions via TGA and DTA methods shows that, first, the sample decomposition is more intense than that of the initial components and, second, the crystalline phase of the herbicide in the modified compositions almost completely disappears. The formation of new properties provides high stability and biological activity to the compositions with a simultaneous possibility to decrease the pesticide consumption norm 10-fold. © Pleiades Publishing, Ltd. 2015
abstractGer	Abstract The modification of arabinogalactan by poorly soluble pesticides (chlorsulfuron, carbendasim, and thiram) is studied via an impact–deformation action method. It is found that the mechanochemical action on arabinogalactan leads to change in its macromolecular structure owing to the polymer chain breakage, splitting of the side fragments, and the appearance of new functional (carboxyl) groups. The impact–shear action on pesticides leads to disordering of the crystalline structure with the breakage of the intermolecular hydrogen bonds. NMR relaxation, UV, IR, and 13C NMR spectroscopic methods are used to demonstrate the formation of the inclusion complexes with the participation of the nitrogen-containing groups of a herbicide and hydroxyl and ester groups of the polymer. The complex formation results in increases in the characteristic viscosities of the composition solutions relative to those of the components activated individually and an increase in the pesticide content going into solution (from 1.5 to 5.0 times). The investigation of the thermal characteristics of the compositions via TGA and DTA methods shows that, first, the sample decomposition is more intense than that of the initial components and, second, the crystalline phase of the herbicide in the modified compositions almost completely disappears. The formation of new properties provides high stability and biological activity to the compositions with a simultaneous possibility to decrease the pesticide consumption norm 10-fold. © Pleiades Publishing, Ltd. 2015
abstract_unstemmed	Abstract The modification of arabinogalactan by poorly soluble pesticides (chlorsulfuron, carbendasim, and thiram) is studied via an impact–deformation action method. It is found that the mechanochemical action on arabinogalactan leads to change in its macromolecular structure owing to the polymer chain breakage, splitting of the side fragments, and the appearance of new functional (carboxyl) groups. The impact–shear action on pesticides leads to disordering of the crystalline structure with the breakage of the intermolecular hydrogen bonds. NMR relaxation, UV, IR, and 13C NMR spectroscopic methods are used to demonstrate the formation of the inclusion complexes with the participation of the nitrogen-containing groups of a herbicide and hydroxyl and ester groups of the polymer. The complex formation results in increases in the characteristic viscosities of the composition solutions relative to those of the components activated individually and an increase in the pesticide content going into solution (from 1.5 to 5.0 times). The investigation of the thermal characteristics of the compositions via TGA and DTA methods shows that, first, the sample decomposition is more intense than that of the initial components and, second, the crystalline phase of the herbicide in the modified compositions almost completely disappears. The formation of new properties provides high stability and biological activity to the compositions with a simultaneous possibility to decrease the pesticide consumption norm 10-fold. © Pleiades Publishing, Ltd. 2015
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container_issue	6
title_short	Solid-phase modification of the natural polysaccharide arabinogalactan by poorly soluble pesticides
url	https://dx.doi.org/10.1134/S1560090415060147
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author2	Koptyaeva, E. I. Badykova, L. A.
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up_date	2024-07-03T14:54:45.689Z
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Kh.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Solid-phase modification of the natural polysaccharide arabinogalactan by poorly soluble pesticides</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2015</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Pleiades Publishing, Ltd. 2015</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The modification of arabinogalactan by poorly soluble pesticides (chlorsulfuron, carbendasim, and thiram) is studied via an impact–deformation action method. It is found that the mechanochemical action on arabinogalactan leads to change in its macromolecular structure owing to the polymer chain breakage, splitting of the side fragments, and the appearance of new functional (carboxyl) groups. The impact–shear action on pesticides leads to disordering of the crystalline structure with the breakage of the intermolecular hydrogen bonds. NMR relaxation, UV, IR, and 13C NMR spectroscopic methods are used to demonstrate the formation of the inclusion complexes with the participation of the nitrogen-containing groups of a herbicide and hydroxyl and ester groups of the polymer. The complex formation results in increases in the characteristic viscosities of the composition solutions relative to those of the components activated individually and an increase in the pesticide content going into solution (from 1.5 to 5.0 times). The investigation of the thermal characteristics of the compositions via TGA and DTA methods shows that, first, the sample decomposition is more intense than that of the initial components and, second, the crystalline phase of the herbicide in the modified compositions almost completely disappears. The formation of new properties provides high stability and biological activity to the compositions with a simultaneous possibility to decrease the pesticide consumption norm 10-fold.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Inclusion Complex</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polymer Science Series</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Thiram</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mechanochemical Action</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Chlorsulfuron</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Koptyaeva, E. 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Solid-phase modification of the natural polysaccharide arabinogalactan by poorly soluble pesticides

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