Aggregation effects in solutions of model oligopeptides and other amphiphilic polymers
Abstract The problems of the aggregation behavior of amphiphilic macromolecules in solution are discussed. The cases of electrically neutral and polyelectrolyte chains are examined. The effect of chain parameters, interaction parameters, and external factors—temperature, solvent quality, medium pH,...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Subbotin, A. V. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2012 |
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| Schlagwörter: |
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| Anmerkung: |
© Pleiades Publishing, Ltd. 2012 |
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| Übergeordnetes Werk: |
Enthalten in: Polymer science - Moscow : MAIK Nauka/Interperiodics Publ., 2006, 54(2012), 1 vom: Sept., Seite 36-47 |
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| Übergeordnetes Werk: |
volume:54 ; year:2012 ; number:1 ; month:09 ; pages:36-47 |
| Links: |
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| DOI / URN: |
10.1134/S1811238212030010 |
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| Katalog-ID: |
SPR020261888 |
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| 100 | 1 | |a Subbotin, A. V. |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Aggregation effects in solutions of model oligopeptides and other amphiphilic polymers |
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| 520 | |a Abstract The problems of the aggregation behavior of amphiphilic macromolecules in solution are discussed. The cases of electrically neutral and polyelectrolyte chains are examined. The effect of chain parameters, interaction parameters, and external factors—temperature, solvent quality, medium pH, and solution ionic strength—on the structure and stability of the aggregates is analyzed. As examples, two systems are selected: (i) a solution of model oligopeptides with different chain architectures that contain hydrophobic alanine and negatively charged polar aspartic acid and (ii) a solution of HP copolymers in which hydrophobic (H) groups are located in the backbone and polar (P) side groups have a rigid bond to the backbone. The micelles formed by the oligopeptides are thermodynamically stabilized after the addition of a univalent salt; in addition, the effect heavily depends on the pH of a medium and the size of the added cations. For the second system, the regions of stability of aggregates of different geometries are determined and the corresponding phase diagram is constructed as a function of the surface tension and bending modulus of the surface of the aggregate. The problems related to the kinetics of coalescence of the aggregates are discussed. | ||
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| 650 | 4 | |a Amphiphilic Polymer |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Lamellar Layer |7 (dpeaa)DE-He213 | |
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| 700 | 1 | |a Semenov, A. N. |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Polymer science |d Moscow : MAIK Nauka/Interperiodics Publ., 2006 |g 54(2012), 1 vom: Sept., Seite 36-47 |w (DE-627)51620484X |w (DE-600)2247059-1 |x 1555-614X |7 nnns |
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| 856 | 4 | 0 | |u https://dx.doi.org/10.1134/S1811238212030010 |z lizenzpflichtig |3 Volltext |
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10.1134/S1811238212030010 doi (DE-627)SPR020261888 (SPR)S1811238212030010-e DE-627 ger DE-627 rakwb eng Subbotin, A. V. verfasserin aut Aggregation effects in solutions of model oligopeptides and other amphiphilic polymers 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2012 Abstract The problems of the aggregation behavior of amphiphilic macromolecules in solution are discussed. The cases of electrically neutral and polyelectrolyte chains are examined. The effect of chain parameters, interaction parameters, and external factors—temperature, solvent quality, medium pH, and solution ionic strength—on the structure and stability of the aggregates is analyzed. As examples, two systems are selected: (i) a solution of model oligopeptides with different chain architectures that contain hydrophobic alanine and negatively charged polar aspartic acid and (ii) a solution of HP copolymers in which hydrophobic (H) groups are located in the backbone and polar (P) side groups have a rigid bond to the backbone. The micelles formed by the oligopeptides are thermodynamically stabilized after the addition of a univalent salt; in addition, the effect heavily depends on the pH of a medium and the size of the added cations. For the second system, the regions of stability of aggregates of different geometries are determined and the corresponding phase diagram is constructed as a function of the surface tension and bending modulus of the surface of the aggregate. The problems related to the kinetics of coalescence of the aggregates are discussed. Polymer Science Series (dpeaa)DE-He213 Aggregation Effect (dpeaa)DE-He213 Amphiphilic Polymer (dpeaa)DE-He213 Lamellar Layer (dpeaa)DE-He213 Chain Architecture (dpeaa)DE-He213 Semenov, A. N. aut Enthalten in Polymer science Moscow : MAIK Nauka/Interperiodics Publ., 2006 54(2012), 1 vom: Sept., Seite 36-47 (DE-627)51620484X (DE-600)2247059-1 1555-614X nnns volume:54 year:2012 number:1 month:09 pages:36-47 https://dx.doi.org/10.1134/S1811238212030010 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 54 2012 1 09 36-47 |
| spelling |
10.1134/S1811238212030010 doi (DE-627)SPR020261888 (SPR)S1811238212030010-e DE-627 ger DE-627 rakwb eng Subbotin, A. V. verfasserin aut Aggregation effects in solutions of model oligopeptides and other amphiphilic polymers 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2012 Abstract The problems of the aggregation behavior of amphiphilic macromolecules in solution are discussed. The cases of electrically neutral and polyelectrolyte chains are examined. The effect of chain parameters, interaction parameters, and external factors—temperature, solvent quality, medium pH, and solution ionic strength—on the structure and stability of the aggregates is analyzed. As examples, two systems are selected: (i) a solution of model oligopeptides with different chain architectures that contain hydrophobic alanine and negatively charged polar aspartic acid and (ii) a solution of HP copolymers in which hydrophobic (H) groups are located in the backbone and polar (P) side groups have a rigid bond to the backbone. The micelles formed by the oligopeptides are thermodynamically stabilized after the addition of a univalent salt; in addition, the effect heavily depends on the pH of a medium and the size of the added cations. For the second system, the regions of stability of aggregates of different geometries are determined and the corresponding phase diagram is constructed as a function of the surface tension and bending modulus of the surface of the aggregate. The problems related to the kinetics of coalescence of the aggregates are discussed. Polymer Science Series (dpeaa)DE-He213 Aggregation Effect (dpeaa)DE-He213 Amphiphilic Polymer (dpeaa)DE-He213 Lamellar Layer (dpeaa)DE-He213 Chain Architecture (dpeaa)DE-He213 Semenov, A. N. aut Enthalten in Polymer science Moscow : MAIK Nauka/Interperiodics Publ., 2006 54(2012), 1 vom: Sept., Seite 36-47 (DE-627)51620484X (DE-600)2247059-1 1555-614X nnns volume:54 year:2012 number:1 month:09 pages:36-47 https://dx.doi.org/10.1134/S1811238212030010 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 54 2012 1 09 36-47 |
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10.1134/S1811238212030010 doi (DE-627)SPR020261888 (SPR)S1811238212030010-e DE-627 ger DE-627 rakwb eng Subbotin, A. V. verfasserin aut Aggregation effects in solutions of model oligopeptides and other amphiphilic polymers 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2012 Abstract The problems of the aggregation behavior of amphiphilic macromolecules in solution are discussed. The cases of electrically neutral and polyelectrolyte chains are examined. The effect of chain parameters, interaction parameters, and external factors—temperature, solvent quality, medium pH, and solution ionic strength—on the structure and stability of the aggregates is analyzed. As examples, two systems are selected: (i) a solution of model oligopeptides with different chain architectures that contain hydrophobic alanine and negatively charged polar aspartic acid and (ii) a solution of HP copolymers in which hydrophobic (H) groups are located in the backbone and polar (P) side groups have a rigid bond to the backbone. The micelles formed by the oligopeptides are thermodynamically stabilized after the addition of a univalent salt; in addition, the effect heavily depends on the pH of a medium and the size of the added cations. For the second system, the regions of stability of aggregates of different geometries are determined and the corresponding phase diagram is constructed as a function of the surface tension and bending modulus of the surface of the aggregate. The problems related to the kinetics of coalescence of the aggregates are discussed. Polymer Science Series (dpeaa)DE-He213 Aggregation Effect (dpeaa)DE-He213 Amphiphilic Polymer (dpeaa)DE-He213 Lamellar Layer (dpeaa)DE-He213 Chain Architecture (dpeaa)DE-He213 Semenov, A. N. aut Enthalten in Polymer science Moscow : MAIK Nauka/Interperiodics Publ., 2006 54(2012), 1 vom: Sept., Seite 36-47 (DE-627)51620484X (DE-600)2247059-1 1555-614X nnns volume:54 year:2012 number:1 month:09 pages:36-47 https://dx.doi.org/10.1134/S1811238212030010 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 54 2012 1 09 36-47 |
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10.1134/S1811238212030010 doi (DE-627)SPR020261888 (SPR)S1811238212030010-e DE-627 ger DE-627 rakwb eng Subbotin, A. V. verfasserin aut Aggregation effects in solutions of model oligopeptides and other amphiphilic polymers 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2012 Abstract The problems of the aggregation behavior of amphiphilic macromolecules in solution are discussed. The cases of electrically neutral and polyelectrolyte chains are examined. The effect of chain parameters, interaction parameters, and external factors—temperature, solvent quality, medium pH, and solution ionic strength—on the structure and stability of the aggregates is analyzed. As examples, two systems are selected: (i) a solution of model oligopeptides with different chain architectures that contain hydrophobic alanine and negatively charged polar aspartic acid and (ii) a solution of HP copolymers in which hydrophobic (H) groups are located in the backbone and polar (P) side groups have a rigid bond to the backbone. The micelles formed by the oligopeptides are thermodynamically stabilized after the addition of a univalent salt; in addition, the effect heavily depends on the pH of a medium and the size of the added cations. For the second system, the regions of stability of aggregates of different geometries are determined and the corresponding phase diagram is constructed as a function of the surface tension and bending modulus of the surface of the aggregate. The problems related to the kinetics of coalescence of the aggregates are discussed. Polymer Science Series (dpeaa)DE-He213 Aggregation Effect (dpeaa)DE-He213 Amphiphilic Polymer (dpeaa)DE-He213 Lamellar Layer (dpeaa)DE-He213 Chain Architecture (dpeaa)DE-He213 Semenov, A. N. aut Enthalten in Polymer science Moscow : MAIK Nauka/Interperiodics Publ., 2006 54(2012), 1 vom: Sept., Seite 36-47 (DE-627)51620484X (DE-600)2247059-1 1555-614X nnns volume:54 year:2012 number:1 month:09 pages:36-47 https://dx.doi.org/10.1134/S1811238212030010 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 54 2012 1 09 36-47 |
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10.1134/S1811238212030010 doi (DE-627)SPR020261888 (SPR)S1811238212030010-e DE-627 ger DE-627 rakwb eng Subbotin, A. V. verfasserin aut Aggregation effects in solutions of model oligopeptides and other amphiphilic polymers 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2012 Abstract The problems of the aggregation behavior of amphiphilic macromolecules in solution are discussed. The cases of electrically neutral and polyelectrolyte chains are examined. The effect of chain parameters, interaction parameters, and external factors—temperature, solvent quality, medium pH, and solution ionic strength—on the structure and stability of the aggregates is analyzed. As examples, two systems are selected: (i) a solution of model oligopeptides with different chain architectures that contain hydrophobic alanine and negatively charged polar aspartic acid and (ii) a solution of HP copolymers in which hydrophobic (H) groups are located in the backbone and polar (P) side groups have a rigid bond to the backbone. The micelles formed by the oligopeptides are thermodynamically stabilized after the addition of a univalent salt; in addition, the effect heavily depends on the pH of a medium and the size of the added cations. For the second system, the regions of stability of aggregates of different geometries are determined and the corresponding phase diagram is constructed as a function of the surface tension and bending modulus of the surface of the aggregate. The problems related to the kinetics of coalescence of the aggregates are discussed. Polymer Science Series (dpeaa)DE-He213 Aggregation Effect (dpeaa)DE-He213 Amphiphilic Polymer (dpeaa)DE-He213 Lamellar Layer (dpeaa)DE-He213 Chain Architecture (dpeaa)DE-He213 Semenov, A. N. aut Enthalten in Polymer science Moscow : MAIK Nauka/Interperiodics Publ., 2006 54(2012), 1 vom: Sept., Seite 36-47 (DE-627)51620484X (DE-600)2247059-1 1555-614X nnns volume:54 year:2012 number:1 month:09 pages:36-47 https://dx.doi.org/10.1134/S1811238212030010 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 54 2012 1 09 36-47 |
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Enthalten in Polymer science 54(2012), 1 vom: Sept., Seite 36-47 volume:54 year:2012 number:1 month:09 pages:36-47 |
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Subbotin, A. V. |
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Subbotin, A. V. misc Polymer Science Series misc Aggregation Effect misc Amphiphilic Polymer misc Lamellar Layer misc Chain Architecture Aggregation effects in solutions of model oligopeptides and other amphiphilic polymers |
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Aggregation effects in solutions of model oligopeptides and other amphiphilic polymers Polymer Science Series (dpeaa)DE-He213 Aggregation Effect (dpeaa)DE-He213 Amphiphilic Polymer (dpeaa)DE-He213 Lamellar Layer (dpeaa)DE-He213 Chain Architecture (dpeaa)DE-He213 |
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aggregation effects in solutions of model oligopeptides and other amphiphilic polymers |
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Aggregation effects in solutions of model oligopeptides and other amphiphilic polymers |
| abstract |
Abstract The problems of the aggregation behavior of amphiphilic macromolecules in solution are discussed. The cases of electrically neutral and polyelectrolyte chains are examined. The effect of chain parameters, interaction parameters, and external factors—temperature, solvent quality, medium pH, and solution ionic strength—on the structure and stability of the aggregates is analyzed. As examples, two systems are selected: (i) a solution of model oligopeptides with different chain architectures that contain hydrophobic alanine and negatively charged polar aspartic acid and (ii) a solution of HP copolymers in which hydrophobic (H) groups are located in the backbone and polar (P) side groups have a rigid bond to the backbone. The micelles formed by the oligopeptides are thermodynamically stabilized after the addition of a univalent salt; in addition, the effect heavily depends on the pH of a medium and the size of the added cations. For the second system, the regions of stability of aggregates of different geometries are determined and the corresponding phase diagram is constructed as a function of the surface tension and bending modulus of the surface of the aggregate. The problems related to the kinetics of coalescence of the aggregates are discussed. © Pleiades Publishing, Ltd. 2012 |
| abstractGer |
Abstract The problems of the aggregation behavior of amphiphilic macromolecules in solution are discussed. The cases of electrically neutral and polyelectrolyte chains are examined. The effect of chain parameters, interaction parameters, and external factors—temperature, solvent quality, medium pH, and solution ionic strength—on the structure and stability of the aggregates is analyzed. As examples, two systems are selected: (i) a solution of model oligopeptides with different chain architectures that contain hydrophobic alanine and negatively charged polar aspartic acid and (ii) a solution of HP copolymers in which hydrophobic (H) groups are located in the backbone and polar (P) side groups have a rigid bond to the backbone. The micelles formed by the oligopeptides are thermodynamically stabilized after the addition of a univalent salt; in addition, the effect heavily depends on the pH of a medium and the size of the added cations. For the second system, the regions of stability of aggregates of different geometries are determined and the corresponding phase diagram is constructed as a function of the surface tension and bending modulus of the surface of the aggregate. The problems related to the kinetics of coalescence of the aggregates are discussed. © Pleiades Publishing, Ltd. 2012 |
| abstract_unstemmed |
Abstract The problems of the aggregation behavior of amphiphilic macromolecules in solution are discussed. The cases of electrically neutral and polyelectrolyte chains are examined. The effect of chain parameters, interaction parameters, and external factors—temperature, solvent quality, medium pH, and solution ionic strength—on the structure and stability of the aggregates is analyzed. As examples, two systems are selected: (i) a solution of model oligopeptides with different chain architectures that contain hydrophobic alanine and negatively charged polar aspartic acid and (ii) a solution of HP copolymers in which hydrophobic (H) groups are located in the backbone and polar (P) side groups have a rigid bond to the backbone. The micelles formed by the oligopeptides are thermodynamically stabilized after the addition of a univalent salt; in addition, the effect heavily depends on the pH of a medium and the size of the added cations. For the second system, the regions of stability of aggregates of different geometries are determined and the corresponding phase diagram is constructed as a function of the surface tension and bending modulus of the surface of the aggregate. The problems related to the kinetics of coalescence of the aggregates are discussed. © Pleiades Publishing, Ltd. 2012 |
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Aggregation effects in solutions of model oligopeptides and other amphiphilic polymers |
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https://dx.doi.org/10.1134/S1811238212030010 |
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Semenov, A. N. |
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| doi_str |
10.1134/S1811238212030010 |
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2024-07-03T14:56:30.372Z |
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