Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [$ PtEnPyCl_{3} $]Cl. Molecular structure of [PtPy($ NH_{2} $-$ CH_{2} $-C≡N)$ Cl_{4} $] and [PtPy(NCl-($ CH_{2} $)2-$ NH_{2} $)$ Cl_{3} $] crystals
Abstract The reaction of chlorine with triamine [$ PtEnPyCl_{3} $]Cl in aqueous solution yields an insoluble powdered product, which is a mixture of compounds. Extraction with acetonitrile isolates a number of complexes: a glassy polymeric product (I), which contains a C=O group, an amino group, and...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Baranovskii, I. B. [verfasserIn] |
|---|
| Format: |
E-Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2008 |
|---|
| Schlagwörter: |
|---|
| Anmerkung: |
© Pleiades Publishing, Ltd. 2008 |
|---|
| Übergeordnetes Werk: |
Enthalten in: Russian journal of inorganic chemistry - Moscow : MAIK Nauka/Interperiodica Publ., 2006, 53(2008), 7 vom: Juli, Seite 1055-1060 |
|---|---|
| Übergeordnetes Werk: |
volume:53 ; year:2008 ; number:7 ; month:07 ; pages:1055-1060 |
| Links: |
|---|
| DOI / URN: |
10.1134/S0036023608070139 |
|---|
| Katalog-ID: |
SPR020285329 |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | SPR020285329 | ||
| 003 | DE-627 | ||
| 005 | 20230519072019.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 201006s2008 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1134/S0036023608070139 |2 doi | |
| 035 | |a (DE-627)SPR020285329 | ||
| 035 | |a (SPR)S0036023608070139-e | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 100 | 1 | |a Baranovskii, I. B. |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [$ PtEnPyCl_{3} $]Cl. Molecular structure of [PtPy($ NH_{2} $-$ CH_{2} $-C≡N)$ Cl_{4} $] and [PtPy(NCl-($ CH_{2} $)2-$ NH_{2} $)$ Cl_{3} $] crystals |
| 264 | 1 | |c 2008 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a © Pleiades Publishing, Ltd. 2008 | ||
| 520 | |a Abstract The reaction of chlorine with triamine [$ PtEnPyCl_{3} $]Cl in aqueous solution yields an insoluble powdered product, which is a mixture of compounds. Extraction with acetonitrile isolates a number of complexes: a glassy polymeric product (I), which contains a C=O group, an amino group, and pyridine; [PtPy($ NH_{2} %$ CH_{2} $CN)$ Cl_{4} $] (II) as the major product (ethylenediamine converts to aminoacetonitrile as a result of oxidative dehydrogenation); and the aminochloro complex [PtPy($ NClCH_{2} %$ CH_{2} %$ NH_{2} $)$ Cl_{3} $] (III) in a minor amount. The IR spectra of the products were studied. X-ray structure analysis was carried out for complexes II and III. Compound II: orthorhombic space group Pbcm, a = 10.925(2) Å, b = 11.413(2) Å, c = 9.979(2) Å, V = 1244.3(4) $ Å^{3} $, Z = 8, Rhk1 = 0.033. The aminoacetonitrile molecule is coordinated to the platinum atom via the amino nitrogen atom in the trans position to pyridine; C≡N 1.07(2) Å, angle C-C≡N 178(1)°. Compound III: space group P$ 2_{1} $/n, a = 7.3016(8) Å, b = 7.8879(9) Å, c = 22.336(2) Å, β = 96.107(2)°, V = 1279.1(2) $ Å^{3} $, Z = 4, Rhk1 = 0.0808, N-Cl = 1.77(2) Å. | ||
| 650 | 4 | |a Chlorine Atom |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Equatorial Plane |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Oxidative Dehydrogenation |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Trans Position |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Platinum Atom |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Surazhskaya, M. D. |4 aut | |
| 700 | 1 | |a Aleksandrov, G. G. |4 aut | |
| 700 | 1 | |a Golubnichaya, M. A. |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Russian journal of inorganic chemistry |d Moscow : MAIK Nauka/Interperiodica Publ., 2006 |g 53(2008), 7 vom: Juli, Seite 1055-1060 |w (DE-627)508334675 |w (DE-600)2223897-9 |x 1531-8613 |7 nnns |
| 773 | 1 | 8 | |g volume:53 |g year:2008 |g number:7 |g month:07 |g pages:1055-1060 |
| 856 | 4 | 0 | |u https://dx.doi.org/10.1134/S0036023608070139 |z lizenzpflichtig |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a SYSFLAG_A | ||
| 912 | |a GBV_SPRINGER | ||
| 912 | |a SSG-OLC-PHA | ||
| 912 | |a GBV_ILN_11 | ||
| 912 | |a GBV_ILN_20 | ||
| 912 | |a GBV_ILN_22 | ||
| 912 | |a GBV_ILN_23 | ||
| 912 | |a GBV_ILN_24 | ||
| 912 | |a GBV_ILN_31 | ||
| 912 | |a GBV_ILN_32 | ||
| 912 | |a GBV_ILN_39 | ||
| 912 | |a GBV_ILN_40 | ||
| 912 | |a GBV_ILN_60 | ||
| 912 | |a GBV_ILN_62 | ||
| 912 | |a GBV_ILN_63 | ||
| 912 | |a GBV_ILN_65 | ||
| 912 | |a GBV_ILN_69 | ||
| 912 | |a GBV_ILN_70 | ||
| 912 | |a GBV_ILN_73 | ||
| 912 | |a GBV_ILN_74 | ||
| 912 | |a GBV_ILN_90 | ||
| 912 | |a GBV_ILN_95 | ||
| 912 | |a GBV_ILN_100 | ||
| 912 | |a GBV_ILN_101 | ||
| 912 | |a GBV_ILN_105 | ||
| 912 | |a GBV_ILN_110 | ||
| 912 | |a GBV_ILN_120 | ||
| 912 | |a GBV_ILN_138 | ||
| 912 | |a GBV_ILN_150 | ||
| 912 | |a GBV_ILN_151 | ||
| 912 | |a GBV_ILN_152 | ||
| 912 | |a GBV_ILN_161 | ||
| 912 | |a GBV_ILN_170 | ||
| 912 | |a GBV_ILN_171 | ||
| 912 | |a GBV_ILN_187 | ||
| 912 | |a GBV_ILN_213 | ||
| 912 | |a GBV_ILN_224 | ||
| 912 | |a GBV_ILN_230 | ||
| 912 | |a GBV_ILN_250 | ||
| 912 | |a GBV_ILN_281 | ||
| 912 | |a GBV_ILN_285 | ||
| 912 | |a GBV_ILN_293 | ||
| 912 | |a GBV_ILN_370 | ||
| 912 | |a GBV_ILN_602 | ||
| 912 | |a GBV_ILN_636 | ||
| 912 | |a GBV_ILN_702 | ||
| 912 | |a GBV_ILN_2001 | ||
| 912 | |a GBV_ILN_2003 | ||
| 912 | |a GBV_ILN_2004 | ||
| 912 | |a GBV_ILN_2005 | ||
| 912 | |a GBV_ILN_2006 | ||
| 912 | |a GBV_ILN_2007 | ||
| 912 | |a GBV_ILN_2008 | ||
| 912 | |a GBV_ILN_2009 | ||
| 912 | |a GBV_ILN_2010 | ||
| 912 | |a GBV_ILN_2011 | ||
| 912 | |a GBV_ILN_2014 | ||
| 912 | |a GBV_ILN_2015 | ||
| 912 | |a GBV_ILN_2020 | ||
| 912 | |a GBV_ILN_2021 | ||
| 912 | |a GBV_ILN_2025 | ||
| 912 | |a GBV_ILN_2026 | ||
| 912 | |a GBV_ILN_2027 | ||
| 912 | |a GBV_ILN_2031 | ||
| 912 | |a GBV_ILN_2034 | ||
| 912 | |a GBV_ILN_2037 | ||
| 912 | |a GBV_ILN_2038 | ||
| 912 | |a GBV_ILN_2039 | ||
| 912 | |a GBV_ILN_2044 | ||
| 912 | |a GBV_ILN_2048 | ||
| 912 | |a GBV_ILN_2049 | ||
| 912 | |a GBV_ILN_2050 | ||
| 912 | |a GBV_ILN_2055 | ||
| 912 | |a GBV_ILN_2057 | ||
| 912 | |a GBV_ILN_2059 | ||
| 912 | |a GBV_ILN_2061 | ||
| 912 | |a GBV_ILN_2064 | ||
| 912 | |a GBV_ILN_2065 | ||
| 912 | |a GBV_ILN_2068 | ||
| 912 | |a GBV_ILN_2070 | ||
| 912 | |a GBV_ILN_2086 | ||
| 912 | |a GBV_ILN_2088 | ||
| 912 | |a GBV_ILN_2093 | ||
| 912 | |a GBV_ILN_2106 | ||
| 912 | |a GBV_ILN_2107 | ||
| 912 | |a GBV_ILN_2108 | ||
| 912 | |a GBV_ILN_2110 | ||
| 912 | |a GBV_ILN_2111 | ||
| 912 | |a GBV_ILN_2112 | ||
| 912 | |a GBV_ILN_2113 | ||
| 912 | |a GBV_ILN_2116 | ||
| 912 | |a GBV_ILN_2118 | ||
| 912 | |a GBV_ILN_2119 | ||
| 912 | |a GBV_ILN_2122 | ||
| 912 | |a GBV_ILN_2129 | ||
| 912 | |a GBV_ILN_2143 | ||
| 912 | |a GBV_ILN_2144 | ||
| 912 | |a GBV_ILN_2147 | ||
| 912 | |a GBV_ILN_2148 | ||
| 912 | |a GBV_ILN_2152 | ||
| 912 | |a GBV_ILN_2153 | ||
| 912 | |a GBV_ILN_2188 | ||
| 912 | |a GBV_ILN_2190 | ||
| 912 | |a GBV_ILN_2232 | ||
| 912 | |a GBV_ILN_2336 | ||
| 912 | |a GBV_ILN_2446 | ||
| 912 | |a GBV_ILN_2470 | ||
| 912 | |a GBV_ILN_2472 | ||
| 912 | |a GBV_ILN_2507 | ||
| 912 | |a GBV_ILN_2522 | ||
| 912 | |a GBV_ILN_2548 | ||
| 912 | |a GBV_ILN_4035 | ||
| 912 | |a GBV_ILN_4037 | ||
| 912 | |a GBV_ILN_4046 | ||
| 912 | |a GBV_ILN_4112 | ||
| 912 | |a GBV_ILN_4125 | ||
| 912 | |a GBV_ILN_4242 | ||
| 912 | |a GBV_ILN_4246 | ||
| 912 | |a GBV_ILN_4249 | ||
| 912 | |a GBV_ILN_4251 | ||
| 912 | |a GBV_ILN_4305 | ||
| 912 | |a GBV_ILN_4306 | ||
| 912 | |a GBV_ILN_4307 | ||
| 912 | |a GBV_ILN_4313 | ||
| 912 | |a GBV_ILN_4322 | ||
| 912 | |a GBV_ILN_4323 | ||
| 912 | |a GBV_ILN_4324 | ||
| 912 | |a GBV_ILN_4325 | ||
| 912 | |a GBV_ILN_4326 | ||
| 912 | |a GBV_ILN_4333 | ||
| 912 | |a GBV_ILN_4334 | ||
| 912 | |a GBV_ILN_4335 | ||
| 912 | |a GBV_ILN_4336 | ||
| 912 | |a GBV_ILN_4338 | ||
| 912 | |a GBV_ILN_4393 | ||
| 912 | |a GBV_ILN_4700 | ||
| 951 | |a AR | ||
| 952 | |d 53 |j 2008 |e 7 |c 07 |h 1055-1060 | ||
| author_variant |
i b b ib ibb m d s md mds g g a gg gga m a g ma mag |
|---|---|
| matchkey_str |
article:15318613:2008----::hoiexdtoocodntdtyeeimnitimnpaiuicmlxtnyl3loeuasrcueftyh2h |
| hierarchy_sort_str |
2008 |
| publishDate |
2008 |
| allfields |
10.1134/S0036023608070139 doi (DE-627)SPR020285329 (SPR)S0036023608070139-e DE-627 ger DE-627 rakwb eng Baranovskii, I. B. verfasserin aut Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [$ PtEnPyCl_{3} $]Cl. Molecular structure of [PtPy($ NH_{2} $-$ CH_{2} $-C≡N)$ Cl_{4} $] and [PtPy(NCl-($ CH_{2} $)2-$ NH_{2} $)$ Cl_{3} $] crystals 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2008 Abstract The reaction of chlorine with triamine [$ PtEnPyCl_{3} $]Cl in aqueous solution yields an insoluble powdered product, which is a mixture of compounds. Extraction with acetonitrile isolates a number of complexes: a glassy polymeric product (I), which contains a C=O group, an amino group, and pyridine; [PtPy($ NH_{2} %$ CH_{2} $CN)$ Cl_{4} $] (II) as the major product (ethylenediamine converts to aminoacetonitrile as a result of oxidative dehydrogenation); and the aminochloro complex [PtPy($ NClCH_{2} %$ CH_{2} %$ NH_{2} $)$ Cl_{3} $] (III) in a minor amount. The IR spectra of the products were studied. X-ray structure analysis was carried out for complexes II and III. Compound II: orthorhombic space group Pbcm, a = 10.925(2) Å, b = 11.413(2) Å, c = 9.979(2) Å, V = 1244.3(4) $ Å^{3} $, Z = 8, Rhk1 = 0.033. The aminoacetonitrile molecule is coordinated to the platinum atom via the amino nitrogen atom in the trans position to pyridine; C≡N 1.07(2) Å, angle C-C≡N 178(1)°. Compound III: space group P$ 2_{1} $/n, a = 7.3016(8) Å, b = 7.8879(9) Å, c = 22.336(2) Å, β = 96.107(2)°, V = 1279.1(2) $ Å^{3} $, Z = 4, Rhk1 = 0.0808, N-Cl = 1.77(2) Å. Chlorine Atom (dpeaa)DE-He213 Equatorial Plane (dpeaa)DE-He213 Oxidative Dehydrogenation (dpeaa)DE-He213 Trans Position (dpeaa)DE-He213 Platinum Atom (dpeaa)DE-He213 Surazhskaya, M. D. aut Aleksandrov, G. G. aut Golubnichaya, M. A. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 53(2008), 7 vom: Juli, Seite 1055-1060 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:53 year:2008 number:7 month:07 pages:1055-1060 https://dx.doi.org/10.1134/S0036023608070139 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 53 2008 7 07 1055-1060 |
| spelling |
10.1134/S0036023608070139 doi (DE-627)SPR020285329 (SPR)S0036023608070139-e DE-627 ger DE-627 rakwb eng Baranovskii, I. B. verfasserin aut Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [$ PtEnPyCl_{3} $]Cl. Molecular structure of [PtPy($ NH_{2} $-$ CH_{2} $-C≡N)$ Cl_{4} $] and [PtPy(NCl-($ CH_{2} $)2-$ NH_{2} $)$ Cl_{3} $] crystals 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2008 Abstract The reaction of chlorine with triamine [$ PtEnPyCl_{3} $]Cl in aqueous solution yields an insoluble powdered product, which is a mixture of compounds. Extraction with acetonitrile isolates a number of complexes: a glassy polymeric product (I), which contains a C=O group, an amino group, and pyridine; [PtPy($ NH_{2} %$ CH_{2} $CN)$ Cl_{4} $] (II) as the major product (ethylenediamine converts to aminoacetonitrile as a result of oxidative dehydrogenation); and the aminochloro complex [PtPy($ NClCH_{2} %$ CH_{2} %$ NH_{2} $)$ Cl_{3} $] (III) in a minor amount. The IR spectra of the products were studied. X-ray structure analysis was carried out for complexes II and III. Compound II: orthorhombic space group Pbcm, a = 10.925(2) Å, b = 11.413(2) Å, c = 9.979(2) Å, V = 1244.3(4) $ Å^{3} $, Z = 8, Rhk1 = 0.033. The aminoacetonitrile molecule is coordinated to the platinum atom via the amino nitrogen atom in the trans position to pyridine; C≡N 1.07(2) Å, angle C-C≡N 178(1)°. Compound III: space group P$ 2_{1} $/n, a = 7.3016(8) Å, b = 7.8879(9) Å, c = 22.336(2) Å, β = 96.107(2)°, V = 1279.1(2) $ Å^{3} $, Z = 4, Rhk1 = 0.0808, N-Cl = 1.77(2) Å. Chlorine Atom (dpeaa)DE-He213 Equatorial Plane (dpeaa)DE-He213 Oxidative Dehydrogenation (dpeaa)DE-He213 Trans Position (dpeaa)DE-He213 Platinum Atom (dpeaa)DE-He213 Surazhskaya, M. D. aut Aleksandrov, G. G. aut Golubnichaya, M. A. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 53(2008), 7 vom: Juli, Seite 1055-1060 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:53 year:2008 number:7 month:07 pages:1055-1060 https://dx.doi.org/10.1134/S0036023608070139 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 53 2008 7 07 1055-1060 |
| allfields_unstemmed |
10.1134/S0036023608070139 doi (DE-627)SPR020285329 (SPR)S0036023608070139-e DE-627 ger DE-627 rakwb eng Baranovskii, I. B. verfasserin aut Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [$ PtEnPyCl_{3} $]Cl. Molecular structure of [PtPy($ NH_{2} $-$ CH_{2} $-C≡N)$ Cl_{4} $] and [PtPy(NCl-($ CH_{2} $)2-$ NH_{2} $)$ Cl_{3} $] crystals 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2008 Abstract The reaction of chlorine with triamine [$ PtEnPyCl_{3} $]Cl in aqueous solution yields an insoluble powdered product, which is a mixture of compounds. Extraction with acetonitrile isolates a number of complexes: a glassy polymeric product (I), which contains a C=O group, an amino group, and pyridine; [PtPy($ NH_{2} %$ CH_{2} $CN)$ Cl_{4} $] (II) as the major product (ethylenediamine converts to aminoacetonitrile as a result of oxidative dehydrogenation); and the aminochloro complex [PtPy($ NClCH_{2} %$ CH_{2} %$ NH_{2} $)$ Cl_{3} $] (III) in a minor amount. The IR spectra of the products were studied. X-ray structure analysis was carried out for complexes II and III. Compound II: orthorhombic space group Pbcm, a = 10.925(2) Å, b = 11.413(2) Å, c = 9.979(2) Å, V = 1244.3(4) $ Å^{3} $, Z = 8, Rhk1 = 0.033. The aminoacetonitrile molecule is coordinated to the platinum atom via the amino nitrogen atom in the trans position to pyridine; C≡N 1.07(2) Å, angle C-C≡N 178(1)°. Compound III: space group P$ 2_{1} $/n, a = 7.3016(8) Å, b = 7.8879(9) Å, c = 22.336(2) Å, β = 96.107(2)°, V = 1279.1(2) $ Å^{3} $, Z = 4, Rhk1 = 0.0808, N-Cl = 1.77(2) Å. Chlorine Atom (dpeaa)DE-He213 Equatorial Plane (dpeaa)DE-He213 Oxidative Dehydrogenation (dpeaa)DE-He213 Trans Position (dpeaa)DE-He213 Platinum Atom (dpeaa)DE-He213 Surazhskaya, M. D. aut Aleksandrov, G. G. aut Golubnichaya, M. A. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 53(2008), 7 vom: Juli, Seite 1055-1060 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:53 year:2008 number:7 month:07 pages:1055-1060 https://dx.doi.org/10.1134/S0036023608070139 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 53 2008 7 07 1055-1060 |
| allfieldsGer |
10.1134/S0036023608070139 doi (DE-627)SPR020285329 (SPR)S0036023608070139-e DE-627 ger DE-627 rakwb eng Baranovskii, I. B. verfasserin aut Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [$ PtEnPyCl_{3} $]Cl. Molecular structure of [PtPy($ NH_{2} $-$ CH_{2} $-C≡N)$ Cl_{4} $] and [PtPy(NCl-($ CH_{2} $)2-$ NH_{2} $)$ Cl_{3} $] crystals 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2008 Abstract The reaction of chlorine with triamine [$ PtEnPyCl_{3} $]Cl in aqueous solution yields an insoluble powdered product, which is a mixture of compounds. Extraction with acetonitrile isolates a number of complexes: a glassy polymeric product (I), which contains a C=O group, an amino group, and pyridine; [PtPy($ NH_{2} %$ CH_{2} $CN)$ Cl_{4} $] (II) as the major product (ethylenediamine converts to aminoacetonitrile as a result of oxidative dehydrogenation); and the aminochloro complex [PtPy($ NClCH_{2} %$ CH_{2} %$ NH_{2} $)$ Cl_{3} $] (III) in a minor amount. The IR spectra of the products were studied. X-ray structure analysis was carried out for complexes II and III. Compound II: orthorhombic space group Pbcm, a = 10.925(2) Å, b = 11.413(2) Å, c = 9.979(2) Å, V = 1244.3(4) $ Å^{3} $, Z = 8, Rhk1 = 0.033. The aminoacetonitrile molecule is coordinated to the platinum atom via the amino nitrogen atom in the trans position to pyridine; C≡N 1.07(2) Å, angle C-C≡N 178(1)°. Compound III: space group P$ 2_{1} $/n, a = 7.3016(8) Å, b = 7.8879(9) Å, c = 22.336(2) Å, β = 96.107(2)°, V = 1279.1(2) $ Å^{3} $, Z = 4, Rhk1 = 0.0808, N-Cl = 1.77(2) Å. Chlorine Atom (dpeaa)DE-He213 Equatorial Plane (dpeaa)DE-He213 Oxidative Dehydrogenation (dpeaa)DE-He213 Trans Position (dpeaa)DE-He213 Platinum Atom (dpeaa)DE-He213 Surazhskaya, M. D. aut Aleksandrov, G. G. aut Golubnichaya, M. A. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 53(2008), 7 vom: Juli, Seite 1055-1060 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:53 year:2008 number:7 month:07 pages:1055-1060 https://dx.doi.org/10.1134/S0036023608070139 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 53 2008 7 07 1055-1060 |
| allfieldsSound |
10.1134/S0036023608070139 doi (DE-627)SPR020285329 (SPR)S0036023608070139-e DE-627 ger DE-627 rakwb eng Baranovskii, I. B. verfasserin aut Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [$ PtEnPyCl_{3} $]Cl. Molecular structure of [PtPy($ NH_{2} $-$ CH_{2} $-C≡N)$ Cl_{4} $] and [PtPy(NCl-($ CH_{2} $)2-$ NH_{2} $)$ Cl_{3} $] crystals 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2008 Abstract The reaction of chlorine with triamine [$ PtEnPyCl_{3} $]Cl in aqueous solution yields an insoluble powdered product, which is a mixture of compounds. Extraction with acetonitrile isolates a number of complexes: a glassy polymeric product (I), which contains a C=O group, an amino group, and pyridine; [PtPy($ NH_{2} %$ CH_{2} $CN)$ Cl_{4} $] (II) as the major product (ethylenediamine converts to aminoacetonitrile as a result of oxidative dehydrogenation); and the aminochloro complex [PtPy($ NClCH_{2} %$ CH_{2} %$ NH_{2} $)$ Cl_{3} $] (III) in a minor amount. The IR spectra of the products were studied. X-ray structure analysis was carried out for complexes II and III. Compound II: orthorhombic space group Pbcm, a = 10.925(2) Å, b = 11.413(2) Å, c = 9.979(2) Å, V = 1244.3(4) $ Å^{3} $, Z = 8, Rhk1 = 0.033. The aminoacetonitrile molecule is coordinated to the platinum atom via the amino nitrogen atom in the trans position to pyridine; C≡N 1.07(2) Å, angle C-C≡N 178(1)°. Compound III: space group P$ 2_{1} $/n, a = 7.3016(8) Å, b = 7.8879(9) Å, c = 22.336(2) Å, β = 96.107(2)°, V = 1279.1(2) $ Å^{3} $, Z = 4, Rhk1 = 0.0808, N-Cl = 1.77(2) Å. Chlorine Atom (dpeaa)DE-He213 Equatorial Plane (dpeaa)DE-He213 Oxidative Dehydrogenation (dpeaa)DE-He213 Trans Position (dpeaa)DE-He213 Platinum Atom (dpeaa)DE-He213 Surazhskaya, M. D. aut Aleksandrov, G. G. aut Golubnichaya, M. A. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 53(2008), 7 vom: Juli, Seite 1055-1060 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:53 year:2008 number:7 month:07 pages:1055-1060 https://dx.doi.org/10.1134/S0036023608070139 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 53 2008 7 07 1055-1060 |
| language |
English |
| source |
Enthalten in Russian journal of inorganic chemistry 53(2008), 7 vom: Juli, Seite 1055-1060 volume:53 year:2008 number:7 month:07 pages:1055-1060 |
| sourceStr |
Enthalten in Russian journal of inorganic chemistry 53(2008), 7 vom: Juli, Seite 1055-1060 volume:53 year:2008 number:7 month:07 pages:1055-1060 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| topic_facet |
Chlorine Atom Equatorial Plane Oxidative Dehydrogenation Trans Position Platinum Atom |
| isfreeaccess_bool |
false |
| container_title |
Russian journal of inorganic chemistry |
| authorswithroles_txt_mv |
Baranovskii, I. B. @@aut@@ Surazhskaya, M. D. @@aut@@ Aleksandrov, G. G. @@aut@@ Golubnichaya, M. A. @@aut@@ |
| publishDateDaySort_date |
2008-07-01T00:00:00Z |
| hierarchy_top_id |
508334675 |
| id |
SPR020285329 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR020285329</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519072019.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2008 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1134/S0036023608070139</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR020285329</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)S0036023608070139-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Baranovskii, I. B.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [$ PtEnPyCl_{3} $]Cl. Molecular structure of [PtPy($ NH_{2} $-$ CH_{2} $-C≡N)$ Cl_{4} $] and [PtPy(NCl-($ CH_{2} $)2-$ NH_{2} $)$ Cl_{3} $] crystals</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2008</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Pleiades Publishing, Ltd. 2008</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The reaction of chlorine with triamine [$ PtEnPyCl_{3} $]Cl in aqueous solution yields an insoluble powdered product, which is a mixture of compounds. Extraction with acetonitrile isolates a number of complexes: a glassy polymeric product (I), which contains a C=O group, an amino group, and pyridine; [PtPy($ NH_{2} %$ CH_{2} $CN)$ Cl_{4} $] (II) as the major product (ethylenediamine converts to aminoacetonitrile as a result of oxidative dehydrogenation); and the aminochloro complex [PtPy($ NClCH_{2} %$ CH_{2} %$ NH_{2} $)$ Cl_{3} $] (III) in a minor amount. The IR spectra of the products were studied. X-ray structure analysis was carried out for complexes II and III. Compound II: orthorhombic space group Pbcm, a = 10.925(2) Å, b = 11.413(2) Å, c = 9.979(2) Å, V = 1244.3(4) $ Å^{3} $, Z = 8, Rhk1 = 0.033. The aminoacetonitrile molecule is coordinated to the platinum atom via the amino nitrogen atom in the trans position to pyridine; C≡N 1.07(2) Å, angle C-C≡N 178(1)°. Compound III: space group P$ 2_{1} $/n, a = 7.3016(8) Å, b = 7.8879(9) Å, c = 22.336(2) Å, β = 96.107(2)°, V = 1279.1(2) $ Å^{3} $, Z = 4, Rhk1 = 0.0808, N-Cl = 1.77(2) Å.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Chlorine Atom</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Equatorial Plane</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Oxidative Dehydrogenation</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Trans Position</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Platinum Atom</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Surazhskaya, M. D.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Aleksandrov, G. G.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Golubnichaya, M. A.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Russian journal of inorganic chemistry</subfield><subfield code="d">Moscow : MAIK Nauka/Interperiodica Publ., 2006</subfield><subfield code="g">53(2008), 7 vom: Juli, Seite 1055-1060</subfield><subfield code="w">(DE-627)508334675</subfield><subfield code="w">(DE-600)2223897-9</subfield><subfield code="x">1531-8613</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:53</subfield><subfield code="g">year:2008</subfield><subfield code="g">number:7</subfield><subfield code="g">month:07</subfield><subfield code="g">pages:1055-1060</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1134/S0036023608070139</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_11</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_101</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_120</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_138</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_171</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_250</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_281</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_636</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2031</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2039</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2057</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2070</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2086</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2093</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2107</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2108</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2116</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2119</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2144</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2188</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2446</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2472</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2548</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4246</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">53</subfield><subfield code="j">2008</subfield><subfield code="e">7</subfield><subfield code="c">07</subfield><subfield code="h">1055-1060</subfield></datafield></record></collection>
|
| author |
Baranovskii, I. B. |
| spellingShingle |
Baranovskii, I. B. misc Chlorine Atom misc Equatorial Plane misc Oxidative Dehydrogenation misc Trans Position misc Platinum Atom Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [$ PtEnPyCl_{3} $]Cl. Molecular structure of [PtPy($ NH_{2} $-$ CH_{2} $-C≡N)$ Cl_{4} $] and [PtPy(NCl-($ CH_{2} $)2-$ NH_{2} $)$ Cl_{3} $] crystals |
| authorStr |
Baranovskii, I. B. |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)508334675 |
| format |
electronic Article |
| delete_txt_mv |
keep |
| author_role |
aut aut aut aut |
| collection |
springer |
| remote_str |
true |
| illustrated |
Not Illustrated |
| issn |
1531-8613 |
| topic_title |
Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [$ PtEnPyCl_{3} $]Cl. Molecular structure of [PtPy($ NH_{2} $-$ CH_{2} $-C≡N)$ Cl_{4} $] and [PtPy(NCl-($ CH_{2} $)2-$ NH_{2} $)$ Cl_{3} $] crystals Chlorine Atom (dpeaa)DE-He213 Equatorial Plane (dpeaa)DE-He213 Oxidative Dehydrogenation (dpeaa)DE-He213 Trans Position (dpeaa)DE-He213 Platinum Atom (dpeaa)DE-He213 |
| topic |
misc Chlorine Atom misc Equatorial Plane misc Oxidative Dehydrogenation misc Trans Position misc Platinum Atom |
| topic_unstemmed |
misc Chlorine Atom misc Equatorial Plane misc Oxidative Dehydrogenation misc Trans Position misc Platinum Atom |
| topic_browse |
misc Chlorine Atom misc Equatorial Plane misc Oxidative Dehydrogenation misc Trans Position misc Platinum Atom |
| format_facet |
Elektronische Aufsätze Aufsätze Elektronische Ressource |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
cr |
| hierarchy_parent_title |
Russian journal of inorganic chemistry |
| hierarchy_parent_id |
508334675 |
| hierarchy_top_title |
Russian journal of inorganic chemistry |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)508334675 (DE-600)2223897-9 |
| title |
Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [$ PtEnPyCl_{3} $]Cl. Molecular structure of [PtPy($ NH_{2} $-$ CH_{2} $-C≡N)$ Cl_{4} $] and [PtPy(NCl-($ CH_{2} $)2-$ NH_{2} $)$ Cl_{3} $] crystals |
| ctrlnum |
(DE-627)SPR020285329 (SPR)S0036023608070139-e |
| title_full |
Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [$ PtEnPyCl_{3} $]Cl. Molecular structure of [PtPy($ NH_{2} $-$ CH_{2} $-C≡N)$ Cl_{4} $] and [PtPy(NCl-($ CH_{2} $)2-$ NH_{2} $)$ Cl_{3} $] crystals |
| author_sort |
Baranovskii, I. B. |
| journal |
Russian journal of inorganic chemistry |
| journalStr |
Russian journal of inorganic chemistry |
| lang_code |
eng |
| isOA_bool |
false |
| recordtype |
marc |
| publishDateSort |
2008 |
| contenttype_str_mv |
txt |
| container_start_page |
1055 |
| author_browse |
Baranovskii, I. B. Surazhskaya, M. D. Aleksandrov, G. G. Golubnichaya, M. A. |
| container_volume |
53 |
| format_se |
Elektronische Aufsätze |
| author-letter |
Baranovskii, I. B. |
| doi_str_mv |
10.1134/S0036023608070139 |
| title_sort |
chlorine oxidation of coordinated ethylenediamine in triamineplatinum(iv) complex [$ ptenpycl_{3} $]cl. molecular structure of [ptpy($ nh_{2} $-$ ch_{2} $-c≡n)$ cl_{4} $] and [ptpy(ncl-($ ch_{2} $)2-$ nh_{2} $)$ cl_{3} $] crystals |
| title_auth |
Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [$ PtEnPyCl_{3} $]Cl. Molecular structure of [PtPy($ NH_{2} $-$ CH_{2} $-C≡N)$ Cl_{4} $] and [PtPy(NCl-($ CH_{2} $)2-$ NH_{2} $)$ Cl_{3} $] crystals |
| abstract |
Abstract The reaction of chlorine with triamine [$ PtEnPyCl_{3} $]Cl in aqueous solution yields an insoluble powdered product, which is a mixture of compounds. Extraction with acetonitrile isolates a number of complexes: a glassy polymeric product (I), which contains a C=O group, an amino group, and pyridine; [PtPy($ NH_{2} %$ CH_{2} $CN)$ Cl_{4} $] (II) as the major product (ethylenediamine converts to aminoacetonitrile as a result of oxidative dehydrogenation); and the aminochloro complex [PtPy($ NClCH_{2} %$ CH_{2} %$ NH_{2} $)$ Cl_{3} $] (III) in a minor amount. The IR spectra of the products were studied. X-ray structure analysis was carried out for complexes II and III. Compound II: orthorhombic space group Pbcm, a = 10.925(2) Å, b = 11.413(2) Å, c = 9.979(2) Å, V = 1244.3(4) $ Å^{3} $, Z = 8, Rhk1 = 0.033. The aminoacetonitrile molecule is coordinated to the platinum atom via the amino nitrogen atom in the trans position to pyridine; C≡N 1.07(2) Å, angle C-C≡N 178(1)°. Compound III: space group P$ 2_{1} $/n, a = 7.3016(8) Å, b = 7.8879(9) Å, c = 22.336(2) Å, β = 96.107(2)°, V = 1279.1(2) $ Å^{3} $, Z = 4, Rhk1 = 0.0808, N-Cl = 1.77(2) Å. © Pleiades Publishing, Ltd. 2008 |
| abstractGer |
Abstract The reaction of chlorine with triamine [$ PtEnPyCl_{3} $]Cl in aqueous solution yields an insoluble powdered product, which is a mixture of compounds. Extraction with acetonitrile isolates a number of complexes: a glassy polymeric product (I), which contains a C=O group, an amino group, and pyridine; [PtPy($ NH_{2} %$ CH_{2} $CN)$ Cl_{4} $] (II) as the major product (ethylenediamine converts to aminoacetonitrile as a result of oxidative dehydrogenation); and the aminochloro complex [PtPy($ NClCH_{2} %$ CH_{2} %$ NH_{2} $)$ Cl_{3} $] (III) in a minor amount. The IR spectra of the products were studied. X-ray structure analysis was carried out for complexes II and III. Compound II: orthorhombic space group Pbcm, a = 10.925(2) Å, b = 11.413(2) Å, c = 9.979(2) Å, V = 1244.3(4) $ Å^{3} $, Z = 8, Rhk1 = 0.033. The aminoacetonitrile molecule is coordinated to the platinum atom via the amino nitrogen atom in the trans position to pyridine; C≡N 1.07(2) Å, angle C-C≡N 178(1)°. Compound III: space group P$ 2_{1} $/n, a = 7.3016(8) Å, b = 7.8879(9) Å, c = 22.336(2) Å, β = 96.107(2)°, V = 1279.1(2) $ Å^{3} $, Z = 4, Rhk1 = 0.0808, N-Cl = 1.77(2) Å. © Pleiades Publishing, Ltd. 2008 |
| abstract_unstemmed |
Abstract The reaction of chlorine with triamine [$ PtEnPyCl_{3} $]Cl in aqueous solution yields an insoluble powdered product, which is a mixture of compounds. Extraction with acetonitrile isolates a number of complexes: a glassy polymeric product (I), which contains a C=O group, an amino group, and pyridine; [PtPy($ NH_{2} %$ CH_{2} $CN)$ Cl_{4} $] (II) as the major product (ethylenediamine converts to aminoacetonitrile as a result of oxidative dehydrogenation); and the aminochloro complex [PtPy($ NClCH_{2} %$ CH_{2} %$ NH_{2} $)$ Cl_{3} $] (III) in a minor amount. The IR spectra of the products were studied. X-ray structure analysis was carried out for complexes II and III. Compound II: orthorhombic space group Pbcm, a = 10.925(2) Å, b = 11.413(2) Å, c = 9.979(2) Å, V = 1244.3(4) $ Å^{3} $, Z = 8, Rhk1 = 0.033. The aminoacetonitrile molecule is coordinated to the platinum atom via the amino nitrogen atom in the trans position to pyridine; C≡N 1.07(2) Å, angle C-C≡N 178(1)°. Compound III: space group P$ 2_{1} $/n, a = 7.3016(8) Å, b = 7.8879(9) Å, c = 22.336(2) Å, β = 96.107(2)°, V = 1279.1(2) $ Å^{3} $, Z = 4, Rhk1 = 0.0808, N-Cl = 1.77(2) Å. © Pleiades Publishing, Ltd. 2008 |
| collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 |
| container_issue |
7 |
| title_short |
Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [$ PtEnPyCl_{3} $]Cl. Molecular structure of [PtPy($ NH_{2} $-$ CH_{2} $-C≡N)$ Cl_{4} $] and [PtPy(NCl-($ CH_{2} $)2-$ NH_{2} $)$ Cl_{3} $] crystals |
| url |
https://dx.doi.org/10.1134/S0036023608070139 |
| remote_bool |
true |
| author2 |
Surazhskaya, M. D. Aleksandrov, G. G. Golubnichaya, M. A. |
| author2Str |
Surazhskaya, M. D. Aleksandrov, G. G. Golubnichaya, M. A. |
| ppnlink |
508334675 |
| mediatype_str_mv |
c |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| doi_str |
10.1134/S0036023608070139 |
| up_date |
2024-07-03T15:04:43.823Z |
| _version_ |
1803570730848223232 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR020285329</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519072019.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2008 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1134/S0036023608070139</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR020285329</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)S0036023608070139-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Baranovskii, I. B.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [$ PtEnPyCl_{3} $]Cl. Molecular structure of [PtPy($ NH_{2} $-$ CH_{2} $-C≡N)$ Cl_{4} $] and [PtPy(NCl-($ CH_{2} $)2-$ NH_{2} $)$ Cl_{3} $] crystals</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2008</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Pleiades Publishing, Ltd. 2008</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The reaction of chlorine with triamine [$ PtEnPyCl_{3} $]Cl in aqueous solution yields an insoluble powdered product, which is a mixture of compounds. Extraction with acetonitrile isolates a number of complexes: a glassy polymeric product (I), which contains a C=O group, an amino group, and pyridine; [PtPy($ NH_{2} %$ CH_{2} $CN)$ Cl_{4} $] (II) as the major product (ethylenediamine converts to aminoacetonitrile as a result of oxidative dehydrogenation); and the aminochloro complex [PtPy($ NClCH_{2} %$ CH_{2} %$ NH_{2} $)$ Cl_{3} $] (III) in a minor amount. The IR spectra of the products were studied. X-ray structure analysis was carried out for complexes II and III. Compound II: orthorhombic space group Pbcm, a = 10.925(2) Å, b = 11.413(2) Å, c = 9.979(2) Å, V = 1244.3(4) $ Å^{3} $, Z = 8, Rhk1 = 0.033. The aminoacetonitrile molecule is coordinated to the platinum atom via the amino nitrogen atom in the trans position to pyridine; C≡N 1.07(2) Å, angle C-C≡N 178(1)°. Compound III: space group P$ 2_{1} $/n, a = 7.3016(8) Å, b = 7.8879(9) Å, c = 22.336(2) Å, β = 96.107(2)°, V = 1279.1(2) $ Å^{3} $, Z = 4, Rhk1 = 0.0808, N-Cl = 1.77(2) Å.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Chlorine Atom</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Equatorial Plane</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Oxidative Dehydrogenation</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Trans Position</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Platinum Atom</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Surazhskaya, M. D.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Aleksandrov, G. G.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Golubnichaya, M. A.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Russian journal of inorganic chemistry</subfield><subfield code="d">Moscow : MAIK Nauka/Interperiodica Publ., 2006</subfield><subfield code="g">53(2008), 7 vom: Juli, Seite 1055-1060</subfield><subfield code="w">(DE-627)508334675</subfield><subfield code="w">(DE-600)2223897-9</subfield><subfield code="x">1531-8613</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:53</subfield><subfield code="g">year:2008</subfield><subfield code="g">number:7</subfield><subfield code="g">month:07</subfield><subfield code="g">pages:1055-1060</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1134/S0036023608070139</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_11</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_101</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_120</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_138</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_171</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_250</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_281</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_636</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2031</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2039</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2057</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2070</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2086</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2093</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2107</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2108</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2116</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2119</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2144</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2188</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2446</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2472</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2548</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4246</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">53</subfield><subfield code="j">2008</subfield><subfield code="e">7</subfield><subfield code="c">07</subfield><subfield code="h">1055-1060</subfield></datafield></record></collection>
|
| score |
7.399004 |