Hydrolytic precipitation of magnesium polyvanadates in vanadium (IV, V) solutions

Abstract The phase and chemical composition of precipitates formed in Mg($ VO_{3} $)2-VOSO4-$ H_{2} $O system at initial pH from 1 to 7 and temperature from 80 to 90°C was studied. Polyvanadates of variable composition $ Mg_{x} $Vy4+V12-y5+1$ O_{31–δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 1.3, 1.2 ≤ y ≤ 2.4, 0...
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Autor*in:	Podval’naya, N. V. [verfasserIn] Volkov, V. L.

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2010

Schlagwörter:	Vanadium Vanadium Oxide Vanadium Pentoxide Second Order Reaction Vanadium Compound

Anmerkung:	© Pleiades Publishing, Ltd. 2010

Übergeordnetes Werk:	Enthalten in: Russian journal of inorganic chemistry - Moscow : MAIK Nauka/Interperiodica Publ., 2006, 55(2010), 2 vom: Feb., Seite 305-311
Übergeordnetes Werk:	volume:55 ; year:2010 ; number:2 ; month:02 ; pages:305-311

Links:	Volltext

DOI / URN:	10.1134/S0036023610020270

Katalog-ID:	SPR020291256

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100	1		\|a Podval’naya, N. V. \|e verfasserin \|4 aut
245	1	0	\|a Hydrolytic precipitation of magnesium polyvanadates in vanadium (IV, V) solutions
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520			\|a Abstract The phase and chemical composition of precipitates formed in Mg($ VO_{3} $)2-VOSO4-$ H_{2} $O system at initial pH from 1 to 7 and temperature from 80 to 90°C was studied. Polyvanadates of variable composition $ Mg_{x} $Vy4+V12-y5+1$ O_{31–δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 1.3, 1.2 ≤ y ≤ 2.4, 0.7 ≤ δ = 1.4) were formed at pH from 1 to 4 and $ V^{4+} $/$ V^{5+} $ ratio from 0.43 to 9. Compounds with the general formula $ Mg_{x} $Vy4+V6-y5+$ O_{16-δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 0.65, y = 1.0, 0.8 ≤ δ ≤ 0.85) were formed at pH from 6.0 to 7.0 and $ V^{4+} $/$ V^{5+} $ ratios from 0.11 to 0.25. The maximum $ V^{4+} $ concentration (y = 2.4) in the precipitates was achieved at the $ VV^{4+} $/$ V^{5+} $ solution ratio of 1.0 and pH = 3. The precipitates in solutions with pH 3 were formed only upon addition of $ VO^{2+} $ ions with the maximum rate at a $ V^{4+} $/$ V^{5+} $ ratio of 0.33. These processes were limited by second-order reactions on the surface of polyvanadates.
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700	1		\|a Volkov, V. L. \|4 aut
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912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2116
912			\|a GBV_ILN_2118
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912			\|a GBV_ILN_4046
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4246
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4251
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912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4336
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951			\|a AR
952			\|d 55 \|j 2010 \|e 2 \|c 02 \|h 305-311

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matchkey_str	article:15318613:2010----::yrltcrcpttoomgeimoyaaaeiv
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publishDate	2010
allfields	10.1134/S0036023610020270 doi (DE-627)SPR020291256 (SPR)S0036023610020270-e DE-627 ger DE-627 rakwb eng Podval’naya, N. V. verfasserin aut Hydrolytic precipitation of magnesium polyvanadates in vanadium (IV, V) solutions 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2010 Abstract The phase and chemical composition of precipitates formed in Mg($ VO_{3} $)2-VOSO4-$ H_{2} $O system at initial pH from 1 to 7 and temperature from 80 to 90°C was studied. Polyvanadates of variable composition $ Mg_{x} $Vy4+V12-y5+1$ O_{31–δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 1.3, 1.2 ≤ y ≤ 2.4, 0.7 ≤ δ = 1.4) were formed at pH from 1 to 4 and $ V^{4+} $/$ V^{5+} $ ratio from 0.43 to 9. Compounds with the general formula $ Mg_{x} $Vy4+V6-y5+$ O_{16-δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 0.65, y = 1.0, 0.8 ≤ δ ≤ 0.85) were formed at pH from 6.0 to 7.0 and $ V^{4+} $/$ V^{5+} $ ratios from 0.11 to 0.25. The maximum $ V^{4+} $ concentration (y = 2.4) in the precipitates was achieved at the $ VV^{4+} $/$ V^{5+} $ solution ratio of 1.0 and pH = 3. The precipitates in solutions with pH 3 were formed only upon addition of $ VO^{2+} $ ions with the maximum rate at a $ V^{4+} $/$ V^{5+} $ ratio of 0.33. These processes were limited by second-order reactions on the surface of polyvanadates. Vanadium (dpeaa)DE-He213 Vanadium Oxide (dpeaa)DE-He213 Vanadium Pentoxide (dpeaa)DE-He213 Second Order Reaction (dpeaa)DE-He213 Vanadium Compound (dpeaa)DE-He213 Volkov, V. L. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 55(2010), 2 vom: Feb., Seite 305-311 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:55 year:2010 number:2 month:02 pages:305-311 https://dx.doi.org/10.1134/S0036023610020270 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 55 2010 2 02 305-311
spelling	10.1134/S0036023610020270 doi (DE-627)SPR020291256 (SPR)S0036023610020270-e DE-627 ger DE-627 rakwb eng Podval’naya, N. V. verfasserin aut Hydrolytic precipitation of magnesium polyvanadates in vanadium (IV, V) solutions 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2010 Abstract The phase and chemical composition of precipitates formed in Mg($ VO_{3} $)2-VOSO4-$ H_{2} $O system at initial pH from 1 to 7 and temperature from 80 to 90°C was studied. Polyvanadates of variable composition $ Mg_{x} $Vy4+V12-y5+1$ O_{31–δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 1.3, 1.2 ≤ y ≤ 2.4, 0.7 ≤ δ = 1.4) were formed at pH from 1 to 4 and $ V^{4+} $/$ V^{5+} $ ratio from 0.43 to 9. Compounds with the general formula $ Mg_{x} $Vy4+V6-y5+$ O_{16-δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 0.65, y = 1.0, 0.8 ≤ δ ≤ 0.85) were formed at pH from 6.0 to 7.0 and $ V^{4+} $/$ V^{5+} $ ratios from 0.11 to 0.25. The maximum $ V^{4+} $ concentration (y = 2.4) in the precipitates was achieved at the $ VV^{4+} $/$ V^{5+} $ solution ratio of 1.0 and pH = 3. The precipitates in solutions with pH 3 were formed only upon addition of $ VO^{2+} $ ions with the maximum rate at a $ V^{4+} $/$ V^{5+} $ ratio of 0.33. These processes were limited by second-order reactions on the surface of polyvanadates. Vanadium (dpeaa)DE-He213 Vanadium Oxide (dpeaa)DE-He213 Vanadium Pentoxide (dpeaa)DE-He213 Second Order Reaction (dpeaa)DE-He213 Vanadium Compound (dpeaa)DE-He213 Volkov, V. L. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 55(2010), 2 vom: Feb., Seite 305-311 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:55 year:2010 number:2 month:02 pages:305-311 https://dx.doi.org/10.1134/S0036023610020270 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 55 2010 2 02 305-311
allfields_unstemmed	10.1134/S0036023610020270 doi (DE-627)SPR020291256 (SPR)S0036023610020270-e DE-627 ger DE-627 rakwb eng Podval’naya, N. V. verfasserin aut Hydrolytic precipitation of magnesium polyvanadates in vanadium (IV, V) solutions 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2010 Abstract The phase and chemical composition of precipitates formed in Mg($ VO_{3} $)2-VOSO4-$ H_{2} $O system at initial pH from 1 to 7 and temperature from 80 to 90°C was studied. Polyvanadates of variable composition $ Mg_{x} $Vy4+V12-y5+1$ O_{31–δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 1.3, 1.2 ≤ y ≤ 2.4, 0.7 ≤ δ = 1.4) were formed at pH from 1 to 4 and $ V^{4+} $/$ V^{5+} $ ratio from 0.43 to 9. Compounds with the general formula $ Mg_{x} $Vy4+V6-y5+$ O_{16-δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 0.65, y = 1.0, 0.8 ≤ δ ≤ 0.85) were formed at pH from 6.0 to 7.0 and $ V^{4+} $/$ V^{5+} $ ratios from 0.11 to 0.25. The maximum $ V^{4+} $ concentration (y = 2.4) in the precipitates was achieved at the $ VV^{4+} $/$ V^{5+} $ solution ratio of 1.0 and pH = 3. The precipitates in solutions with pH 3 were formed only upon addition of $ VO^{2+} $ ions with the maximum rate at a $ V^{4+} $/$ V^{5+} $ ratio of 0.33. These processes were limited by second-order reactions on the surface of polyvanadates. Vanadium (dpeaa)DE-He213 Vanadium Oxide (dpeaa)DE-He213 Vanadium Pentoxide (dpeaa)DE-He213 Second Order Reaction (dpeaa)DE-He213 Vanadium Compound (dpeaa)DE-He213 Volkov, V. L. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 55(2010), 2 vom: Feb., Seite 305-311 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:55 year:2010 number:2 month:02 pages:305-311 https://dx.doi.org/10.1134/S0036023610020270 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 55 2010 2 02 305-311
allfieldsGer	10.1134/S0036023610020270 doi (DE-627)SPR020291256 (SPR)S0036023610020270-e DE-627 ger DE-627 rakwb eng Podval’naya, N. V. verfasserin aut Hydrolytic precipitation of magnesium polyvanadates in vanadium (IV, V) solutions 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2010 Abstract The phase and chemical composition of precipitates formed in Mg($ VO_{3} $)2-VOSO4-$ H_{2} $O system at initial pH from 1 to 7 and temperature from 80 to 90°C was studied. Polyvanadates of variable composition $ Mg_{x} $Vy4+V12-y5+1$ O_{31–δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 1.3, 1.2 ≤ y ≤ 2.4, 0.7 ≤ δ = 1.4) were formed at pH from 1 to 4 and $ V^{4+} $/$ V^{5+} $ ratio from 0.43 to 9. Compounds with the general formula $ Mg_{x} $Vy4+V6-y5+$ O_{16-δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 0.65, y = 1.0, 0.8 ≤ δ ≤ 0.85) were formed at pH from 6.0 to 7.0 and $ V^{4+} $/$ V^{5+} $ ratios from 0.11 to 0.25. The maximum $ V^{4+} $ concentration (y = 2.4) in the precipitates was achieved at the $ VV^{4+} $/$ V^{5+} $ solution ratio of 1.0 and pH = 3. The precipitates in solutions with pH 3 were formed only upon addition of $ VO^{2+} $ ions with the maximum rate at a $ V^{4+} $/$ V^{5+} $ ratio of 0.33. These processes were limited by second-order reactions on the surface of polyvanadates. Vanadium (dpeaa)DE-He213 Vanadium Oxide (dpeaa)DE-He213 Vanadium Pentoxide (dpeaa)DE-He213 Second Order Reaction (dpeaa)DE-He213 Vanadium Compound (dpeaa)DE-He213 Volkov, V. L. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 55(2010), 2 vom: Feb., Seite 305-311 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:55 year:2010 number:2 month:02 pages:305-311 https://dx.doi.org/10.1134/S0036023610020270 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 55 2010 2 02 305-311
allfieldsSound	10.1134/S0036023610020270 doi (DE-627)SPR020291256 (SPR)S0036023610020270-e DE-627 ger DE-627 rakwb eng Podval’naya, N. V. verfasserin aut Hydrolytic precipitation of magnesium polyvanadates in vanadium (IV, V) solutions 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2010 Abstract The phase and chemical composition of precipitates formed in Mg($ VO_{3} $)2-VOSO4-$ H_{2} $O system at initial pH from 1 to 7 and temperature from 80 to 90°C was studied. Polyvanadates of variable composition $ Mg_{x} $Vy4+V12-y5+1$ O_{31–δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 1.3, 1.2 ≤ y ≤ 2.4, 0.7 ≤ δ = 1.4) were formed at pH from 1 to 4 and $ V^{4+} $/$ V^{5+} $ ratio from 0.43 to 9. Compounds with the general formula $ Mg_{x} $Vy4+V6-y5+$ O_{16-δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 0.65, y = 1.0, 0.8 ≤ δ ≤ 0.85) were formed at pH from 6.0 to 7.0 and $ V^{4+} $/$ V^{5+} $ ratios from 0.11 to 0.25. The maximum $ V^{4+} $ concentration (y = 2.4) in the precipitates was achieved at the $ VV^{4+} $/$ V^{5+} $ solution ratio of 1.0 and pH = 3. The precipitates in solutions with pH 3 were formed only upon addition of $ VO^{2+} $ ions with the maximum rate at a $ V^{4+} $/$ V^{5+} $ ratio of 0.33. These processes were limited by second-order reactions on the surface of polyvanadates. Vanadium (dpeaa)DE-He213 Vanadium Oxide (dpeaa)DE-He213 Vanadium Pentoxide (dpeaa)DE-He213 Second Order Reaction (dpeaa)DE-He213 Vanadium Compound (dpeaa)DE-He213 Volkov, V. L. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 55(2010), 2 vom: Feb., Seite 305-311 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:55 year:2010 number:2 month:02 pages:305-311 https://dx.doi.org/10.1134/S0036023610020270 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 55 2010 2 02 305-311
language	English
source	Enthalten in Russian journal of inorganic chemistry 55(2010), 2 vom: Feb., Seite 305-311 volume:55 year:2010 number:2 month:02 pages:305-311
sourceStr	Enthalten in Russian journal of inorganic chemistry 55(2010), 2 vom: Feb., Seite 305-311 volume:55 year:2010 number:2 month:02 pages:305-311
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Vanadium Vanadium Oxide Vanadium Pentoxide Second Order Reaction Vanadium Compound
isfreeaccess_bool	false
container_title	Russian journal of inorganic chemistry
authorswithroles_txt_mv	Podval’naya, N. V. @@aut@@ Volkov, V. L. @@aut@@
publishDateDaySort_date	2010-02-01T00:00:00Z
hierarchy_top_id	508334675
id	SPR020291256
language_de	englisch
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Polyvanadates of variable composition $ Mg_{x} $Vy4+V12-y5+1$ O_{31–δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 1.3, 1.2 ≤ y ≤ 2.4, 0.7 ≤ δ = 1.4) were formed at pH from 1 to 4 and $ V^{4+} $/$ V^{5+} $ ratio from 0.43 to 9. Compounds with the general formula $ Mg_{x} $Vy4+V6-y5+$ O_{16-δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 0.65, y = 1.0, 0.8 ≤ δ ≤ 0.85) were formed at pH from 6.0 to 7.0 and $ V^{4+} $/$ V^{5+} $ ratios from 0.11 to 0.25. The maximum $ V^{4+} $ concentration (y = 2.4) in the precipitates was achieved at the $ VV^{4+} $/$ V^{5+} $ solution ratio of 1.0 and pH = 3. The precipitates in solutions with pH 3 were formed only upon addition of $ VO^{2+} $ ions with the maximum rate at a $ V^{4+} $/$ V^{5+} $ ratio of 0.33. 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author	Podval’naya, N. V.
spellingShingle	Podval’naya, N. V. misc Vanadium misc Vanadium Oxide misc Vanadium Pentoxide misc Second Order Reaction misc Vanadium Compound Hydrolytic precipitation of magnesium polyvanadates in vanadium (IV, V) solutions
authorStr	Podval’naya, N. V.
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topic_title	Hydrolytic precipitation of magnesium polyvanadates in vanadium (IV, V) solutions Vanadium (dpeaa)DE-He213 Vanadium Oxide (dpeaa)DE-He213 Vanadium Pentoxide (dpeaa)DE-He213 Second Order Reaction (dpeaa)DE-He213 Vanadium Compound (dpeaa)DE-He213
topic	misc Vanadium misc Vanadium Oxide misc Vanadium Pentoxide misc Second Order Reaction misc Vanadium Compound
topic_unstemmed	misc Vanadium misc Vanadium Oxide misc Vanadium Pentoxide misc Second Order Reaction misc Vanadium Compound
topic_browse	misc Vanadium misc Vanadium Oxide misc Vanadium Pentoxide misc Second Order Reaction misc Vanadium Compound
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hierarchy_parent_title	Russian journal of inorganic chemistry
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title	Hydrolytic precipitation of magnesium polyvanadates in vanadium (IV, V) solutions
ctrlnum	(DE-627)SPR020291256 (SPR)S0036023610020270-e
title_full	Hydrolytic precipitation of magnesium polyvanadates in vanadium (IV, V) solutions
author_sort	Podval’naya, N. V.
journal	Russian journal of inorganic chemistry
journalStr	Russian journal of inorganic chemistry
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container_start_page	305
author_browse	Podval’naya, N. V. Volkov, V. L.
container_volume	55
format_se	Elektronische Aufsätze
author-letter	Podval’naya, N. V.
doi_str_mv	10.1134/S0036023610020270
title_sort	hydrolytic precipitation of magnesium polyvanadates in vanadium (iv, v) solutions
title_auth	Hydrolytic precipitation of magnesium polyvanadates in vanadium (IV, V) solutions
abstract	Abstract The phase and chemical composition of precipitates formed in Mg($ VO_{3} $)2-VOSO4-$ H_{2} $O system at initial pH from 1 to 7 and temperature from 80 to 90°C was studied. Polyvanadates of variable composition $ Mg_{x} $Vy4+V12-y5+1$ O_{31–δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 1.3, 1.2 ≤ y ≤ 2.4, 0.7 ≤ δ = 1.4) were formed at pH from 1 to 4 and $ V^{4+} $/$ V^{5+} $ ratio from 0.43 to 9. Compounds with the general formula $ Mg_{x} $Vy4+V6-y5+$ O_{16-δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 0.65, y = 1.0, 0.8 ≤ δ ≤ 0.85) were formed at pH from 6.0 to 7.0 and $ V^{4+} $/$ V^{5+} $ ratios from 0.11 to 0.25. The maximum $ V^{4+} $ concentration (y = 2.4) in the precipitates was achieved at the $ VV^{4+} $/$ V^{5+} $ solution ratio of 1.0 and pH = 3. The precipitates in solutions with pH 3 were formed only upon addition of $ VO^{2+} $ ions with the maximum rate at a $ V^{4+} $/$ V^{5+} $ ratio of 0.33. These processes were limited by second-order reactions on the surface of polyvanadates. © Pleiades Publishing, Ltd. 2010
abstractGer	Abstract The phase and chemical composition of precipitates formed in Mg($ VO_{3} $)2-VOSO4-$ H_{2} $O system at initial pH from 1 to 7 and temperature from 80 to 90°C was studied. Polyvanadates of variable composition $ Mg_{x} $Vy4+V12-y5+1$ O_{31–δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 1.3, 1.2 ≤ y ≤ 2.4, 0.7 ≤ δ = 1.4) were formed at pH from 1 to 4 and $ V^{4+} $/$ V^{5+} $ ratio from 0.43 to 9. Compounds with the general formula $ Mg_{x} $Vy4+V6-y5+$ O_{16-δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 0.65, y = 1.0, 0.8 ≤ δ ≤ 0.85) were formed at pH from 6.0 to 7.0 and $ V^{4+} $/$ V^{5+} $ ratios from 0.11 to 0.25. The maximum $ V^{4+} $ concentration (y = 2.4) in the precipitates was achieved at the $ VV^{4+} $/$ V^{5+} $ solution ratio of 1.0 and pH = 3. The precipitates in solutions with pH 3 were formed only upon addition of $ VO^{2+} $ ions with the maximum rate at a $ V^{4+} $/$ V^{5+} $ ratio of 0.33. These processes were limited by second-order reactions on the surface of polyvanadates. © Pleiades Publishing, Ltd. 2010
abstract_unstemmed	Abstract The phase and chemical composition of precipitates formed in Mg($ VO_{3} $)2-VOSO4-$ H_{2} $O system at initial pH from 1 to 7 and temperature from 80 to 90°C was studied. Polyvanadates of variable composition $ Mg_{x} $Vy4+V12-y5+1$ O_{31–δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 1.3, 1.2 ≤ y ≤ 2.4, 0.7 ≤ δ = 1.4) were formed at pH from 1 to 4 and $ V^{4+} $/$ V^{5+} $ ratio from 0.43 to 9. Compounds with the general formula $ Mg_{x} $Vy4+V6-y5+$ O_{16-δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 0.65, y = 1.0, 0.8 ≤ δ ≤ 0.85) were formed at pH from 6.0 to 7.0 and $ V^{4+} $/$ V^{5+} $ ratios from 0.11 to 0.25. The maximum $ V^{4+} $ concentration (y = 2.4) in the precipitates was achieved at the $ VV^{4+} $/$ V^{5+} $ solution ratio of 1.0 and pH = 3. The precipitates in solutions with pH 3 were formed only upon addition of $ VO^{2+} $ ions with the maximum rate at a $ V^{4+} $/$ V^{5+} $ ratio of 0.33. These processes were limited by second-order reactions on the surface of polyvanadates. © Pleiades Publishing, Ltd. 2010
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title_short	Hydrolytic precipitation of magnesium polyvanadates in vanadium (IV, V) solutions
url	https://dx.doi.org/10.1134/S0036023610020270
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author2	Volkov, V. L.
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doi_str	10.1134/S0036023610020270
up_date	2024-07-03T15:06:59.972Z
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fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR020291256</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519214035.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2010 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1134/S0036023610020270</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR020291256</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)S0036023610020270-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Podval’naya, N. V.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Hydrolytic precipitation of magnesium polyvanadates in vanadium (IV, V) solutions</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2010</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Pleiades Publishing, Ltd. 2010</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The phase and chemical composition of precipitates formed in Mg($ VO_{3} $)2-VOSO4-$ H_{2} $O system at initial pH from 1 to 7 and temperature from 80 to 90°C was studied. Polyvanadates of variable composition $ Mg_{x} $Vy4+V12-y5+1$ O_{31–δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 1.3, 1.2 ≤ y ≤ 2.4, 0.7 ≤ δ = 1.4) were formed at pH from 1 to 4 and $ V^{4+} $/$ V^{5+} $ ratio from 0.43 to 9. Compounds with the general formula $ Mg_{x} $Vy4+V6-y5+$ O_{16-δ} $ · n$ H_{2} $O (0.7 ≤ x ≤ 0.65, y = 1.0, 0.8 ≤ δ ≤ 0.85) were formed at pH from 6.0 to 7.0 and $ V^{4+} $/$ V^{5+} $ ratios from 0.11 to 0.25. The maximum $ V^{4+} $ concentration (y = 2.4) in the precipitates was achieved at the $ VV^{4+} $/$ V^{5+} $ solution ratio of 1.0 and pH = 3. The precipitates in solutions with pH 3 were formed only upon addition of $ VO^{2+} $ ions with the maximum rate at a $ V^{4+} $/$ V^{5+} $ ratio of 0.33. These processes were limited by second-order reactions on the surface of polyvanadates.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Vanadium</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Vanadium Oxide</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Vanadium Pentoxide</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Second Order Reaction</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Vanadium Compound</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Volkov, V. L.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Russian journal of inorganic chemistry</subfield><subfield code="d">Moscow : MAIK Nauka/Interperiodica Publ., 2006</subfield><subfield code="g">55(2010), 2 vom: Feb., Seite 305-311</subfield><subfield code="w">(DE-627)508334675</subfield><subfield code="w">(DE-600)2223897-9</subfield><subfield code="x">1531-8613</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:55</subfield><subfield code="g">year:2010</subfield><subfield code="g">number:2</subfield><subfield code="g">month:02</subfield><subfield code="g">pages:305-311</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1134/S0036023610020270</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield 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Hydrolytic precipitation of magnesium polyvanadates in vanadium (IV, V) solutions

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