Heteroligand polynuclear nickel(II) complexonates in aqueous solutions of 2,2′-dipyridyl

Abstract Formation of nickel(II) complexes with ethylenediaminetetraacetic acid (Edta) and 2,2′-dipyridyl (Dipy) has been studied by electronic absorption spectroscopy. Mathematical modeling has demonstrated that the most probable mathematical models to describe the experimental dependences of absor...
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Gespeichert in:

Autor*in:	Kornev, V. I. [verfasserIn] Buldakova, N. S. Didik, M. V.

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2014

Schlagwörter:	Ternary System Dipyridyl Polynuclear Complex Complex Stability Constant Heteroligand Complex

Anmerkung:	© Pleiades Publishing, Ltd. 2014

Übergeordnetes Werk:	Enthalten in: Russian journal of inorganic chemistry - Moscow : MAIK Nauka/Interperiodica Publ., 2006, 59(2014), 6 vom: Juni, Seite 626-631
Übergeordnetes Werk:	volume:59 ; year:2014 ; number:6 ; month:06 ; pages:626-631

Links:	Volltext

DOI / URN:	10.1134/S0036023614060114

Katalog-ID:	SPR02030529X

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520			\|a Abstract Formation of nickel(II) complexes with ethylenediaminetetraacetic acid (Edta) and 2,2′-dipyridyl (Dipy) has been studied by electronic absorption spectroscopy. Mathematical modeling has demonstrated that the most probable mathematical models to describe the experimental dependences of absorption on the medium acidity and concentration of solution components relies on the dissociation constants of the ligands (Ki) and stability constants (β) of homoligand, heteroligand, and polynuclear complexes of general composition [$ Ni_{m} %$ Dipy_{n} %$ Edta_{r} $]2m − 4r (m = 1–4, n = 0–8, r = 0–1) as parameters. The reaction equilibrium constants and stability constants of the resulting complexes have been calculated. The structures of these complexes have been suggested.
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650		4	\|a Heteroligand Complex \|7 (dpeaa)DE-He213
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700	1		\|a Didik, M. V. \|4 aut
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912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
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912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2116
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2119
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2144
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912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2188
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912			\|a GBV_ILN_2336
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912			\|a GBV_ILN_4333
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publishDate	2014
allfields	10.1134/S0036023614060114 doi (DE-627)SPR02030529X (SPR)S0036023614060114-e DE-627 ger DE-627 rakwb eng Kornev, V. I. verfasserin aut Heteroligand polynuclear nickel(II) complexonates in aqueous solutions of 2,2′-dipyridyl 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract Formation of nickel(II) complexes with ethylenediaminetetraacetic acid (Edta) and 2,2′-dipyridyl (Dipy) has been studied by electronic absorption spectroscopy. Mathematical modeling has demonstrated that the most probable mathematical models to describe the experimental dependences of absorption on the medium acidity and concentration of solution components relies on the dissociation constants of the ligands (Ki) and stability constants (β) of homoligand, heteroligand, and polynuclear complexes of general composition [$ Ni_{m} %$ Dipy_{n} %$ Edta_{r} $]2m − 4r (m = 1–4, n = 0–8, r = 0–1) as parameters. The reaction equilibrium constants and stability constants of the resulting complexes have been calculated. The structures of these complexes have been suggested. Ternary System (dpeaa)DE-He213 Dipyridyl (dpeaa)DE-He213 Polynuclear Complex (dpeaa)DE-He213 Complex Stability Constant (dpeaa)DE-He213 Heteroligand Complex (dpeaa)DE-He213 Buldakova, N. S. aut Didik, M. V. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 59(2014), 6 vom: Juni, Seite 626-631 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:59 year:2014 number:6 month:06 pages:626-631 https://dx.doi.org/10.1134/S0036023614060114 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 59 2014 6 06 626-631
spelling	10.1134/S0036023614060114 doi (DE-627)SPR02030529X (SPR)S0036023614060114-e DE-627 ger DE-627 rakwb eng Kornev, V. I. verfasserin aut Heteroligand polynuclear nickel(II) complexonates in aqueous solutions of 2,2′-dipyridyl 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract Formation of nickel(II) complexes with ethylenediaminetetraacetic acid (Edta) and 2,2′-dipyridyl (Dipy) has been studied by electronic absorption spectroscopy. Mathematical modeling has demonstrated that the most probable mathematical models to describe the experimental dependences of absorption on the medium acidity and concentration of solution components relies on the dissociation constants of the ligands (Ki) and stability constants (β) of homoligand, heteroligand, and polynuclear complexes of general composition [$ Ni_{m} %$ Dipy_{n} %$ Edta_{r} $]2m − 4r (m = 1–4, n = 0–8, r = 0–1) as parameters. The reaction equilibrium constants and stability constants of the resulting complexes have been calculated. The structures of these complexes have been suggested. Ternary System (dpeaa)DE-He213 Dipyridyl (dpeaa)DE-He213 Polynuclear Complex (dpeaa)DE-He213 Complex Stability Constant (dpeaa)DE-He213 Heteroligand Complex (dpeaa)DE-He213 Buldakova, N. S. aut Didik, M. V. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 59(2014), 6 vom: Juni, Seite 626-631 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:59 year:2014 number:6 month:06 pages:626-631 https://dx.doi.org/10.1134/S0036023614060114 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 59 2014 6 06 626-631
allfields_unstemmed	10.1134/S0036023614060114 doi (DE-627)SPR02030529X (SPR)S0036023614060114-e DE-627 ger DE-627 rakwb eng Kornev, V. I. verfasserin aut Heteroligand polynuclear nickel(II) complexonates in aqueous solutions of 2,2′-dipyridyl 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract Formation of nickel(II) complexes with ethylenediaminetetraacetic acid (Edta) and 2,2′-dipyridyl (Dipy) has been studied by electronic absorption spectroscopy. Mathematical modeling has demonstrated that the most probable mathematical models to describe the experimental dependences of absorption on the medium acidity and concentration of solution components relies on the dissociation constants of the ligands (Ki) and stability constants (β) of homoligand, heteroligand, and polynuclear complexes of general composition [$ Ni_{m} %$ Dipy_{n} %$ Edta_{r} $]2m − 4r (m = 1–4, n = 0–8, r = 0–1) as parameters. The reaction equilibrium constants and stability constants of the resulting complexes have been calculated. The structures of these complexes have been suggested. Ternary System (dpeaa)DE-He213 Dipyridyl (dpeaa)DE-He213 Polynuclear Complex (dpeaa)DE-He213 Complex Stability Constant (dpeaa)DE-He213 Heteroligand Complex (dpeaa)DE-He213 Buldakova, N. S. aut Didik, M. V. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 59(2014), 6 vom: Juni, Seite 626-631 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:59 year:2014 number:6 month:06 pages:626-631 https://dx.doi.org/10.1134/S0036023614060114 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 59 2014 6 06 626-631
allfieldsGer	10.1134/S0036023614060114 doi (DE-627)SPR02030529X (SPR)S0036023614060114-e DE-627 ger DE-627 rakwb eng Kornev, V. I. verfasserin aut Heteroligand polynuclear nickel(II) complexonates in aqueous solutions of 2,2′-dipyridyl 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract Formation of nickel(II) complexes with ethylenediaminetetraacetic acid (Edta) and 2,2′-dipyridyl (Dipy) has been studied by electronic absorption spectroscopy. Mathematical modeling has demonstrated that the most probable mathematical models to describe the experimental dependences of absorption on the medium acidity and concentration of solution components relies on the dissociation constants of the ligands (Ki) and stability constants (β) of homoligand, heteroligand, and polynuclear complexes of general composition [$ Ni_{m} %$ Dipy_{n} %$ Edta_{r} $]2m − 4r (m = 1–4, n = 0–8, r = 0–1) as parameters. The reaction equilibrium constants and stability constants of the resulting complexes have been calculated. The structures of these complexes have been suggested. Ternary System (dpeaa)DE-He213 Dipyridyl (dpeaa)DE-He213 Polynuclear Complex (dpeaa)DE-He213 Complex Stability Constant (dpeaa)DE-He213 Heteroligand Complex (dpeaa)DE-He213 Buldakova, N. S. aut Didik, M. V. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 59(2014), 6 vom: Juni, Seite 626-631 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:59 year:2014 number:6 month:06 pages:626-631 https://dx.doi.org/10.1134/S0036023614060114 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 59 2014 6 06 626-631
allfieldsSound	10.1134/S0036023614060114 doi (DE-627)SPR02030529X (SPR)S0036023614060114-e DE-627 ger DE-627 rakwb eng Kornev, V. I. verfasserin aut Heteroligand polynuclear nickel(II) complexonates in aqueous solutions of 2,2′-dipyridyl 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract Formation of nickel(II) complexes with ethylenediaminetetraacetic acid (Edta) and 2,2′-dipyridyl (Dipy) has been studied by electronic absorption spectroscopy. Mathematical modeling has demonstrated that the most probable mathematical models to describe the experimental dependences of absorption on the medium acidity and concentration of solution components relies on the dissociation constants of the ligands (Ki) and stability constants (β) of homoligand, heteroligand, and polynuclear complexes of general composition [$ Ni_{m} %$ Dipy_{n} %$ Edta_{r} $]2m − 4r (m = 1–4, n = 0–8, r = 0–1) as parameters. The reaction equilibrium constants and stability constants of the resulting complexes have been calculated. The structures of these complexes have been suggested. Ternary System (dpeaa)DE-He213 Dipyridyl (dpeaa)DE-He213 Polynuclear Complex (dpeaa)DE-He213 Complex Stability Constant (dpeaa)DE-He213 Heteroligand Complex (dpeaa)DE-He213 Buldakova, N. S. aut Didik, M. V. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 59(2014), 6 vom: Juni, Seite 626-631 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:59 year:2014 number:6 month:06 pages:626-631 https://dx.doi.org/10.1134/S0036023614060114 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 59 2014 6 06 626-631
language	English
source	Enthalten in Russian journal of inorganic chemistry 59(2014), 6 vom: Juni, Seite 626-631 volume:59 year:2014 number:6 month:06 pages:626-631
sourceStr	Enthalten in Russian journal of inorganic chemistry 59(2014), 6 vom: Juni, Seite 626-631 volume:59 year:2014 number:6 month:06 pages:626-631
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Ternary System Dipyridyl Polynuclear Complex Complex Stability Constant Heteroligand Complex
isfreeaccess_bool	false
container_title	Russian journal of inorganic chemistry
authorswithroles_txt_mv	Kornev, V. I. @@aut@@ Buldakova, N. S. @@aut@@ Didik, M. V. @@aut@@
publishDateDaySort_date	2014-06-01T00:00:00Z
hierarchy_top_id	508334675
id	SPR02030529X
language_de	englisch
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author	Kornev, V. I.
spellingShingle	Kornev, V. I. misc Ternary System misc Dipyridyl misc Polynuclear Complex misc Complex Stability Constant misc Heteroligand Complex Heteroligand polynuclear nickel(II) complexonates in aqueous solutions of 2,2′-dipyridyl
authorStr	Kornev, V. I.
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topic_title	Heteroligand polynuclear nickel(II) complexonates in aqueous solutions of 2,2′-dipyridyl Ternary System (dpeaa)DE-He213 Dipyridyl (dpeaa)DE-He213 Polynuclear Complex (dpeaa)DE-He213 Complex Stability Constant (dpeaa)DE-He213 Heteroligand Complex (dpeaa)DE-He213
topic	misc Ternary System misc Dipyridyl misc Polynuclear Complex misc Complex Stability Constant misc Heteroligand Complex
topic_unstemmed	misc Ternary System misc Dipyridyl misc Polynuclear Complex misc Complex Stability Constant misc Heteroligand Complex
topic_browse	misc Ternary System misc Dipyridyl misc Polynuclear Complex misc Complex Stability Constant misc Heteroligand Complex
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title	Heteroligand polynuclear nickel(II) complexonates in aqueous solutions of 2,2′-dipyridyl
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title_full	Heteroligand polynuclear nickel(II) complexonates in aqueous solutions of 2,2′-dipyridyl
author_sort	Kornev, V. I.
journal	Russian journal of inorganic chemistry
journalStr	Russian journal of inorganic chemistry
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author_browse	Kornev, V. I. Buldakova, N. S. Didik, M. V.
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author-letter	Kornev, V. I.
doi_str_mv	10.1134/S0036023614060114
title_sort	heteroligand polynuclear nickel(ii) complexonates in aqueous solutions of 2,2′-dipyridyl
title_auth	Heteroligand polynuclear nickel(II) complexonates in aqueous solutions of 2,2′-dipyridyl
abstract	Abstract Formation of nickel(II) complexes with ethylenediaminetetraacetic acid (Edta) and 2,2′-dipyridyl (Dipy) has been studied by electronic absorption spectroscopy. Mathematical modeling has demonstrated that the most probable mathematical models to describe the experimental dependences of absorption on the medium acidity and concentration of solution components relies on the dissociation constants of the ligands (Ki) and stability constants (β) of homoligand, heteroligand, and polynuclear complexes of general composition [$ Ni_{m} %$ Dipy_{n} %$ Edta_{r} $]2m − 4r (m = 1–4, n = 0–8, r = 0–1) as parameters. The reaction equilibrium constants and stability constants of the resulting complexes have been calculated. The structures of these complexes have been suggested. © Pleiades Publishing, Ltd. 2014
abstractGer	Abstract Formation of nickel(II) complexes with ethylenediaminetetraacetic acid (Edta) and 2,2′-dipyridyl (Dipy) has been studied by electronic absorption spectroscopy. Mathematical modeling has demonstrated that the most probable mathematical models to describe the experimental dependences of absorption on the medium acidity and concentration of solution components relies on the dissociation constants of the ligands (Ki) and stability constants (β) of homoligand, heteroligand, and polynuclear complexes of general composition [$ Ni_{m} %$ Dipy_{n} %$ Edta_{r} $]2m − 4r (m = 1–4, n = 0–8, r = 0–1) as parameters. The reaction equilibrium constants and stability constants of the resulting complexes have been calculated. The structures of these complexes have been suggested. © Pleiades Publishing, Ltd. 2014
abstract_unstemmed	Abstract Formation of nickel(II) complexes with ethylenediaminetetraacetic acid (Edta) and 2,2′-dipyridyl (Dipy) has been studied by electronic absorption spectroscopy. Mathematical modeling has demonstrated that the most probable mathematical models to describe the experimental dependences of absorption on the medium acidity and concentration of solution components relies on the dissociation constants of the ligands (Ki) and stability constants (β) of homoligand, heteroligand, and polynuclear complexes of general composition [$ Ni_{m} %$ Dipy_{n} %$ Edta_{r} $]2m − 4r (m = 1–4, n = 0–8, r = 0–1) as parameters. The reaction equilibrium constants and stability constants of the resulting complexes have been calculated. The structures of these complexes have been suggested. © Pleiades Publishing, Ltd. 2014
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title_short	Heteroligand polynuclear nickel(II) complexonates in aqueous solutions of 2,2′-dipyridyl
url	https://dx.doi.org/10.1134/S0036023614060114
remote_bool	true
author2	Buldakova, N. S. Didik, M. V.
author2Str	Buldakova, N. S. Didik, M. V.
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doi_str	10.1134/S0036023614060114
up_date	2024-07-03T15:12:41.034Z
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Heteroligand polynuclear nickel(II) complexonates in aqueous solutions of 2,2′-dipyridyl

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