Stabilization of water structure in ammonium hydrogenphosphate solutions

Abstract Radio-frequency permittivity and dielectric loss of ($ NH_{4} $)2 $ HPO_{4} $ solutions at 288–308 K in the water permittivity dispersion region (7.5–25 GHz) are studied. Low-frequency electrical conductivities of these solutions are measured, and ionic losses at high frequencies are calcul...
Ausführliche Beschreibung

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Autor*in:	Lyashchenko, A. K. [verfasserIn] Lotsmanova, E. A. Lileev, A. S.

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2014

Schlagwörter:	Dielectric Relaxation Bond Network Static Dielectric Constant Ammo Nium Fluoride Dielectric Relaxation Time

Anmerkung:	© Pleiades Publishing, Ltd. 2014

Übergeordnetes Werk:	Enthalten in: Russian journal of inorganic chemistry - Moscow : MAIK Nauka/Interperiodica Publ., 2006, 59(2014), 7 vom: Juli, Seite 751-756
Übergeordnetes Werk:	volume:59 ; year:2014 ; number:7 ; month:07 ; pages:751-756

Links:	Volltext

DOI / URN:	10.1134/S0036023614070134

Katalog-ID:	SPR020305494

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520			\|a Abstract Radio-frequency permittivity and dielectric loss of ($ NH_{4} $)2 $ HPO_{4} $ solutions at 288–308 K in the water permittivity dispersion region (7.5–25 GHz) are studied. Low-frequency electrical conductivities of these solutions are measured, and ionic losses at high frequencies are calculated. The analysis is carried out in terms of the Cole-Cole relaxation model. Static dielectric constants $ ɛ_{s} $ and the activation times τ and thermodynamic parameters of activation (ΔHɛ++, ΔGɛ++, and TΔSɛ++) for the dielectric relaxation of the solutions are calculated. The values of $ ɛ_{s} $ decrease in response to increasing salt concentration at all temperatures. The increasing τ and ΔHɛ++ values indicate the stabilization of water structure in solutions where the anion and cation are hydrophilically hydrated.
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allfields	10.1134/S0036023614070134 doi (DE-627)SPR020305494 (SPR)S0036023614070134-e DE-627 ger DE-627 rakwb eng Lyashchenko, A. K. verfasserin aut Stabilization of water structure in ammonium hydrogenphosphate solutions 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract Radio-frequency permittivity and dielectric loss of ($ NH_{4} $)2 $ HPO_{4} $ solutions at 288–308 K in the water permittivity dispersion region (7.5–25 GHz) are studied. Low-frequency electrical conductivities of these solutions are measured, and ionic losses at high frequencies are calculated. The analysis is carried out in terms of the Cole-Cole relaxation model. Static dielectric constants $ ɛ_{s} $ and the activation times τ and thermodynamic parameters of activation (ΔHɛ++, ΔGɛ++, and TΔSɛ++) for the dielectric relaxation of the solutions are calculated. The values of $ ɛ_{s} $ decrease in response to increasing salt concentration at all temperatures. The increasing τ and ΔHɛ++ values indicate the stabilization of water structure in solutions where the anion and cation are hydrophilically hydrated. Dielectric Relaxation (dpeaa)DE-He213 Bond Network (dpeaa)DE-He213 Static Dielectric Constant (dpeaa)DE-He213 Ammo Nium Fluoride (dpeaa)DE-He213 Dielectric Relaxation Time (dpeaa)DE-He213 Lotsmanova, E. A. aut Lileev, A. S. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 59(2014), 7 vom: Juli, Seite 751-756 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:59 year:2014 number:7 month:07 pages:751-756 https://dx.doi.org/10.1134/S0036023614070134 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 59 2014 7 07 751-756
spelling	10.1134/S0036023614070134 doi (DE-627)SPR020305494 (SPR)S0036023614070134-e DE-627 ger DE-627 rakwb eng Lyashchenko, A. K. verfasserin aut Stabilization of water structure in ammonium hydrogenphosphate solutions 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract Radio-frequency permittivity and dielectric loss of ($ NH_{4} $)2 $ HPO_{4} $ solutions at 288–308 K in the water permittivity dispersion region (7.5–25 GHz) are studied. Low-frequency electrical conductivities of these solutions are measured, and ionic losses at high frequencies are calculated. The analysis is carried out in terms of the Cole-Cole relaxation model. Static dielectric constants $ ɛ_{s} $ and the activation times τ and thermodynamic parameters of activation (ΔHɛ++, ΔGɛ++, and TΔSɛ++) for the dielectric relaxation of the solutions are calculated. The values of $ ɛ_{s} $ decrease in response to increasing salt concentration at all temperatures. The increasing τ and ΔHɛ++ values indicate the stabilization of water structure in solutions where the anion and cation are hydrophilically hydrated. Dielectric Relaxation (dpeaa)DE-He213 Bond Network (dpeaa)DE-He213 Static Dielectric Constant (dpeaa)DE-He213 Ammo Nium Fluoride (dpeaa)DE-He213 Dielectric Relaxation Time (dpeaa)DE-He213 Lotsmanova, E. A. aut Lileev, A. S. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 59(2014), 7 vom: Juli, Seite 751-756 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:59 year:2014 number:7 month:07 pages:751-756 https://dx.doi.org/10.1134/S0036023614070134 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 59 2014 7 07 751-756
allfields_unstemmed	10.1134/S0036023614070134 doi (DE-627)SPR020305494 (SPR)S0036023614070134-e DE-627 ger DE-627 rakwb eng Lyashchenko, A. K. verfasserin aut Stabilization of water structure in ammonium hydrogenphosphate solutions 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract Radio-frequency permittivity and dielectric loss of ($ NH_{4} $)2 $ HPO_{4} $ solutions at 288–308 K in the water permittivity dispersion region (7.5–25 GHz) are studied. Low-frequency electrical conductivities of these solutions are measured, and ionic losses at high frequencies are calculated. The analysis is carried out in terms of the Cole-Cole relaxation model. Static dielectric constants $ ɛ_{s} $ and the activation times τ and thermodynamic parameters of activation (ΔHɛ++, ΔGɛ++, and TΔSɛ++) for the dielectric relaxation of the solutions are calculated. The values of $ ɛ_{s} $ decrease in response to increasing salt concentration at all temperatures. The increasing τ and ΔHɛ++ values indicate the stabilization of water structure in solutions where the anion and cation are hydrophilically hydrated. Dielectric Relaxation (dpeaa)DE-He213 Bond Network (dpeaa)DE-He213 Static Dielectric Constant (dpeaa)DE-He213 Ammo Nium Fluoride (dpeaa)DE-He213 Dielectric Relaxation Time (dpeaa)DE-He213 Lotsmanova, E. A. aut Lileev, A. S. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 59(2014), 7 vom: Juli, Seite 751-756 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:59 year:2014 number:7 month:07 pages:751-756 https://dx.doi.org/10.1134/S0036023614070134 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 59 2014 7 07 751-756
allfieldsGer	10.1134/S0036023614070134 doi (DE-627)SPR020305494 (SPR)S0036023614070134-e DE-627 ger DE-627 rakwb eng Lyashchenko, A. K. verfasserin aut Stabilization of water structure in ammonium hydrogenphosphate solutions 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract Radio-frequency permittivity and dielectric loss of ($ NH_{4} $)2 $ HPO_{4} $ solutions at 288–308 K in the water permittivity dispersion region (7.5–25 GHz) are studied. Low-frequency electrical conductivities of these solutions are measured, and ionic losses at high frequencies are calculated. The analysis is carried out in terms of the Cole-Cole relaxation model. Static dielectric constants $ ɛ_{s} $ and the activation times τ and thermodynamic parameters of activation (ΔHɛ++, ΔGɛ++, and TΔSɛ++) for the dielectric relaxation of the solutions are calculated. The values of $ ɛ_{s} $ decrease in response to increasing salt concentration at all temperatures. The increasing τ and ΔHɛ++ values indicate the stabilization of water structure in solutions where the anion and cation are hydrophilically hydrated. Dielectric Relaxation (dpeaa)DE-He213 Bond Network (dpeaa)DE-He213 Static Dielectric Constant (dpeaa)DE-He213 Ammo Nium Fluoride (dpeaa)DE-He213 Dielectric Relaxation Time (dpeaa)DE-He213 Lotsmanova, E. A. aut Lileev, A. S. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 59(2014), 7 vom: Juli, Seite 751-756 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:59 year:2014 number:7 month:07 pages:751-756 https://dx.doi.org/10.1134/S0036023614070134 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 59 2014 7 07 751-756
allfieldsSound	10.1134/S0036023614070134 doi (DE-627)SPR020305494 (SPR)S0036023614070134-e DE-627 ger DE-627 rakwb eng Lyashchenko, A. K. verfasserin aut Stabilization of water structure in ammonium hydrogenphosphate solutions 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Pleiades Publishing, Ltd. 2014 Abstract Radio-frequency permittivity and dielectric loss of ($ NH_{4} $)2 $ HPO_{4} $ solutions at 288–308 K in the water permittivity dispersion region (7.5–25 GHz) are studied. Low-frequency electrical conductivities of these solutions are measured, and ionic losses at high frequencies are calculated. The analysis is carried out in terms of the Cole-Cole relaxation model. Static dielectric constants $ ɛ_{s} $ and the activation times τ and thermodynamic parameters of activation (ΔHɛ++, ΔGɛ++, and TΔSɛ++) for the dielectric relaxation of the solutions are calculated. The values of $ ɛ_{s} $ decrease in response to increasing salt concentration at all temperatures. The increasing τ and ΔHɛ++ values indicate the stabilization of water structure in solutions where the anion and cation are hydrophilically hydrated. Dielectric Relaxation (dpeaa)DE-He213 Bond Network (dpeaa)DE-He213 Static Dielectric Constant (dpeaa)DE-He213 Ammo Nium Fluoride (dpeaa)DE-He213 Dielectric Relaxation Time (dpeaa)DE-He213 Lotsmanova, E. A. aut Lileev, A. S. aut Enthalten in Russian journal of inorganic chemistry Moscow : MAIK Nauka/Interperiodica Publ., 2006 59(2014), 7 vom: Juli, Seite 751-756 (DE-627)508334675 (DE-600)2223897-9 1531-8613 nnns volume:59 year:2014 number:7 month:07 pages:751-756 https://dx.doi.org/10.1134/S0036023614070134 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 59 2014 7 07 751-756
language	English
source	Enthalten in Russian journal of inorganic chemistry 59(2014), 7 vom: Juli, Seite 751-756 volume:59 year:2014 number:7 month:07 pages:751-756
sourceStr	Enthalten in Russian journal of inorganic chemistry 59(2014), 7 vom: Juli, Seite 751-756 volume:59 year:2014 number:7 month:07 pages:751-756
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Dielectric Relaxation Bond Network Static Dielectric Constant Ammo Nium Fluoride Dielectric Relaxation Time
isfreeaccess_bool	false
container_title	Russian journal of inorganic chemistry
authorswithroles_txt_mv	Lyashchenko, A. K. @@aut@@ Lotsmanova, E. A. @@aut@@ Lileev, A. S. @@aut@@
publishDateDaySort_date	2014-07-01T00:00:00Z
hierarchy_top_id	508334675
id	SPR020305494
language_de	englisch
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author	Lyashchenko, A. K.
spellingShingle	Lyashchenko, A. K. misc Dielectric Relaxation misc Bond Network misc Static Dielectric Constant misc Ammo Nium Fluoride misc Dielectric Relaxation Time Stabilization of water structure in ammonium hydrogenphosphate solutions
authorStr	Lyashchenko, A. K.
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topic_title	Stabilization of water structure in ammonium hydrogenphosphate solutions Dielectric Relaxation (dpeaa)DE-He213 Bond Network (dpeaa)DE-He213 Static Dielectric Constant (dpeaa)DE-He213 Ammo Nium Fluoride (dpeaa)DE-He213 Dielectric Relaxation Time (dpeaa)DE-He213
topic	misc Dielectric Relaxation misc Bond Network misc Static Dielectric Constant misc Ammo Nium Fluoride misc Dielectric Relaxation Time
topic_unstemmed	misc Dielectric Relaxation misc Bond Network misc Static Dielectric Constant misc Ammo Nium Fluoride misc Dielectric Relaxation Time
topic_browse	misc Dielectric Relaxation misc Bond Network misc Static Dielectric Constant misc Ammo Nium Fluoride misc Dielectric Relaxation Time
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title	Stabilization of water structure in ammonium hydrogenphosphate solutions
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title_full	Stabilization of water structure in ammonium hydrogenphosphate solutions
author_sort	Lyashchenko, A. K.
journal	Russian journal of inorganic chemistry
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author_browse	Lyashchenko, A. K. Lotsmanova, E. A. Lileev, A. S.
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title_sort	stabilization of water structure in ammonium hydrogenphosphate solutions
title_auth	Stabilization of water structure in ammonium hydrogenphosphate solutions
abstract	Abstract Radio-frequency permittivity and dielectric loss of ($ NH_{4} $)2 $ HPO_{4} $ solutions at 288–308 K in the water permittivity dispersion region (7.5–25 GHz) are studied. Low-frequency electrical conductivities of these solutions are measured, and ionic losses at high frequencies are calculated. The analysis is carried out in terms of the Cole-Cole relaxation model. Static dielectric constants $ ɛ_{s} $ and the activation times τ and thermodynamic parameters of activation (ΔHɛ++, ΔGɛ++, and TΔSɛ++) for the dielectric relaxation of the solutions are calculated. The values of $ ɛ_{s} $ decrease in response to increasing salt concentration at all temperatures. The increasing τ and ΔHɛ++ values indicate the stabilization of water structure in solutions where the anion and cation are hydrophilically hydrated. © Pleiades Publishing, Ltd. 2014
abstractGer	Abstract Radio-frequency permittivity and dielectric loss of ($ NH_{4} $)2 $ HPO_{4} $ solutions at 288–308 K in the water permittivity dispersion region (7.5–25 GHz) are studied. Low-frequency electrical conductivities of these solutions are measured, and ionic losses at high frequencies are calculated. The analysis is carried out in terms of the Cole-Cole relaxation model. Static dielectric constants $ ɛ_{s} $ and the activation times τ and thermodynamic parameters of activation (ΔHɛ++, ΔGɛ++, and TΔSɛ++) for the dielectric relaxation of the solutions are calculated. The values of $ ɛ_{s} $ decrease in response to increasing salt concentration at all temperatures. The increasing τ and ΔHɛ++ values indicate the stabilization of water structure in solutions where the anion and cation are hydrophilically hydrated. © Pleiades Publishing, Ltd. 2014
abstract_unstemmed	Abstract Radio-frequency permittivity and dielectric loss of ($ NH_{4} $)2 $ HPO_{4} $ solutions at 288–308 K in the water permittivity dispersion region (7.5–25 GHz) are studied. Low-frequency electrical conductivities of these solutions are measured, and ionic losses at high frequencies are calculated. The analysis is carried out in terms of the Cole-Cole relaxation model. Static dielectric constants $ ɛ_{s} $ and the activation times τ and thermodynamic parameters of activation (ΔHɛ++, ΔGɛ++, and TΔSɛ++) for the dielectric relaxation of the solutions are calculated. The values of $ ɛ_{s} $ decrease in response to increasing salt concentration at all temperatures. The increasing τ and ΔHɛ++ values indicate the stabilization of water structure in solutions where the anion and cation are hydrophilically hydrated. © Pleiades Publishing, Ltd. 2014
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title_short	Stabilization of water structure in ammonium hydrogenphosphate solutions
url	https://dx.doi.org/10.1134/S0036023614070134
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author2	Lotsmanova, E. A. Lileev, A. S.
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up_date	2024-07-03T15:12:45.600Z
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K.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Stabilization of water structure in ammonium hydrogenphosphate solutions</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2014</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Pleiades Publishing, Ltd. 2014</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Radio-frequency permittivity and dielectric loss of ($ NH_{4} $)2 $ HPO_{4} $ solutions at 288–308 K in the water permittivity dispersion region (7.5–25 GHz) are studied. Low-frequency electrical conductivities of these solutions are measured, and ionic losses at high frequencies are calculated. The analysis is carried out in terms of the Cole-Cole relaxation model. Static dielectric constants $ ɛ_{s} $ and the activation times τ and thermodynamic parameters of activation (ΔHɛ++, ΔGɛ++, and TΔSɛ++) for the dielectric relaxation of the solutions are calculated. The values of $ ɛ_{s} $ decrease in response to increasing salt concentration at all temperatures. 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Stabilization of water structure in ammonium hydrogenphosphate solutions

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