Gas chromatographic detection of volatile amines found in indoor air due to putrefactive degradation of casein-containing building materials

Abstract The use of non-sterile casein in building materials, especially in self-levelling floor-topping compound (putty), led to various defects in buildings with these materials. Bubbles in the mattings, dark patches unevenly spread over the floor and a very unpleasant odour developed. The defects...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Karlsson, S. [verfasserIn] Bánhidi, Z. G. Albertsson, A. -C.

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	1989

Schlagwörter:	Pyrrolidine Butylamine Sulphuric Acid Solution Volatile Organic Acid Volatile Amine

Anmerkung:	© RILEM 1989

Übergeordnetes Werk:	Enthalten in: Materials and structures - Cachan : RILEM Publications SARL, 1968, 22(1989), 3 vom: 01. Mai, Seite 163-169
Übergeordnetes Werk:	volume:22 ; year:1989 ; number:3 ; day:01 ; month:05 ; pages:163-169

Links:	Volltext

DOI / URN:	10.1007/BF02472183

Katalog-ID:	SPR020555121

Internformat


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100	1		\|a Karlsson, S. \|e verfasserin \|4 aut
245	1	0	\|a Gas chromatographic detection of volatile amines found in indoor air due to putrefactive degradation of casein-containing building materials
264		1	\|c 1989
336			\|a Text \|b txt \|2 rdacontent
337			\|a Computermedien \|b c \|2 rdamedia
338			\|a Online-Ressource \|b cr \|2 rdacarrier
500			\|a © RILEM 1989
520			\|a Abstract The use of non-sterile casein in building materials, especially in self-levelling floor-topping compound (putty), led to various defects in buildings with these materials. Bubbles in the mattings, dark patches unevenly spread over the floor and a very unpleasant odour developed. The defects were commonly induced or accelerated if the humidity in the floor was high. Our earlier studies have concluded that the cause of these problems is due to the growth of alkalitolerantClostridia. The presence of volatile mono-amines in air samples taken in the buildings also confirms our early theories. Due to the high pH of the putty, amines formed in the topping compound will easily be emitted into the air. Some of the amines are commonly found in spent growth media ofClostridia as well as in head-space samples from bacterial suspensions. By the use of gas chromatography (GC) we have been able to detect triethylamine, pyrrolidine, di-iso-butylamine, 2-ethyl-hexylamine and n-octylamine in the air samples. Air sampling was carried out by impinging in weak acidic solutions and adsorption on silica gel. Along with the mono-amines, ammonia has also been detected. The sampling was carried out using Draeger Tubes, which also non-specifically indicate several volatile amines in addition to ammonia. The amount of amines recovered was well below official threshold limits. The amount was in the parts per billion (ppb) region, whereas official threshold limits are usually in the 1–25 parts per million (ppm) region.
650		4	\|a Pyrrolidine \|7 (dpeaa)DE-He213
650		4	\|a Butylamine \|7 (dpeaa)DE-He213
650		4	\|a Sulphuric Acid Solution \|7 (dpeaa)DE-He213
650		4	\|a Volatile Organic Acid \|7 (dpeaa)DE-He213
650		4	\|a Volatile Amine \|7 (dpeaa)DE-He213
700	1		\|a Bánhidi, Z. G. \|4 aut
700	1		\|a Albertsson, A. -C. \|4 aut
773	0	8	\|i Enthalten in \|t Materials and structures \|d Cachan : RILEM Publications SARL, 1968 \|g 22(1989), 3 vom: 01. Mai, Seite 163-169 \|w (DE-627)356252612 \|w (DE-600)2091922-0 \|x 1871-6873 \|7 nnns
773	1	8	\|g volume:22 \|g year:1989 \|g number:3 \|g day:01 \|g month:05 \|g pages:163-169
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912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_39
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
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912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_121
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_206
912			\|a GBV_ILN_224
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_374
912			\|a GBV_ILN_602
912			\|a GBV_ILN_647
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2018
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2043
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2116
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2119
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2144
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2158
912			\|a GBV_ILN_2188
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2193
912			\|a GBV_ILN_2232
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2446
912			\|a GBV_ILN_2470
912			\|a GBV_ILN_2472
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_2548
912			\|a GBV_ILN_2808
912			\|a GBV_ILN_4012
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4046
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4246
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4277
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4328
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4336
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4346
912			\|a GBV_ILN_4367
912			\|a GBV_ILN_4393
912			\|a GBV_ILN_4700
912			\|a GBV_ILN_4753
951			\|a AR
952			\|d 22 \|j 1989 \|e 3 \|b 01 \|c 05 \|h 163-169

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matchkey_str	article:18716873:1989----::acrmtgahceetoovltlaiefudnnorideourfcieerdtooc
hierarchy_sort_str	1989
publishDate	1989
allfields	10.1007/BF02472183 doi (DE-627)SPR020555121 (SPR)BF02472183-e DE-627 ger DE-627 rakwb eng Karlsson, S. verfasserin aut Gas chromatographic detection of volatile amines found in indoor air due to putrefactive degradation of casein-containing building materials 1989 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © RILEM 1989 Abstract The use of non-sterile casein in building materials, especially in self-levelling floor-topping compound (putty), led to various defects in buildings with these materials. Bubbles in the mattings, dark patches unevenly spread over the floor and a very unpleasant odour developed. The defects were commonly induced or accelerated if the humidity in the floor was high. Our earlier studies have concluded that the cause of these problems is due to the growth of alkalitolerantClostridia. The presence of volatile mono-amines in air samples taken in the buildings also confirms our early theories. Due to the high pH of the putty, amines formed in the topping compound will easily be emitted into the air. Some of the amines are commonly found in spent growth media ofClostridia as well as in head-space samples from bacterial suspensions. By the use of gas chromatography (GC) we have been able to detect triethylamine, pyrrolidine, di-iso-butylamine, 2-ethyl-hexylamine and n-octylamine in the air samples. Air sampling was carried out by impinging in weak acidic solutions and adsorption on silica gel. Along with the mono-amines, ammonia has also been detected. The sampling was carried out using Draeger Tubes, which also non-specifically indicate several volatile amines in addition to ammonia. The amount of amines recovered was well below official threshold limits. The amount was in the parts per billion (ppb) region, whereas official threshold limits are usually in the 1–25 parts per million (ppm) region. Pyrrolidine (dpeaa)DE-He213 Butylamine (dpeaa)DE-He213 Sulphuric Acid Solution (dpeaa)DE-He213 Volatile Organic Acid (dpeaa)DE-He213 Volatile Amine (dpeaa)DE-He213 Bánhidi, Z. G. aut Albertsson, A. -C. aut Enthalten in Materials and structures Cachan : RILEM Publications SARL, 1968 22(1989), 3 vom: 01. Mai, Seite 163-169 (DE-627)356252612 (DE-600)2091922-0 1871-6873 nnns volume:22 year:1989 number:3 day:01 month:05 pages:163-169 https://dx.doi.org/10.1007/BF02472183 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_121 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_224 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2043 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2158 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2193 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2808 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4346 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 GBV_ILN_4753 AR 22 1989 3 01 05 163-169
spelling	10.1007/BF02472183 doi (DE-627)SPR020555121 (SPR)BF02472183-e DE-627 ger DE-627 rakwb eng Karlsson, S. verfasserin aut Gas chromatographic detection of volatile amines found in indoor air due to putrefactive degradation of casein-containing building materials 1989 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © RILEM 1989 Abstract The use of non-sterile casein in building materials, especially in self-levelling floor-topping compound (putty), led to various defects in buildings with these materials. Bubbles in the mattings, dark patches unevenly spread over the floor and a very unpleasant odour developed. The defects were commonly induced or accelerated if the humidity in the floor was high. Our earlier studies have concluded that the cause of these problems is due to the growth of alkalitolerantClostridia. The presence of volatile mono-amines in air samples taken in the buildings also confirms our early theories. Due to the high pH of the putty, amines formed in the topping compound will easily be emitted into the air. Some of the amines are commonly found in spent growth media ofClostridia as well as in head-space samples from bacterial suspensions. By the use of gas chromatography (GC) we have been able to detect triethylamine, pyrrolidine, di-iso-butylamine, 2-ethyl-hexylamine and n-octylamine in the air samples. Air sampling was carried out by impinging in weak acidic solutions and adsorption on silica gel. Along with the mono-amines, ammonia has also been detected. The sampling was carried out using Draeger Tubes, which also non-specifically indicate several volatile amines in addition to ammonia. The amount of amines recovered was well below official threshold limits. The amount was in the parts per billion (ppb) region, whereas official threshold limits are usually in the 1–25 parts per million (ppm) region. Pyrrolidine (dpeaa)DE-He213 Butylamine (dpeaa)DE-He213 Sulphuric Acid Solution (dpeaa)DE-He213 Volatile Organic Acid (dpeaa)DE-He213 Volatile Amine (dpeaa)DE-He213 Bánhidi, Z. G. aut Albertsson, A. -C. aut Enthalten in Materials and structures Cachan : RILEM Publications SARL, 1968 22(1989), 3 vom: 01. Mai, Seite 163-169 (DE-627)356252612 (DE-600)2091922-0 1871-6873 nnns volume:22 year:1989 number:3 day:01 month:05 pages:163-169 https://dx.doi.org/10.1007/BF02472183 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_121 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_224 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2043 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2158 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2193 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2808 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4346 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 GBV_ILN_4753 AR 22 1989 3 01 05 163-169
allfields_unstemmed	10.1007/BF02472183 doi (DE-627)SPR020555121 (SPR)BF02472183-e DE-627 ger DE-627 rakwb eng Karlsson, S. verfasserin aut Gas chromatographic detection of volatile amines found in indoor air due to putrefactive degradation of casein-containing building materials 1989 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © RILEM 1989 Abstract The use of non-sterile casein in building materials, especially in self-levelling floor-topping compound (putty), led to various defects in buildings with these materials. Bubbles in the mattings, dark patches unevenly spread over the floor and a very unpleasant odour developed. The defects were commonly induced or accelerated if the humidity in the floor was high. Our earlier studies have concluded that the cause of these problems is due to the growth of alkalitolerantClostridia. The presence of volatile mono-amines in air samples taken in the buildings also confirms our early theories. Due to the high pH of the putty, amines formed in the topping compound will easily be emitted into the air. Some of the amines are commonly found in spent growth media ofClostridia as well as in head-space samples from bacterial suspensions. By the use of gas chromatography (GC) we have been able to detect triethylamine, pyrrolidine, di-iso-butylamine, 2-ethyl-hexylamine and n-octylamine in the air samples. Air sampling was carried out by impinging in weak acidic solutions and adsorption on silica gel. Along with the mono-amines, ammonia has also been detected. The sampling was carried out using Draeger Tubes, which also non-specifically indicate several volatile amines in addition to ammonia. The amount of amines recovered was well below official threshold limits. The amount was in the parts per billion (ppb) region, whereas official threshold limits are usually in the 1–25 parts per million (ppm) region. Pyrrolidine (dpeaa)DE-He213 Butylamine (dpeaa)DE-He213 Sulphuric Acid Solution (dpeaa)DE-He213 Volatile Organic Acid (dpeaa)DE-He213 Volatile Amine (dpeaa)DE-He213 Bánhidi, Z. G. aut Albertsson, A. -C. aut Enthalten in Materials and structures Cachan : RILEM Publications SARL, 1968 22(1989), 3 vom: 01. Mai, Seite 163-169 (DE-627)356252612 (DE-600)2091922-0 1871-6873 nnns volume:22 year:1989 number:3 day:01 month:05 pages:163-169 https://dx.doi.org/10.1007/BF02472183 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_121 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_224 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2043 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2158 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2193 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2808 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4346 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 GBV_ILN_4753 AR 22 1989 3 01 05 163-169
allfieldsGer	10.1007/BF02472183 doi (DE-627)SPR020555121 (SPR)BF02472183-e DE-627 ger DE-627 rakwb eng Karlsson, S. verfasserin aut Gas chromatographic detection of volatile amines found in indoor air due to putrefactive degradation of casein-containing building materials 1989 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © RILEM 1989 Abstract The use of non-sterile casein in building materials, especially in self-levelling floor-topping compound (putty), led to various defects in buildings with these materials. Bubbles in the mattings, dark patches unevenly spread over the floor and a very unpleasant odour developed. The defects were commonly induced or accelerated if the humidity in the floor was high. Our earlier studies have concluded that the cause of these problems is due to the growth of alkalitolerantClostridia. The presence of volatile mono-amines in air samples taken in the buildings also confirms our early theories. Due to the high pH of the putty, amines formed in the topping compound will easily be emitted into the air. Some of the amines are commonly found in spent growth media ofClostridia as well as in head-space samples from bacterial suspensions. By the use of gas chromatography (GC) we have been able to detect triethylamine, pyrrolidine, di-iso-butylamine, 2-ethyl-hexylamine and n-octylamine in the air samples. Air sampling was carried out by impinging in weak acidic solutions and adsorption on silica gel. Along with the mono-amines, ammonia has also been detected. The sampling was carried out using Draeger Tubes, which also non-specifically indicate several volatile amines in addition to ammonia. The amount of amines recovered was well below official threshold limits. The amount was in the parts per billion (ppb) region, whereas official threshold limits are usually in the 1–25 parts per million (ppm) region. Pyrrolidine (dpeaa)DE-He213 Butylamine (dpeaa)DE-He213 Sulphuric Acid Solution (dpeaa)DE-He213 Volatile Organic Acid (dpeaa)DE-He213 Volatile Amine (dpeaa)DE-He213 Bánhidi, Z. G. aut Albertsson, A. -C. aut Enthalten in Materials and structures Cachan : RILEM Publications SARL, 1968 22(1989), 3 vom: 01. Mai, Seite 163-169 (DE-627)356252612 (DE-600)2091922-0 1871-6873 nnns volume:22 year:1989 number:3 day:01 month:05 pages:163-169 https://dx.doi.org/10.1007/BF02472183 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_121 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_224 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2043 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2158 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2193 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2808 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4346 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 GBV_ILN_4753 AR 22 1989 3 01 05 163-169
allfieldsSound	10.1007/BF02472183 doi (DE-627)SPR020555121 (SPR)BF02472183-e DE-627 ger DE-627 rakwb eng Karlsson, S. verfasserin aut Gas chromatographic detection of volatile amines found in indoor air due to putrefactive degradation of casein-containing building materials 1989 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © RILEM 1989 Abstract The use of non-sterile casein in building materials, especially in self-levelling floor-topping compound (putty), led to various defects in buildings with these materials. Bubbles in the mattings, dark patches unevenly spread over the floor and a very unpleasant odour developed. The defects were commonly induced or accelerated if the humidity in the floor was high. Our earlier studies have concluded that the cause of these problems is due to the growth of alkalitolerantClostridia. The presence of volatile mono-amines in air samples taken in the buildings also confirms our early theories. Due to the high pH of the putty, amines formed in the topping compound will easily be emitted into the air. Some of the amines are commonly found in spent growth media ofClostridia as well as in head-space samples from bacterial suspensions. By the use of gas chromatography (GC) we have been able to detect triethylamine, pyrrolidine, di-iso-butylamine, 2-ethyl-hexylamine and n-octylamine in the air samples. Air sampling was carried out by impinging in weak acidic solutions and adsorption on silica gel. Along with the mono-amines, ammonia has also been detected. The sampling was carried out using Draeger Tubes, which also non-specifically indicate several volatile amines in addition to ammonia. The amount of amines recovered was well below official threshold limits. The amount was in the parts per billion (ppb) region, whereas official threshold limits are usually in the 1–25 parts per million (ppm) region. Pyrrolidine (dpeaa)DE-He213 Butylamine (dpeaa)DE-He213 Sulphuric Acid Solution (dpeaa)DE-He213 Volatile Organic Acid (dpeaa)DE-He213 Volatile Amine (dpeaa)DE-He213 Bánhidi, Z. G. aut Albertsson, A. -C. aut Enthalten in Materials and structures Cachan : RILEM Publications SARL, 1968 22(1989), 3 vom: 01. Mai, Seite 163-169 (DE-627)356252612 (DE-600)2091922-0 1871-6873 nnns volume:22 year:1989 number:3 day:01 month:05 pages:163-169 https://dx.doi.org/10.1007/BF02472183 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_121 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_206 GBV_ILN_224 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_647 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2043 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2158 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2193 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_2808 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4346 GBV_ILN_4367 GBV_ILN_4393 GBV_ILN_4700 GBV_ILN_4753 AR 22 1989 3 01 05 163-169
language	English
source	Enthalten in Materials and structures 22(1989), 3 vom: 01. Mai, Seite 163-169 volume:22 year:1989 number:3 day:01 month:05 pages:163-169
sourceStr	Enthalten in Materials and structures 22(1989), 3 vom: 01. Mai, Seite 163-169 volume:22 year:1989 number:3 day:01 month:05 pages:163-169
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Pyrrolidine Butylamine Sulphuric Acid Solution Volatile Organic Acid Volatile Amine
isfreeaccess_bool	false
container_title	Materials and structures
authorswithroles_txt_mv	Karlsson, S. @@aut@@ Bánhidi, Z. G. @@aut@@ Albertsson, A. -C. @@aut@@
publishDateDaySort_date	1989-05-01T00:00:00Z
hierarchy_top_id	356252612
id	SPR020555121
language_de	englisch
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author	Karlsson, S.
spellingShingle	Karlsson, S. misc Pyrrolidine misc Butylamine misc Sulphuric Acid Solution misc Volatile Organic Acid misc Volatile Amine Gas chromatographic detection of volatile amines found in indoor air due to putrefactive degradation of casein-containing building materials
authorStr	Karlsson, S.
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topic_title	Gas chromatographic detection of volatile amines found in indoor air due to putrefactive degradation of casein-containing building materials Pyrrolidine (dpeaa)DE-He213 Butylamine (dpeaa)DE-He213 Sulphuric Acid Solution (dpeaa)DE-He213 Volatile Organic Acid (dpeaa)DE-He213 Volatile Amine (dpeaa)DE-He213
topic	misc Pyrrolidine misc Butylamine misc Sulphuric Acid Solution misc Volatile Organic Acid misc Volatile Amine
topic_unstemmed	misc Pyrrolidine misc Butylamine misc Sulphuric Acid Solution misc Volatile Organic Acid misc Volatile Amine
topic_browse	misc Pyrrolidine misc Butylamine misc Sulphuric Acid Solution misc Volatile Organic Acid misc Volatile Amine
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
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title	Gas chromatographic detection of volatile amines found in indoor air due to putrefactive degradation of casein-containing building materials
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title_full	Gas chromatographic detection of volatile amines found in indoor air due to putrefactive degradation of casein-containing building materials
author_sort	Karlsson, S.
journal	Materials and structures
journalStr	Materials and structures
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container_start_page	163
author_browse	Karlsson, S. Bánhidi, Z. G. Albertsson, A. -C.
container_volume	22
format_se	Elektronische Aufsätze
author-letter	Karlsson, S.
doi_str_mv	10.1007/BF02472183
title_sort	gas chromatographic detection of volatile amines found in indoor air due to putrefactive degradation of casein-containing building materials
title_auth	Gas chromatographic detection of volatile amines found in indoor air due to putrefactive degradation of casein-containing building materials
abstract	Abstract The use of non-sterile casein in building materials, especially in self-levelling floor-topping compound (putty), led to various defects in buildings with these materials. Bubbles in the mattings, dark patches unevenly spread over the floor and a very unpleasant odour developed. The defects were commonly induced or accelerated if the humidity in the floor was high. Our earlier studies have concluded that the cause of these problems is due to the growth of alkalitolerantClostridia. The presence of volatile mono-amines in air samples taken in the buildings also confirms our early theories. Due to the high pH of the putty, amines formed in the topping compound will easily be emitted into the air. Some of the amines are commonly found in spent growth media ofClostridia as well as in head-space samples from bacterial suspensions. By the use of gas chromatography (GC) we have been able to detect triethylamine, pyrrolidine, di-iso-butylamine, 2-ethyl-hexylamine and n-octylamine in the air samples. Air sampling was carried out by impinging in weak acidic solutions and adsorption on silica gel. Along with the mono-amines, ammonia has also been detected. The sampling was carried out using Draeger Tubes, which also non-specifically indicate several volatile amines in addition to ammonia. The amount of amines recovered was well below official threshold limits. The amount was in the parts per billion (ppb) region, whereas official threshold limits are usually in the 1–25 parts per million (ppm) region. © RILEM 1989
abstractGer	Abstract The use of non-sterile casein in building materials, especially in self-levelling floor-topping compound (putty), led to various defects in buildings with these materials. Bubbles in the mattings, dark patches unevenly spread over the floor and a very unpleasant odour developed. The defects were commonly induced or accelerated if the humidity in the floor was high. Our earlier studies have concluded that the cause of these problems is due to the growth of alkalitolerantClostridia. The presence of volatile mono-amines in air samples taken in the buildings also confirms our early theories. Due to the high pH of the putty, amines formed in the topping compound will easily be emitted into the air. Some of the amines are commonly found in spent growth media ofClostridia as well as in head-space samples from bacterial suspensions. By the use of gas chromatography (GC) we have been able to detect triethylamine, pyrrolidine, di-iso-butylamine, 2-ethyl-hexylamine and n-octylamine in the air samples. Air sampling was carried out by impinging in weak acidic solutions and adsorption on silica gel. Along with the mono-amines, ammonia has also been detected. The sampling was carried out using Draeger Tubes, which also non-specifically indicate several volatile amines in addition to ammonia. The amount of amines recovered was well below official threshold limits. The amount was in the parts per billion (ppb) region, whereas official threshold limits are usually in the 1–25 parts per million (ppm) region. © RILEM 1989
abstract_unstemmed	Abstract The use of non-sterile casein in building materials, especially in self-levelling floor-topping compound (putty), led to various defects in buildings with these materials. Bubbles in the mattings, dark patches unevenly spread over the floor and a very unpleasant odour developed. The defects were commonly induced or accelerated if the humidity in the floor was high. Our earlier studies have concluded that the cause of these problems is due to the growth of alkalitolerantClostridia. The presence of volatile mono-amines in air samples taken in the buildings also confirms our early theories. Due to the high pH of the putty, amines formed in the topping compound will easily be emitted into the air. Some of the amines are commonly found in spent growth media ofClostridia as well as in head-space samples from bacterial suspensions. By the use of gas chromatography (GC) we have been able to detect triethylamine, pyrrolidine, di-iso-butylamine, 2-ethyl-hexylamine and n-octylamine in the air samples. Air sampling was carried out by impinging in weak acidic solutions and adsorption on silica gel. Along with the mono-amines, ammonia has also been detected. The sampling was carried out using Draeger Tubes, which also non-specifically indicate several volatile amines in addition to ammonia. The amount of amines recovered was well below official threshold limits. The amount was in the parts per billion (ppb) region, whereas official threshold limits are usually in the 1–25 parts per million (ppm) region. © RILEM 1989
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title_short	Gas chromatographic detection of volatile amines found in indoor air due to putrefactive degradation of casein-containing building materials
url	https://dx.doi.org/10.1007/BF02472183
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author2	Bánhidi, Z. G. Albertsson, A. -C.
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doi_str	10.1007/BF02472183
up_date	2024-07-03T16:49:22.914Z
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Bubbles in the mattings, dark patches unevenly spread over the floor and a very unpleasant odour developed. The defects were commonly induced or accelerated if the humidity in the floor was high. Our earlier studies have concluded that the cause of these problems is due to the growth of alkalitolerantClostridia. The presence of volatile mono-amines in air samples taken in the buildings also confirms our early theories. Due to the high pH of the putty, amines formed in the topping compound will easily be emitted into the air. Some of the amines are commonly found in spent growth media ofClostridia as well as in head-space samples from bacterial suspensions. By the use of gas chromatography (GC) we have been able to detect triethylamine, pyrrolidine, di-iso-butylamine, 2-ethyl-hexylamine and n-octylamine in the air samples. Air sampling was carried out by impinging in weak acidic solutions and adsorption on silica gel. Along with the mono-amines, ammonia has also been detected. 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Gas chromatographic detection of volatile amines found in indoor air due to putrefactive degradation of casein-containing building materials

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