Potential and limits of FTIR methods for reclaimed asphalt characterisation
Abstract In recent years, as a result of both environmental policy and industrial economic strategy, the amount of asphalt pavement that has been recycled has risen dramatically. As a result of this, several international research projects have shown the need for improvements in reclaimed asphalt (R...
Ausführliche Beschreibung
Autor*in: |
Marsac, Paul [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
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2014 |
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Anmerkung: |
© RILEM 2014 |
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Übergeordnetes Werk: |
Enthalten in: Materials and structures - Cachan : RILEM Publications SARL, 1968, 47(2014), 8 vom: 23. Jan., Seite 1273-1286 |
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Übergeordnetes Werk: |
volume:47 ; year:2014 ; number:8 ; day:23 ; month:01 ; pages:1273-1286 |
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DOI / URN: |
10.1617/s11527-014-0248-0 |
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Katalog-ID: |
SPR020569246 |
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520 | |a Abstract In recent years, as a result of both environmental policy and industrial economic strategy, the amount of asphalt pavement that has been recycled has risen dramatically. As a result of this, several international research projects have shown the need for improvements in reclaimed asphalt (RA) characterisation to support these higher recycling rates. During the life of a pavement, as well as the structural damage induced by traffic, the intrinsic properties of asphaltic materials are affected through the oxidative ageing of the bituminous binder. The molecular changes associated with this oxidation can be monitored via variations in Fourier transform infrared (FTIR) spectra. Therefore, if the relationships between binder properties, such as penetration, softening point and complex shear modulus and the spectra parameters can be established, the characterisation of RA produced by the milling of old pavements can be greatly improved. However, the interpretation of oxidation parameters from these spectra is not straightforward, and many different techniques are used to calculate them in the asphalt community. This paper gives a brief overview of asphalt oxidation and the FTIR principle. It then presents the results from four different calculation methods for the oxidation parameters applied to a set of more than 100 spectra obtained during the RILEM TC-ATB-TG5 round robin test. From this study, it is obvious that the conclusions of the analysis performed on the same set of raw spectra can differ considerably according to the FTIR oxidation index calculation method adopted. Using the RILEM database, the potential links between a given ageing index and the physical properties are then evaluated. As a result of this study it can be concluded that ageing comparison through FTIR should be considered as relative and restricted for use in measurements at different ageing steps on the same type of initial mixture. For FTIR spectra to be comparable between different laboratories, harmonisation of the data acquisition procedures is needed. Also the different calculation methods of the oxidation indicators seem to reflect different physical properties. So a first step toward harmonisation would be to agree on the relevant physical properties actually needed for efficient RA characterisation. This could then lead to a common FTIR index calculation method, which would reflect the properties of interest. For this, additional research is needed to improve knowledge of the relationship between the chemical oxidative process of a binder and the evolution of its physical properties. | ||
650 | 4 | |a Reclaimed asphalt characterisation |7 (dpeaa)DE-He213 | |
650 | 4 | |a Asphalt recycling |7 (dpeaa)DE-He213 | |
650 | 4 | |a FTIR |7 (dpeaa)DE-He213 | |
650 | 4 | |a Asphalt ageing |7 (dpeaa)DE-He213 | |
650 | 4 | |a Asphalt oxidation |7 (dpeaa)DE-He213 | |
650 | 4 | |a Round-robin test |7 (dpeaa)DE-He213 | |
700 | 1 | |a Piérard, Nathalie |4 aut | |
700 | 1 | |a Porot, Laurent |4 aut | |
700 | 1 | |a Van den bergh, Wim |4 aut | |
700 | 1 | |a Grenfell, James |4 aut | |
700 | 1 | |a Mouillet, Virginie |4 aut | |
700 | 1 | |a Pouget, Simon |4 aut | |
700 | 1 | |a Besamusca, Jeroen |4 aut | |
700 | 1 | |a Farcas, Fabienne |4 aut | |
700 | 1 | |a Gabet, Thomas |4 aut | |
700 | 1 | |a Hugener, Martin |4 aut | |
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10.1617/s11527-014-0248-0 doi (DE-627)SPR020569246 (SPR)s11527-014-0248-0-e DE-627 ger DE-627 rakwb eng Marsac, Paul verfasserin aut Potential and limits of FTIR methods for reclaimed asphalt characterisation 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © RILEM 2014 Abstract In recent years, as a result of both environmental policy and industrial economic strategy, the amount of asphalt pavement that has been recycled has risen dramatically. As a result of this, several international research projects have shown the need for improvements in reclaimed asphalt (RA) characterisation to support these higher recycling rates. During the life of a pavement, as well as the structural damage induced by traffic, the intrinsic properties of asphaltic materials are affected through the oxidative ageing of the bituminous binder. The molecular changes associated with this oxidation can be monitored via variations in Fourier transform infrared (FTIR) spectra. Therefore, if the relationships between binder properties, such as penetration, softening point and complex shear modulus and the spectra parameters can be established, the characterisation of RA produced by the milling of old pavements can be greatly improved. However, the interpretation of oxidation parameters from these spectra is not straightforward, and many different techniques are used to calculate them in the asphalt community. This paper gives a brief overview of asphalt oxidation and the FTIR principle. It then presents the results from four different calculation methods for the oxidation parameters applied to a set of more than 100 spectra obtained during the RILEM TC-ATB-TG5 round robin test. From this study, it is obvious that the conclusions of the analysis performed on the same set of raw spectra can differ considerably according to the FTIR oxidation index calculation method adopted. Using the RILEM database, the potential links between a given ageing index and the physical properties are then evaluated. As a result of this study it can be concluded that ageing comparison through FTIR should be considered as relative and restricted for use in measurements at different ageing steps on the same type of initial mixture. For FTIR spectra to be comparable between different laboratories, harmonisation of the data acquisition procedures is needed. Also the different calculation methods of the oxidation indicators seem to reflect different physical properties. So a first step toward harmonisation would be to agree on the relevant physical properties actually needed for efficient RA characterisation. This could then lead to a common FTIR index calculation method, which would reflect the properties of interest. For this, additional research is needed to improve knowledge of the relationship between the chemical oxidative process of a binder and the evolution of its physical properties. Reclaimed asphalt characterisation (dpeaa)DE-He213 Asphalt recycling (dpeaa)DE-He213 FTIR (dpeaa)DE-He213 Asphalt ageing (dpeaa)DE-He213 Asphalt oxidation (dpeaa)DE-He213 Round-robin test (dpeaa)DE-He213 Piérard, Nathalie aut Porot, Laurent aut Van den bergh, Wim aut Grenfell, James aut Mouillet, Virginie aut Pouget, Simon aut Besamusca, Jeroen aut Farcas, Fabienne aut Gabet, Thomas aut Hugener, Martin aut Enthalten in Materials and structures Cachan : RILEM Publications SARL, 1968 47(2014), 8 vom: 23. Jan., Seite 1273-1286 (DE-627)356252612 (DE-600)2091922-0 1871-6873 nnns volume:47 year:2014 number:8 day:23 month:01 pages:1273-1286 https://dx.doi.org/10.1617/s11527-014-0248-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 47 2014 8 23 01 1273-1286 |
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10.1617/s11527-014-0248-0 doi (DE-627)SPR020569246 (SPR)s11527-014-0248-0-e DE-627 ger DE-627 rakwb eng Marsac, Paul verfasserin aut Potential and limits of FTIR methods for reclaimed asphalt characterisation 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © RILEM 2014 Abstract In recent years, as a result of both environmental policy and industrial economic strategy, the amount of asphalt pavement that has been recycled has risen dramatically. As a result of this, several international research projects have shown the need for improvements in reclaimed asphalt (RA) characterisation to support these higher recycling rates. During the life of a pavement, as well as the structural damage induced by traffic, the intrinsic properties of asphaltic materials are affected through the oxidative ageing of the bituminous binder. The molecular changes associated with this oxidation can be monitored via variations in Fourier transform infrared (FTIR) spectra. Therefore, if the relationships between binder properties, such as penetration, softening point and complex shear modulus and the spectra parameters can be established, the characterisation of RA produced by the milling of old pavements can be greatly improved. However, the interpretation of oxidation parameters from these spectra is not straightforward, and many different techniques are used to calculate them in the asphalt community. This paper gives a brief overview of asphalt oxidation and the FTIR principle. It then presents the results from four different calculation methods for the oxidation parameters applied to a set of more than 100 spectra obtained during the RILEM TC-ATB-TG5 round robin test. From this study, it is obvious that the conclusions of the analysis performed on the same set of raw spectra can differ considerably according to the FTIR oxidation index calculation method adopted. Using the RILEM database, the potential links between a given ageing index and the physical properties are then evaluated. As a result of this study it can be concluded that ageing comparison through FTIR should be considered as relative and restricted for use in measurements at different ageing steps on the same type of initial mixture. For FTIR spectra to be comparable between different laboratories, harmonisation of the data acquisition procedures is needed. Also the different calculation methods of the oxidation indicators seem to reflect different physical properties. So a first step toward harmonisation would be to agree on the relevant physical properties actually needed for efficient RA characterisation. This could then lead to a common FTIR index calculation method, which would reflect the properties of interest. For this, additional research is needed to improve knowledge of the relationship between the chemical oxidative process of a binder and the evolution of its physical properties. Reclaimed asphalt characterisation (dpeaa)DE-He213 Asphalt recycling (dpeaa)DE-He213 FTIR (dpeaa)DE-He213 Asphalt ageing (dpeaa)DE-He213 Asphalt oxidation (dpeaa)DE-He213 Round-robin test (dpeaa)DE-He213 Piérard, Nathalie aut Porot, Laurent aut Van den bergh, Wim aut Grenfell, James aut Mouillet, Virginie aut Pouget, Simon aut Besamusca, Jeroen aut Farcas, Fabienne aut Gabet, Thomas aut Hugener, Martin aut Enthalten in Materials and structures Cachan : RILEM Publications SARL, 1968 47(2014), 8 vom: 23. Jan., Seite 1273-1286 (DE-627)356252612 (DE-600)2091922-0 1871-6873 nnns volume:47 year:2014 number:8 day:23 month:01 pages:1273-1286 https://dx.doi.org/10.1617/s11527-014-0248-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 47 2014 8 23 01 1273-1286 |
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10.1617/s11527-014-0248-0 doi (DE-627)SPR020569246 (SPR)s11527-014-0248-0-e DE-627 ger DE-627 rakwb eng Marsac, Paul verfasserin aut Potential and limits of FTIR methods for reclaimed asphalt characterisation 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © RILEM 2014 Abstract In recent years, as a result of both environmental policy and industrial economic strategy, the amount of asphalt pavement that has been recycled has risen dramatically. As a result of this, several international research projects have shown the need for improvements in reclaimed asphalt (RA) characterisation to support these higher recycling rates. During the life of a pavement, as well as the structural damage induced by traffic, the intrinsic properties of asphaltic materials are affected through the oxidative ageing of the bituminous binder. The molecular changes associated with this oxidation can be monitored via variations in Fourier transform infrared (FTIR) spectra. Therefore, if the relationships between binder properties, such as penetration, softening point and complex shear modulus and the spectra parameters can be established, the characterisation of RA produced by the milling of old pavements can be greatly improved. However, the interpretation of oxidation parameters from these spectra is not straightforward, and many different techniques are used to calculate them in the asphalt community. This paper gives a brief overview of asphalt oxidation and the FTIR principle. It then presents the results from four different calculation methods for the oxidation parameters applied to a set of more than 100 spectra obtained during the RILEM TC-ATB-TG5 round robin test. From this study, it is obvious that the conclusions of the analysis performed on the same set of raw spectra can differ considerably according to the FTIR oxidation index calculation method adopted. Using the RILEM database, the potential links between a given ageing index and the physical properties are then evaluated. As a result of this study it can be concluded that ageing comparison through FTIR should be considered as relative and restricted for use in measurements at different ageing steps on the same type of initial mixture. For FTIR spectra to be comparable between different laboratories, harmonisation of the data acquisition procedures is needed. Also the different calculation methods of the oxidation indicators seem to reflect different physical properties. So a first step toward harmonisation would be to agree on the relevant physical properties actually needed for efficient RA characterisation. This could then lead to a common FTIR index calculation method, which would reflect the properties of interest. For this, additional research is needed to improve knowledge of the relationship between the chemical oxidative process of a binder and the evolution of its physical properties. Reclaimed asphalt characterisation (dpeaa)DE-He213 Asphalt recycling (dpeaa)DE-He213 FTIR (dpeaa)DE-He213 Asphalt ageing (dpeaa)DE-He213 Asphalt oxidation (dpeaa)DE-He213 Round-robin test (dpeaa)DE-He213 Piérard, Nathalie aut Porot, Laurent aut Van den bergh, Wim aut Grenfell, James aut Mouillet, Virginie aut Pouget, Simon aut Besamusca, Jeroen aut Farcas, Fabienne aut Gabet, Thomas aut Hugener, Martin aut Enthalten in Materials and structures Cachan : RILEM Publications SARL, 1968 47(2014), 8 vom: 23. Jan., Seite 1273-1286 (DE-627)356252612 (DE-600)2091922-0 1871-6873 nnns volume:47 year:2014 number:8 day:23 month:01 pages:1273-1286 https://dx.doi.org/10.1617/s11527-014-0248-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 47 2014 8 23 01 1273-1286 |
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10.1617/s11527-014-0248-0 doi (DE-627)SPR020569246 (SPR)s11527-014-0248-0-e DE-627 ger DE-627 rakwb eng Marsac, Paul verfasserin aut Potential and limits of FTIR methods for reclaimed asphalt characterisation 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © RILEM 2014 Abstract In recent years, as a result of both environmental policy and industrial economic strategy, the amount of asphalt pavement that has been recycled has risen dramatically. As a result of this, several international research projects have shown the need for improvements in reclaimed asphalt (RA) characterisation to support these higher recycling rates. During the life of a pavement, as well as the structural damage induced by traffic, the intrinsic properties of asphaltic materials are affected through the oxidative ageing of the bituminous binder. The molecular changes associated with this oxidation can be monitored via variations in Fourier transform infrared (FTIR) spectra. Therefore, if the relationships between binder properties, such as penetration, softening point and complex shear modulus and the spectra parameters can be established, the characterisation of RA produced by the milling of old pavements can be greatly improved. However, the interpretation of oxidation parameters from these spectra is not straightforward, and many different techniques are used to calculate them in the asphalt community. This paper gives a brief overview of asphalt oxidation and the FTIR principle. It then presents the results from four different calculation methods for the oxidation parameters applied to a set of more than 100 spectra obtained during the RILEM TC-ATB-TG5 round robin test. From this study, it is obvious that the conclusions of the analysis performed on the same set of raw spectra can differ considerably according to the FTIR oxidation index calculation method adopted. Using the RILEM database, the potential links between a given ageing index and the physical properties are then evaluated. As a result of this study it can be concluded that ageing comparison through FTIR should be considered as relative and restricted for use in measurements at different ageing steps on the same type of initial mixture. For FTIR spectra to be comparable between different laboratories, harmonisation of the data acquisition procedures is needed. Also the different calculation methods of the oxidation indicators seem to reflect different physical properties. So a first step toward harmonisation would be to agree on the relevant physical properties actually needed for efficient RA characterisation. This could then lead to a common FTIR index calculation method, which would reflect the properties of interest. For this, additional research is needed to improve knowledge of the relationship between the chemical oxidative process of a binder and the evolution of its physical properties. Reclaimed asphalt characterisation (dpeaa)DE-He213 Asphalt recycling (dpeaa)DE-He213 FTIR (dpeaa)DE-He213 Asphalt ageing (dpeaa)DE-He213 Asphalt oxidation (dpeaa)DE-He213 Round-robin test (dpeaa)DE-He213 Piérard, Nathalie aut Porot, Laurent aut Van den bergh, Wim aut Grenfell, James aut Mouillet, Virginie aut Pouget, Simon aut Besamusca, Jeroen aut Farcas, Fabienne aut Gabet, Thomas aut Hugener, Martin aut Enthalten in Materials and structures Cachan : RILEM Publications SARL, 1968 47(2014), 8 vom: 23. Jan., Seite 1273-1286 (DE-627)356252612 (DE-600)2091922-0 1871-6873 nnns volume:47 year:2014 number:8 day:23 month:01 pages:1273-1286 https://dx.doi.org/10.1617/s11527-014-0248-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 47 2014 8 23 01 1273-1286 |
allfieldsSound |
10.1617/s11527-014-0248-0 doi (DE-627)SPR020569246 (SPR)s11527-014-0248-0-e DE-627 ger DE-627 rakwb eng Marsac, Paul verfasserin aut Potential and limits of FTIR methods for reclaimed asphalt characterisation 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © RILEM 2014 Abstract In recent years, as a result of both environmental policy and industrial economic strategy, the amount of asphalt pavement that has been recycled has risen dramatically. As a result of this, several international research projects have shown the need for improvements in reclaimed asphalt (RA) characterisation to support these higher recycling rates. During the life of a pavement, as well as the structural damage induced by traffic, the intrinsic properties of asphaltic materials are affected through the oxidative ageing of the bituminous binder. The molecular changes associated with this oxidation can be monitored via variations in Fourier transform infrared (FTIR) spectra. Therefore, if the relationships between binder properties, such as penetration, softening point and complex shear modulus and the spectra parameters can be established, the characterisation of RA produced by the milling of old pavements can be greatly improved. However, the interpretation of oxidation parameters from these spectra is not straightforward, and many different techniques are used to calculate them in the asphalt community. This paper gives a brief overview of asphalt oxidation and the FTIR principle. It then presents the results from four different calculation methods for the oxidation parameters applied to a set of more than 100 spectra obtained during the RILEM TC-ATB-TG5 round robin test. From this study, it is obvious that the conclusions of the analysis performed on the same set of raw spectra can differ considerably according to the FTIR oxidation index calculation method adopted. Using the RILEM database, the potential links between a given ageing index and the physical properties are then evaluated. As a result of this study it can be concluded that ageing comparison through FTIR should be considered as relative and restricted for use in measurements at different ageing steps on the same type of initial mixture. For FTIR spectra to be comparable between different laboratories, harmonisation of the data acquisition procedures is needed. Also the different calculation methods of the oxidation indicators seem to reflect different physical properties. So a first step toward harmonisation would be to agree on the relevant physical properties actually needed for efficient RA characterisation. This could then lead to a common FTIR index calculation method, which would reflect the properties of interest. For this, additional research is needed to improve knowledge of the relationship between the chemical oxidative process of a binder and the evolution of its physical properties. Reclaimed asphalt characterisation (dpeaa)DE-He213 Asphalt recycling (dpeaa)DE-He213 FTIR (dpeaa)DE-He213 Asphalt ageing (dpeaa)DE-He213 Asphalt oxidation (dpeaa)DE-He213 Round-robin test (dpeaa)DE-He213 Piérard, Nathalie aut Porot, Laurent aut Van den bergh, Wim aut Grenfell, James aut Mouillet, Virginie aut Pouget, Simon aut Besamusca, Jeroen aut Farcas, Fabienne aut Gabet, Thomas aut Hugener, Martin aut Enthalten in Materials and structures Cachan : RILEM Publications SARL, 1968 47(2014), 8 vom: 23. Jan., Seite 1273-1286 (DE-627)356252612 (DE-600)2091922-0 1871-6873 nnns volume:47 year:2014 number:8 day:23 month:01 pages:1273-1286 https://dx.doi.org/10.1617/s11527-014-0248-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 47 2014 8 23 01 1273-1286 |
language |
English |
source |
Enthalten in Materials and structures 47(2014), 8 vom: 23. Jan., Seite 1273-1286 volume:47 year:2014 number:8 day:23 month:01 pages:1273-1286 |
sourceStr |
Enthalten in Materials and structures 47(2014), 8 vom: 23. Jan., Seite 1273-1286 volume:47 year:2014 number:8 day:23 month:01 pages:1273-1286 |
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Reclaimed asphalt characterisation Asphalt recycling FTIR Asphalt ageing Asphalt oxidation Round-robin test |
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Marsac, Paul @@aut@@ Piérard, Nathalie @@aut@@ Porot, Laurent @@aut@@ Van den bergh, Wim @@aut@@ Grenfell, James @@aut@@ Mouillet, Virginie @@aut@@ Pouget, Simon @@aut@@ Besamusca, Jeroen @@aut@@ Farcas, Fabienne @@aut@@ Gabet, Thomas @@aut@@ Hugener, Martin @@aut@@ |
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This paper gives a brief overview of asphalt oxidation and the FTIR principle. It then presents the results from four different calculation methods for the oxidation parameters applied to a set of more than 100 spectra obtained during the RILEM TC-ATB-TG5 round robin test. From this study, it is obvious that the conclusions of the analysis performed on the same set of raw spectra can differ considerably according to the FTIR oxidation index calculation method adopted. Using the RILEM database, the potential links between a given ageing index and the physical properties are then evaluated. As a result of this study it can be concluded that ageing comparison through FTIR should be considered as relative and restricted for use in measurements at different ageing steps on the same type of initial mixture. For FTIR spectra to be comparable between different laboratories, harmonisation of the data acquisition procedures is needed. 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Marsac, Paul |
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Marsac, Paul misc Reclaimed asphalt characterisation misc Asphalt recycling misc FTIR misc Asphalt ageing misc Asphalt oxidation misc Round-robin test Potential and limits of FTIR methods for reclaimed asphalt characterisation |
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Potential and limits of FTIR methods for reclaimed asphalt characterisation Reclaimed asphalt characterisation (dpeaa)DE-He213 Asphalt recycling (dpeaa)DE-He213 FTIR (dpeaa)DE-He213 Asphalt ageing (dpeaa)DE-He213 Asphalt oxidation (dpeaa)DE-He213 Round-robin test (dpeaa)DE-He213 |
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misc Reclaimed asphalt characterisation misc Asphalt recycling misc FTIR misc Asphalt ageing misc Asphalt oxidation misc Round-robin test |
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Potential and limits of FTIR methods for reclaimed asphalt characterisation |
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Potential and limits of FTIR methods for reclaimed asphalt characterisation |
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Materials and structures |
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Marsac, Paul Piérard, Nathalie Porot, Laurent Van den bergh, Wim Grenfell, James Mouillet, Virginie Pouget, Simon Besamusca, Jeroen Farcas, Fabienne Gabet, Thomas Hugener, Martin |
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potential and limits of ftir methods for reclaimed asphalt characterisation |
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Potential and limits of FTIR methods for reclaimed asphalt characterisation |
abstract |
Abstract In recent years, as a result of both environmental policy and industrial economic strategy, the amount of asphalt pavement that has been recycled has risen dramatically. As a result of this, several international research projects have shown the need for improvements in reclaimed asphalt (RA) characterisation to support these higher recycling rates. During the life of a pavement, as well as the structural damage induced by traffic, the intrinsic properties of asphaltic materials are affected through the oxidative ageing of the bituminous binder. The molecular changes associated with this oxidation can be monitored via variations in Fourier transform infrared (FTIR) spectra. Therefore, if the relationships between binder properties, such as penetration, softening point and complex shear modulus and the spectra parameters can be established, the characterisation of RA produced by the milling of old pavements can be greatly improved. However, the interpretation of oxidation parameters from these spectra is not straightforward, and many different techniques are used to calculate them in the asphalt community. This paper gives a brief overview of asphalt oxidation and the FTIR principle. It then presents the results from four different calculation methods for the oxidation parameters applied to a set of more than 100 spectra obtained during the RILEM TC-ATB-TG5 round robin test. From this study, it is obvious that the conclusions of the analysis performed on the same set of raw spectra can differ considerably according to the FTIR oxidation index calculation method adopted. Using the RILEM database, the potential links between a given ageing index and the physical properties are then evaluated. As a result of this study it can be concluded that ageing comparison through FTIR should be considered as relative and restricted for use in measurements at different ageing steps on the same type of initial mixture. For FTIR spectra to be comparable between different laboratories, harmonisation of the data acquisition procedures is needed. Also the different calculation methods of the oxidation indicators seem to reflect different physical properties. So a first step toward harmonisation would be to agree on the relevant physical properties actually needed for efficient RA characterisation. This could then lead to a common FTIR index calculation method, which would reflect the properties of interest. For this, additional research is needed to improve knowledge of the relationship between the chemical oxidative process of a binder and the evolution of its physical properties. © RILEM 2014 |
abstractGer |
Abstract In recent years, as a result of both environmental policy and industrial economic strategy, the amount of asphalt pavement that has been recycled has risen dramatically. As a result of this, several international research projects have shown the need for improvements in reclaimed asphalt (RA) characterisation to support these higher recycling rates. During the life of a pavement, as well as the structural damage induced by traffic, the intrinsic properties of asphaltic materials are affected through the oxidative ageing of the bituminous binder. The molecular changes associated with this oxidation can be monitored via variations in Fourier transform infrared (FTIR) spectra. Therefore, if the relationships between binder properties, such as penetration, softening point and complex shear modulus and the spectra parameters can be established, the characterisation of RA produced by the milling of old pavements can be greatly improved. However, the interpretation of oxidation parameters from these spectra is not straightforward, and many different techniques are used to calculate them in the asphalt community. This paper gives a brief overview of asphalt oxidation and the FTIR principle. It then presents the results from four different calculation methods for the oxidation parameters applied to a set of more than 100 spectra obtained during the RILEM TC-ATB-TG5 round robin test. From this study, it is obvious that the conclusions of the analysis performed on the same set of raw spectra can differ considerably according to the FTIR oxidation index calculation method adopted. Using the RILEM database, the potential links between a given ageing index and the physical properties are then evaluated. As a result of this study it can be concluded that ageing comparison through FTIR should be considered as relative and restricted for use in measurements at different ageing steps on the same type of initial mixture. For FTIR spectra to be comparable between different laboratories, harmonisation of the data acquisition procedures is needed. Also the different calculation methods of the oxidation indicators seem to reflect different physical properties. So a first step toward harmonisation would be to agree on the relevant physical properties actually needed for efficient RA characterisation. This could then lead to a common FTIR index calculation method, which would reflect the properties of interest. For this, additional research is needed to improve knowledge of the relationship between the chemical oxidative process of a binder and the evolution of its physical properties. © RILEM 2014 |
abstract_unstemmed |
Abstract In recent years, as a result of both environmental policy and industrial economic strategy, the amount of asphalt pavement that has been recycled has risen dramatically. As a result of this, several international research projects have shown the need for improvements in reclaimed asphalt (RA) characterisation to support these higher recycling rates. During the life of a pavement, as well as the structural damage induced by traffic, the intrinsic properties of asphaltic materials are affected through the oxidative ageing of the bituminous binder. The molecular changes associated with this oxidation can be monitored via variations in Fourier transform infrared (FTIR) spectra. Therefore, if the relationships between binder properties, such as penetration, softening point and complex shear modulus and the spectra parameters can be established, the characterisation of RA produced by the milling of old pavements can be greatly improved. However, the interpretation of oxidation parameters from these spectra is not straightforward, and many different techniques are used to calculate them in the asphalt community. This paper gives a brief overview of asphalt oxidation and the FTIR principle. It then presents the results from four different calculation methods for the oxidation parameters applied to a set of more than 100 spectra obtained during the RILEM TC-ATB-TG5 round robin test. From this study, it is obvious that the conclusions of the analysis performed on the same set of raw spectra can differ considerably according to the FTIR oxidation index calculation method adopted. Using the RILEM database, the potential links between a given ageing index and the physical properties are then evaluated. As a result of this study it can be concluded that ageing comparison through FTIR should be considered as relative and restricted for use in measurements at different ageing steps on the same type of initial mixture. For FTIR spectra to be comparable between different laboratories, harmonisation of the data acquisition procedures is needed. Also the different calculation methods of the oxidation indicators seem to reflect different physical properties. So a first step toward harmonisation would be to agree on the relevant physical properties actually needed for efficient RA characterisation. This could then lead to a common FTIR index calculation method, which would reflect the properties of interest. For this, additional research is needed to improve knowledge of the relationship between the chemical oxidative process of a binder and the evolution of its physical properties. © RILEM 2014 |
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container_issue |
8 |
title_short |
Potential and limits of FTIR methods for reclaimed asphalt characterisation |
url |
https://dx.doi.org/10.1617/s11527-014-0248-0 |
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author2 |
Piérard, Nathalie Porot, Laurent Van den bergh, Wim Grenfell, James Mouillet, Virginie Pouget, Simon Besamusca, Jeroen Farcas, Fabienne Gabet, Thomas Hugener, Martin |
author2Str |
Piérard, Nathalie Porot, Laurent Van den bergh, Wim Grenfell, James Mouillet, Virginie Pouget, Simon Besamusca, Jeroen Farcas, Fabienne Gabet, Thomas Hugener, Martin |
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doi_str |
10.1617/s11527-014-0248-0 |
up_date |
2024-07-03T16:55:02.205Z |
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score |
7.4016542 |