A comparative study of lithium and sodium salts in PAN-based ion conducting polymer electrolytes
Abstract The conducting polymer electrolyte films consisting of polyacrylonitrile (PAN) as the host polymer, lithium triflate ($ LiCF_{3} %$ SO_{3} $) and sodium triflate ($ NaCF_{3} %$ SO_{3} $) as inorganic salts were prepared by the solution-cast technique. The pure PAN film was prepared as a ref...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Osman, Zurina [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2010 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer-Verlag 2010 |
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| Übergeordnetes Werk: |
Enthalten in: Ionics - Berlin : Springer, 1995, 16(2010), 5 vom: 13. Jan., Seite 431-435 |
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| Übergeordnetes Werk: |
volume:16 ; year:2010 ; number:5 ; day:13 ; month:01 ; pages:431-435 |
| Links: |
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| DOI / URN: |
10.1007/s11581-009-0410-9 |
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| Katalog-ID: |
SPR020847572 |
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| 245 | 1 | 2 | |a A comparative study of lithium and sodium salts in PAN-based ion conducting polymer electrolytes |
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| 520 | |a Abstract The conducting polymer electrolyte films consisting of polyacrylonitrile (PAN) as the host polymer, lithium triflate ($ LiCF_{3} %$ SO_{3} $) and sodium triflate ($ NaCF_{3} %$ SO_{3} $) as inorganic salts were prepared by the solution-cast technique. The pure PAN film was prepared as a reference. The ionic conductivity for the films is characterized using impedance spectroscopy. The room temperature conductivity for the PAN + 26 wt.% $ LiCF_{3} %$ SO_{3} $ film and the PAN + 24 wt.% $ NaCF_{3} %$ SO_{3} $ film is 3.04 × $ 10^{−4} $ S $ cm^{−1} $ and 7.13 × $ 10^{−4} $ S $ cm^{−1} $, respectively. XRD studies show that the complexation that has occurred in the PAN containing salt films and complexes formed are amorphous. The FTIR spectra results confirmed the complexation has taken place between the salt and the polymer. These results correspond with surface morphology images obtained from SEM analysis. The conductivity–temperature dependence of the highest conducting film from PAN + $ LiCF_{3} %$ SO_{3} $ and PAN + $ NaCF_{3} %$ SO_{3} $ systems follows Arrhenius equation in the temperature range of 303 to 353 K. The PAN containing 24 wt.% $ LiCF_{3} %$ SO_{3} $ film has a higher ionic conductivity and lower activation energy compared to the PAN containing 26 wt.%$ LiCF_{3} %$ SO_{3} $ film. These results can be explained based on the Lewis acidity of the alkali ions, i.e., the interaction between $ Li^{+} $ ion and the nitrogen atom of PAN is stronger than that of $ Na^{+} $ ion. | ||
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| 650 | 4 | |a Polymer electrolytes |7 (dpeaa)DE-He213 | |
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| 700 | 1 | |a Md Isa, Khairul Bahiyah |4 aut | |
| 700 | 1 | |a Ahmad, Azhar |4 aut | |
| 700 | 1 | |a Othman, Lisani |4 aut | |
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10.1007/s11581-009-0410-9 doi (DE-627)SPR020847572 (SPR)s11581-009-0410-9-e DE-627 ger DE-627 rakwb eng Osman, Zurina verfasserin aut A comparative study of lithium and sodium salts in PAN-based ion conducting polymer electrolytes 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2010 Abstract The conducting polymer electrolyte films consisting of polyacrylonitrile (PAN) as the host polymer, lithium triflate ($ LiCF_{3} %$ SO_{3} $) and sodium triflate ($ NaCF_{3} %$ SO_{3} $) as inorganic salts were prepared by the solution-cast technique. The pure PAN film was prepared as a reference. The ionic conductivity for the films is characterized using impedance spectroscopy. The room temperature conductivity for the PAN + 26 wt.% $ LiCF_{3} %$ SO_{3} $ film and the PAN + 24 wt.% $ NaCF_{3} %$ SO_{3} $ film is 3.04 × $ 10^{−4} $ S $ cm^{−1} $ and 7.13 × $ 10^{−4} $ S $ cm^{−1} $, respectively. XRD studies show that the complexation that has occurred in the PAN containing salt films and complexes formed are amorphous. The FTIR spectra results confirmed the complexation has taken place between the salt and the polymer. These results correspond with surface morphology images obtained from SEM analysis. The conductivity–temperature dependence of the highest conducting film from PAN + $ LiCF_{3} %$ SO_{3} $ and PAN + $ NaCF_{3} %$ SO_{3} $ systems follows Arrhenius equation in the temperature range of 303 to 353 K. The PAN containing 24 wt.% $ LiCF_{3} %$ SO_{3} $ film has a higher ionic conductivity and lower activation energy compared to the PAN containing 26 wt.%$ LiCF_{3} %$ SO_{3} $ film. These results can be explained based on the Lewis acidity of the alkali ions, i.e., the interaction between $ Li^{+} $ ion and the nitrogen atom of PAN is stronger than that of $ Na^{+} $ ion. Conducting polymer (dpeaa)DE-He213 PAN (dpeaa)DE-He213 XRD (dpeaa)DE-He213 FTIR (dpeaa)DE-He213 Conductivity (dpeaa)DE-He213 SEM (dpeaa)DE-He213 Polymer electrolytes (dpeaa)DE-He213 Ionic conductivities (dpeaa)DE-He213 Electron microscopies (dpeaa)DE-He213 Md Isa, Khairul Bahiyah aut Ahmad, Azhar aut Othman, Lisani aut Enthalten in Ionics Berlin : Springer, 1995 16(2010), 5 vom: 13. Jan., Seite 431-435 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:16 year:2010 number:5 day:13 month:01 pages:431-435 https://dx.doi.org/10.1007/s11581-009-0410-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2010 5 13 01 431-435 |
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10.1007/s11581-009-0410-9 doi (DE-627)SPR020847572 (SPR)s11581-009-0410-9-e DE-627 ger DE-627 rakwb eng Osman, Zurina verfasserin aut A comparative study of lithium and sodium salts in PAN-based ion conducting polymer electrolytes 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2010 Abstract The conducting polymer electrolyte films consisting of polyacrylonitrile (PAN) as the host polymer, lithium triflate ($ LiCF_{3} %$ SO_{3} $) and sodium triflate ($ NaCF_{3} %$ SO_{3} $) as inorganic salts were prepared by the solution-cast technique. The pure PAN film was prepared as a reference. The ionic conductivity for the films is characterized using impedance spectroscopy. The room temperature conductivity for the PAN + 26 wt.% $ LiCF_{3} %$ SO_{3} $ film and the PAN + 24 wt.% $ NaCF_{3} %$ SO_{3} $ film is 3.04 × $ 10^{−4} $ S $ cm^{−1} $ and 7.13 × $ 10^{−4} $ S $ cm^{−1} $, respectively. XRD studies show that the complexation that has occurred in the PAN containing salt films and complexes formed are amorphous. The FTIR spectra results confirmed the complexation has taken place between the salt and the polymer. These results correspond with surface morphology images obtained from SEM analysis. The conductivity–temperature dependence of the highest conducting film from PAN + $ LiCF_{3} %$ SO_{3} $ and PAN + $ NaCF_{3} %$ SO_{3} $ systems follows Arrhenius equation in the temperature range of 303 to 353 K. The PAN containing 24 wt.% $ LiCF_{3} %$ SO_{3} $ film has a higher ionic conductivity and lower activation energy compared to the PAN containing 26 wt.%$ LiCF_{3} %$ SO_{3} $ film. These results can be explained based on the Lewis acidity of the alkali ions, i.e., the interaction between $ Li^{+} $ ion and the nitrogen atom of PAN is stronger than that of $ Na^{+} $ ion. Conducting polymer (dpeaa)DE-He213 PAN (dpeaa)DE-He213 XRD (dpeaa)DE-He213 FTIR (dpeaa)DE-He213 Conductivity (dpeaa)DE-He213 SEM (dpeaa)DE-He213 Polymer electrolytes (dpeaa)DE-He213 Ionic conductivities (dpeaa)DE-He213 Electron microscopies (dpeaa)DE-He213 Md Isa, Khairul Bahiyah aut Ahmad, Azhar aut Othman, Lisani aut Enthalten in Ionics Berlin : Springer, 1995 16(2010), 5 vom: 13. Jan., Seite 431-435 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:16 year:2010 number:5 day:13 month:01 pages:431-435 https://dx.doi.org/10.1007/s11581-009-0410-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2010 5 13 01 431-435 |
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10.1007/s11581-009-0410-9 doi (DE-627)SPR020847572 (SPR)s11581-009-0410-9-e DE-627 ger DE-627 rakwb eng Osman, Zurina verfasserin aut A comparative study of lithium and sodium salts in PAN-based ion conducting polymer electrolytes 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2010 Abstract The conducting polymer electrolyte films consisting of polyacrylonitrile (PAN) as the host polymer, lithium triflate ($ LiCF_{3} %$ SO_{3} $) and sodium triflate ($ NaCF_{3} %$ SO_{3} $) as inorganic salts were prepared by the solution-cast technique. The pure PAN film was prepared as a reference. The ionic conductivity for the films is characterized using impedance spectroscopy. The room temperature conductivity for the PAN + 26 wt.% $ LiCF_{3} %$ SO_{3} $ film and the PAN + 24 wt.% $ NaCF_{3} %$ SO_{3} $ film is 3.04 × $ 10^{−4} $ S $ cm^{−1} $ and 7.13 × $ 10^{−4} $ S $ cm^{−1} $, respectively. XRD studies show that the complexation that has occurred in the PAN containing salt films and complexes formed are amorphous. The FTIR spectra results confirmed the complexation has taken place between the salt and the polymer. These results correspond with surface morphology images obtained from SEM analysis. The conductivity–temperature dependence of the highest conducting film from PAN + $ LiCF_{3} %$ SO_{3} $ and PAN + $ NaCF_{3} %$ SO_{3} $ systems follows Arrhenius equation in the temperature range of 303 to 353 K. The PAN containing 24 wt.% $ LiCF_{3} %$ SO_{3} $ film has a higher ionic conductivity and lower activation energy compared to the PAN containing 26 wt.%$ LiCF_{3} %$ SO_{3} $ film. These results can be explained based on the Lewis acidity of the alkali ions, i.e., the interaction between $ Li^{+} $ ion and the nitrogen atom of PAN is stronger than that of $ Na^{+} $ ion. Conducting polymer (dpeaa)DE-He213 PAN (dpeaa)DE-He213 XRD (dpeaa)DE-He213 FTIR (dpeaa)DE-He213 Conductivity (dpeaa)DE-He213 SEM (dpeaa)DE-He213 Polymer electrolytes (dpeaa)DE-He213 Ionic conductivities (dpeaa)DE-He213 Electron microscopies (dpeaa)DE-He213 Md Isa, Khairul Bahiyah aut Ahmad, Azhar aut Othman, Lisani aut Enthalten in Ionics Berlin : Springer, 1995 16(2010), 5 vom: 13. Jan., Seite 431-435 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:16 year:2010 number:5 day:13 month:01 pages:431-435 https://dx.doi.org/10.1007/s11581-009-0410-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2010 5 13 01 431-435 |
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10.1007/s11581-009-0410-9 doi (DE-627)SPR020847572 (SPR)s11581-009-0410-9-e DE-627 ger DE-627 rakwb eng Osman, Zurina verfasserin aut A comparative study of lithium and sodium salts in PAN-based ion conducting polymer electrolytes 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2010 Abstract The conducting polymer electrolyte films consisting of polyacrylonitrile (PAN) as the host polymer, lithium triflate ($ LiCF_{3} %$ SO_{3} $) and sodium triflate ($ NaCF_{3} %$ SO_{3} $) as inorganic salts were prepared by the solution-cast technique. The pure PAN film was prepared as a reference. The ionic conductivity for the films is characterized using impedance spectroscopy. The room temperature conductivity for the PAN + 26 wt.% $ LiCF_{3} %$ SO_{3} $ film and the PAN + 24 wt.% $ NaCF_{3} %$ SO_{3} $ film is 3.04 × $ 10^{−4} $ S $ cm^{−1} $ and 7.13 × $ 10^{−4} $ S $ cm^{−1} $, respectively. XRD studies show that the complexation that has occurred in the PAN containing salt films and complexes formed are amorphous. The FTIR spectra results confirmed the complexation has taken place between the salt and the polymer. These results correspond with surface morphology images obtained from SEM analysis. The conductivity–temperature dependence of the highest conducting film from PAN + $ LiCF_{3} %$ SO_{3} $ and PAN + $ NaCF_{3} %$ SO_{3} $ systems follows Arrhenius equation in the temperature range of 303 to 353 K. The PAN containing 24 wt.% $ LiCF_{3} %$ SO_{3} $ film has a higher ionic conductivity and lower activation energy compared to the PAN containing 26 wt.%$ LiCF_{3} %$ SO_{3} $ film. These results can be explained based on the Lewis acidity of the alkali ions, i.e., the interaction between $ Li^{+} $ ion and the nitrogen atom of PAN is stronger than that of $ Na^{+} $ ion. Conducting polymer (dpeaa)DE-He213 PAN (dpeaa)DE-He213 XRD (dpeaa)DE-He213 FTIR (dpeaa)DE-He213 Conductivity (dpeaa)DE-He213 SEM (dpeaa)DE-He213 Polymer electrolytes (dpeaa)DE-He213 Ionic conductivities (dpeaa)DE-He213 Electron microscopies (dpeaa)DE-He213 Md Isa, Khairul Bahiyah aut Ahmad, Azhar aut Othman, Lisani aut Enthalten in Ionics Berlin : Springer, 1995 16(2010), 5 vom: 13. Jan., Seite 431-435 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:16 year:2010 number:5 day:13 month:01 pages:431-435 https://dx.doi.org/10.1007/s11581-009-0410-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2010 5 13 01 431-435 |
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10.1007/s11581-009-0410-9 doi (DE-627)SPR020847572 (SPR)s11581-009-0410-9-e DE-627 ger DE-627 rakwb eng Osman, Zurina verfasserin aut A comparative study of lithium and sodium salts in PAN-based ion conducting polymer electrolytes 2010 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2010 Abstract The conducting polymer electrolyte films consisting of polyacrylonitrile (PAN) as the host polymer, lithium triflate ($ LiCF_{3} %$ SO_{3} $) and sodium triflate ($ NaCF_{3} %$ SO_{3} $) as inorganic salts were prepared by the solution-cast technique. The pure PAN film was prepared as a reference. The ionic conductivity for the films is characterized using impedance spectroscopy. The room temperature conductivity for the PAN + 26 wt.% $ LiCF_{3} %$ SO_{3} $ film and the PAN + 24 wt.% $ NaCF_{3} %$ SO_{3} $ film is 3.04 × $ 10^{−4} $ S $ cm^{−1} $ and 7.13 × $ 10^{−4} $ S $ cm^{−1} $, respectively. XRD studies show that the complexation that has occurred in the PAN containing salt films and complexes formed are amorphous. The FTIR spectra results confirmed the complexation has taken place between the salt and the polymer. These results correspond with surface morphology images obtained from SEM analysis. The conductivity–temperature dependence of the highest conducting film from PAN + $ LiCF_{3} %$ SO_{3} $ and PAN + $ NaCF_{3} %$ SO_{3} $ systems follows Arrhenius equation in the temperature range of 303 to 353 K. The PAN containing 24 wt.% $ LiCF_{3} %$ SO_{3} $ film has a higher ionic conductivity and lower activation energy compared to the PAN containing 26 wt.%$ LiCF_{3} %$ SO_{3} $ film. These results can be explained based on the Lewis acidity of the alkali ions, i.e., the interaction between $ Li^{+} $ ion and the nitrogen atom of PAN is stronger than that of $ Na^{+} $ ion. Conducting polymer (dpeaa)DE-He213 PAN (dpeaa)DE-He213 XRD (dpeaa)DE-He213 FTIR (dpeaa)DE-He213 Conductivity (dpeaa)DE-He213 SEM (dpeaa)DE-He213 Polymer electrolytes (dpeaa)DE-He213 Ionic conductivities (dpeaa)DE-He213 Electron microscopies (dpeaa)DE-He213 Md Isa, Khairul Bahiyah aut Ahmad, Azhar aut Othman, Lisani aut Enthalten in Ionics Berlin : Springer, 1995 16(2010), 5 vom: 13. Jan., Seite 431-435 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:16 year:2010 number:5 day:13 month:01 pages:431-435 https://dx.doi.org/10.1007/s11581-009-0410-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 16 2010 5 13 01 431-435 |
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English |
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Enthalten in Ionics 16(2010), 5 vom: 13. Jan., Seite 431-435 volume:16 year:2010 number:5 day:13 month:01 pages:431-435 |
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Enthalten in Ionics 16(2010), 5 vom: 13. Jan., Seite 431-435 volume:16 year:2010 number:5 day:13 month:01 pages:431-435 |
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Conducting polymer PAN XRD FTIR Conductivity SEM Polymer electrolytes Ionic conductivities Electron microscopies |
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Ionics |
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Osman, Zurina @@aut@@ Md Isa, Khairul Bahiyah @@aut@@ Ahmad, Azhar @@aut@@ Othman, Lisani @@aut@@ |
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2010-01-13T00:00:00Z |
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The pure PAN film was prepared as a reference. The ionic conductivity for the films is characterized using impedance spectroscopy. The room temperature conductivity for the PAN + 26 wt.% $ LiCF_{3} %$ SO_{3} $ film and the PAN + 24 wt.% $ NaCF_{3} %$ SO_{3} $ film is 3.04 × $ 10^{−4} $ S $ cm^{−1} $ and 7.13 × $ 10^{−4} $ S $ cm^{−1} $, respectively. XRD studies show that the complexation that has occurred in the PAN containing salt films and complexes formed are amorphous. The FTIR spectra results confirmed the complexation has taken place between the salt and the polymer. These results correspond with surface morphology images obtained from SEM analysis. The conductivity–temperature dependence of the highest conducting film from PAN + $ LiCF_{3} %$ SO_{3} $ and PAN + $ NaCF_{3} %$ SO_{3} $ systems follows Arrhenius equation in the temperature range of 303 to 353 K. The PAN containing 24 wt.% $ LiCF_{3} %$ SO_{3} $ film has a higher ionic conductivity and lower activation energy compared to the PAN containing 26 wt.%$ LiCF_{3} %$ SO_{3} $ film. 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Osman, Zurina |
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Osman, Zurina misc Conducting polymer misc PAN misc XRD misc FTIR misc Conductivity misc SEM misc Polymer electrolytes misc Ionic conductivities misc Electron microscopies A comparative study of lithium and sodium salts in PAN-based ion conducting polymer electrolytes |
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A comparative study of lithium and sodium salts in PAN-based ion conducting polymer electrolytes Conducting polymer (dpeaa)DE-He213 PAN (dpeaa)DE-He213 XRD (dpeaa)DE-He213 FTIR (dpeaa)DE-He213 Conductivity (dpeaa)DE-He213 SEM (dpeaa)DE-He213 Polymer electrolytes (dpeaa)DE-He213 Ionic conductivities (dpeaa)DE-He213 Electron microscopies (dpeaa)DE-He213 |
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A comparative study of lithium and sodium salts in PAN-based ion conducting polymer electrolytes |
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Osman, Zurina Md Isa, Khairul Bahiyah Ahmad, Azhar Othman, Lisani |
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comparative study of lithium and sodium salts in pan-based ion conducting polymer electrolytes |
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A comparative study of lithium and sodium salts in PAN-based ion conducting polymer electrolytes |
| abstract |
Abstract The conducting polymer electrolyte films consisting of polyacrylonitrile (PAN) as the host polymer, lithium triflate ($ LiCF_{3} %$ SO_{3} $) and sodium triflate ($ NaCF_{3} %$ SO_{3} $) as inorganic salts were prepared by the solution-cast technique. The pure PAN film was prepared as a reference. The ionic conductivity for the films is characterized using impedance spectroscopy. The room temperature conductivity for the PAN + 26 wt.% $ LiCF_{3} %$ SO_{3} $ film and the PAN + 24 wt.% $ NaCF_{3} %$ SO_{3} $ film is 3.04 × $ 10^{−4} $ S $ cm^{−1} $ and 7.13 × $ 10^{−4} $ S $ cm^{−1} $, respectively. XRD studies show that the complexation that has occurred in the PAN containing salt films and complexes formed are amorphous. The FTIR spectra results confirmed the complexation has taken place between the salt and the polymer. These results correspond with surface morphology images obtained from SEM analysis. The conductivity–temperature dependence of the highest conducting film from PAN + $ LiCF_{3} %$ SO_{3} $ and PAN + $ NaCF_{3} %$ SO_{3} $ systems follows Arrhenius equation in the temperature range of 303 to 353 K. The PAN containing 24 wt.% $ LiCF_{3} %$ SO_{3} $ film has a higher ionic conductivity and lower activation energy compared to the PAN containing 26 wt.%$ LiCF_{3} %$ SO_{3} $ film. These results can be explained based on the Lewis acidity of the alkali ions, i.e., the interaction between $ Li^{+} $ ion and the nitrogen atom of PAN is stronger than that of $ Na^{+} $ ion. © Springer-Verlag 2010 |
| abstractGer |
Abstract The conducting polymer electrolyte films consisting of polyacrylonitrile (PAN) as the host polymer, lithium triflate ($ LiCF_{3} %$ SO_{3} $) and sodium triflate ($ NaCF_{3} %$ SO_{3} $) as inorganic salts were prepared by the solution-cast technique. The pure PAN film was prepared as a reference. The ionic conductivity for the films is characterized using impedance spectroscopy. The room temperature conductivity for the PAN + 26 wt.% $ LiCF_{3} %$ SO_{3} $ film and the PAN + 24 wt.% $ NaCF_{3} %$ SO_{3} $ film is 3.04 × $ 10^{−4} $ S $ cm^{−1} $ and 7.13 × $ 10^{−4} $ S $ cm^{−1} $, respectively. XRD studies show that the complexation that has occurred in the PAN containing salt films and complexes formed are amorphous. The FTIR spectra results confirmed the complexation has taken place between the salt and the polymer. These results correspond with surface morphology images obtained from SEM analysis. The conductivity–temperature dependence of the highest conducting film from PAN + $ LiCF_{3} %$ SO_{3} $ and PAN + $ NaCF_{3} %$ SO_{3} $ systems follows Arrhenius equation in the temperature range of 303 to 353 K. The PAN containing 24 wt.% $ LiCF_{3} %$ SO_{3} $ film has a higher ionic conductivity and lower activation energy compared to the PAN containing 26 wt.%$ LiCF_{3} %$ SO_{3} $ film. These results can be explained based on the Lewis acidity of the alkali ions, i.e., the interaction between $ Li^{+} $ ion and the nitrogen atom of PAN is stronger than that of $ Na^{+} $ ion. © Springer-Verlag 2010 |
| abstract_unstemmed |
Abstract The conducting polymer electrolyte films consisting of polyacrylonitrile (PAN) as the host polymer, lithium triflate ($ LiCF_{3} %$ SO_{3} $) and sodium triflate ($ NaCF_{3} %$ SO_{3} $) as inorganic salts were prepared by the solution-cast technique. The pure PAN film was prepared as a reference. The ionic conductivity for the films is characterized using impedance spectroscopy. The room temperature conductivity for the PAN + 26 wt.% $ LiCF_{3} %$ SO_{3} $ film and the PAN + 24 wt.% $ NaCF_{3} %$ SO_{3} $ film is 3.04 × $ 10^{−4} $ S $ cm^{−1} $ and 7.13 × $ 10^{−4} $ S $ cm^{−1} $, respectively. XRD studies show that the complexation that has occurred in the PAN containing salt films and complexes formed are amorphous. The FTIR spectra results confirmed the complexation has taken place between the salt and the polymer. These results correspond with surface morphology images obtained from SEM analysis. The conductivity–temperature dependence of the highest conducting film from PAN + $ LiCF_{3} %$ SO_{3} $ and PAN + $ NaCF_{3} %$ SO_{3} $ systems follows Arrhenius equation in the temperature range of 303 to 353 K. The PAN containing 24 wt.% $ LiCF_{3} %$ SO_{3} $ film has a higher ionic conductivity and lower activation energy compared to the PAN containing 26 wt.%$ LiCF_{3} %$ SO_{3} $ film. These results can be explained based on the Lewis acidity of the alkali ions, i.e., the interaction between $ Li^{+} $ ion and the nitrogen atom of PAN is stronger than that of $ Na^{+} $ ion. © Springer-Verlag 2010 |
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| title_short |
A comparative study of lithium and sodium salts in PAN-based ion conducting polymer electrolytes |
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https://dx.doi.org/10.1007/s11581-009-0410-9 |
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Md Isa, Khairul Bahiyah Ahmad, Azhar Othman, Lisani |
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10.1007/s11581-009-0410-9 |
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| score |
7.3996916 |