Electrochemical behavior of olivine-type $ LiMnPO_{4} $-based material in a mild aqueous electrolyte

Abstract Olivine-type pristine $ LiMnPO_{4} $ and nickel-substituted $ LiNi_{0.05} %$ Mn_{0.95} %$ PO_{4} $ electrode materials were synthesized via a sol–gel route, and characterized by X-ray diffraction (XRD), transmission electron microscopy, and X-ray fluorescence analysis techniques. Their elec...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Chen, Chen [verfasserIn] Yuan, Anbao Zhao, Hongbin Xu, Jiaqiang

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2012

Schlagwörter:	Aqueous lithium-ion battery Lithium manganese phosphate Nickel substitution Lithium insertion/extraction Electrochemical behavior

Anmerkung:	© Springer-Verlag 2012

Übergeordnetes Werk:	Enthalten in: Ionics - Berlin : Springer, 1995, 18(2012), 7 vom: 05. Feb., Seite 635-641
Übergeordnetes Werk:	volume:18 ; year:2012 ; number:7 ; day:05 ; month:02 ; pages:635-641

Links:	Volltext

DOI / URN:	10.1007/s11581-012-0677-0

Katalog-ID:	SPR020850328

Internformat


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245	1	0	\|a Electrochemical behavior of olivine-type $ LiMnPO_{4} $-based material in a mild aqueous electrolyte
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520			\|a Abstract Olivine-type pristine $ LiMnPO_{4} $ and nickel-substituted $ LiNi_{0.05} %$ Mn_{0.95} %$ PO_{4} $ electrode materials were synthesized via a sol–gel route, and characterized by X-ray diffraction (XRD), transmission electron microscopy, and X-ray fluorescence analysis techniques. Their electrochemical properties in 2 M $ Li_{2} %$ SO_{4} $ aqueous solution were investigated by cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge/discharge methods. Furthermore, X-ray absorption near edge structure analysis and XRD technique were employed to study the structural change of the pristine $ LiMnPO_{4} $ during the first charge/discharge cycle and the first-stage repeated charge/discharge activation cycles (increase in discharge capacity with increasing cycle number). The $ LiMnPO_{4} $-based electrodes were found to undergo a first-stage activation process with gradual increase in discharge capacity prior to capacity degradation in the experimental condition. Partial nickel substitution for manganese in $ LiMnPO_{4} $ can enhance the charge transfer reaction kinetics, and thereby increase the specific capacity of the $ LiMnPO_{4} $-based electrode.
650		4	\|a Aqueous lithium-ion battery \|7 (dpeaa)DE-He213
650		4	\|a Lithium manganese phosphate \|7 (dpeaa)DE-He213
650		4	\|a Nickel substitution \|7 (dpeaa)DE-He213
650		4	\|a Lithium insertion/extraction \|7 (dpeaa)DE-He213
650		4	\|a Electrochemical behavior \|7 (dpeaa)DE-He213
700	1		\|a Yuan, Anbao \|4 aut
700	1		\|a Zhao, Hongbin \|4 aut
700	1		\|a Xu, Jiaqiang \|4 aut
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publishDate	2012
allfields	10.1007/s11581-012-0677-0 doi (DE-627)SPR020850328 (SPR)s11581-012-0677-0-e DE-627 ger DE-627 rakwb eng Chen, Chen verfasserin aut Electrochemical behavior of olivine-type $ LiMnPO_{4} $-based material in a mild aqueous electrolyte 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2012 Abstract Olivine-type pristine $ LiMnPO_{4} $ and nickel-substituted $ LiNi_{0.05} %$ Mn_{0.95} %$ PO_{4} $ electrode materials were synthesized via a sol–gel route, and characterized by X-ray diffraction (XRD), transmission electron microscopy, and X-ray fluorescence analysis techniques. Their electrochemical properties in 2 M $ Li_{2} %$ SO_{4} $ aqueous solution were investigated by cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge/discharge methods. Furthermore, X-ray absorption near edge structure analysis and XRD technique were employed to study the structural change of the pristine $ LiMnPO_{4} $ during the first charge/discharge cycle and the first-stage repeated charge/discharge activation cycles (increase in discharge capacity with increasing cycle number). The $ LiMnPO_{4} $-based electrodes were found to undergo a first-stage activation process with gradual increase in discharge capacity prior to capacity degradation in the experimental condition. Partial nickel substitution for manganese in $ LiMnPO_{4} $ can enhance the charge transfer reaction kinetics, and thereby increase the specific capacity of the $ LiMnPO_{4} $-based electrode. Aqueous lithium-ion battery (dpeaa)DE-He213 Lithium manganese phosphate (dpeaa)DE-He213 Nickel substitution (dpeaa)DE-He213 Lithium insertion/extraction (dpeaa)DE-He213 Electrochemical behavior (dpeaa)DE-He213 Yuan, Anbao aut Zhao, Hongbin aut Xu, Jiaqiang aut Enthalten in Ionics Berlin : Springer, 1995 18(2012), 7 vom: 05. Feb., Seite 635-641 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:18 year:2012 number:7 day:05 month:02 pages:635-641 https://dx.doi.org/10.1007/s11581-012-0677-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 18 2012 7 05 02 635-641
spelling	10.1007/s11581-012-0677-0 doi (DE-627)SPR020850328 (SPR)s11581-012-0677-0-e DE-627 ger DE-627 rakwb eng Chen, Chen verfasserin aut Electrochemical behavior of olivine-type $ LiMnPO_{4} $-based material in a mild aqueous electrolyte 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2012 Abstract Olivine-type pristine $ LiMnPO_{4} $ and nickel-substituted $ LiNi_{0.05} %$ Mn_{0.95} %$ PO_{4} $ electrode materials were synthesized via a sol–gel route, and characterized by X-ray diffraction (XRD), transmission electron microscopy, and X-ray fluorescence analysis techniques. Their electrochemical properties in 2 M $ Li_{2} %$ SO_{4} $ aqueous solution were investigated by cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge/discharge methods. Furthermore, X-ray absorption near edge structure analysis and XRD technique were employed to study the structural change of the pristine $ LiMnPO_{4} $ during the first charge/discharge cycle and the first-stage repeated charge/discharge activation cycles (increase in discharge capacity with increasing cycle number). The $ LiMnPO_{4} $-based electrodes were found to undergo a first-stage activation process with gradual increase in discharge capacity prior to capacity degradation in the experimental condition. Partial nickel substitution for manganese in $ LiMnPO_{4} $ can enhance the charge transfer reaction kinetics, and thereby increase the specific capacity of the $ LiMnPO_{4} $-based electrode. Aqueous lithium-ion battery (dpeaa)DE-He213 Lithium manganese phosphate (dpeaa)DE-He213 Nickel substitution (dpeaa)DE-He213 Lithium insertion/extraction (dpeaa)DE-He213 Electrochemical behavior (dpeaa)DE-He213 Yuan, Anbao aut Zhao, Hongbin aut Xu, Jiaqiang aut Enthalten in Ionics Berlin : Springer, 1995 18(2012), 7 vom: 05. Feb., Seite 635-641 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:18 year:2012 number:7 day:05 month:02 pages:635-641 https://dx.doi.org/10.1007/s11581-012-0677-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 18 2012 7 05 02 635-641
allfields_unstemmed	10.1007/s11581-012-0677-0 doi (DE-627)SPR020850328 (SPR)s11581-012-0677-0-e DE-627 ger DE-627 rakwb eng Chen, Chen verfasserin aut Electrochemical behavior of olivine-type $ LiMnPO_{4} $-based material in a mild aqueous electrolyte 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2012 Abstract Olivine-type pristine $ LiMnPO_{4} $ and nickel-substituted $ LiNi_{0.05} %$ Mn_{0.95} %$ PO_{4} $ electrode materials were synthesized via a sol–gel route, and characterized by X-ray diffraction (XRD), transmission electron microscopy, and X-ray fluorescence analysis techniques. Their electrochemical properties in 2 M $ Li_{2} %$ SO_{4} $ aqueous solution were investigated by cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge/discharge methods. Furthermore, X-ray absorption near edge structure analysis and XRD technique were employed to study the structural change of the pristine $ LiMnPO_{4} $ during the first charge/discharge cycle and the first-stage repeated charge/discharge activation cycles (increase in discharge capacity with increasing cycle number). The $ LiMnPO_{4} $-based electrodes were found to undergo a first-stage activation process with gradual increase in discharge capacity prior to capacity degradation in the experimental condition. Partial nickel substitution for manganese in $ LiMnPO_{4} $ can enhance the charge transfer reaction kinetics, and thereby increase the specific capacity of the $ LiMnPO_{4} $-based electrode. Aqueous lithium-ion battery (dpeaa)DE-He213 Lithium manganese phosphate (dpeaa)DE-He213 Nickel substitution (dpeaa)DE-He213 Lithium insertion/extraction (dpeaa)DE-He213 Electrochemical behavior (dpeaa)DE-He213 Yuan, Anbao aut Zhao, Hongbin aut Xu, Jiaqiang aut Enthalten in Ionics Berlin : Springer, 1995 18(2012), 7 vom: 05. Feb., Seite 635-641 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:18 year:2012 number:7 day:05 month:02 pages:635-641 https://dx.doi.org/10.1007/s11581-012-0677-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 18 2012 7 05 02 635-641
allfieldsGer	10.1007/s11581-012-0677-0 doi (DE-627)SPR020850328 (SPR)s11581-012-0677-0-e DE-627 ger DE-627 rakwb eng Chen, Chen verfasserin aut Electrochemical behavior of olivine-type $ LiMnPO_{4} $-based material in a mild aqueous electrolyte 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2012 Abstract Olivine-type pristine $ LiMnPO_{4} $ and nickel-substituted $ LiNi_{0.05} %$ Mn_{0.95} %$ PO_{4} $ electrode materials were synthesized via a sol–gel route, and characterized by X-ray diffraction (XRD), transmission electron microscopy, and X-ray fluorescence analysis techniques. Their electrochemical properties in 2 M $ Li_{2} %$ SO_{4} $ aqueous solution were investigated by cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge/discharge methods. Furthermore, X-ray absorption near edge structure analysis and XRD technique were employed to study the structural change of the pristine $ LiMnPO_{4} $ during the first charge/discharge cycle and the first-stage repeated charge/discharge activation cycles (increase in discharge capacity with increasing cycle number). The $ LiMnPO_{4} $-based electrodes were found to undergo a first-stage activation process with gradual increase in discharge capacity prior to capacity degradation in the experimental condition. Partial nickel substitution for manganese in $ LiMnPO_{4} $ can enhance the charge transfer reaction kinetics, and thereby increase the specific capacity of the $ LiMnPO_{4} $-based electrode. Aqueous lithium-ion battery (dpeaa)DE-He213 Lithium manganese phosphate (dpeaa)DE-He213 Nickel substitution (dpeaa)DE-He213 Lithium insertion/extraction (dpeaa)DE-He213 Electrochemical behavior (dpeaa)DE-He213 Yuan, Anbao aut Zhao, Hongbin aut Xu, Jiaqiang aut Enthalten in Ionics Berlin : Springer, 1995 18(2012), 7 vom: 05. Feb., Seite 635-641 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:18 year:2012 number:7 day:05 month:02 pages:635-641 https://dx.doi.org/10.1007/s11581-012-0677-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 18 2012 7 05 02 635-641
allfieldsSound	10.1007/s11581-012-0677-0 doi (DE-627)SPR020850328 (SPR)s11581-012-0677-0-e DE-627 ger DE-627 rakwb eng Chen, Chen verfasserin aut Electrochemical behavior of olivine-type $ LiMnPO_{4} $-based material in a mild aqueous electrolyte 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2012 Abstract Olivine-type pristine $ LiMnPO_{4} $ and nickel-substituted $ LiNi_{0.05} %$ Mn_{0.95} %$ PO_{4} $ electrode materials were synthesized via a sol–gel route, and characterized by X-ray diffraction (XRD), transmission electron microscopy, and X-ray fluorescence analysis techniques. Their electrochemical properties in 2 M $ Li_{2} %$ SO_{4} $ aqueous solution were investigated by cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge/discharge methods. Furthermore, X-ray absorption near edge structure analysis and XRD technique were employed to study the structural change of the pristine $ LiMnPO_{4} $ during the first charge/discharge cycle and the first-stage repeated charge/discharge activation cycles (increase in discharge capacity with increasing cycle number). The $ LiMnPO_{4} $-based electrodes were found to undergo a first-stage activation process with gradual increase in discharge capacity prior to capacity degradation in the experimental condition. Partial nickel substitution for manganese in $ LiMnPO_{4} $ can enhance the charge transfer reaction kinetics, and thereby increase the specific capacity of the $ LiMnPO_{4} $-based electrode. Aqueous lithium-ion battery (dpeaa)DE-He213 Lithium manganese phosphate (dpeaa)DE-He213 Nickel substitution (dpeaa)DE-He213 Lithium insertion/extraction (dpeaa)DE-He213 Electrochemical behavior (dpeaa)DE-He213 Yuan, Anbao aut Zhao, Hongbin aut Xu, Jiaqiang aut Enthalten in Ionics Berlin : Springer, 1995 18(2012), 7 vom: 05. Feb., Seite 635-641 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:18 year:2012 number:7 day:05 month:02 pages:635-641 https://dx.doi.org/10.1007/s11581-012-0677-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 18 2012 7 05 02 635-641
language	English
source	Enthalten in Ionics 18(2012), 7 vom: 05. Feb., Seite 635-641 volume:18 year:2012 number:7 day:05 month:02 pages:635-641
sourceStr	Enthalten in Ionics 18(2012), 7 vom: 05. Feb., Seite 635-641 volume:18 year:2012 number:7 day:05 month:02 pages:635-641
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Aqueous lithium-ion battery Lithium manganese phosphate Nickel substitution Lithium insertion/extraction Electrochemical behavior
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container_title	Ionics
authorswithroles_txt_mv	Chen, Chen @@aut@@ Yuan, Anbao @@aut@@ Zhao, Hongbin @@aut@@ Xu, Jiaqiang @@aut@@
publishDateDaySort_date	2012-02-05T00:00:00Z
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language_de	englisch
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author	Chen, Chen
spellingShingle	Chen, Chen misc Aqueous lithium-ion battery misc Lithium manganese phosphate misc Nickel substitution misc Lithium insertion/extraction misc Electrochemical behavior Electrochemical behavior of olivine-type $ LiMnPO_{4} $-based material in a mild aqueous electrolyte
authorStr	Chen, Chen
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topic_title	Electrochemical behavior of olivine-type $ LiMnPO_{4} $-based material in a mild aqueous electrolyte Aqueous lithium-ion battery (dpeaa)DE-He213 Lithium manganese phosphate (dpeaa)DE-He213 Nickel substitution (dpeaa)DE-He213 Lithium insertion/extraction (dpeaa)DE-He213 Electrochemical behavior (dpeaa)DE-He213
topic	misc Aqueous lithium-ion battery misc Lithium manganese phosphate misc Nickel substitution misc Lithium insertion/extraction misc Electrochemical behavior
topic_unstemmed	misc Aqueous lithium-ion battery misc Lithium manganese phosphate misc Nickel substitution misc Lithium insertion/extraction misc Electrochemical behavior
topic_browse	misc Aqueous lithium-ion battery misc Lithium manganese phosphate misc Nickel substitution misc Lithium insertion/extraction misc Electrochemical behavior
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title	Electrochemical behavior of olivine-type $ LiMnPO_{4} $-based material in a mild aqueous electrolyte
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title_full	Electrochemical behavior of olivine-type $ LiMnPO_{4} $-based material in a mild aqueous electrolyte
author_sort	Chen, Chen
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author_browse	Chen, Chen Yuan, Anbao Zhao, Hongbin Xu, Jiaqiang
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title_sort	electrochemical behavior of olivine-type $ limnpo_{4} $-based material in a mild aqueous electrolyte
title_auth	Electrochemical behavior of olivine-type $ LiMnPO_{4} $-based material in a mild aqueous electrolyte
abstract	Abstract Olivine-type pristine $ LiMnPO_{4} $ and nickel-substituted $ LiNi_{0.05} %$ Mn_{0.95} %$ PO_{4} $ electrode materials were synthesized via a sol–gel route, and characterized by X-ray diffraction (XRD), transmission electron microscopy, and X-ray fluorescence analysis techniques. Their electrochemical properties in 2 M $ Li_{2} %$ SO_{4} $ aqueous solution were investigated by cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge/discharge methods. Furthermore, X-ray absorption near edge structure analysis and XRD technique were employed to study the structural change of the pristine $ LiMnPO_{4} $ during the first charge/discharge cycle and the first-stage repeated charge/discharge activation cycles (increase in discharge capacity with increasing cycle number). The $ LiMnPO_{4} $-based electrodes were found to undergo a first-stage activation process with gradual increase in discharge capacity prior to capacity degradation in the experimental condition. Partial nickel substitution for manganese in $ LiMnPO_{4} $ can enhance the charge transfer reaction kinetics, and thereby increase the specific capacity of the $ LiMnPO_{4} $-based electrode. © Springer-Verlag 2012
abstractGer	Abstract Olivine-type pristine $ LiMnPO_{4} $ and nickel-substituted $ LiNi_{0.05} %$ Mn_{0.95} %$ PO_{4} $ electrode materials were synthesized via a sol–gel route, and characterized by X-ray diffraction (XRD), transmission electron microscopy, and X-ray fluorescence analysis techniques. Their electrochemical properties in 2 M $ Li_{2} %$ SO_{4} $ aqueous solution were investigated by cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge/discharge methods. Furthermore, X-ray absorption near edge structure analysis and XRD technique were employed to study the structural change of the pristine $ LiMnPO_{4} $ during the first charge/discharge cycle and the first-stage repeated charge/discharge activation cycles (increase in discharge capacity with increasing cycle number). The $ LiMnPO_{4} $-based electrodes were found to undergo a first-stage activation process with gradual increase in discharge capacity prior to capacity degradation in the experimental condition. Partial nickel substitution for manganese in $ LiMnPO_{4} $ can enhance the charge transfer reaction kinetics, and thereby increase the specific capacity of the $ LiMnPO_{4} $-based electrode. © Springer-Verlag 2012
abstract_unstemmed	Abstract Olivine-type pristine $ LiMnPO_{4} $ and nickel-substituted $ LiNi_{0.05} %$ Mn_{0.95} %$ PO_{4} $ electrode materials were synthesized via a sol–gel route, and characterized by X-ray diffraction (XRD), transmission electron microscopy, and X-ray fluorescence analysis techniques. Their electrochemical properties in 2 M $ Li_{2} %$ SO_{4} $ aqueous solution were investigated by cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge/discharge methods. Furthermore, X-ray absorption near edge structure analysis and XRD technique were employed to study the structural change of the pristine $ LiMnPO_{4} $ during the first charge/discharge cycle and the first-stage repeated charge/discharge activation cycles (increase in discharge capacity with increasing cycle number). The $ LiMnPO_{4} $-based electrodes were found to undergo a first-stage activation process with gradual increase in discharge capacity prior to capacity degradation in the experimental condition. Partial nickel substitution for manganese in $ LiMnPO_{4} $ can enhance the charge transfer reaction kinetics, and thereby increase the specific capacity of the $ LiMnPO_{4} $-based electrode. © Springer-Verlag 2012
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container_issue	7
title_short	Electrochemical behavior of olivine-type $ LiMnPO_{4} $-based material in a mild aqueous electrolyte
url	https://dx.doi.org/10.1007/s11581-012-0677-0
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author2	Yuan, Anbao Zhao, Hongbin Xu, Jiaqiang
author2Str	Yuan, Anbao Zhao, Hongbin Xu, Jiaqiang
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doi_str	10.1007/s11581-012-0677-0
up_date	2024-07-03T18:39:12.031Z
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Electrochemical behavior of olivine-type $ LiMnPO_{4} $-based material in a mild aqueous electrolyte

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