Transport numbers in the molten system NaF–KF–$ AlF_{3} $–$ Al_{2} %$ O_{3} $

Abstract Transport numbers in the molten system NaF–KF–$ AlF_{3} $ ($ Al_{2} %$ O_{3} $, $ CaF_{2} $) were investigated by the Hittorf method. It was confirmed that in molten cryolite, $ Na_{3} %$ AlF_{6} $, 1,010 °C, the current is transported almost exclusively by the $ Na^{+} $ cations (t($ Na^{+...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Híveš, Ján [verfasserIn] Fellner, Pavel Thonstad, Jomar

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2012

Schlagwörter:	Molten cryolite Charge transport Acid bath BN cell

Anmerkung:	© Springer-Verlag 2012

Übergeordnetes Werk:	Enthalten in: Ionics - Berlin : Springer, 1995, 19(2012), 2 vom: 26. Mai, Seite 315-319
Übergeordnetes Werk:	volume:19 ; year:2012 ; number:2 ; day:26 ; month:05 ; pages:315-319

Links:	Volltext

DOI / URN:	10.1007/s11581-012-0736-6

Katalog-ID:	SPR020851715

Internformat


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520			\|a Abstract Transport numbers in the molten system NaF–KF–$ AlF_{3} $ ($ Al_{2} %$ O_{3} $, $ CaF_{2} $) were investigated by the Hittorf method. It was confirmed that in molten cryolite, $ Na_{3} %$ AlF_{6} $, 1,010 °C, the current is transported almost exclusively by the $ Na^{+} $ cations (t($ Na^{+} $) = 0.99). When $ AlF_{3} $ was added to a $ Na_{3} %$ AlF_{6} $ melt, the transport number of sodium cations decreased to 0.74 at the composition corresponding to $ NaAlF_{4} $. In molten $ K_{3} %$ AlF_{6} $, the transport number of $ K^{+} $ cations equals 0.836 at 1,005 °C. In melts containing both $ Na^{+} $ and $ K^{+} $, the cations contribute to the charge transport approximately in the ratio of the squares of their ionic radii. When 5 mass % of $ CaF_{2} $ was added to the molten NaF–KF–$ AlF_{3} $ system, it remarkably influenced the transport numbers of potassium and fluoride anions.
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650		4	\|a Charge transport \|7 (dpeaa)DE-He213
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912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_39
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_101
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2116
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2119
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2144
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2188
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2232
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2446
912			\|a GBV_ILN_2470
912			\|a GBV_ILN_2472
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_2548
912			\|a GBV_ILN_4012
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4046
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4126
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4246
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4336
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
912			\|a GBV_ILN_4700
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952			\|d 19 \|j 2012 \|e 2 \|b 26 \|c 05 \|h 315-319

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matchkey_str	article:18620760:2012----::rnprnmesnhmlessenf
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publishDate	2012
allfields	10.1007/s11581-012-0736-6 doi (DE-627)SPR020851715 (SPR)s11581-012-0736-6-e DE-627 ger DE-627 rakwb eng Híveš, Ján verfasserin aut Transport numbers in the molten system NaF–KF–$ AlF_{3} $–$ Al_{2} %$ O_{3} $ 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2012 Abstract Transport numbers in the molten system NaF–KF–$ AlF_{3} $ ($ Al_{2} %$ O_{3} $, $ CaF_{2} $) were investigated by the Hittorf method. It was confirmed that in molten cryolite, $ Na_{3} %$ AlF_{6} $, 1,010 °C, the current is transported almost exclusively by the $ Na^{+} $ cations (t($ Na^{+} $) = 0.99). When $ AlF_{3} $ was added to a $ Na_{3} %$ AlF_{6} $ melt, the transport number of sodium cations decreased to 0.74 at the composition corresponding to $ NaAlF_{4} $. In molten $ K_{3} %$ AlF_{6} $, the transport number of $ K^{+} $ cations equals 0.836 at 1,005 °C. In melts containing both $ Na^{+} $ and $ K^{+} $, the cations contribute to the charge transport approximately in the ratio of the squares of their ionic radii. When 5 mass % of $ CaF_{2} $ was added to the molten NaF–KF–$ AlF_{3} $ system, it remarkably influenced the transport numbers of potassium and fluoride anions. Molten cryolite (dpeaa)DE-He213 Charge transport (dpeaa)DE-He213 Acid bath (dpeaa)DE-He213 BN cell (dpeaa)DE-He213 Fellner, Pavel aut Thonstad, Jomar aut Enthalten in Ionics Berlin : Springer, 1995 19(2012), 2 vom: 26. Mai, Seite 315-319 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:19 year:2012 number:2 day:26 month:05 pages:315-319 https://dx.doi.org/10.1007/s11581-012-0736-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 19 2012 2 26 05 315-319
spelling	10.1007/s11581-012-0736-6 doi (DE-627)SPR020851715 (SPR)s11581-012-0736-6-e DE-627 ger DE-627 rakwb eng Híveš, Ján verfasserin aut Transport numbers in the molten system NaF–KF–$ AlF_{3} $–$ Al_{2} %$ O_{3} $ 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2012 Abstract Transport numbers in the molten system NaF–KF–$ AlF_{3} $ ($ Al_{2} %$ O_{3} $, $ CaF_{2} $) were investigated by the Hittorf method. It was confirmed that in molten cryolite, $ Na_{3} %$ AlF_{6} $, 1,010 °C, the current is transported almost exclusively by the $ Na^{+} $ cations (t($ Na^{+} $) = 0.99). When $ AlF_{3} $ was added to a $ Na_{3} %$ AlF_{6} $ melt, the transport number of sodium cations decreased to 0.74 at the composition corresponding to $ NaAlF_{4} $. In molten $ K_{3} %$ AlF_{6} $, the transport number of $ K^{+} $ cations equals 0.836 at 1,005 °C. In melts containing both $ Na^{+} $ and $ K^{+} $, the cations contribute to the charge transport approximately in the ratio of the squares of their ionic radii. When 5 mass % of $ CaF_{2} $ was added to the molten NaF–KF–$ AlF_{3} $ system, it remarkably influenced the transport numbers of potassium and fluoride anions. Molten cryolite (dpeaa)DE-He213 Charge transport (dpeaa)DE-He213 Acid bath (dpeaa)DE-He213 BN cell (dpeaa)DE-He213 Fellner, Pavel aut Thonstad, Jomar aut Enthalten in Ionics Berlin : Springer, 1995 19(2012), 2 vom: 26. Mai, Seite 315-319 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:19 year:2012 number:2 day:26 month:05 pages:315-319 https://dx.doi.org/10.1007/s11581-012-0736-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 19 2012 2 26 05 315-319
allfields_unstemmed	10.1007/s11581-012-0736-6 doi (DE-627)SPR020851715 (SPR)s11581-012-0736-6-e DE-627 ger DE-627 rakwb eng Híveš, Ján verfasserin aut Transport numbers in the molten system NaF–KF–$ AlF_{3} $–$ Al_{2} %$ O_{3} $ 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2012 Abstract Transport numbers in the molten system NaF–KF–$ AlF_{3} $ ($ Al_{2} %$ O_{3} $, $ CaF_{2} $) were investigated by the Hittorf method. It was confirmed that in molten cryolite, $ Na_{3} %$ AlF_{6} $, 1,010 °C, the current is transported almost exclusively by the $ Na^{+} $ cations (t($ Na^{+} $) = 0.99). When $ AlF_{3} $ was added to a $ Na_{3} %$ AlF_{6} $ melt, the transport number of sodium cations decreased to 0.74 at the composition corresponding to $ NaAlF_{4} $. In molten $ K_{3} %$ AlF_{6} $, the transport number of $ K^{+} $ cations equals 0.836 at 1,005 °C. In melts containing both $ Na^{+} $ and $ K^{+} $, the cations contribute to the charge transport approximately in the ratio of the squares of their ionic radii. When 5 mass % of $ CaF_{2} $ was added to the molten NaF–KF–$ AlF_{3} $ system, it remarkably influenced the transport numbers of potassium and fluoride anions. Molten cryolite (dpeaa)DE-He213 Charge transport (dpeaa)DE-He213 Acid bath (dpeaa)DE-He213 BN cell (dpeaa)DE-He213 Fellner, Pavel aut Thonstad, Jomar aut Enthalten in Ionics Berlin : Springer, 1995 19(2012), 2 vom: 26. Mai, Seite 315-319 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:19 year:2012 number:2 day:26 month:05 pages:315-319 https://dx.doi.org/10.1007/s11581-012-0736-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 19 2012 2 26 05 315-319
allfieldsGer	10.1007/s11581-012-0736-6 doi (DE-627)SPR020851715 (SPR)s11581-012-0736-6-e DE-627 ger DE-627 rakwb eng Híveš, Ján verfasserin aut Transport numbers in the molten system NaF–KF–$ AlF_{3} $–$ Al_{2} %$ O_{3} $ 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2012 Abstract Transport numbers in the molten system NaF–KF–$ AlF_{3} $ ($ Al_{2} %$ O_{3} $, $ CaF_{2} $) were investigated by the Hittorf method. It was confirmed that in molten cryolite, $ Na_{3} %$ AlF_{6} $, 1,010 °C, the current is transported almost exclusively by the $ Na^{+} $ cations (t($ Na^{+} $) = 0.99). When $ AlF_{3} $ was added to a $ Na_{3} %$ AlF_{6} $ melt, the transport number of sodium cations decreased to 0.74 at the composition corresponding to $ NaAlF_{4} $. In molten $ K_{3} %$ AlF_{6} $, the transport number of $ K^{+} $ cations equals 0.836 at 1,005 °C. In melts containing both $ Na^{+} $ and $ K^{+} $, the cations contribute to the charge transport approximately in the ratio of the squares of their ionic radii. When 5 mass % of $ CaF_{2} $ was added to the molten NaF–KF–$ AlF_{3} $ system, it remarkably influenced the transport numbers of potassium and fluoride anions. Molten cryolite (dpeaa)DE-He213 Charge transport (dpeaa)DE-He213 Acid bath (dpeaa)DE-He213 BN cell (dpeaa)DE-He213 Fellner, Pavel aut Thonstad, Jomar aut Enthalten in Ionics Berlin : Springer, 1995 19(2012), 2 vom: 26. Mai, Seite 315-319 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:19 year:2012 number:2 day:26 month:05 pages:315-319 https://dx.doi.org/10.1007/s11581-012-0736-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 19 2012 2 26 05 315-319
allfieldsSound	10.1007/s11581-012-0736-6 doi (DE-627)SPR020851715 (SPR)s11581-012-0736-6-e DE-627 ger DE-627 rakwb eng Híveš, Ján verfasserin aut Transport numbers in the molten system NaF–KF–$ AlF_{3} $–$ Al_{2} %$ O_{3} $ 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2012 Abstract Transport numbers in the molten system NaF–KF–$ AlF_{3} $ ($ Al_{2} %$ O_{3} $, $ CaF_{2} $) were investigated by the Hittorf method. It was confirmed that in molten cryolite, $ Na_{3} %$ AlF_{6} $, 1,010 °C, the current is transported almost exclusively by the $ Na^{+} $ cations (t($ Na^{+} $) = 0.99). When $ AlF_{3} $ was added to a $ Na_{3} %$ AlF_{6} $ melt, the transport number of sodium cations decreased to 0.74 at the composition corresponding to $ NaAlF_{4} $. In molten $ K_{3} %$ AlF_{6} $, the transport number of $ K^{+} $ cations equals 0.836 at 1,005 °C. In melts containing both $ Na^{+} $ and $ K^{+} $, the cations contribute to the charge transport approximately in the ratio of the squares of their ionic radii. When 5 mass % of $ CaF_{2} $ was added to the molten NaF–KF–$ AlF_{3} $ system, it remarkably influenced the transport numbers of potassium and fluoride anions. Molten cryolite (dpeaa)DE-He213 Charge transport (dpeaa)DE-He213 Acid bath (dpeaa)DE-He213 BN cell (dpeaa)DE-He213 Fellner, Pavel aut Thonstad, Jomar aut Enthalten in Ionics Berlin : Springer, 1995 19(2012), 2 vom: 26. Mai, Seite 315-319 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:19 year:2012 number:2 day:26 month:05 pages:315-319 https://dx.doi.org/10.1007/s11581-012-0736-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 19 2012 2 26 05 315-319
language	English
source	Enthalten in Ionics 19(2012), 2 vom: 26. Mai, Seite 315-319 volume:19 year:2012 number:2 day:26 month:05 pages:315-319
sourceStr	Enthalten in Ionics 19(2012), 2 vom: 26. Mai, Seite 315-319 volume:19 year:2012 number:2 day:26 month:05 pages:315-319
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Molten cryolite Charge transport Acid bath BN cell
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container_title	Ionics
authorswithroles_txt_mv	Híveš, Ján @@aut@@ Fellner, Pavel @@aut@@ Thonstad, Jomar @@aut@@
publishDateDaySort_date	2012-05-26T00:00:00Z
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It was confirmed that in molten cryolite, $ Na_{3} %$ AlF_{6} $, 1,010 °C, the current is transported almost exclusively by the $ Na^{+} $ cations (t($ Na^{+} $) = 0.99). When $ AlF_{3} $ was added to a $ Na_{3} %$ AlF_{6} $ melt, the transport number of sodium cations decreased to 0.74 at the composition corresponding to $ NaAlF_{4} $. In molten $ K_{3} %$ AlF_{6} $, the transport number of $ K^{+} $ cations equals 0.836 at 1,005 °C. In melts containing both $ Na^{+} $ and $ K^{+} $, the cations contribute to the charge transport approximately in the ratio of the squares of their ionic radii. 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author	Híveš, Ján
spellingShingle	Híveš, Ján misc Molten cryolite misc Charge transport misc Acid bath misc BN cell Transport numbers in the molten system NaF–KF–$ AlF_{3} $–$ Al_{2} %$ O_{3} $
authorStr	Híveš, Ján
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topic_title	Transport numbers in the molten system NaF–KF–$ AlF_{3} $–$ Al_{2} %$ O_{3} $ Molten cryolite (dpeaa)DE-He213 Charge transport (dpeaa)DE-He213 Acid bath (dpeaa)DE-He213 BN cell (dpeaa)DE-He213
topic	misc Molten cryolite misc Charge transport misc Acid bath misc BN cell
topic_unstemmed	misc Molten cryolite misc Charge transport misc Acid bath misc BN cell
topic_browse	misc Molten cryolite misc Charge transport misc Acid bath misc BN cell
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title	Transport numbers in the molten system NaF–KF–$ AlF_{3} $–$ Al_{2} %$ O_{3} $
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title_full	Transport numbers in the molten system NaF–KF–$ AlF_{3} $–$ Al_{2} %$ O_{3} $
author_sort	Híveš, Ján
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author-letter	Híveš, Ján
doi_str_mv	10.1007/s11581-012-0736-6
title_sort	transport numbers in the molten system naf–kf–$ alf_{3} $–$ al_{2} %$ o_{3} $
title_auth	Transport numbers in the molten system NaF–KF–$ AlF_{3} $–$ Al_{2} %$ O_{3} $
abstract	Abstract Transport numbers in the molten system NaF–KF–$ AlF_{3} $ ($ Al_{2} %$ O_{3} $, $ CaF_{2} $) were investigated by the Hittorf method. It was confirmed that in molten cryolite, $ Na_{3} %$ AlF_{6} $, 1,010 °C, the current is transported almost exclusively by the $ Na^{+} $ cations (t($ Na^{+} $) = 0.99). When $ AlF_{3} $ was added to a $ Na_{3} %$ AlF_{6} $ melt, the transport number of sodium cations decreased to 0.74 at the composition corresponding to $ NaAlF_{4} $. In molten $ K_{3} %$ AlF_{6} $, the transport number of $ K^{+} $ cations equals 0.836 at 1,005 °C. In melts containing both $ Na^{+} $ and $ K^{+} $, the cations contribute to the charge transport approximately in the ratio of the squares of their ionic radii. When 5 mass % of $ CaF_{2} $ was added to the molten NaF–KF–$ AlF_{3} $ system, it remarkably influenced the transport numbers of potassium and fluoride anions. © Springer-Verlag 2012
abstractGer	Abstract Transport numbers in the molten system NaF–KF–$ AlF_{3} $ ($ Al_{2} %$ O_{3} $, $ CaF_{2} $) were investigated by the Hittorf method. It was confirmed that in molten cryolite, $ Na_{3} %$ AlF_{6} $, 1,010 °C, the current is transported almost exclusively by the $ Na^{+} $ cations (t($ Na^{+} $) = 0.99). When $ AlF_{3} $ was added to a $ Na_{3} %$ AlF_{6} $ melt, the transport number of sodium cations decreased to 0.74 at the composition corresponding to $ NaAlF_{4} $. In molten $ K_{3} %$ AlF_{6} $, the transport number of $ K^{+} $ cations equals 0.836 at 1,005 °C. In melts containing both $ Na^{+} $ and $ K^{+} $, the cations contribute to the charge transport approximately in the ratio of the squares of their ionic radii. When 5 mass % of $ CaF_{2} $ was added to the molten NaF–KF–$ AlF_{3} $ system, it remarkably influenced the transport numbers of potassium and fluoride anions. © Springer-Verlag 2012
abstract_unstemmed	Abstract Transport numbers in the molten system NaF–KF–$ AlF_{3} $ ($ Al_{2} %$ O_{3} $, $ CaF_{2} $) were investigated by the Hittorf method. It was confirmed that in molten cryolite, $ Na_{3} %$ AlF_{6} $, 1,010 °C, the current is transported almost exclusively by the $ Na^{+} $ cations (t($ Na^{+} $) = 0.99). When $ AlF_{3} $ was added to a $ Na_{3} %$ AlF_{6} $ melt, the transport number of sodium cations decreased to 0.74 at the composition corresponding to $ NaAlF_{4} $. In molten $ K_{3} %$ AlF_{6} $, the transport number of $ K^{+} $ cations equals 0.836 at 1,005 °C. In melts containing both $ Na^{+} $ and $ K^{+} $, the cations contribute to the charge transport approximately in the ratio of the squares of their ionic radii. When 5 mass % of $ CaF_{2} $ was added to the molten NaF–KF–$ AlF_{3} $ system, it remarkably influenced the transport numbers of potassium and fluoride anions. © Springer-Verlag 2012
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title_short	Transport numbers in the molten system NaF–KF–$ AlF_{3} $–$ Al_{2} %$ O_{3} $
url	https://dx.doi.org/10.1007/s11581-012-0736-6
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author2	Fellner, Pavel Thonstad, Jomar
author2Str	Fellner, Pavel Thonstad, Jomar
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doi_str	10.1007/s11581-012-0736-6
up_date	2024-07-03T18:39:49.257Z
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score	7.401017

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Transport numbers in the molten system NaF–KF–$ AlF_{3} $–$ Al_{2} %$ O_{3} $

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