Synthesis of sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres via in situ conversion for rechargeable lithium-ion batteries
Abstract Among several materials (transition metal oxide) under development for use as a cathode in lithium-ion batteries, cubic spinel $ LiMn_{2} %$ O_{4} $ is one of the most promising cathode materials. In this study, the sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres were synthesized...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Ni, Liping [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2012 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer-Verlag 2012 |
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| Übergeordnetes Werk: |
Enthalten in: Ionics - Berlin : Springer, 1995, 19(2012), 2 vom: 29. Juni, Seite 259-264 |
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| Übergeordnetes Werk: |
volume:19 ; year:2012 ; number:2 ; day:29 ; month:06 ; pages:259-264 |
| Links: |
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| DOI / URN: |
10.1007/s11581-012-0759-z |
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| Katalog-ID: |
SPR020851820 |
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| 245 | 1 | 0 | |a Synthesis of sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres via in situ conversion for rechargeable lithium-ion batteries |
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| 520 | |a Abstract Among several materials (transition metal oxide) under development for use as a cathode in lithium-ion batteries, cubic spinel $ LiMn_{2} %$ O_{4} $ is one of the most promising cathode materials. In this study, the sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres were synthesized by using sea urchin-like α-$ MnO_{2} $ precursors through solid-state in situ self-sacrificing conversion route. The as-prepared $ LiMn_{2} %$ O_{4} $ was assembled by many single-crystalline “thorns” of ca.10–20 nm in diameter and ca. 400–500 nm in length. Galvanostatic battery testing showed that sea urchin-like $ LiMn_{2} %$ O_{4} $ had an initial discharge capacity of 126.8 mAh/g at the rate of 0.2 C in the potential range between 3.0 and 4.5 V. More than 96.67 % of the initial discharge capacity was maintained for over 50 cycles. The improved electrochemical properties were attributed to the reduced particle size and enhanced electrical contacts by the materials. This particular sea urchin-like structured composite conceptually provides a new strategy for designing electrodes in energy storage applications. | ||
| 650 | 4 | |a Batteries |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Cathodes |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Charging/discharging |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Li-ion batteries |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Cheng, Xiaomin |4 aut | |
| 700 | 1 | |a Wang, Xiufang |4 aut | |
| 700 | 1 | |a Tao, Yulun |4 aut | |
| 700 | 1 | |a Shen, Yuhua |4 aut | |
| 700 | 1 | |a Zhang, Tong |4 aut | |
| 700 | 1 | |a Sun, Haoran |4 aut | |
| 700 | 1 | |a Xie, Anjian |4 aut | |
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10.1007/s11581-012-0759-z doi (DE-627)SPR020851820 (SPR)s11581-012-0759-z-e DE-627 ger DE-627 rakwb eng Ni, Liping verfasserin aut Synthesis of sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres via in situ conversion for rechargeable lithium-ion batteries 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2012 Abstract Among several materials (transition metal oxide) under development for use as a cathode in lithium-ion batteries, cubic spinel $ LiMn_{2} %$ O_{4} $ is one of the most promising cathode materials. In this study, the sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres were synthesized by using sea urchin-like α-$ MnO_{2} $ precursors through solid-state in situ self-sacrificing conversion route. The as-prepared $ LiMn_{2} %$ O_{4} $ was assembled by many single-crystalline “thorns” of ca.10–20 nm in diameter and ca. 400–500 nm in length. Galvanostatic battery testing showed that sea urchin-like $ LiMn_{2} %$ O_{4} $ had an initial discharge capacity of 126.8 mAh/g at the rate of 0.2 C in the potential range between 3.0 and 4.5 V. More than 96.67 % of the initial discharge capacity was maintained for over 50 cycles. The improved electrochemical properties were attributed to the reduced particle size and enhanced electrical contacts by the materials. This particular sea urchin-like structured composite conceptually provides a new strategy for designing electrodes in energy storage applications. Batteries (dpeaa)DE-He213 Cathodes (dpeaa)DE-He213 Charging/discharging (dpeaa)DE-He213 Li-ion batteries (dpeaa)DE-He213 Cheng, Xiaomin aut Wang, Xiufang aut Tao, Yulun aut Shen, Yuhua aut Zhang, Tong aut Sun, Haoran aut Xie, Anjian aut Enthalten in Ionics Berlin : Springer, 1995 19(2012), 2 vom: 29. Juni, Seite 259-264 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:19 year:2012 number:2 day:29 month:06 pages:259-264 https://dx.doi.org/10.1007/s11581-012-0759-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 19 2012 2 29 06 259-264 |
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10.1007/s11581-012-0759-z doi (DE-627)SPR020851820 (SPR)s11581-012-0759-z-e DE-627 ger DE-627 rakwb eng Ni, Liping verfasserin aut Synthesis of sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres via in situ conversion for rechargeable lithium-ion batteries 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2012 Abstract Among several materials (transition metal oxide) under development for use as a cathode in lithium-ion batteries, cubic spinel $ LiMn_{2} %$ O_{4} $ is one of the most promising cathode materials. In this study, the sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres were synthesized by using sea urchin-like α-$ MnO_{2} $ precursors through solid-state in situ self-sacrificing conversion route. The as-prepared $ LiMn_{2} %$ O_{4} $ was assembled by many single-crystalline “thorns” of ca.10–20 nm in diameter and ca. 400–500 nm in length. Galvanostatic battery testing showed that sea urchin-like $ LiMn_{2} %$ O_{4} $ had an initial discharge capacity of 126.8 mAh/g at the rate of 0.2 C in the potential range between 3.0 and 4.5 V. More than 96.67 % of the initial discharge capacity was maintained for over 50 cycles. The improved electrochemical properties were attributed to the reduced particle size and enhanced electrical contacts by the materials. This particular sea urchin-like structured composite conceptually provides a new strategy for designing electrodes in energy storage applications. Batteries (dpeaa)DE-He213 Cathodes (dpeaa)DE-He213 Charging/discharging (dpeaa)DE-He213 Li-ion batteries (dpeaa)DE-He213 Cheng, Xiaomin aut Wang, Xiufang aut Tao, Yulun aut Shen, Yuhua aut Zhang, Tong aut Sun, Haoran aut Xie, Anjian aut Enthalten in Ionics Berlin : Springer, 1995 19(2012), 2 vom: 29. Juni, Seite 259-264 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:19 year:2012 number:2 day:29 month:06 pages:259-264 https://dx.doi.org/10.1007/s11581-012-0759-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 19 2012 2 29 06 259-264 |
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10.1007/s11581-012-0759-z doi (DE-627)SPR020851820 (SPR)s11581-012-0759-z-e DE-627 ger DE-627 rakwb eng Ni, Liping verfasserin aut Synthesis of sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres via in situ conversion for rechargeable lithium-ion batteries 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2012 Abstract Among several materials (transition metal oxide) under development for use as a cathode in lithium-ion batteries, cubic spinel $ LiMn_{2} %$ O_{4} $ is one of the most promising cathode materials. In this study, the sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres were synthesized by using sea urchin-like α-$ MnO_{2} $ precursors through solid-state in situ self-sacrificing conversion route. The as-prepared $ LiMn_{2} %$ O_{4} $ was assembled by many single-crystalline “thorns” of ca.10–20 nm in diameter and ca. 400–500 nm in length. Galvanostatic battery testing showed that sea urchin-like $ LiMn_{2} %$ O_{4} $ had an initial discharge capacity of 126.8 mAh/g at the rate of 0.2 C in the potential range between 3.0 and 4.5 V. More than 96.67 % of the initial discharge capacity was maintained for over 50 cycles. The improved electrochemical properties were attributed to the reduced particle size and enhanced electrical contacts by the materials. This particular sea urchin-like structured composite conceptually provides a new strategy for designing electrodes in energy storage applications. Batteries (dpeaa)DE-He213 Cathodes (dpeaa)DE-He213 Charging/discharging (dpeaa)DE-He213 Li-ion batteries (dpeaa)DE-He213 Cheng, Xiaomin aut Wang, Xiufang aut Tao, Yulun aut Shen, Yuhua aut Zhang, Tong aut Sun, Haoran aut Xie, Anjian aut Enthalten in Ionics Berlin : Springer, 1995 19(2012), 2 vom: 29. Juni, Seite 259-264 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:19 year:2012 number:2 day:29 month:06 pages:259-264 https://dx.doi.org/10.1007/s11581-012-0759-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 19 2012 2 29 06 259-264 |
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10.1007/s11581-012-0759-z doi (DE-627)SPR020851820 (SPR)s11581-012-0759-z-e DE-627 ger DE-627 rakwb eng Ni, Liping verfasserin aut Synthesis of sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres via in situ conversion for rechargeable lithium-ion batteries 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2012 Abstract Among several materials (transition metal oxide) under development for use as a cathode in lithium-ion batteries, cubic spinel $ LiMn_{2} %$ O_{4} $ is one of the most promising cathode materials. In this study, the sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres were synthesized by using sea urchin-like α-$ MnO_{2} $ precursors through solid-state in situ self-sacrificing conversion route. The as-prepared $ LiMn_{2} %$ O_{4} $ was assembled by many single-crystalline “thorns” of ca.10–20 nm in diameter and ca. 400–500 nm in length. Galvanostatic battery testing showed that sea urchin-like $ LiMn_{2} %$ O_{4} $ had an initial discharge capacity of 126.8 mAh/g at the rate of 0.2 C in the potential range between 3.0 and 4.5 V. More than 96.67 % of the initial discharge capacity was maintained for over 50 cycles. The improved electrochemical properties were attributed to the reduced particle size and enhanced electrical contacts by the materials. This particular sea urchin-like structured composite conceptually provides a new strategy for designing electrodes in energy storage applications. Batteries (dpeaa)DE-He213 Cathodes (dpeaa)DE-He213 Charging/discharging (dpeaa)DE-He213 Li-ion batteries (dpeaa)DE-He213 Cheng, Xiaomin aut Wang, Xiufang aut Tao, Yulun aut Shen, Yuhua aut Zhang, Tong aut Sun, Haoran aut Xie, Anjian aut Enthalten in Ionics Berlin : Springer, 1995 19(2012), 2 vom: 29. Juni, Seite 259-264 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:19 year:2012 number:2 day:29 month:06 pages:259-264 https://dx.doi.org/10.1007/s11581-012-0759-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 19 2012 2 29 06 259-264 |
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10.1007/s11581-012-0759-z doi (DE-627)SPR020851820 (SPR)s11581-012-0759-z-e DE-627 ger DE-627 rakwb eng Ni, Liping verfasserin aut Synthesis of sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres via in situ conversion for rechargeable lithium-ion batteries 2012 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag 2012 Abstract Among several materials (transition metal oxide) under development for use as a cathode in lithium-ion batteries, cubic spinel $ LiMn_{2} %$ O_{4} $ is one of the most promising cathode materials. In this study, the sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres were synthesized by using sea urchin-like α-$ MnO_{2} $ precursors through solid-state in situ self-sacrificing conversion route. The as-prepared $ LiMn_{2} %$ O_{4} $ was assembled by many single-crystalline “thorns” of ca.10–20 nm in diameter and ca. 400–500 nm in length. Galvanostatic battery testing showed that sea urchin-like $ LiMn_{2} %$ O_{4} $ had an initial discharge capacity of 126.8 mAh/g at the rate of 0.2 C in the potential range between 3.0 and 4.5 V. More than 96.67 % of the initial discharge capacity was maintained for over 50 cycles. The improved electrochemical properties were attributed to the reduced particle size and enhanced electrical contacts by the materials. This particular sea urchin-like structured composite conceptually provides a new strategy for designing electrodes in energy storage applications. Batteries (dpeaa)DE-He213 Cathodes (dpeaa)DE-He213 Charging/discharging (dpeaa)DE-He213 Li-ion batteries (dpeaa)DE-He213 Cheng, Xiaomin aut Wang, Xiufang aut Tao, Yulun aut Shen, Yuhua aut Zhang, Tong aut Sun, Haoran aut Xie, Anjian aut Enthalten in Ionics Berlin : Springer, 1995 19(2012), 2 vom: 29. Juni, Seite 259-264 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:19 year:2012 number:2 day:29 month:06 pages:259-264 https://dx.doi.org/10.1007/s11581-012-0759-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 19 2012 2 29 06 259-264 |
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Batteries Cathodes Charging/discharging Li-ion batteries |
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Ni, Liping @@aut@@ Cheng, Xiaomin @@aut@@ Wang, Xiufang @@aut@@ Tao, Yulun @@aut@@ Shen, Yuhua @@aut@@ Zhang, Tong @@aut@@ Sun, Haoran @@aut@@ Xie, Anjian @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR020851820</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230330174426.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2012 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11581-012-0759-z</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR020851820</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s11581-012-0759-z-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Ni, Liping</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Synthesis of sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres via in situ conversion for rechargeable lithium-ion batteries</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2012</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer-Verlag 2012</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Among several materials (transition metal oxide) under development for use as a cathode in lithium-ion batteries, cubic spinel $ LiMn_{2} %$ O_{4} $ is one of the most promising cathode materials. In this study, the sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres were synthesized by using sea urchin-like α-$ MnO_{2} $ precursors through solid-state in situ self-sacrificing conversion route. The as-prepared $ LiMn_{2} %$ O_{4} $ was assembled by many single-crystalline “thorns” of ca.10–20 nm in diameter and ca. 400–500 nm in length. Galvanostatic battery testing showed that sea urchin-like $ LiMn_{2} %$ O_{4} $ had an initial discharge capacity of 126.8 mAh/g at the rate of 0.2 C in the potential range between 3.0 and 4.5 V. More than 96.67 % of the initial discharge capacity was maintained for over 50 cycles. The improved electrochemical properties were attributed to the reduced particle size and enhanced electrical contacts by the materials. 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Ni, Liping |
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Ni, Liping misc Batteries misc Cathodes misc Charging/discharging misc Li-ion batteries Synthesis of sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres via in situ conversion for rechargeable lithium-ion batteries |
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Synthesis of sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres via in situ conversion for rechargeable lithium-ion batteries Batteries (dpeaa)DE-He213 Cathodes (dpeaa)DE-He213 Charging/discharging (dpeaa)DE-He213 Li-ion batteries (dpeaa)DE-He213 |
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Synthesis of sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres via in situ conversion for rechargeable lithium-ion batteries |
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Synthesis of sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres via in situ conversion for rechargeable lithium-ion batteries |
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Ni, Liping Cheng, Xiaomin Wang, Xiufang Tao, Yulun Shen, Yuhua Zhang, Tong Sun, Haoran Xie, Anjian |
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synthesis of sea urchin-like $ limn_{2} %$ o_{4} $ hollow macrospheres via in situ conversion for rechargeable lithium-ion batteries |
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Synthesis of sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres via in situ conversion for rechargeable lithium-ion batteries |
| abstract |
Abstract Among several materials (transition metal oxide) under development for use as a cathode in lithium-ion batteries, cubic spinel $ LiMn_{2} %$ O_{4} $ is one of the most promising cathode materials. In this study, the sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres were synthesized by using sea urchin-like α-$ MnO_{2} $ precursors through solid-state in situ self-sacrificing conversion route. The as-prepared $ LiMn_{2} %$ O_{4} $ was assembled by many single-crystalline “thorns” of ca.10–20 nm in diameter and ca. 400–500 nm in length. Galvanostatic battery testing showed that sea urchin-like $ LiMn_{2} %$ O_{4} $ had an initial discharge capacity of 126.8 mAh/g at the rate of 0.2 C in the potential range between 3.0 and 4.5 V. More than 96.67 % of the initial discharge capacity was maintained for over 50 cycles. The improved electrochemical properties were attributed to the reduced particle size and enhanced electrical contacts by the materials. This particular sea urchin-like structured composite conceptually provides a new strategy for designing electrodes in energy storage applications. © Springer-Verlag 2012 |
| abstractGer |
Abstract Among several materials (transition metal oxide) under development for use as a cathode in lithium-ion batteries, cubic spinel $ LiMn_{2} %$ O_{4} $ is one of the most promising cathode materials. In this study, the sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres were synthesized by using sea urchin-like α-$ MnO_{2} $ precursors through solid-state in situ self-sacrificing conversion route. The as-prepared $ LiMn_{2} %$ O_{4} $ was assembled by many single-crystalline “thorns” of ca.10–20 nm in diameter and ca. 400–500 nm in length. Galvanostatic battery testing showed that sea urchin-like $ LiMn_{2} %$ O_{4} $ had an initial discharge capacity of 126.8 mAh/g at the rate of 0.2 C in the potential range between 3.0 and 4.5 V. More than 96.67 % of the initial discharge capacity was maintained for over 50 cycles. The improved electrochemical properties were attributed to the reduced particle size and enhanced electrical contacts by the materials. This particular sea urchin-like structured composite conceptually provides a new strategy for designing electrodes in energy storage applications. © Springer-Verlag 2012 |
| abstract_unstemmed |
Abstract Among several materials (transition metal oxide) under development for use as a cathode in lithium-ion batteries, cubic spinel $ LiMn_{2} %$ O_{4} $ is one of the most promising cathode materials. In this study, the sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres were synthesized by using sea urchin-like α-$ MnO_{2} $ precursors through solid-state in situ self-sacrificing conversion route. The as-prepared $ LiMn_{2} %$ O_{4} $ was assembled by many single-crystalline “thorns” of ca.10–20 nm in diameter and ca. 400–500 nm in length. Galvanostatic battery testing showed that sea urchin-like $ LiMn_{2} %$ O_{4} $ had an initial discharge capacity of 126.8 mAh/g at the rate of 0.2 C in the potential range between 3.0 and 4.5 V. More than 96.67 % of the initial discharge capacity was maintained for over 50 cycles. The improved electrochemical properties were attributed to the reduced particle size and enhanced electrical contacts by the materials. This particular sea urchin-like structured composite conceptually provides a new strategy for designing electrodes in energy storage applications. © Springer-Verlag 2012 |
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| title_short |
Synthesis of sea urchin-like $ LiMn_{2} %$ O_{4} $ hollow macrospheres via in situ conversion for rechargeable lithium-ion batteries |
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https://dx.doi.org/10.1007/s11581-012-0759-z |
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Cheng, Xiaomin Wang, Xiufang Tao, Yulun Shen, Yuhua Zhang, Tong Sun, Haoran Xie, Anjian |
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Cheng, Xiaomin Wang, Xiufang Tao, Yulun Shen, Yuhua Zhang, Tong Sun, Haoran Xie, Anjian |
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| score |
7.4005537 |