Influence of metals on the structural, vibrational, and electrical properties of lithium nickel phosphate
Abstract $ LiNi_{1 − x} %$ M_{x} %$ PO_{4} $ (M = Zn, Al and x = 0, 0.05, 0.10, 0.15, and 0.20) was synthesized by classical solid-state reaction method. The reaction temperature is determined by thermogravimetric analysis. X-ray diffraction patterns show that an impurity peak is absorbed for $ Al^{...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Karthickprabhu, S. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer-Verlag Berlin Heidelberg 2014 |
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| Übergeordnetes Werk: |
Enthalten in: Ionics - Berlin : Springer, 1995, 21(2014), 2 vom: 29. Juni, Seite 345-357 |
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| Übergeordnetes Werk: |
volume:21 ; year:2014 ; number:2 ; day:29 ; month:06 ; pages:345-357 |
| Links: |
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| DOI / URN: |
10.1007/s11581-014-1192-2 |
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| Katalog-ID: |
SPR020856393 |
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| 100 | 1 | |a Karthickprabhu, S. |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Influence of metals on the structural, vibrational, and electrical properties of lithium nickel phosphate |
| 264 | 1 | |c 2014 | |
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| 520 | |a Abstract $ LiNi_{1 − x} %$ M_{x} %$ PO_{4} $ (M = Zn, Al and x = 0, 0.05, 0.10, 0.15, and 0.20) was synthesized by classical solid-state reaction method. The reaction temperature is determined by thermogravimetric analysis. X-ray diffraction patterns show that an impurity peak is absorbed for $ Al^{3+} $-doped samples but not in the case of $ Zn^{2+} $-doped samples. Laser Raman studies confirm that phase pure $ LiNiPO_{4} $ is formed and the dopant is entered into the host lattice. Impedance spectroscopy is used to study the ion dynamics of both doped and undoped systems. Higher DC conductivity value is observed for $ LiNi_{0.85} %$ Zn_{0.15} %$ PO_{4} $ and $ LiNi_{0.925} %$ Al_{0.05} %$ PO_{4} $ compared with pristine $ LiNiPO_{4} $. The temperature-dependent DC conductivity and the frequency-dependent dielectric loss maxima are found to obey the Arrhenius law of conduction. In the modulus analysis, the stretching exponent β is found to be temperature independent. The scaling behavior of the imaginary part of the electric modulus suggests that the relaxation mechanism is independent of temperatures. Electrochemical impedance spectroscopy (EIS) studies also show that electrical conductivity is increased upon $ Zn^{2+} $ and $ Al^{3+} $ doping. | ||
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| 650 | 4 | |a Impedance spectroscopy |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Olivine phosphate |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Activation energy |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Electrical conductivity |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Electric modulus |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Arrhenius law |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Hirankumar, G. |4 aut | |
| 700 | 1 | |a Maheswaran, A. |4 aut | |
| 700 | 1 | |a Daries Bella, R. S. |4 aut | |
| 700 | 1 | |a Sanjeeviraja, C. |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Ionics |d Berlin : Springer, 1995 |g 21(2014), 2 vom: 29. Juni, Seite 345-357 |w (DE-627)509398944 |w (DE-600)2226746-3 |x 1862-0760 |7 nnns |
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10.1007/s11581-014-1192-2 doi (DE-627)SPR020856393 (SPR)s11581-014-1192-2-e DE-627 ger DE-627 rakwb eng Karthickprabhu, S. verfasserin aut Influence of metals on the structural, vibrational, and electrical properties of lithium nickel phosphate 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2014 Abstract $ LiNi_{1 − x} %$ M_{x} %$ PO_{4} $ (M = Zn, Al and x = 0, 0.05, 0.10, 0.15, and 0.20) was synthesized by classical solid-state reaction method. The reaction temperature is determined by thermogravimetric analysis. X-ray diffraction patterns show that an impurity peak is absorbed for $ Al^{3+} $-doped samples but not in the case of $ Zn^{2+} $-doped samples. Laser Raman studies confirm that phase pure $ LiNiPO_{4} $ is formed and the dopant is entered into the host lattice. Impedance spectroscopy is used to study the ion dynamics of both doped and undoped systems. Higher DC conductivity value is observed for $ LiNi_{0.85} %$ Zn_{0.15} %$ PO_{4} $ and $ LiNi_{0.925} %$ Al_{0.05} %$ PO_{4} $ compared with pristine $ LiNiPO_{4} $. The temperature-dependent DC conductivity and the frequency-dependent dielectric loss maxima are found to obey the Arrhenius law of conduction. In the modulus analysis, the stretching exponent β is found to be temperature independent. The scaling behavior of the imaginary part of the electric modulus suggests that the relaxation mechanism is independent of temperatures. Electrochemical impedance spectroscopy (EIS) studies also show that electrical conductivity is increased upon $ Zn^{2+} $ and $ Al^{3+} $ doping. Solid-state reactions (dpeaa)DE-He213 Impedance spectroscopy (dpeaa)DE-He213 Olivine phosphate (dpeaa)DE-He213 Activation energy (dpeaa)DE-He213 Electrical conductivity (dpeaa)DE-He213 Electric modulus (dpeaa)DE-He213 Arrhenius law (dpeaa)DE-He213 Hirankumar, G. aut Maheswaran, A. aut Daries Bella, R. S. aut Sanjeeviraja, C. aut Enthalten in Ionics Berlin : Springer, 1995 21(2014), 2 vom: 29. Juni, Seite 345-357 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:21 year:2014 number:2 day:29 month:06 pages:345-357 https://dx.doi.org/10.1007/s11581-014-1192-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 21 2014 2 29 06 345-357 |
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10.1007/s11581-014-1192-2 doi (DE-627)SPR020856393 (SPR)s11581-014-1192-2-e DE-627 ger DE-627 rakwb eng Karthickprabhu, S. verfasserin aut Influence of metals on the structural, vibrational, and electrical properties of lithium nickel phosphate 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2014 Abstract $ LiNi_{1 − x} %$ M_{x} %$ PO_{4} $ (M = Zn, Al and x = 0, 0.05, 0.10, 0.15, and 0.20) was synthesized by classical solid-state reaction method. The reaction temperature is determined by thermogravimetric analysis. X-ray diffraction patterns show that an impurity peak is absorbed for $ Al^{3+} $-doped samples but not in the case of $ Zn^{2+} $-doped samples. Laser Raman studies confirm that phase pure $ LiNiPO_{4} $ is formed and the dopant is entered into the host lattice. Impedance spectroscopy is used to study the ion dynamics of both doped and undoped systems. Higher DC conductivity value is observed for $ LiNi_{0.85} %$ Zn_{0.15} %$ PO_{4} $ and $ LiNi_{0.925} %$ Al_{0.05} %$ PO_{4} $ compared with pristine $ LiNiPO_{4} $. The temperature-dependent DC conductivity and the frequency-dependent dielectric loss maxima are found to obey the Arrhenius law of conduction. In the modulus analysis, the stretching exponent β is found to be temperature independent. The scaling behavior of the imaginary part of the electric modulus suggests that the relaxation mechanism is independent of temperatures. Electrochemical impedance spectroscopy (EIS) studies also show that electrical conductivity is increased upon $ Zn^{2+} $ and $ Al^{3+} $ doping. Solid-state reactions (dpeaa)DE-He213 Impedance spectroscopy (dpeaa)DE-He213 Olivine phosphate (dpeaa)DE-He213 Activation energy (dpeaa)DE-He213 Electrical conductivity (dpeaa)DE-He213 Electric modulus (dpeaa)DE-He213 Arrhenius law (dpeaa)DE-He213 Hirankumar, G. aut Maheswaran, A. aut Daries Bella, R. S. aut Sanjeeviraja, C. aut Enthalten in Ionics Berlin : Springer, 1995 21(2014), 2 vom: 29. Juni, Seite 345-357 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:21 year:2014 number:2 day:29 month:06 pages:345-357 https://dx.doi.org/10.1007/s11581-014-1192-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 21 2014 2 29 06 345-357 |
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10.1007/s11581-014-1192-2 doi (DE-627)SPR020856393 (SPR)s11581-014-1192-2-e DE-627 ger DE-627 rakwb eng Karthickprabhu, S. verfasserin aut Influence of metals on the structural, vibrational, and electrical properties of lithium nickel phosphate 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2014 Abstract $ LiNi_{1 − x} %$ M_{x} %$ PO_{4} $ (M = Zn, Al and x = 0, 0.05, 0.10, 0.15, and 0.20) was synthesized by classical solid-state reaction method. The reaction temperature is determined by thermogravimetric analysis. X-ray diffraction patterns show that an impurity peak is absorbed for $ Al^{3+} $-doped samples but not in the case of $ Zn^{2+} $-doped samples. Laser Raman studies confirm that phase pure $ LiNiPO_{4} $ is formed and the dopant is entered into the host lattice. Impedance spectroscopy is used to study the ion dynamics of both doped and undoped systems. Higher DC conductivity value is observed for $ LiNi_{0.85} %$ Zn_{0.15} %$ PO_{4} $ and $ LiNi_{0.925} %$ Al_{0.05} %$ PO_{4} $ compared with pristine $ LiNiPO_{4} $. The temperature-dependent DC conductivity and the frequency-dependent dielectric loss maxima are found to obey the Arrhenius law of conduction. In the modulus analysis, the stretching exponent β is found to be temperature independent. The scaling behavior of the imaginary part of the electric modulus suggests that the relaxation mechanism is independent of temperatures. Electrochemical impedance spectroscopy (EIS) studies also show that electrical conductivity is increased upon $ Zn^{2+} $ and $ Al^{3+} $ doping. Solid-state reactions (dpeaa)DE-He213 Impedance spectroscopy (dpeaa)DE-He213 Olivine phosphate (dpeaa)DE-He213 Activation energy (dpeaa)DE-He213 Electrical conductivity (dpeaa)DE-He213 Electric modulus (dpeaa)DE-He213 Arrhenius law (dpeaa)DE-He213 Hirankumar, G. aut Maheswaran, A. aut Daries Bella, R. S. aut Sanjeeviraja, C. aut Enthalten in Ionics Berlin : Springer, 1995 21(2014), 2 vom: 29. Juni, Seite 345-357 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:21 year:2014 number:2 day:29 month:06 pages:345-357 https://dx.doi.org/10.1007/s11581-014-1192-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 21 2014 2 29 06 345-357 |
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10.1007/s11581-014-1192-2 doi (DE-627)SPR020856393 (SPR)s11581-014-1192-2-e DE-627 ger DE-627 rakwb eng Karthickprabhu, S. verfasserin aut Influence of metals on the structural, vibrational, and electrical properties of lithium nickel phosphate 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2014 Abstract $ LiNi_{1 − x} %$ M_{x} %$ PO_{4} $ (M = Zn, Al and x = 0, 0.05, 0.10, 0.15, and 0.20) was synthesized by classical solid-state reaction method. The reaction temperature is determined by thermogravimetric analysis. X-ray diffraction patterns show that an impurity peak is absorbed for $ Al^{3+} $-doped samples but not in the case of $ Zn^{2+} $-doped samples. Laser Raman studies confirm that phase pure $ LiNiPO_{4} $ is formed and the dopant is entered into the host lattice. Impedance spectroscopy is used to study the ion dynamics of both doped and undoped systems. Higher DC conductivity value is observed for $ LiNi_{0.85} %$ Zn_{0.15} %$ PO_{4} $ and $ LiNi_{0.925} %$ Al_{0.05} %$ PO_{4} $ compared with pristine $ LiNiPO_{4} $. The temperature-dependent DC conductivity and the frequency-dependent dielectric loss maxima are found to obey the Arrhenius law of conduction. In the modulus analysis, the stretching exponent β is found to be temperature independent. The scaling behavior of the imaginary part of the electric modulus suggests that the relaxation mechanism is independent of temperatures. Electrochemical impedance spectroscopy (EIS) studies also show that electrical conductivity is increased upon $ Zn^{2+} $ and $ Al^{3+} $ doping. Solid-state reactions (dpeaa)DE-He213 Impedance spectroscopy (dpeaa)DE-He213 Olivine phosphate (dpeaa)DE-He213 Activation energy (dpeaa)DE-He213 Electrical conductivity (dpeaa)DE-He213 Electric modulus (dpeaa)DE-He213 Arrhenius law (dpeaa)DE-He213 Hirankumar, G. aut Maheswaran, A. aut Daries Bella, R. S. aut Sanjeeviraja, C. aut Enthalten in Ionics Berlin : Springer, 1995 21(2014), 2 vom: 29. Juni, Seite 345-357 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:21 year:2014 number:2 day:29 month:06 pages:345-357 https://dx.doi.org/10.1007/s11581-014-1192-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 21 2014 2 29 06 345-357 |
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10.1007/s11581-014-1192-2 doi (DE-627)SPR020856393 (SPR)s11581-014-1192-2-e DE-627 ger DE-627 rakwb eng Karthickprabhu, S. verfasserin aut Influence of metals on the structural, vibrational, and electrical properties of lithium nickel phosphate 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2014 Abstract $ LiNi_{1 − x} %$ M_{x} %$ PO_{4} $ (M = Zn, Al and x = 0, 0.05, 0.10, 0.15, and 0.20) was synthesized by classical solid-state reaction method. The reaction temperature is determined by thermogravimetric analysis. X-ray diffraction patterns show that an impurity peak is absorbed for $ Al^{3+} $-doped samples but not in the case of $ Zn^{2+} $-doped samples. Laser Raman studies confirm that phase pure $ LiNiPO_{4} $ is formed and the dopant is entered into the host lattice. Impedance spectroscopy is used to study the ion dynamics of both doped and undoped systems. Higher DC conductivity value is observed for $ LiNi_{0.85} %$ Zn_{0.15} %$ PO_{4} $ and $ LiNi_{0.925} %$ Al_{0.05} %$ PO_{4} $ compared with pristine $ LiNiPO_{4} $. The temperature-dependent DC conductivity and the frequency-dependent dielectric loss maxima are found to obey the Arrhenius law of conduction. In the modulus analysis, the stretching exponent β is found to be temperature independent. The scaling behavior of the imaginary part of the electric modulus suggests that the relaxation mechanism is independent of temperatures. Electrochemical impedance spectroscopy (EIS) studies also show that electrical conductivity is increased upon $ Zn^{2+} $ and $ Al^{3+} $ doping. Solid-state reactions (dpeaa)DE-He213 Impedance spectroscopy (dpeaa)DE-He213 Olivine phosphate (dpeaa)DE-He213 Activation energy (dpeaa)DE-He213 Electrical conductivity (dpeaa)DE-He213 Electric modulus (dpeaa)DE-He213 Arrhenius law (dpeaa)DE-He213 Hirankumar, G. aut Maheswaran, A. aut Daries Bella, R. S. aut Sanjeeviraja, C. aut Enthalten in Ionics Berlin : Springer, 1995 21(2014), 2 vom: 29. Juni, Seite 345-357 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:21 year:2014 number:2 day:29 month:06 pages:345-357 https://dx.doi.org/10.1007/s11581-014-1192-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 21 2014 2 29 06 345-357 |
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The reaction temperature is determined by thermogravimetric analysis. X-ray diffraction patterns show that an impurity peak is absorbed for $ Al^{3+} $-doped samples but not in the case of $ Zn^{2+} $-doped samples. Laser Raman studies confirm that phase pure $ LiNiPO_{4} $ is formed and the dopant is entered into the host lattice. Impedance spectroscopy is used to study the ion dynamics of both doped and undoped systems. Higher DC conductivity value is observed for $ LiNi_{0.85} %$ Zn_{0.15} %$ PO_{4} $ and $ LiNi_{0.925} %$ Al_{0.05} %$ PO_{4} $ compared with pristine $ LiNiPO_{4} $. The temperature-dependent DC conductivity and the frequency-dependent dielectric loss maxima are found to obey the Arrhenius law of conduction. In the modulus analysis, the stretching exponent β is found to be temperature independent. The scaling behavior of the imaginary part of the electric modulus suggests that the relaxation mechanism is independent of temperatures. 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Karthickprabhu, S. |
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Karthickprabhu, S. misc Solid-state reactions misc Impedance spectroscopy misc Olivine phosphate misc Activation energy misc Electrical conductivity misc Electric modulus misc Arrhenius law Influence of metals on the structural, vibrational, and electrical properties of lithium nickel phosphate |
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Influence of metals on the structural, vibrational, and electrical properties of lithium nickel phosphate Solid-state reactions (dpeaa)DE-He213 Impedance spectroscopy (dpeaa)DE-He213 Olivine phosphate (dpeaa)DE-He213 Activation energy (dpeaa)DE-He213 Electrical conductivity (dpeaa)DE-He213 Electric modulus (dpeaa)DE-He213 Arrhenius law (dpeaa)DE-He213 |
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misc Solid-state reactions misc Impedance spectroscopy misc Olivine phosphate misc Activation energy misc Electrical conductivity misc Electric modulus misc Arrhenius law |
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misc Solid-state reactions misc Impedance spectroscopy misc Olivine phosphate misc Activation energy misc Electrical conductivity misc Electric modulus misc Arrhenius law |
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Influence of metals on the structural, vibrational, and electrical properties of lithium nickel phosphate |
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Influence of metals on the structural, vibrational, and electrical properties of lithium nickel phosphate |
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Karthickprabhu, S. Hirankumar, G. Maheswaran, A. Daries Bella, R. S. Sanjeeviraja, C. |
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Karthickprabhu, S. |
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10.1007/s11581-014-1192-2 |
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influence of metals on the structural, vibrational, and electrical properties of lithium nickel phosphate |
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Influence of metals on the structural, vibrational, and electrical properties of lithium nickel phosphate |
| abstract |
Abstract $ LiNi_{1 − x} %$ M_{x} %$ PO_{4} $ (M = Zn, Al and x = 0, 0.05, 0.10, 0.15, and 0.20) was synthesized by classical solid-state reaction method. The reaction temperature is determined by thermogravimetric analysis. X-ray diffraction patterns show that an impurity peak is absorbed for $ Al^{3+} $-doped samples but not in the case of $ Zn^{2+} $-doped samples. Laser Raman studies confirm that phase pure $ LiNiPO_{4} $ is formed and the dopant is entered into the host lattice. Impedance spectroscopy is used to study the ion dynamics of both doped and undoped systems. Higher DC conductivity value is observed for $ LiNi_{0.85} %$ Zn_{0.15} %$ PO_{4} $ and $ LiNi_{0.925} %$ Al_{0.05} %$ PO_{4} $ compared with pristine $ LiNiPO_{4} $. The temperature-dependent DC conductivity and the frequency-dependent dielectric loss maxima are found to obey the Arrhenius law of conduction. In the modulus analysis, the stretching exponent β is found to be temperature independent. The scaling behavior of the imaginary part of the electric modulus suggests that the relaxation mechanism is independent of temperatures. Electrochemical impedance spectroscopy (EIS) studies also show that electrical conductivity is increased upon $ Zn^{2+} $ and $ Al^{3+} $ doping. © Springer-Verlag Berlin Heidelberg 2014 |
| abstractGer |
Abstract $ LiNi_{1 − x} %$ M_{x} %$ PO_{4} $ (M = Zn, Al and x = 0, 0.05, 0.10, 0.15, and 0.20) was synthesized by classical solid-state reaction method. The reaction temperature is determined by thermogravimetric analysis. X-ray diffraction patterns show that an impurity peak is absorbed for $ Al^{3+} $-doped samples but not in the case of $ Zn^{2+} $-doped samples. Laser Raman studies confirm that phase pure $ LiNiPO_{4} $ is formed and the dopant is entered into the host lattice. Impedance spectroscopy is used to study the ion dynamics of both doped and undoped systems. Higher DC conductivity value is observed for $ LiNi_{0.85} %$ Zn_{0.15} %$ PO_{4} $ and $ LiNi_{0.925} %$ Al_{0.05} %$ PO_{4} $ compared with pristine $ LiNiPO_{4} $. The temperature-dependent DC conductivity and the frequency-dependent dielectric loss maxima are found to obey the Arrhenius law of conduction. In the modulus analysis, the stretching exponent β is found to be temperature independent. The scaling behavior of the imaginary part of the electric modulus suggests that the relaxation mechanism is independent of temperatures. Electrochemical impedance spectroscopy (EIS) studies also show that electrical conductivity is increased upon $ Zn^{2+} $ and $ Al^{3+} $ doping. © Springer-Verlag Berlin Heidelberg 2014 |
| abstract_unstemmed |
Abstract $ LiNi_{1 − x} %$ M_{x} %$ PO_{4} $ (M = Zn, Al and x = 0, 0.05, 0.10, 0.15, and 0.20) was synthesized by classical solid-state reaction method. The reaction temperature is determined by thermogravimetric analysis. X-ray diffraction patterns show that an impurity peak is absorbed for $ Al^{3+} $-doped samples but not in the case of $ Zn^{2+} $-doped samples. Laser Raman studies confirm that phase pure $ LiNiPO_{4} $ is formed and the dopant is entered into the host lattice. Impedance spectroscopy is used to study the ion dynamics of both doped and undoped systems. Higher DC conductivity value is observed for $ LiNi_{0.85} %$ Zn_{0.15} %$ PO_{4} $ and $ LiNi_{0.925} %$ Al_{0.05} %$ PO_{4} $ compared with pristine $ LiNiPO_{4} $. The temperature-dependent DC conductivity and the frequency-dependent dielectric loss maxima are found to obey the Arrhenius law of conduction. In the modulus analysis, the stretching exponent β is found to be temperature independent. The scaling behavior of the imaginary part of the electric modulus suggests that the relaxation mechanism is independent of temperatures. Electrochemical impedance spectroscopy (EIS) studies also show that electrical conductivity is increased upon $ Zn^{2+} $ and $ Al^{3+} $ doping. © Springer-Verlag Berlin Heidelberg 2014 |
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| title_short |
Influence of metals on the structural, vibrational, and electrical properties of lithium nickel phosphate |
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https://dx.doi.org/10.1007/s11581-014-1192-2 |
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Hirankumar, G. Maheswaran, A. Daries Bella, R. S. Sanjeeviraja, C. |
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| score |
7.399088 |