Electrochemical comparison of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials
Abstract A comparison of electrochemical performance between $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials was conducted in this paper. The cathode samples were synthesized by a nano-milling-assisted solid-state process using caramel as carbon sources....
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Cai, Yuanyuan [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer-Verlag Berlin Heidelberg 2016 |
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| Übergeordnetes Werk: |
Enthalten in: Ionics - Berlin : Springer, 1995, 22(2016), 7 vom: 21. Jan., Seite 1011-1019 |
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| Übergeordnetes Werk: |
volume:22 ; year:2016 ; number:7 ; day:21 ; month:01 ; pages:1011-1019 |
| Links: |
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| DOI / URN: |
10.1007/s11581-015-1633-6 |
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| Katalog-ID: |
SPR020861451 |
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| 100 | 1 | |a Cai, Yuanyuan |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Electrochemical comparison of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials |
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| 520 | |a Abstract A comparison of electrochemical performance between $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials was conducted in this paper. The cathode samples were synthesized by a nano-milling-assisted solid-state process using caramel as carbon sources. The prepared samples were investigated by XRD, SEM, TEM, energy-dispersive X-ray spectroscopy (EDAX), powder conductivity test (PCT), carbon-sulfur analysis, electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge cycling. The results showed that $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C exhibited high specific capacity and high energy density. The initial discharge capacity of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 163.6 mAh $ g^{−1} $ at 0.1C (1C = 160 mA $ g^{−1} $), compared to 112.3 mAh $ g^{−1} $ for $ LiMnPO_{4} $/C. Moreover, the Fe/Cr-substituted sample showed good cycle stability and rate performance. The capacity retention of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 98.84 % over 100 charge-discharge cycles, while it was only 86.64 % for the pristine $ LiMnPO_{4} $/C. These results indicated that Fe/Cr substitution enhanced the electronic conductivity for the prepared sample and facilitated the $ Li^{+} $ diffusion in the structure. Furthermore, $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C composite presented high energy density (606 Wh $ kg^{−1} $) and high power density (574 W $ kg^{−1} $), thus suggested great potential application in lithium ion batteries (LIBs). | ||
| 650 | 4 | |a Cathode materials |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Electrochemical performance |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Energy density |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Cycle stability |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Zhang, Dongyun |4 aut | |
| 700 | 1 | |a Chang, Chengkang |4 aut | |
| 700 | 1 | |a Sheng, Zhaomin |4 aut | |
| 700 | 1 | |a Huang, Kejun |4 aut | |
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10.1007/s11581-015-1633-6 doi (DE-627)SPR020861451 (SPR)s11581-015-1633-6-e DE-627 ger DE-627 rakwb eng Cai, Yuanyuan verfasserin aut Electrochemical comparison of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2016 Abstract A comparison of electrochemical performance between $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials was conducted in this paper. The cathode samples were synthesized by a nano-milling-assisted solid-state process using caramel as carbon sources. The prepared samples were investigated by XRD, SEM, TEM, energy-dispersive X-ray spectroscopy (EDAX), powder conductivity test (PCT), carbon-sulfur analysis, electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge cycling. The results showed that $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C exhibited high specific capacity and high energy density. The initial discharge capacity of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 163.6 mAh $ g^{−1} $ at 0.1C (1C = 160 mA $ g^{−1} $), compared to 112.3 mAh $ g^{−1} $ for $ LiMnPO_{4} $/C. Moreover, the Fe/Cr-substituted sample showed good cycle stability and rate performance. The capacity retention of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 98.84 % over 100 charge-discharge cycles, while it was only 86.64 % for the pristine $ LiMnPO_{4} $/C. These results indicated that Fe/Cr substitution enhanced the electronic conductivity for the prepared sample and facilitated the $ Li^{+} $ diffusion in the structure. Furthermore, $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C composite presented high energy density (606 Wh $ kg^{−1} $) and high power density (574 W $ kg^{−1} $), thus suggested great potential application in lithium ion batteries (LIBs). Cathode materials (dpeaa)DE-He213 Electrochemical performance (dpeaa)DE-He213 Energy density (dpeaa)DE-He213 Cycle stability (dpeaa)DE-He213 Zhang, Dongyun aut Chang, Chengkang aut Sheng, Zhaomin aut Huang, Kejun aut Enthalten in Ionics Berlin : Springer, 1995 22(2016), 7 vom: 21. Jan., Seite 1011-1019 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:22 year:2016 number:7 day:21 month:01 pages:1011-1019 https://dx.doi.org/10.1007/s11581-015-1633-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 22 2016 7 21 01 1011-1019 |
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10.1007/s11581-015-1633-6 doi (DE-627)SPR020861451 (SPR)s11581-015-1633-6-e DE-627 ger DE-627 rakwb eng Cai, Yuanyuan verfasserin aut Electrochemical comparison of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2016 Abstract A comparison of electrochemical performance between $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials was conducted in this paper. The cathode samples were synthesized by a nano-milling-assisted solid-state process using caramel as carbon sources. The prepared samples were investigated by XRD, SEM, TEM, energy-dispersive X-ray spectroscopy (EDAX), powder conductivity test (PCT), carbon-sulfur analysis, electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge cycling. The results showed that $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C exhibited high specific capacity and high energy density. The initial discharge capacity of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 163.6 mAh $ g^{−1} $ at 0.1C (1C = 160 mA $ g^{−1} $), compared to 112.3 mAh $ g^{−1} $ for $ LiMnPO_{4} $/C. Moreover, the Fe/Cr-substituted sample showed good cycle stability and rate performance. The capacity retention of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 98.84 % over 100 charge-discharge cycles, while it was only 86.64 % for the pristine $ LiMnPO_{4} $/C. These results indicated that Fe/Cr substitution enhanced the electronic conductivity for the prepared sample and facilitated the $ Li^{+} $ diffusion in the structure. Furthermore, $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C composite presented high energy density (606 Wh $ kg^{−1} $) and high power density (574 W $ kg^{−1} $), thus suggested great potential application in lithium ion batteries (LIBs). Cathode materials (dpeaa)DE-He213 Electrochemical performance (dpeaa)DE-He213 Energy density (dpeaa)DE-He213 Cycle stability (dpeaa)DE-He213 Zhang, Dongyun aut Chang, Chengkang aut Sheng, Zhaomin aut Huang, Kejun aut Enthalten in Ionics Berlin : Springer, 1995 22(2016), 7 vom: 21. Jan., Seite 1011-1019 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:22 year:2016 number:7 day:21 month:01 pages:1011-1019 https://dx.doi.org/10.1007/s11581-015-1633-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 22 2016 7 21 01 1011-1019 |
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10.1007/s11581-015-1633-6 doi (DE-627)SPR020861451 (SPR)s11581-015-1633-6-e DE-627 ger DE-627 rakwb eng Cai, Yuanyuan verfasserin aut Electrochemical comparison of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2016 Abstract A comparison of electrochemical performance between $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials was conducted in this paper. The cathode samples were synthesized by a nano-milling-assisted solid-state process using caramel as carbon sources. The prepared samples were investigated by XRD, SEM, TEM, energy-dispersive X-ray spectroscopy (EDAX), powder conductivity test (PCT), carbon-sulfur analysis, electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge cycling. The results showed that $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C exhibited high specific capacity and high energy density. The initial discharge capacity of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 163.6 mAh $ g^{−1} $ at 0.1C (1C = 160 mA $ g^{−1} $), compared to 112.3 mAh $ g^{−1} $ for $ LiMnPO_{4} $/C. Moreover, the Fe/Cr-substituted sample showed good cycle stability and rate performance. The capacity retention of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 98.84 % over 100 charge-discharge cycles, while it was only 86.64 % for the pristine $ LiMnPO_{4} $/C. These results indicated that Fe/Cr substitution enhanced the electronic conductivity for the prepared sample and facilitated the $ Li^{+} $ diffusion in the structure. Furthermore, $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C composite presented high energy density (606 Wh $ kg^{−1} $) and high power density (574 W $ kg^{−1} $), thus suggested great potential application in lithium ion batteries (LIBs). Cathode materials (dpeaa)DE-He213 Electrochemical performance (dpeaa)DE-He213 Energy density (dpeaa)DE-He213 Cycle stability (dpeaa)DE-He213 Zhang, Dongyun aut Chang, Chengkang aut Sheng, Zhaomin aut Huang, Kejun aut Enthalten in Ionics Berlin : Springer, 1995 22(2016), 7 vom: 21. Jan., Seite 1011-1019 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:22 year:2016 number:7 day:21 month:01 pages:1011-1019 https://dx.doi.org/10.1007/s11581-015-1633-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 22 2016 7 21 01 1011-1019 |
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10.1007/s11581-015-1633-6 doi (DE-627)SPR020861451 (SPR)s11581-015-1633-6-e DE-627 ger DE-627 rakwb eng Cai, Yuanyuan verfasserin aut Electrochemical comparison of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2016 Abstract A comparison of electrochemical performance between $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials was conducted in this paper. The cathode samples were synthesized by a nano-milling-assisted solid-state process using caramel as carbon sources. The prepared samples were investigated by XRD, SEM, TEM, energy-dispersive X-ray spectroscopy (EDAX), powder conductivity test (PCT), carbon-sulfur analysis, electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge cycling. The results showed that $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C exhibited high specific capacity and high energy density. The initial discharge capacity of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 163.6 mAh $ g^{−1} $ at 0.1C (1C = 160 mA $ g^{−1} $), compared to 112.3 mAh $ g^{−1} $ for $ LiMnPO_{4} $/C. Moreover, the Fe/Cr-substituted sample showed good cycle stability and rate performance. The capacity retention of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 98.84 % over 100 charge-discharge cycles, while it was only 86.64 % for the pristine $ LiMnPO_{4} $/C. These results indicated that Fe/Cr substitution enhanced the electronic conductivity for the prepared sample and facilitated the $ Li^{+} $ diffusion in the structure. Furthermore, $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C composite presented high energy density (606 Wh $ kg^{−1} $) and high power density (574 W $ kg^{−1} $), thus suggested great potential application in lithium ion batteries (LIBs). Cathode materials (dpeaa)DE-He213 Electrochemical performance (dpeaa)DE-He213 Energy density (dpeaa)DE-He213 Cycle stability (dpeaa)DE-He213 Zhang, Dongyun aut Chang, Chengkang aut Sheng, Zhaomin aut Huang, Kejun aut Enthalten in Ionics Berlin : Springer, 1995 22(2016), 7 vom: 21. Jan., Seite 1011-1019 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:22 year:2016 number:7 day:21 month:01 pages:1011-1019 https://dx.doi.org/10.1007/s11581-015-1633-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 22 2016 7 21 01 1011-1019 |
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10.1007/s11581-015-1633-6 doi (DE-627)SPR020861451 (SPR)s11581-015-1633-6-e DE-627 ger DE-627 rakwb eng Cai, Yuanyuan verfasserin aut Electrochemical comparison of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials 2016 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Springer-Verlag Berlin Heidelberg 2016 Abstract A comparison of electrochemical performance between $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials was conducted in this paper. The cathode samples were synthesized by a nano-milling-assisted solid-state process using caramel as carbon sources. The prepared samples were investigated by XRD, SEM, TEM, energy-dispersive X-ray spectroscopy (EDAX), powder conductivity test (PCT), carbon-sulfur analysis, electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge cycling. The results showed that $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C exhibited high specific capacity and high energy density. The initial discharge capacity of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 163.6 mAh $ g^{−1} $ at 0.1C (1C = 160 mA $ g^{−1} $), compared to 112.3 mAh $ g^{−1} $ for $ LiMnPO_{4} $/C. Moreover, the Fe/Cr-substituted sample showed good cycle stability and rate performance. The capacity retention of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 98.84 % over 100 charge-discharge cycles, while it was only 86.64 % for the pristine $ LiMnPO_{4} $/C. These results indicated that Fe/Cr substitution enhanced the electronic conductivity for the prepared sample and facilitated the $ Li^{+} $ diffusion in the structure. Furthermore, $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C composite presented high energy density (606 Wh $ kg^{−1} $) and high power density (574 W $ kg^{−1} $), thus suggested great potential application in lithium ion batteries (LIBs). Cathode materials (dpeaa)DE-He213 Electrochemical performance (dpeaa)DE-He213 Energy density (dpeaa)DE-He213 Cycle stability (dpeaa)DE-He213 Zhang, Dongyun aut Chang, Chengkang aut Sheng, Zhaomin aut Huang, Kejun aut Enthalten in Ionics Berlin : Springer, 1995 22(2016), 7 vom: 21. Jan., Seite 1011-1019 (DE-627)509398944 (DE-600)2226746-3 1862-0760 nnns volume:22 year:2016 number:7 day:21 month:01 pages:1011-1019 https://dx.doi.org/10.1007/s11581-015-1633-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 22 2016 7 21 01 1011-1019 |
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Enthalten in Ionics 22(2016), 7 vom: 21. Jan., Seite 1011-1019 volume:22 year:2016 number:7 day:21 month:01 pages:1011-1019 |
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Enthalten in Ionics 22(2016), 7 vom: 21. Jan., Seite 1011-1019 volume:22 year:2016 number:7 day:21 month:01 pages:1011-1019 |
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Cai, Yuanyuan @@aut@@ Zhang, Dongyun @@aut@@ Chang, Chengkang @@aut@@ Sheng, Zhaomin @@aut@@ Huang, Kejun @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR020861451</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230330174505.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2016 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11581-015-1633-6</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR020861451</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s11581-015-1633-6-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Cai, Yuanyuan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Electrochemical comparison of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2016</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer-Verlag Berlin Heidelberg 2016</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract A comparison of electrochemical performance between $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials was conducted in this paper. The cathode samples were synthesized by a nano-milling-assisted solid-state process using caramel as carbon sources. The prepared samples were investigated by XRD, SEM, TEM, energy-dispersive X-ray spectroscopy (EDAX), powder conductivity test (PCT), carbon-sulfur analysis, electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge cycling. The results showed that $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C exhibited high specific capacity and high energy density. The initial discharge capacity of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 163.6 mAh $ g^{−1} $ at 0.1C (1C = 160 mA $ g^{−1} $), compared to 112.3 mAh $ g^{−1} $ for $ LiMnPO_{4} $/C. Moreover, the Fe/Cr-substituted sample showed good cycle stability and rate performance. The capacity retention of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 98.84 % over 100 charge-discharge cycles, while it was only 86.64 % for the pristine $ LiMnPO_{4} $/C. These results indicated that Fe/Cr substitution enhanced the electronic conductivity for the prepared sample and facilitated the $ Li^{+} $ diffusion in the structure. Furthermore, $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C composite presented high energy density (606 Wh $ kg^{−1} $) and high power density (574 W $ kg^{−1} $), thus suggested great potential application in lithium ion batteries (LIBs).</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Cathode materials</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Electrochemical performance</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Energy density</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Cycle stability</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Dongyun</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chang, Chengkang</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Sheng, Zhaomin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Huang, Kejun</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Ionics</subfield><subfield code="d">Berlin : Springer, 1995</subfield><subfield code="g">22(2016), 7 vom: 21. Jan., Seite 1011-1019</subfield><subfield code="w">(DE-627)509398944</subfield><subfield code="w">(DE-600)2226746-3</subfield><subfield code="x">1862-0760</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:22</subfield><subfield code="g">year:2016</subfield><subfield code="g">number:7</subfield><subfield code="g">day:21</subfield><subfield code="g">month:01</subfield><subfield code="g">pages:1011-1019</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s11581-015-1633-6</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield 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Cai, Yuanyuan |
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Cai, Yuanyuan misc Cathode materials misc Electrochemical performance misc Energy density misc Cycle stability Electrochemical comparison of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials |
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Electrochemical comparison of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials Cathode materials (dpeaa)DE-He213 Electrochemical performance (dpeaa)DE-He213 Energy density (dpeaa)DE-He213 Cycle stability (dpeaa)DE-He213 |
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misc Cathode materials misc Electrochemical performance misc Energy density misc Cycle stability |
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Electrochemical comparison of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials |
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(DE-627)SPR020861451 (SPR)s11581-015-1633-6-e |
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Electrochemical comparison of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials |
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Cai, Yuanyuan Zhang, Dongyun Chang, Chengkang Sheng, Zhaomin Huang, Kejun |
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Elektronische Aufsätze |
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10.1007/s11581-015-1633-6 |
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electrochemical comparison of $ life_{0.4} %$ mn_{0.595} %$ cr_{0.005} %$ po_{4} $/c and $ limnpo_{4} $/c cathode materials |
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Electrochemical comparison of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials |
| abstract |
Abstract A comparison of electrochemical performance between $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials was conducted in this paper. The cathode samples were synthesized by a nano-milling-assisted solid-state process using caramel as carbon sources. The prepared samples were investigated by XRD, SEM, TEM, energy-dispersive X-ray spectroscopy (EDAX), powder conductivity test (PCT), carbon-sulfur analysis, electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge cycling. The results showed that $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C exhibited high specific capacity and high energy density. The initial discharge capacity of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 163.6 mAh $ g^{−1} $ at 0.1C (1C = 160 mA $ g^{−1} $), compared to 112.3 mAh $ g^{−1} $ for $ LiMnPO_{4} $/C. Moreover, the Fe/Cr-substituted sample showed good cycle stability and rate performance. The capacity retention of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 98.84 % over 100 charge-discharge cycles, while it was only 86.64 % for the pristine $ LiMnPO_{4} $/C. These results indicated that Fe/Cr substitution enhanced the electronic conductivity for the prepared sample and facilitated the $ Li^{+} $ diffusion in the structure. Furthermore, $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C composite presented high energy density (606 Wh $ kg^{−1} $) and high power density (574 W $ kg^{−1} $), thus suggested great potential application in lithium ion batteries (LIBs). © Springer-Verlag Berlin Heidelberg 2016 |
| abstractGer |
Abstract A comparison of electrochemical performance between $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials was conducted in this paper. The cathode samples were synthesized by a nano-milling-assisted solid-state process using caramel as carbon sources. The prepared samples were investigated by XRD, SEM, TEM, energy-dispersive X-ray spectroscopy (EDAX), powder conductivity test (PCT), carbon-sulfur analysis, electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge cycling. The results showed that $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C exhibited high specific capacity and high energy density. The initial discharge capacity of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 163.6 mAh $ g^{−1} $ at 0.1C (1C = 160 mA $ g^{−1} $), compared to 112.3 mAh $ g^{−1} $ for $ LiMnPO_{4} $/C. Moreover, the Fe/Cr-substituted sample showed good cycle stability and rate performance. The capacity retention of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 98.84 % over 100 charge-discharge cycles, while it was only 86.64 % for the pristine $ LiMnPO_{4} $/C. These results indicated that Fe/Cr substitution enhanced the electronic conductivity for the prepared sample and facilitated the $ Li^{+} $ diffusion in the structure. Furthermore, $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C composite presented high energy density (606 Wh $ kg^{−1} $) and high power density (574 W $ kg^{−1} $), thus suggested great potential application in lithium ion batteries (LIBs). © Springer-Verlag Berlin Heidelberg 2016 |
| abstract_unstemmed |
Abstract A comparison of electrochemical performance between $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials was conducted in this paper. The cathode samples were synthesized by a nano-milling-assisted solid-state process using caramel as carbon sources. The prepared samples were investigated by XRD, SEM, TEM, energy-dispersive X-ray spectroscopy (EDAX), powder conductivity test (PCT), carbon-sulfur analysis, electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge cycling. The results showed that $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C exhibited high specific capacity and high energy density. The initial discharge capacity of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 163.6 mAh $ g^{−1} $ at 0.1C (1C = 160 mA $ g^{−1} $), compared to 112.3 mAh $ g^{−1} $ for $ LiMnPO_{4} $/C. Moreover, the Fe/Cr-substituted sample showed good cycle stability and rate performance. The capacity retention of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 98.84 % over 100 charge-discharge cycles, while it was only 86.64 % for the pristine $ LiMnPO_{4} $/C. These results indicated that Fe/Cr substitution enhanced the electronic conductivity for the prepared sample and facilitated the $ Li^{+} $ diffusion in the structure. Furthermore, $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C composite presented high energy density (606 Wh $ kg^{−1} $) and high power density (574 W $ kg^{−1} $), thus suggested great potential application in lithium ion batteries (LIBs). © Springer-Verlag Berlin Heidelberg 2016 |
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7 |
| title_short |
Electrochemical comparison of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C and $ LiMnPO_{4} $/C cathode materials |
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https://dx.doi.org/10.1007/s11581-015-1633-6 |
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Zhang, Dongyun Chang, Chengkang Sheng, Zhaomin Huang, Kejun |
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Zhang, Dongyun Chang, Chengkang Sheng, Zhaomin Huang, Kejun |
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| doi_str |
10.1007/s11581-015-1633-6 |
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2024-07-03T18:43:55.539Z |
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The cathode samples were synthesized by a nano-milling-assisted solid-state process using caramel as carbon sources. The prepared samples were investigated by XRD, SEM, TEM, energy-dispersive X-ray spectroscopy (EDAX), powder conductivity test (PCT), carbon-sulfur analysis, electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge cycling. The results showed that $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C exhibited high specific capacity and high energy density. The initial discharge capacity of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 163.6 mAh $ g^{−1} $ at 0.1C (1C = 160 mA $ g^{−1} $), compared to 112.3 mAh $ g^{−1} $ for $ LiMnPO_{4} $/C. Moreover, the Fe/Cr-substituted sample showed good cycle stability and rate performance. The capacity retention of $ LiFe_{0.4} %$ Mn_{0.595} %$ Cr_{0.005} %$ PO_{4} $/C was 98.84 % over 100 charge-discharge cycles, while it was only 86.64 % for the pristine $ LiMnPO_{4} $/C. 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| score |
7.3999805 |