Further Experimental Investigation of Freeze-Lining/Bath Interface at Steady-State Conditions
Abstract In design of the freeze-lining deposits in high-temperature reaction systems, it has been widely assumed that the interface temperature between the deposit and bath at steady-state conditions, that is, when the deposit interface velocity is zero, is the liquidus of the bulk bath material. C...
Ausführliche Beschreibung
Autor*in: |
Fallah-Mehrjardi, Ata [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2014 |
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Schlagwörter: |
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Anmerkung: |
© The Minerals, Metals & Materials Society and ASM International 2014 |
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Übergeordnetes Werk: |
Enthalten in: Metallurgical and materials transactions - New York, NY : Springer Sciences & Business Media, 1975, 45(2014), 6 vom: 06. Aug., Seite 2040-2049 |
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Übergeordnetes Werk: |
volume:45 ; year:2014 ; number:6 ; day:06 ; month:08 ; pages:2040-2049 |
Links: |
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DOI / URN: |
10.1007/s11663-014-0149-1 |
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Katalog-ID: |
SPR021456674 |
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520 | |a Abstract In design of the freeze-lining deposits in high-temperature reaction systems, it has been widely assumed that the interface temperature between the deposit and bath at steady-state conditions, that is, when the deposit interface velocity is zero, is the liquidus of the bulk bath material. Current work provides conclusive evidence that the interface temperature can be lower than that of the bulk liquidus. The observations are consistent with a mechanism involving the nucleation and growth of solids on detached crystals in a subliquidus layer as this fluid material moves toward the stagnant deposit interface and the dissolution of these detached crystals as they are transported away from the interface by turbulent eddies. The temperature and position of the stable deposit/liquid interface are determined by the balance between the extent of crystallization on the detached crystals and mass transfer across the subliquidus layer from the bulk bath. A conceptual framework is developed to analyze the factors influencing the steady-state deposit/interface temperature and deposit thickness in chemical systems operating in a positive temperature gradient. The framework can be used to explain the experimental observations in a diverse range of chemical systems and conditions, including high-temperature melts and aqueous solutions, and to explain why the interface temperature under these conditions can be between Tliquidus and Tsolidus. | ||
650 | 4 | |a Liquidus Temperature |7 (dpeaa)DE-He213 | |
650 | 4 | |a Interface Temperature |7 (dpeaa)DE-He213 | |
650 | 4 | |a Cuprite |7 (dpeaa)DE-He213 | |
650 | 4 | |a Freeze Lining |7 (dpeaa)DE-He213 | |
650 | 4 | |a Deposit Interface |7 (dpeaa)DE-He213 | |
700 | 1 | |a Hayes, Peter |4 aut | |
700 | 1 | |a Jak, Evgueni |4 aut | |
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10.1007/s11663-014-0149-1 doi (DE-627)SPR021456674 (SPR)s11663-014-0149-1-e DE-627 ger DE-627 rakwb eng Fallah-Mehrjardi, Ata verfasserin aut Further Experimental Investigation of Freeze-Lining/Bath Interface at Steady-State Conditions 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Minerals, Metals & Materials Society and ASM International 2014 Abstract In design of the freeze-lining deposits in high-temperature reaction systems, it has been widely assumed that the interface temperature between the deposit and bath at steady-state conditions, that is, when the deposit interface velocity is zero, is the liquidus of the bulk bath material. Current work provides conclusive evidence that the interface temperature can be lower than that of the bulk liquidus. The observations are consistent with a mechanism involving the nucleation and growth of solids on detached crystals in a subliquidus layer as this fluid material moves toward the stagnant deposit interface and the dissolution of these detached crystals as they are transported away from the interface by turbulent eddies. The temperature and position of the stable deposit/liquid interface are determined by the balance between the extent of crystallization on the detached crystals and mass transfer across the subliquidus layer from the bulk bath. A conceptual framework is developed to analyze the factors influencing the steady-state deposit/interface temperature and deposit thickness in chemical systems operating in a positive temperature gradient. The framework can be used to explain the experimental observations in a diverse range of chemical systems and conditions, including high-temperature melts and aqueous solutions, and to explain why the interface temperature under these conditions can be between Tliquidus and Tsolidus. Liquidus Temperature (dpeaa)DE-He213 Interface Temperature (dpeaa)DE-He213 Cuprite (dpeaa)DE-He213 Freeze Lining (dpeaa)DE-He213 Deposit Interface (dpeaa)DE-He213 Hayes, Peter aut Jak, Evgueni aut Enthalten in Metallurgical and materials transactions New York, NY : Springer Sciences & Business Media, 1975 45(2014), 6 vom: 06. Aug., Seite 2040-2049 (DE-627)325572062 (DE-600)2037524-4 1543-1916 nnns volume:45 year:2014 number:6 day:06 month:08 pages:2040-2049 https://dx.doi.org/10.1007/s11663-014-0149-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 45 2014 6 06 08 2040-2049 |
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10.1007/s11663-014-0149-1 doi (DE-627)SPR021456674 (SPR)s11663-014-0149-1-e DE-627 ger DE-627 rakwb eng Fallah-Mehrjardi, Ata verfasserin aut Further Experimental Investigation of Freeze-Lining/Bath Interface at Steady-State Conditions 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Minerals, Metals & Materials Society and ASM International 2014 Abstract In design of the freeze-lining deposits in high-temperature reaction systems, it has been widely assumed that the interface temperature between the deposit and bath at steady-state conditions, that is, when the deposit interface velocity is zero, is the liquidus of the bulk bath material. Current work provides conclusive evidence that the interface temperature can be lower than that of the bulk liquidus. The observations are consistent with a mechanism involving the nucleation and growth of solids on detached crystals in a subliquidus layer as this fluid material moves toward the stagnant deposit interface and the dissolution of these detached crystals as they are transported away from the interface by turbulent eddies. The temperature and position of the stable deposit/liquid interface are determined by the balance between the extent of crystallization on the detached crystals and mass transfer across the subliquidus layer from the bulk bath. A conceptual framework is developed to analyze the factors influencing the steady-state deposit/interface temperature and deposit thickness in chemical systems operating in a positive temperature gradient. The framework can be used to explain the experimental observations in a diverse range of chemical systems and conditions, including high-temperature melts and aqueous solutions, and to explain why the interface temperature under these conditions can be between Tliquidus and Tsolidus. Liquidus Temperature (dpeaa)DE-He213 Interface Temperature (dpeaa)DE-He213 Cuprite (dpeaa)DE-He213 Freeze Lining (dpeaa)DE-He213 Deposit Interface (dpeaa)DE-He213 Hayes, Peter aut Jak, Evgueni aut Enthalten in Metallurgical and materials transactions New York, NY : Springer Sciences & Business Media, 1975 45(2014), 6 vom: 06. Aug., Seite 2040-2049 (DE-627)325572062 (DE-600)2037524-4 1543-1916 nnns volume:45 year:2014 number:6 day:06 month:08 pages:2040-2049 https://dx.doi.org/10.1007/s11663-014-0149-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 45 2014 6 06 08 2040-2049 |
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10.1007/s11663-014-0149-1 doi (DE-627)SPR021456674 (SPR)s11663-014-0149-1-e DE-627 ger DE-627 rakwb eng Fallah-Mehrjardi, Ata verfasserin aut Further Experimental Investigation of Freeze-Lining/Bath Interface at Steady-State Conditions 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Minerals, Metals & Materials Society and ASM International 2014 Abstract In design of the freeze-lining deposits in high-temperature reaction systems, it has been widely assumed that the interface temperature between the deposit and bath at steady-state conditions, that is, when the deposit interface velocity is zero, is the liquidus of the bulk bath material. Current work provides conclusive evidence that the interface temperature can be lower than that of the bulk liquidus. The observations are consistent with a mechanism involving the nucleation and growth of solids on detached crystals in a subliquidus layer as this fluid material moves toward the stagnant deposit interface and the dissolution of these detached crystals as they are transported away from the interface by turbulent eddies. The temperature and position of the stable deposit/liquid interface are determined by the balance between the extent of crystallization on the detached crystals and mass transfer across the subliquidus layer from the bulk bath. A conceptual framework is developed to analyze the factors influencing the steady-state deposit/interface temperature and deposit thickness in chemical systems operating in a positive temperature gradient. The framework can be used to explain the experimental observations in a diverse range of chemical systems and conditions, including high-temperature melts and aqueous solutions, and to explain why the interface temperature under these conditions can be between Tliquidus and Tsolidus. Liquidus Temperature (dpeaa)DE-He213 Interface Temperature (dpeaa)DE-He213 Cuprite (dpeaa)DE-He213 Freeze Lining (dpeaa)DE-He213 Deposit Interface (dpeaa)DE-He213 Hayes, Peter aut Jak, Evgueni aut Enthalten in Metallurgical and materials transactions New York, NY : Springer Sciences & Business Media, 1975 45(2014), 6 vom: 06. Aug., Seite 2040-2049 (DE-627)325572062 (DE-600)2037524-4 1543-1916 nnns volume:45 year:2014 number:6 day:06 month:08 pages:2040-2049 https://dx.doi.org/10.1007/s11663-014-0149-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 45 2014 6 06 08 2040-2049 |
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10.1007/s11663-014-0149-1 doi (DE-627)SPR021456674 (SPR)s11663-014-0149-1-e DE-627 ger DE-627 rakwb eng Fallah-Mehrjardi, Ata verfasserin aut Further Experimental Investigation of Freeze-Lining/Bath Interface at Steady-State Conditions 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Minerals, Metals & Materials Society and ASM International 2014 Abstract In design of the freeze-lining deposits in high-temperature reaction systems, it has been widely assumed that the interface temperature between the deposit and bath at steady-state conditions, that is, when the deposit interface velocity is zero, is the liquidus of the bulk bath material. Current work provides conclusive evidence that the interface temperature can be lower than that of the bulk liquidus. The observations are consistent with a mechanism involving the nucleation and growth of solids on detached crystals in a subliquidus layer as this fluid material moves toward the stagnant deposit interface and the dissolution of these detached crystals as they are transported away from the interface by turbulent eddies. The temperature and position of the stable deposit/liquid interface are determined by the balance between the extent of crystallization on the detached crystals and mass transfer across the subliquidus layer from the bulk bath. A conceptual framework is developed to analyze the factors influencing the steady-state deposit/interface temperature and deposit thickness in chemical systems operating in a positive temperature gradient. The framework can be used to explain the experimental observations in a diverse range of chemical systems and conditions, including high-temperature melts and aqueous solutions, and to explain why the interface temperature under these conditions can be between Tliquidus and Tsolidus. Liquidus Temperature (dpeaa)DE-He213 Interface Temperature (dpeaa)DE-He213 Cuprite (dpeaa)DE-He213 Freeze Lining (dpeaa)DE-He213 Deposit Interface (dpeaa)DE-He213 Hayes, Peter aut Jak, Evgueni aut Enthalten in Metallurgical and materials transactions New York, NY : Springer Sciences & Business Media, 1975 45(2014), 6 vom: 06. Aug., Seite 2040-2049 (DE-627)325572062 (DE-600)2037524-4 1543-1916 nnns volume:45 year:2014 number:6 day:06 month:08 pages:2040-2049 https://dx.doi.org/10.1007/s11663-014-0149-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 45 2014 6 06 08 2040-2049 |
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10.1007/s11663-014-0149-1 doi (DE-627)SPR021456674 (SPR)s11663-014-0149-1-e DE-627 ger DE-627 rakwb eng Fallah-Mehrjardi, Ata verfasserin aut Further Experimental Investigation of Freeze-Lining/Bath Interface at Steady-State Conditions 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Minerals, Metals & Materials Society and ASM International 2014 Abstract In design of the freeze-lining deposits in high-temperature reaction systems, it has been widely assumed that the interface temperature between the deposit and bath at steady-state conditions, that is, when the deposit interface velocity is zero, is the liquidus of the bulk bath material. Current work provides conclusive evidence that the interface temperature can be lower than that of the bulk liquidus. The observations are consistent with a mechanism involving the nucleation and growth of solids on detached crystals in a subliquidus layer as this fluid material moves toward the stagnant deposit interface and the dissolution of these detached crystals as they are transported away from the interface by turbulent eddies. The temperature and position of the stable deposit/liquid interface are determined by the balance between the extent of crystallization on the detached crystals and mass transfer across the subliquidus layer from the bulk bath. A conceptual framework is developed to analyze the factors influencing the steady-state deposit/interface temperature and deposit thickness in chemical systems operating in a positive temperature gradient. The framework can be used to explain the experimental observations in a diverse range of chemical systems and conditions, including high-temperature melts and aqueous solutions, and to explain why the interface temperature under these conditions can be between Tliquidus and Tsolidus. Liquidus Temperature (dpeaa)DE-He213 Interface Temperature (dpeaa)DE-He213 Cuprite (dpeaa)DE-He213 Freeze Lining (dpeaa)DE-He213 Deposit Interface (dpeaa)DE-He213 Hayes, Peter aut Jak, Evgueni aut Enthalten in Metallurgical and materials transactions New York, NY : Springer Sciences & Business Media, 1975 45(2014), 6 vom: 06. Aug., Seite 2040-2049 (DE-627)325572062 (DE-600)2037524-4 1543-1916 nnns volume:45 year:2014 number:6 day:06 month:08 pages:2040-2049 https://dx.doi.org/10.1007/s11663-014-0149-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 45 2014 6 06 08 2040-2049 |
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Enthalten in Metallurgical and materials transactions 45(2014), 6 vom: 06. Aug., Seite 2040-2049 volume:45 year:2014 number:6 day:06 month:08 pages:2040-2049 |
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Fallah-Mehrjardi, Ata @@aut@@ Hayes, Peter @@aut@@ Jak, Evgueni @@aut@@ |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR021456674</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519191128.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2014 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11663-014-0149-1</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR021456674</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s11663-014-0149-1-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Fallah-Mehrjardi, Ata</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Further Experimental Investigation of Freeze-Lining/Bath Interface at Steady-State Conditions</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2014</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Minerals, Metals & Materials Society and ASM International 2014</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract In design of the freeze-lining deposits in high-temperature reaction systems, it has been widely assumed that the interface temperature between the deposit and bath at steady-state conditions, that is, when the deposit interface velocity is zero, is the liquidus of the bulk bath material. Current work provides conclusive evidence that the interface temperature can be lower than that of the bulk liquidus. The observations are consistent with a mechanism involving the nucleation and growth of solids on detached crystals in a subliquidus layer as this fluid material moves toward the stagnant deposit interface and the dissolution of these detached crystals as they are transported away from the interface by turbulent eddies. The temperature and position of the stable deposit/liquid interface are determined by the balance between the extent of crystallization on the detached crystals and mass transfer across the subliquidus layer from the bulk bath. A conceptual framework is developed to analyze the factors influencing the steady-state deposit/interface temperature and deposit thickness in chemical systems operating in a positive temperature gradient. 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Fallah-Mehrjardi, Ata |
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Fallah-Mehrjardi, Ata misc Liquidus Temperature misc Interface Temperature misc Cuprite misc Freeze Lining misc Deposit Interface Further Experimental Investigation of Freeze-Lining/Bath Interface at Steady-State Conditions |
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Further Experimental Investigation of Freeze-Lining/Bath Interface at Steady-State Conditions Liquidus Temperature (dpeaa)DE-He213 Interface Temperature (dpeaa)DE-He213 Cuprite (dpeaa)DE-He213 Freeze Lining (dpeaa)DE-He213 Deposit Interface (dpeaa)DE-He213 |
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Further Experimental Investigation of Freeze-Lining/Bath Interface at Steady-State Conditions |
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Further Experimental Investigation of Freeze-Lining/Bath Interface at Steady-State Conditions |
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further experimental investigation of freeze-lining/bath interface at steady-state conditions |
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Further Experimental Investigation of Freeze-Lining/Bath Interface at Steady-State Conditions |
abstract |
Abstract In design of the freeze-lining deposits in high-temperature reaction systems, it has been widely assumed that the interface temperature between the deposit and bath at steady-state conditions, that is, when the deposit interface velocity is zero, is the liquidus of the bulk bath material. Current work provides conclusive evidence that the interface temperature can be lower than that of the bulk liquidus. The observations are consistent with a mechanism involving the nucleation and growth of solids on detached crystals in a subliquidus layer as this fluid material moves toward the stagnant deposit interface and the dissolution of these detached crystals as they are transported away from the interface by turbulent eddies. The temperature and position of the stable deposit/liquid interface are determined by the balance between the extent of crystallization on the detached crystals and mass transfer across the subliquidus layer from the bulk bath. A conceptual framework is developed to analyze the factors influencing the steady-state deposit/interface temperature and deposit thickness in chemical systems operating in a positive temperature gradient. The framework can be used to explain the experimental observations in a diverse range of chemical systems and conditions, including high-temperature melts and aqueous solutions, and to explain why the interface temperature under these conditions can be between Tliquidus and Tsolidus. © The Minerals, Metals & Materials Society and ASM International 2014 |
abstractGer |
Abstract In design of the freeze-lining deposits in high-temperature reaction systems, it has been widely assumed that the interface temperature between the deposit and bath at steady-state conditions, that is, when the deposit interface velocity is zero, is the liquidus of the bulk bath material. Current work provides conclusive evidence that the interface temperature can be lower than that of the bulk liquidus. The observations are consistent with a mechanism involving the nucleation and growth of solids on detached crystals in a subliquidus layer as this fluid material moves toward the stagnant deposit interface and the dissolution of these detached crystals as they are transported away from the interface by turbulent eddies. The temperature and position of the stable deposit/liquid interface are determined by the balance between the extent of crystallization on the detached crystals and mass transfer across the subliquidus layer from the bulk bath. A conceptual framework is developed to analyze the factors influencing the steady-state deposit/interface temperature and deposit thickness in chemical systems operating in a positive temperature gradient. The framework can be used to explain the experimental observations in a diverse range of chemical systems and conditions, including high-temperature melts and aqueous solutions, and to explain why the interface temperature under these conditions can be between Tliquidus and Tsolidus. © The Minerals, Metals & Materials Society and ASM International 2014 |
abstract_unstemmed |
Abstract In design of the freeze-lining deposits in high-temperature reaction systems, it has been widely assumed that the interface temperature between the deposit and bath at steady-state conditions, that is, when the deposit interface velocity is zero, is the liquidus of the bulk bath material. Current work provides conclusive evidence that the interface temperature can be lower than that of the bulk liquidus. The observations are consistent with a mechanism involving the nucleation and growth of solids on detached crystals in a subliquidus layer as this fluid material moves toward the stagnant deposit interface and the dissolution of these detached crystals as they are transported away from the interface by turbulent eddies. The temperature and position of the stable deposit/liquid interface are determined by the balance between the extent of crystallization on the detached crystals and mass transfer across the subliquidus layer from the bulk bath. A conceptual framework is developed to analyze the factors influencing the steady-state deposit/interface temperature and deposit thickness in chemical systems operating in a positive temperature gradient. The framework can be used to explain the experimental observations in a diverse range of chemical systems and conditions, including high-temperature melts and aqueous solutions, and to explain why the interface temperature under these conditions can be between Tliquidus and Tsolidus. © The Minerals, Metals & Materials Society and ASM International 2014 |
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container_issue |
6 |
title_short |
Further Experimental Investigation of Freeze-Lining/Bath Interface at Steady-State Conditions |
url |
https://dx.doi.org/10.1007/s11663-014-0149-1 |
remote_bool |
true |
author2 |
Hayes, Peter Jak, Evgueni |
author2Str |
Hayes, Peter Jak, Evgueni |
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doi_str |
10.1007/s11663-014-0149-1 |
up_date |
2024-07-03T22:40:21.579Z |
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|
score |
7.401231 |