Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites

Abstract p-Type $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ (0.8 ≤ z ≤1.0, and 0.25 ≤ x ≤0.5) skutterudites were prepared, and the effects of Yb filling and Ni substitution on the thermoelectric properties were examined. X-ray diffraction patterns revealed that $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Lee, Woo-Man [verfasserIn] Shin, Dong-Kil Kim, Il-Ho

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2014

Schlagwörter:	Thermoelectric skutterudite filling charge compensation

Anmerkung:	© The Minerals, Metals & Materials Society 2014

Übergeordnetes Werk:	Enthalten in: Journal of electronic materials - Warrendale, Pa : TMS, 1972, 44(2014), 6 vom: 13. Sept., Seite 1432-1437
Übergeordnetes Werk:	volume:44 ; year:2014 ; number:6 ; day:13 ; month:09 ; pages:1432-1437

Links:	Volltext

DOI / URN:	10.1007/s11664-014-3401-1

Katalog-ID:	SPR021521646

Internformat


LEADER	01000caa a22002652 4500
001	SPR021521646
003	DE-627
005	20230331055101.0
007	cr uuu---uuuuu
008	201006s2014 xx \|\|\|\|\|o 00\| \|\|eng c
024	7		\|a 10.1007/s11664-014-3401-1 \|2 doi
035			\|a (DE-627)SPR021521646
035			\|a (SPR)s11664-014-3401-1-e
040			\|a DE-627 \|b ger \|c DE-627 \|e rakwb
041			\|a eng
100	1		\|a Lee, Woo-Man \|e verfasserin \|4 aut
245	1	0	\|a Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites
264		1	\|c 2014
336			\|a Text \|b txt \|2 rdacontent
337			\|a Computermedien \|b c \|2 rdamedia
338			\|a Online-Ressource \|b cr \|2 rdacarrier
500			\|a © The Minerals, Metals & Materials Society 2014
520			\|a Abstract p-Type $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ (0.8 ≤ z ≤1.0, and 0.25 ≤ x ≤0.5) skutterudites were prepared, and the effects of Yb filling and Ni substitution on the thermoelectric properties were examined. X-ray diffraction patterns revealed that $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ skutterudites were synthesized, but small amounts of secondary phases ($ FeSb_{2} $ and Sb) were produced, except for the $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ specimen. This meant that the charge compensation with Ni and the amount of Yb filling should be sufficient to stabilize the skutterudite structure. All specimens had positive Hall coefficients and Seebeck coefficients, and the carrier concentration ranged from 9.80 × $ 10^{20} $ $ cm^{−3} $ to 3.37 × $ 10^{21} $ $ cm^{−3} $. The electrical conductivity decreased and the Seebeck coefficient increased with increasing Yb and Ni contents due to the decreased carrier concentration. The thermal conductivity decreased with increasing Yb and Ni contents, and $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ showed the lowest thermal conductivity. The maximum dimensionless figure of merit achieved was of 0.62 at 723 K for $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $, based on the high power factor (2.6 $ mWm^{−1} $ $ K^{−2} $) and the low thermal conductivity (2.9 $ Wm^{−1} $ $ K^{−1} $).
650		4	\|a Thermoelectric \|7 (dpeaa)DE-He213
650		4	\|a skutterudite \|7 (dpeaa)DE-He213
650		4	\|a filling \|7 (dpeaa)DE-He213
650		4	\|a charge compensation \|7 (dpeaa)DE-He213
700	1		\|a Shin, Dong-Kil \|4 aut
700	1		\|a Kim, Il-Ho \|4 aut
773	0	8	\|i Enthalten in \|t Journal of electronic materials \|d Warrendale, Pa : TMS, 1972 \|g 44(2014), 6 vom: 13. Sept., Seite 1432-1437 \|w (DE-627)324918739 \|w (DE-600)2032868-0 \|x 1543-186X \|7 nnns
773	1	8	\|g volume:44 \|g year:2014 \|g number:6 \|g day:13 \|g month:09 \|g pages:1432-1437
856	4	0	\|u https://dx.doi.org/10.1007/s11664-014-3401-1 \|z lizenzpflichtig \|3 Volltext
912			\|a GBV_USEFLAG_A
912			\|a SYSFLAG_A
912			\|a GBV_SPRINGER
912			\|a GBV_ILN_11
912			\|a GBV_ILN_20
912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_39
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_63
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_120
912			\|a GBV_ILN_138
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_152
912			\|a GBV_ILN_161
912			\|a GBV_ILN_170
912			\|a GBV_ILN_171
912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_250
912			\|a GBV_ILN_281
912			\|a GBV_ILN_285
912			\|a GBV_ILN_293
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_636
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2006
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2031
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2037
912			\|a GBV_ILN_2038
912			\|a GBV_ILN_2039
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2057
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2065
912			\|a GBV_ILN_2068
912			\|a GBV_ILN_2070
912			\|a GBV_ILN_2086
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2093
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2107
912			\|a GBV_ILN_2108
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2113
912			\|a GBV_ILN_2116
912			\|a GBV_ILN_2118
912			\|a GBV_ILN_2119
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2144
912			\|a GBV_ILN_2147
912			\|a GBV_ILN_2148
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2188
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2232
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2446
912			\|a GBV_ILN_2470
912			\|a GBV_ILN_2472
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_2522
912			\|a GBV_ILN_2548
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4046
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4246
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4328
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4335
912			\|a GBV_ILN_4336
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
912			\|a GBV_ILN_4700
951			\|a AR
952			\|d 44 \|j 2014 \|e 6 \|b 13 \|c 09 \|h 1432-1437

Indexfelder

author_variant	w m l wml d k s dks i h k ihk
matchkey_str	article:1543186X:2014----::hrolcrcntasotrprisfbze4n_
hierarchy_sort_str	2014
publishDate	2014
allfields	10.1007/s11664-014-3401-1 doi (DE-627)SPR021521646 (SPR)s11664-014-3401-1-e DE-627 ger DE-627 rakwb eng Lee, Woo-Man verfasserin aut Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Minerals, Metals & Materials Society 2014 Abstract p-Type $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ (0.8 ≤ z ≤1.0, and 0.25 ≤ x ≤0.5) skutterudites were prepared, and the effects of Yb filling and Ni substitution on the thermoelectric properties were examined. X-ray diffraction patterns revealed that $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ skutterudites were synthesized, but small amounts of secondary phases ($ FeSb_{2} $ and Sb) were produced, except for the $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ specimen. This meant that the charge compensation with Ni and the amount of Yb filling should be sufficient to stabilize the skutterudite structure. All specimens had positive Hall coefficients and Seebeck coefficients, and the carrier concentration ranged from 9.80 × $ 10^{20} $ $ cm^{−3} $ to 3.37 × $ 10^{21} $ $ cm^{−3} $. The electrical conductivity decreased and the Seebeck coefficient increased with increasing Yb and Ni contents due to the decreased carrier concentration. The thermal conductivity decreased with increasing Yb and Ni contents, and $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ showed the lowest thermal conductivity. The maximum dimensionless figure of merit achieved was of 0.62 at 723 K for $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $, based on the high power factor (2.6 $ mWm^{−1} $ $ K^{−2} $) and the low thermal conductivity (2.9 $ Wm^{−1} $ $ K^{−1} $). Thermoelectric (dpeaa)DE-He213 skutterudite (dpeaa)DE-He213 filling (dpeaa)DE-He213 charge compensation (dpeaa)DE-He213 Shin, Dong-Kil aut Kim, Il-Ho aut Enthalten in Journal of electronic materials Warrendale, Pa : TMS, 1972 44(2014), 6 vom: 13. Sept., Seite 1432-1437 (DE-627)324918739 (DE-600)2032868-0 1543-186X nnns volume:44 year:2014 number:6 day:13 month:09 pages:1432-1437 https://dx.doi.org/10.1007/s11664-014-3401-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 44 2014 6 13 09 1432-1437
spelling	10.1007/s11664-014-3401-1 doi (DE-627)SPR021521646 (SPR)s11664-014-3401-1-e DE-627 ger DE-627 rakwb eng Lee, Woo-Man verfasserin aut Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Minerals, Metals & Materials Society 2014 Abstract p-Type $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ (0.8 ≤ z ≤1.0, and 0.25 ≤ x ≤0.5) skutterudites were prepared, and the effects of Yb filling and Ni substitution on the thermoelectric properties were examined. X-ray diffraction patterns revealed that $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ skutterudites were synthesized, but small amounts of secondary phases ($ FeSb_{2} $ and Sb) were produced, except for the $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ specimen. This meant that the charge compensation with Ni and the amount of Yb filling should be sufficient to stabilize the skutterudite structure. All specimens had positive Hall coefficients and Seebeck coefficients, and the carrier concentration ranged from 9.80 × $ 10^{20} $ $ cm^{−3} $ to 3.37 × $ 10^{21} $ $ cm^{−3} $. The electrical conductivity decreased and the Seebeck coefficient increased with increasing Yb and Ni contents due to the decreased carrier concentration. The thermal conductivity decreased with increasing Yb and Ni contents, and $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ showed the lowest thermal conductivity. The maximum dimensionless figure of merit achieved was of 0.62 at 723 K for $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $, based on the high power factor (2.6 $ mWm^{−1} $ $ K^{−2} $) and the low thermal conductivity (2.9 $ Wm^{−1} $ $ K^{−1} $). Thermoelectric (dpeaa)DE-He213 skutterudite (dpeaa)DE-He213 filling (dpeaa)DE-He213 charge compensation (dpeaa)DE-He213 Shin, Dong-Kil aut Kim, Il-Ho aut Enthalten in Journal of electronic materials Warrendale, Pa : TMS, 1972 44(2014), 6 vom: 13. Sept., Seite 1432-1437 (DE-627)324918739 (DE-600)2032868-0 1543-186X nnns volume:44 year:2014 number:6 day:13 month:09 pages:1432-1437 https://dx.doi.org/10.1007/s11664-014-3401-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 44 2014 6 13 09 1432-1437
allfields_unstemmed	10.1007/s11664-014-3401-1 doi (DE-627)SPR021521646 (SPR)s11664-014-3401-1-e DE-627 ger DE-627 rakwb eng Lee, Woo-Man verfasserin aut Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Minerals, Metals & Materials Society 2014 Abstract p-Type $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ (0.8 ≤ z ≤1.0, and 0.25 ≤ x ≤0.5) skutterudites were prepared, and the effects of Yb filling and Ni substitution on the thermoelectric properties were examined. X-ray diffraction patterns revealed that $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ skutterudites were synthesized, but small amounts of secondary phases ($ FeSb_{2} $ and Sb) were produced, except for the $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ specimen. This meant that the charge compensation with Ni and the amount of Yb filling should be sufficient to stabilize the skutterudite structure. All specimens had positive Hall coefficients and Seebeck coefficients, and the carrier concentration ranged from 9.80 × $ 10^{20} $ $ cm^{−3} $ to 3.37 × $ 10^{21} $ $ cm^{−3} $. The electrical conductivity decreased and the Seebeck coefficient increased with increasing Yb and Ni contents due to the decreased carrier concentration. The thermal conductivity decreased with increasing Yb and Ni contents, and $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ showed the lowest thermal conductivity. The maximum dimensionless figure of merit achieved was of 0.62 at 723 K for $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $, based on the high power factor (2.6 $ mWm^{−1} $ $ K^{−2} $) and the low thermal conductivity (2.9 $ Wm^{−1} $ $ K^{−1} $). Thermoelectric (dpeaa)DE-He213 skutterudite (dpeaa)DE-He213 filling (dpeaa)DE-He213 charge compensation (dpeaa)DE-He213 Shin, Dong-Kil aut Kim, Il-Ho aut Enthalten in Journal of electronic materials Warrendale, Pa : TMS, 1972 44(2014), 6 vom: 13. Sept., Seite 1432-1437 (DE-627)324918739 (DE-600)2032868-0 1543-186X nnns volume:44 year:2014 number:6 day:13 month:09 pages:1432-1437 https://dx.doi.org/10.1007/s11664-014-3401-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 44 2014 6 13 09 1432-1437
allfieldsGer	10.1007/s11664-014-3401-1 doi (DE-627)SPR021521646 (SPR)s11664-014-3401-1-e DE-627 ger DE-627 rakwb eng Lee, Woo-Man verfasserin aut Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Minerals, Metals & Materials Society 2014 Abstract p-Type $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ (0.8 ≤ z ≤1.0, and 0.25 ≤ x ≤0.5) skutterudites were prepared, and the effects of Yb filling and Ni substitution on the thermoelectric properties were examined. X-ray diffraction patterns revealed that $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ skutterudites were synthesized, but small amounts of secondary phases ($ FeSb_{2} $ and Sb) were produced, except for the $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ specimen. This meant that the charge compensation with Ni and the amount of Yb filling should be sufficient to stabilize the skutterudite structure. All specimens had positive Hall coefficients and Seebeck coefficients, and the carrier concentration ranged from 9.80 × $ 10^{20} $ $ cm^{−3} $ to 3.37 × $ 10^{21} $ $ cm^{−3} $. The electrical conductivity decreased and the Seebeck coefficient increased with increasing Yb and Ni contents due to the decreased carrier concentration. The thermal conductivity decreased with increasing Yb and Ni contents, and $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ showed the lowest thermal conductivity. The maximum dimensionless figure of merit achieved was of 0.62 at 723 K for $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $, based on the high power factor (2.6 $ mWm^{−1} $ $ K^{−2} $) and the low thermal conductivity (2.9 $ Wm^{−1} $ $ K^{−1} $). Thermoelectric (dpeaa)DE-He213 skutterudite (dpeaa)DE-He213 filling (dpeaa)DE-He213 charge compensation (dpeaa)DE-He213 Shin, Dong-Kil aut Kim, Il-Ho aut Enthalten in Journal of electronic materials Warrendale, Pa : TMS, 1972 44(2014), 6 vom: 13. Sept., Seite 1432-1437 (DE-627)324918739 (DE-600)2032868-0 1543-186X nnns volume:44 year:2014 number:6 day:13 month:09 pages:1432-1437 https://dx.doi.org/10.1007/s11664-014-3401-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 44 2014 6 13 09 1432-1437
allfieldsSound	10.1007/s11664-014-3401-1 doi (DE-627)SPR021521646 (SPR)s11664-014-3401-1-e DE-627 ger DE-627 rakwb eng Lee, Woo-Man verfasserin aut Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites 2014 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © The Minerals, Metals & Materials Society 2014 Abstract p-Type $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ (0.8 ≤ z ≤1.0, and 0.25 ≤ x ≤0.5) skutterudites were prepared, and the effects of Yb filling and Ni substitution on the thermoelectric properties were examined. X-ray diffraction patterns revealed that $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ skutterudites were synthesized, but small amounts of secondary phases ($ FeSb_{2} $ and Sb) were produced, except for the $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ specimen. This meant that the charge compensation with Ni and the amount of Yb filling should be sufficient to stabilize the skutterudite structure. All specimens had positive Hall coefficients and Seebeck coefficients, and the carrier concentration ranged from 9.80 × $ 10^{20} $ $ cm^{−3} $ to 3.37 × $ 10^{21} $ $ cm^{−3} $. The electrical conductivity decreased and the Seebeck coefficient increased with increasing Yb and Ni contents due to the decreased carrier concentration. The thermal conductivity decreased with increasing Yb and Ni contents, and $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ showed the lowest thermal conductivity. The maximum dimensionless figure of merit achieved was of 0.62 at 723 K for $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $, based on the high power factor (2.6 $ mWm^{−1} $ $ K^{−2} $) and the low thermal conductivity (2.9 $ Wm^{−1} $ $ K^{−1} $). Thermoelectric (dpeaa)DE-He213 skutterudite (dpeaa)DE-He213 filling (dpeaa)DE-He213 charge compensation (dpeaa)DE-He213 Shin, Dong-Kil aut Kim, Il-Ho aut Enthalten in Journal of electronic materials Warrendale, Pa : TMS, 1972 44(2014), 6 vom: 13. Sept., Seite 1432-1437 (DE-627)324918739 (DE-600)2032868-0 1543-186X nnns volume:44 year:2014 number:6 day:13 month:09 pages:1432-1437 https://dx.doi.org/10.1007/s11664-014-3401-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 44 2014 6 13 09 1432-1437
language	English
source	Enthalten in Journal of electronic materials 44(2014), 6 vom: 13. Sept., Seite 1432-1437 volume:44 year:2014 number:6 day:13 month:09 pages:1432-1437
sourceStr	Enthalten in Journal of electronic materials 44(2014), 6 vom: 13. Sept., Seite 1432-1437 volume:44 year:2014 number:6 day:13 month:09 pages:1432-1437
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Thermoelectric skutterudite filling charge compensation
isfreeaccess_bool	false
container_title	Journal of electronic materials
authorswithroles_txt_mv	Lee, Woo-Man @@aut@@ Shin, Dong-Kil @@aut@@ Kim, Il-Ho @@aut@@
publishDateDaySort_date	2014-09-13T00:00:00Z
hierarchy_top_id	324918739
id	SPR021521646
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR021521646</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230331055101.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2014 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11664-014-3401-1</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR021521646</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s11664-014-3401-1-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Lee, Woo-Man</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2014</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Minerals, Metals & Materials Society 2014</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract p-Type $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ (0.8 ≤ z ≤1.0, and 0.25 ≤ x ≤0.5) skutterudites were prepared, and the effects of Yb filling and Ni substitution on the thermoelectric properties were examined. X-ray diffraction patterns revealed that $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ skutterudites were synthesized, but small amounts of secondary phases ($ FeSb_{2} $ and Sb) were produced, except for the $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ specimen. This meant that the charge compensation with Ni and the amount of Yb filling should be sufficient to stabilize the skutterudite structure. All specimens had positive Hall coefficients and Seebeck coefficients, and the carrier concentration ranged from 9.80 × $ 10^{20} $ $ cm^{−3} $ to 3.37 × $ 10^{21} $ $ cm^{−3} $. The electrical conductivity decreased and the Seebeck coefficient increased with increasing Yb and Ni contents due to the decreased carrier concentration. The thermal conductivity decreased with increasing Yb and Ni contents, and $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ showed the lowest thermal conductivity. The maximum dimensionless figure of merit achieved was of 0.62 at 723 K for $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $, based on the high power factor (2.6 $ mWm^{−1} $ $ K^{−2} $) and the low thermal conductivity (2.9 $ Wm^{−1} $ $ K^{−1} $).</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Thermoelectric</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">skutterudite</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">filling</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">charge compensation</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Shin, Dong-Kil</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kim, Il-Ho</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of electronic materials</subfield><subfield code="d">Warrendale, Pa : TMS, 1972</subfield><subfield code="g">44(2014), 6 vom: 13. Sept., Seite 1432-1437</subfield><subfield code="w">(DE-627)324918739</subfield><subfield code="w">(DE-600)2032868-0</subfield><subfield code="x">1543-186X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:44</subfield><subfield code="g">year:2014</subfield><subfield code="g">number:6</subfield><subfield code="g">day:13</subfield><subfield code="g">month:09</subfield><subfield code="g">pages:1432-1437</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s11664-014-3401-1</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_11</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_120</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_138</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_171</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_250</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_281</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_636</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2031</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2039</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2057</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2070</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2086</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2093</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2107</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2108</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2116</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2119</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2144</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2188</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2446</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2472</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2548</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4246</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4328</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">44</subfield><subfield code="j">2014</subfield><subfield code="e">6</subfield><subfield code="b">13</subfield><subfield code="c">09</subfield><subfield code="h">1432-1437</subfield></datafield></record></collection>
author	Lee, Woo-Man
spellingShingle	Lee, Woo-Man misc Thermoelectric misc skutterudite misc filling misc charge compensation Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites
authorStr	Lee, Woo-Man
ppnlink_with_tag_str_mv	@@773@@(DE-627)324918739
format	electronic Article
delete_txt_mv	keep
author_role	aut aut aut
collection	springer
remote_str	true
illustrated	Not Illustrated
issn	1543-186X
topic_title	Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites Thermoelectric (dpeaa)DE-He213 skutterudite (dpeaa)DE-He213 filling (dpeaa)DE-He213 charge compensation (dpeaa)DE-He213
topic	misc Thermoelectric misc skutterudite misc filling misc charge compensation
topic_unstemmed	misc Thermoelectric misc skutterudite misc filling misc charge compensation
topic_browse	misc Thermoelectric misc skutterudite misc filling misc charge compensation
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	cr
hierarchy_parent_title	Journal of electronic materials
hierarchy_parent_id	324918739
hierarchy_top_title	Journal of electronic materials
isfreeaccess_txt	false
familylinks_str_mv	(DE-627)324918739 (DE-600)2032868-0
title	Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites
ctrlnum	(DE-627)SPR021521646 (SPR)s11664-014-3401-1-e
title_full	Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites
author_sort	Lee, Woo-Man
journal	Journal of electronic materials
journalStr	Journal of electronic materials
lang_code	eng
isOA_bool	false
recordtype	marc
publishDateSort	2014
contenttype_str_mv	txt
container_start_page	1432
author_browse	Lee, Woo-Man Shin, Dong-Kil Kim, Il-Ho
container_volume	44
format_se	Elektronische Aufsätze
author-letter	Lee, Woo-Man
doi_str_mv	10.1007/s11664-014-3401-1
title_sort	thermoelectric and transport properties of $ yb_{z} %$ fe_{4−x} %$ ni_{x} %$ sb_{12} $ skutterudites
title_auth	Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites
abstract	Abstract p-Type $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ (0.8 ≤ z ≤1.0, and 0.25 ≤ x ≤0.5) skutterudites were prepared, and the effects of Yb filling and Ni substitution on the thermoelectric properties were examined. X-ray diffraction patterns revealed that $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ skutterudites were synthesized, but small amounts of secondary phases ($ FeSb_{2} $ and Sb) were produced, except for the $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ specimen. This meant that the charge compensation with Ni and the amount of Yb filling should be sufficient to stabilize the skutterudite structure. All specimens had positive Hall coefficients and Seebeck coefficients, and the carrier concentration ranged from 9.80 × $ 10^{20} $ $ cm^{−3} $ to 3.37 × $ 10^{21} $ $ cm^{−3} $. The electrical conductivity decreased and the Seebeck coefficient increased with increasing Yb and Ni contents due to the decreased carrier concentration. The thermal conductivity decreased with increasing Yb and Ni contents, and $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ showed the lowest thermal conductivity. The maximum dimensionless figure of merit achieved was of 0.62 at 723 K for $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $, based on the high power factor (2.6 $ mWm^{−1} $ $ K^{−2} $) and the low thermal conductivity (2.9 $ Wm^{−1} $ $ K^{−1} $). © The Minerals, Metals & Materials Society 2014
abstractGer	Abstract p-Type $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ (0.8 ≤ z ≤1.0, and 0.25 ≤ x ≤0.5) skutterudites were prepared, and the effects of Yb filling and Ni substitution on the thermoelectric properties were examined. X-ray diffraction patterns revealed that $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ skutterudites were synthesized, but small amounts of secondary phases ($ FeSb_{2} $ and Sb) were produced, except for the $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ specimen. This meant that the charge compensation with Ni and the amount of Yb filling should be sufficient to stabilize the skutterudite structure. All specimens had positive Hall coefficients and Seebeck coefficients, and the carrier concentration ranged from 9.80 × $ 10^{20} $ $ cm^{−3} $ to 3.37 × $ 10^{21} $ $ cm^{−3} $. The electrical conductivity decreased and the Seebeck coefficient increased with increasing Yb and Ni contents due to the decreased carrier concentration. The thermal conductivity decreased with increasing Yb and Ni contents, and $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ showed the lowest thermal conductivity. The maximum dimensionless figure of merit achieved was of 0.62 at 723 K for $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $, based on the high power factor (2.6 $ mWm^{−1} $ $ K^{−2} $) and the low thermal conductivity (2.9 $ Wm^{−1} $ $ K^{−1} $). © The Minerals, Metals & Materials Society 2014
abstract_unstemmed	Abstract p-Type $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ (0.8 ≤ z ≤1.0, and 0.25 ≤ x ≤0.5) skutterudites were prepared, and the effects of Yb filling and Ni substitution on the thermoelectric properties were examined. X-ray diffraction patterns revealed that $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ skutterudites were synthesized, but small amounts of secondary phases ($ FeSb_{2} $ and Sb) were produced, except for the $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ specimen. This meant that the charge compensation with Ni and the amount of Yb filling should be sufficient to stabilize the skutterudite structure. All specimens had positive Hall coefficients and Seebeck coefficients, and the carrier concentration ranged from 9.80 × $ 10^{20} $ $ cm^{−3} $ to 3.37 × $ 10^{21} $ $ cm^{−3} $. The electrical conductivity decreased and the Seebeck coefficient increased with increasing Yb and Ni contents due to the decreased carrier concentration. The thermal conductivity decreased with increasing Yb and Ni contents, and $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ showed the lowest thermal conductivity. The maximum dimensionless figure of merit achieved was of 0.62 at 723 K for $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $, based on the high power factor (2.6 $ mWm^{−1} $ $ K^{−2} $) and the low thermal conductivity (2.9 $ Wm^{−1} $ $ K^{−1} $). © The Minerals, Metals & Materials Society 2014
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4328 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700
container_issue	6
title_short	Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites
url	https://dx.doi.org/10.1007/s11664-014-3401-1
remote_bool	true
author2	Shin, Dong-Kil Kim, Il-Ho
author2Str	Shin, Dong-Kil Kim, Il-Ho
ppnlink	324918739
mediatype_str_mv	c
isOA_txt	false
hochschulschrift_bool	false
doi_str	10.1007/s11664-014-3401-1
up_date	2024-07-03T23:04:31.422Z
_version_	1803600916832583680
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR021521646</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230331055101.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2014 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11664-014-3401-1</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR021521646</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s11664-014-3401-1-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Lee, Woo-Man</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2014</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© The Minerals, Metals & Materials Society 2014</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract p-Type $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ (0.8 ≤ z ≤1.0, and 0.25 ≤ x ≤0.5) skutterudites were prepared, and the effects of Yb filling and Ni substitution on the thermoelectric properties were examined. X-ray diffraction patterns revealed that $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ skutterudites were synthesized, but small amounts of secondary phases ($ FeSb_{2} $ and Sb) were produced, except for the $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ specimen. This meant that the charge compensation with Ni and the amount of Yb filling should be sufficient to stabilize the skutterudite structure. All specimens had positive Hall coefficients and Seebeck coefficients, and the carrier concentration ranged from 9.80 × $ 10^{20} $ $ cm^{−3} $ to 3.37 × $ 10^{21} $ $ cm^{−3} $. The electrical conductivity decreased and the Seebeck coefficient increased with increasing Yb and Ni contents due to the decreased carrier concentration. The thermal conductivity decreased with increasing Yb and Ni contents, and $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $ showed the lowest thermal conductivity. The maximum dimensionless figure of merit achieved was of 0.62 at 723 K for $ YbFe_{3.5} %$ Ni_{0.5} %$ Sb_{12} $, based on the high power factor (2.6 $ mWm^{−1} $ $ K^{−2} $) and the low thermal conductivity (2.9 $ Wm^{−1} $ $ K^{−1} $).</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Thermoelectric</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">skutterudite</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">filling</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">charge compensation</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Shin, Dong-Kil</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kim, Il-Ho</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of electronic materials</subfield><subfield code="d">Warrendale, Pa : TMS, 1972</subfield><subfield code="g">44(2014), 6 vom: 13. Sept., Seite 1432-1437</subfield><subfield code="w">(DE-627)324918739</subfield><subfield code="w">(DE-600)2032868-0</subfield><subfield code="x">1543-186X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:44</subfield><subfield code="g">year:2014</subfield><subfield code="g">number:6</subfield><subfield code="g">day:13</subfield><subfield code="g">month:09</subfield><subfield code="g">pages:1432-1437</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://dx.doi.org/10.1007/s11664-014-3401-1</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_SPRINGER</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_11</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_39</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_120</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_138</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_161</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_170</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_171</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_250</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_281</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_285</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_293</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_636</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2031</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2039</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2057</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2070</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2086</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2093</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2107</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2108</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2116</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2119</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2144</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2188</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2446</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2472</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2548</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4246</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4328</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">44</subfield><subfield code="j">2014</subfield><subfield code="e">6</subfield><subfield code="b">13</subfield><subfield code="c">09</subfield><subfield code="h">1432-1437</subfield></datafield></record></collection>
score	7.4004955

Nicht das Richtige dabei?

Schreiben Sie uns!

Thermoelectric and Transport Properties of $ Yb_{z} %$ Fe_{4−x} %$ Ni_{x} %$ Sb_{12} $ Skutterudites

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?