Synthesis and Properties of Novel Double-Tail Trisiloxane Surfactants
Abstract To improve the hydrolysis resistant ability of trisiloxane surfactants, ethoxylated single-tail and double-tail trisiloxane surfactants of the general formulas $ Me_{3} %$ SiOSiMeR^{1} %$ OSiMe_{3} $ (R1 = ($ CH_{2} $)3$ NHCH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; x = 8.4...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Peng, Zhongli [verfasserIn] Lu, Caifeng [verfasserIn] Lai, Jianxiong [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2009 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of surfactants and detergents - Hoboken, NJ : Wiley, 1998, 12(2009), 4 vom: 19. Mai, Seite 331-336 |
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| Übergeordnetes Werk: |
volume:12 ; year:2009 ; number:4 ; day:19 ; month:05 ; pages:331-336 |
| Links: |
|---|
| DOI / URN: |
10.1007/s11743-009-1134-6 |
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| Katalog-ID: |
SPR022153756 |
|---|
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| 520 | |a Abstract To improve the hydrolysis resistant ability of trisiloxane surfactants, ethoxylated single-tail and double-tail trisiloxane surfactants of the general formulas $ Me_{3} %$ SiOSiMeR^{1} %$ OSiMe_{3} $ (R1 = ($ CH_{2} $)3$ NHCH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; x = 8.4, 12.9, 17.5, 22) and $ Me_{3} %$ SiOSiMeR^{2} %$ OSiMe_{3} $ (R2 = ($ CH_{2} $)3$ NR^{3} %$ CH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; R3 = $ CH_{2} $($ CH_{2} $)y$ CH_{3} $; x = 8.4, 12.9, 17.5, 22; y = 2, 6) were synthesized. Their structures were characterized by 1H NMR and 13C NMR. The surface activity and hydrolysis resistant properties of the trisiloxane surfactants prepared were also studied. The values of the critical micelle concentration of all trisiloxane surfactants prepared were at levels of $ 10^{−5} $ and $ 10^{−4} $ mol/L. They can reduce the surface tension of water to less than 24 mN/m. The hydrolysis resistant properties of double-tail trisiloxane surfactants are superior to those of single-tail trisiloxane surfactants. The double-tail trisiloxane surfactants 1B (x = 8.4; y = 2) and 2C (x = 12.9; y = 6) can be stable for 8 days in an acidic solution (pH 4.0) and 11 days in an alkaline environment (pH 10.0). | ||
| 650 | 4 | |a Double-tail surfactants |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Trisiloxane |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Hydrolysis resistance |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Synthesis |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Lu, Caifeng |e verfasserin |4 aut | |
| 700 | 1 | |a Lai, Jianxiong |e verfasserin |4 aut | |
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| 773 | 1 | 8 | |g volume:12 |g year:2009 |g number:4 |g day:19 |g month:05 |g pages:331-336 |
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| allfields |
10.1007/s11743-009-1134-6 doi (DE-627)SPR022153756 (SPR)s11743-009-1134-6-e DE-627 ger DE-627 rakwb eng 540 ASE 58.28 bkl 44.40 bkl Peng, Zhongli verfasserin aut Synthesis and Properties of Novel Double-Tail Trisiloxane Surfactants 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract To improve the hydrolysis resistant ability of trisiloxane surfactants, ethoxylated single-tail and double-tail trisiloxane surfactants of the general formulas $ Me_{3} %$ SiOSiMeR^{1} %$ OSiMe_{3} $ (R1 = ($ CH_{2} $)3$ NHCH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; x = 8.4, 12.9, 17.5, 22) and $ Me_{3} %$ SiOSiMeR^{2} %$ OSiMe_{3} $ (R2 = ($ CH_{2} $)3$ NR^{3} %$ CH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; R3 = $ CH_{2} $($ CH_{2} $)y$ CH_{3} $; x = 8.4, 12.9, 17.5, 22; y = 2, 6) were synthesized. Their structures were characterized by 1H NMR and 13C NMR. The surface activity and hydrolysis resistant properties of the trisiloxane surfactants prepared were also studied. The values of the critical micelle concentration of all trisiloxane surfactants prepared were at levels of $ 10^{−5} $ and $ 10^{−4} $ mol/L. They can reduce the surface tension of water to less than 24 mN/m. The hydrolysis resistant properties of double-tail trisiloxane surfactants are superior to those of single-tail trisiloxane surfactants. The double-tail trisiloxane surfactants 1B (x = 8.4; y = 2) and 2C (x = 12.9; y = 6) can be stable for 8 days in an acidic solution (pH 4.0) and 11 days in an alkaline environment (pH 10.0). Double-tail surfactants (dpeaa)DE-He213 Trisiloxane (dpeaa)DE-He213 Hydrolysis resistance (dpeaa)DE-He213 Synthesis (dpeaa)DE-He213 Lu, Caifeng verfasserin aut Lai, Jianxiong verfasserin aut Enthalten in Journal of surfactants and detergents Hoboken, NJ : Wiley, 1998 12(2009), 4 vom: 19. Mai, Seite 331-336 (DE-627)364463481 (DE-600)2109638-7 1558-9293 nnns volume:12 year:2009 number:4 day:19 month:05 pages:331-336 https://dx.doi.org/10.1007/s11743-009-1134-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-PHA SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_266 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.28 ASE 44.40 ASE AR 12 2009 4 19 05 331-336 |
| spelling |
10.1007/s11743-009-1134-6 doi (DE-627)SPR022153756 (SPR)s11743-009-1134-6-e DE-627 ger DE-627 rakwb eng 540 ASE 58.28 bkl 44.40 bkl Peng, Zhongli verfasserin aut Synthesis and Properties of Novel Double-Tail Trisiloxane Surfactants 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract To improve the hydrolysis resistant ability of trisiloxane surfactants, ethoxylated single-tail and double-tail trisiloxane surfactants of the general formulas $ Me_{3} %$ SiOSiMeR^{1} %$ OSiMe_{3} $ (R1 = ($ CH_{2} $)3$ NHCH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; x = 8.4, 12.9, 17.5, 22) and $ Me_{3} %$ SiOSiMeR^{2} %$ OSiMe_{3} $ (R2 = ($ CH_{2} $)3$ NR^{3} %$ CH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; R3 = $ CH_{2} $($ CH_{2} $)y$ CH_{3} $; x = 8.4, 12.9, 17.5, 22; y = 2, 6) were synthesized. Their structures were characterized by 1H NMR and 13C NMR. The surface activity and hydrolysis resistant properties of the trisiloxane surfactants prepared were also studied. The values of the critical micelle concentration of all trisiloxane surfactants prepared were at levels of $ 10^{−5} $ and $ 10^{−4} $ mol/L. They can reduce the surface tension of water to less than 24 mN/m. The hydrolysis resistant properties of double-tail trisiloxane surfactants are superior to those of single-tail trisiloxane surfactants. The double-tail trisiloxane surfactants 1B (x = 8.4; y = 2) and 2C (x = 12.9; y = 6) can be stable for 8 days in an acidic solution (pH 4.0) and 11 days in an alkaline environment (pH 10.0). Double-tail surfactants (dpeaa)DE-He213 Trisiloxane (dpeaa)DE-He213 Hydrolysis resistance (dpeaa)DE-He213 Synthesis (dpeaa)DE-He213 Lu, Caifeng verfasserin aut Lai, Jianxiong verfasserin aut Enthalten in Journal of surfactants and detergents Hoboken, NJ : Wiley, 1998 12(2009), 4 vom: 19. Mai, Seite 331-336 (DE-627)364463481 (DE-600)2109638-7 1558-9293 nnns volume:12 year:2009 number:4 day:19 month:05 pages:331-336 https://dx.doi.org/10.1007/s11743-009-1134-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-PHA SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_266 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.28 ASE 44.40 ASE AR 12 2009 4 19 05 331-336 |
| allfields_unstemmed |
10.1007/s11743-009-1134-6 doi (DE-627)SPR022153756 (SPR)s11743-009-1134-6-e DE-627 ger DE-627 rakwb eng 540 ASE 58.28 bkl 44.40 bkl Peng, Zhongli verfasserin aut Synthesis and Properties of Novel Double-Tail Trisiloxane Surfactants 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract To improve the hydrolysis resistant ability of trisiloxane surfactants, ethoxylated single-tail and double-tail trisiloxane surfactants of the general formulas $ Me_{3} %$ SiOSiMeR^{1} %$ OSiMe_{3} $ (R1 = ($ CH_{2} $)3$ NHCH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; x = 8.4, 12.9, 17.5, 22) and $ Me_{3} %$ SiOSiMeR^{2} %$ OSiMe_{3} $ (R2 = ($ CH_{2} $)3$ NR^{3} %$ CH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; R3 = $ CH_{2} $($ CH_{2} $)y$ CH_{3} $; x = 8.4, 12.9, 17.5, 22; y = 2, 6) were synthesized. Their structures were characterized by 1H NMR and 13C NMR. The surface activity and hydrolysis resistant properties of the trisiloxane surfactants prepared were also studied. The values of the critical micelle concentration of all trisiloxane surfactants prepared were at levels of $ 10^{−5} $ and $ 10^{−4} $ mol/L. They can reduce the surface tension of water to less than 24 mN/m. The hydrolysis resistant properties of double-tail trisiloxane surfactants are superior to those of single-tail trisiloxane surfactants. The double-tail trisiloxane surfactants 1B (x = 8.4; y = 2) and 2C (x = 12.9; y = 6) can be stable for 8 days in an acidic solution (pH 4.0) and 11 days in an alkaline environment (pH 10.0). Double-tail surfactants (dpeaa)DE-He213 Trisiloxane (dpeaa)DE-He213 Hydrolysis resistance (dpeaa)DE-He213 Synthesis (dpeaa)DE-He213 Lu, Caifeng verfasserin aut Lai, Jianxiong verfasserin aut Enthalten in Journal of surfactants and detergents Hoboken, NJ : Wiley, 1998 12(2009), 4 vom: 19. Mai, Seite 331-336 (DE-627)364463481 (DE-600)2109638-7 1558-9293 nnns volume:12 year:2009 number:4 day:19 month:05 pages:331-336 https://dx.doi.org/10.1007/s11743-009-1134-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-PHA SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_266 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.28 ASE 44.40 ASE AR 12 2009 4 19 05 331-336 |
| allfieldsGer |
10.1007/s11743-009-1134-6 doi (DE-627)SPR022153756 (SPR)s11743-009-1134-6-e DE-627 ger DE-627 rakwb eng 540 ASE 58.28 bkl 44.40 bkl Peng, Zhongli verfasserin aut Synthesis and Properties of Novel Double-Tail Trisiloxane Surfactants 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract To improve the hydrolysis resistant ability of trisiloxane surfactants, ethoxylated single-tail and double-tail trisiloxane surfactants of the general formulas $ Me_{3} %$ SiOSiMeR^{1} %$ OSiMe_{3} $ (R1 = ($ CH_{2} $)3$ NHCH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; x = 8.4, 12.9, 17.5, 22) and $ Me_{3} %$ SiOSiMeR^{2} %$ OSiMe_{3} $ (R2 = ($ CH_{2} $)3$ NR^{3} %$ CH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; R3 = $ CH_{2} $($ CH_{2} $)y$ CH_{3} $; x = 8.4, 12.9, 17.5, 22; y = 2, 6) were synthesized. Their structures were characterized by 1H NMR and 13C NMR. The surface activity and hydrolysis resistant properties of the trisiloxane surfactants prepared were also studied. The values of the critical micelle concentration of all trisiloxane surfactants prepared were at levels of $ 10^{−5} $ and $ 10^{−4} $ mol/L. They can reduce the surface tension of water to less than 24 mN/m. The hydrolysis resistant properties of double-tail trisiloxane surfactants are superior to those of single-tail trisiloxane surfactants. The double-tail trisiloxane surfactants 1B (x = 8.4; y = 2) and 2C (x = 12.9; y = 6) can be stable for 8 days in an acidic solution (pH 4.0) and 11 days in an alkaline environment (pH 10.0). Double-tail surfactants (dpeaa)DE-He213 Trisiloxane (dpeaa)DE-He213 Hydrolysis resistance (dpeaa)DE-He213 Synthesis (dpeaa)DE-He213 Lu, Caifeng verfasserin aut Lai, Jianxiong verfasserin aut Enthalten in Journal of surfactants and detergents Hoboken, NJ : Wiley, 1998 12(2009), 4 vom: 19. Mai, Seite 331-336 (DE-627)364463481 (DE-600)2109638-7 1558-9293 nnns volume:12 year:2009 number:4 day:19 month:05 pages:331-336 https://dx.doi.org/10.1007/s11743-009-1134-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-PHA SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_266 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.28 ASE 44.40 ASE AR 12 2009 4 19 05 331-336 |
| allfieldsSound |
10.1007/s11743-009-1134-6 doi (DE-627)SPR022153756 (SPR)s11743-009-1134-6-e DE-627 ger DE-627 rakwb eng 540 ASE 58.28 bkl 44.40 bkl Peng, Zhongli verfasserin aut Synthesis and Properties of Novel Double-Tail Trisiloxane Surfactants 2009 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Abstract To improve the hydrolysis resistant ability of trisiloxane surfactants, ethoxylated single-tail and double-tail trisiloxane surfactants of the general formulas $ Me_{3} %$ SiOSiMeR^{1} %$ OSiMe_{3} $ (R1 = ($ CH_{2} $)3$ NHCH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; x = 8.4, 12.9, 17.5, 22) and $ Me_{3} %$ SiOSiMeR^{2} %$ OSiMe_{3} $ (R2 = ($ CH_{2} $)3$ NR^{3} %$ CH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; R3 = $ CH_{2} $($ CH_{2} $)y$ CH_{3} $; x = 8.4, 12.9, 17.5, 22; y = 2, 6) were synthesized. Their structures were characterized by 1H NMR and 13C NMR. The surface activity and hydrolysis resistant properties of the trisiloxane surfactants prepared were also studied. The values of the critical micelle concentration of all trisiloxane surfactants prepared were at levels of $ 10^{−5} $ and $ 10^{−4} $ mol/L. They can reduce the surface tension of water to less than 24 mN/m. The hydrolysis resistant properties of double-tail trisiloxane surfactants are superior to those of single-tail trisiloxane surfactants. The double-tail trisiloxane surfactants 1B (x = 8.4; y = 2) and 2C (x = 12.9; y = 6) can be stable for 8 days in an acidic solution (pH 4.0) and 11 days in an alkaline environment (pH 10.0). Double-tail surfactants (dpeaa)DE-He213 Trisiloxane (dpeaa)DE-He213 Hydrolysis resistance (dpeaa)DE-He213 Synthesis (dpeaa)DE-He213 Lu, Caifeng verfasserin aut Lai, Jianxiong verfasserin aut Enthalten in Journal of surfactants and detergents Hoboken, NJ : Wiley, 1998 12(2009), 4 vom: 19. Mai, Seite 331-336 (DE-627)364463481 (DE-600)2109638-7 1558-9293 nnns volume:12 year:2009 number:4 day:19 month:05 pages:331-336 https://dx.doi.org/10.1007/s11743-009-1134-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA SSG-OPC-PHA SSG-OPC-ASE GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_266 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.28 ASE 44.40 ASE AR 12 2009 4 19 05 331-336 |
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English |
| source |
Enthalten in Journal of surfactants and detergents 12(2009), 4 vom: 19. Mai, Seite 331-336 volume:12 year:2009 number:4 day:19 month:05 pages:331-336 |
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Enthalten in Journal of surfactants and detergents 12(2009), 4 vom: 19. Mai, Seite 331-336 volume:12 year:2009 number:4 day:19 month:05 pages:331-336 |
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Article |
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findex.gbv.de |
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Double-tail surfactants Trisiloxane Hydrolysis resistance Synthesis |
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540 |
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Journal of surfactants and detergents |
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Peng, Zhongli @@aut@@ Lu, Caifeng @@aut@@ Lai, Jianxiong @@aut@@ |
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2009-05-19T00:00:00Z |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR022153756</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230519191910.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2009 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11743-009-1134-6</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR022153756</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s11743-009-1134-6-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">ASE</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.28</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">44.40</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Peng, Zhongli</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Synthesis and Properties of Novel Double-Tail Trisiloxane Surfactants</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2009</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract To improve the hydrolysis resistant ability of trisiloxane surfactants, ethoxylated single-tail and double-tail trisiloxane surfactants of the general formulas $ Me_{3} %$ SiOSiMeR^{1} %$ OSiMe_{3} $ (R1 = ($ CH_{2} $)3$ NHCH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; x = 8.4, 12.9, 17.5, 22) and $ Me_{3} %$ SiOSiMeR^{2} %$ OSiMe_{3} $ (R2 = ($ CH_{2} $)3$ NR^{3} %$ CH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; R3 = $ CH_{2} $($ CH_{2} $)y$ CH_{3} $; x = 8.4, 12.9, 17.5, 22; y = 2, 6) were synthesized. Their structures were characterized by 1H NMR and 13C NMR. The surface activity and hydrolysis resistant properties of the trisiloxane surfactants prepared were also studied. The values of the critical micelle concentration of all trisiloxane surfactants prepared were at levels of $ 10^{−5} $ and $ 10^{−4} $ mol/L. They can reduce the surface tension of water to less than 24 mN/m. The hydrolysis resistant properties of double-tail trisiloxane surfactants are superior to those of single-tail trisiloxane surfactants. The double-tail trisiloxane surfactants 1B (x = 8.4; y = 2) and 2C (x = 12.9; y = 6) can be stable for 8 days in an acidic solution (pH 4.0) and 11 days in an alkaline environment (pH 10.0).</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Double-tail surfactants</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Trisiloxane</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hydrolysis resistance</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Synthesis</subfield><subfield code="7">(dpeaa)DE-He213</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lu, Caifeng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lai, Jianxiong</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of surfactants and detergents</subfield><subfield code="d">Hoboken, NJ : Wiley, 1998</subfield><subfield code="g">12(2009), 4 vom: 19. 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Peng, Zhongli |
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Peng, Zhongli ddc 540 bkl 58.28 bkl 44.40 misc Double-tail surfactants misc Trisiloxane misc Hydrolysis resistance misc Synthesis Synthesis and Properties of Novel Double-Tail Trisiloxane Surfactants |
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540 ASE 58.28 bkl 44.40 bkl Synthesis and Properties of Novel Double-Tail Trisiloxane Surfactants Double-tail surfactants (dpeaa)DE-He213 Trisiloxane (dpeaa)DE-He213 Hydrolysis resistance (dpeaa)DE-He213 Synthesis (dpeaa)DE-He213 |
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ddc 540 bkl 58.28 bkl 44.40 misc Double-tail surfactants misc Trisiloxane misc Hydrolysis resistance misc Synthesis |
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ddc 540 bkl 58.28 bkl 44.40 misc Double-tail surfactants misc Trisiloxane misc Hydrolysis resistance misc Synthesis |
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ddc 540 bkl 58.28 bkl 44.40 misc Double-tail surfactants misc Trisiloxane misc Hydrolysis resistance misc Synthesis |
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Synthesis and Properties of Novel Double-Tail Trisiloxane Surfactants |
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Synthesis and Properties of Novel Double-Tail Trisiloxane Surfactants |
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Peng, Zhongli |
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Peng, Zhongli Lu, Caifeng Lai, Jianxiong |
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540 ASE 58.28 bkl 44.40 bkl |
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Peng, Zhongli |
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10.1007/s11743-009-1134-6 |
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synthesis and properties of novel double-tail trisiloxane surfactants |
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Synthesis and Properties of Novel Double-Tail Trisiloxane Surfactants |
| abstract |
Abstract To improve the hydrolysis resistant ability of trisiloxane surfactants, ethoxylated single-tail and double-tail trisiloxane surfactants of the general formulas $ Me_{3} %$ SiOSiMeR^{1} %$ OSiMe_{3} $ (R1 = ($ CH_{2} $)3$ NHCH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; x = 8.4, 12.9, 17.5, 22) and $ Me_{3} %$ SiOSiMeR^{2} %$ OSiMe_{3} $ (R2 = ($ CH_{2} $)3$ NR^{3} %$ CH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; R3 = $ CH_{2} $($ CH_{2} $)y$ CH_{3} $; x = 8.4, 12.9, 17.5, 22; y = 2, 6) were synthesized. Their structures were characterized by 1H NMR and 13C NMR. The surface activity and hydrolysis resistant properties of the trisiloxane surfactants prepared were also studied. The values of the critical micelle concentration of all trisiloxane surfactants prepared were at levels of $ 10^{−5} $ and $ 10^{−4} $ mol/L. They can reduce the surface tension of water to less than 24 mN/m. The hydrolysis resistant properties of double-tail trisiloxane surfactants are superior to those of single-tail trisiloxane surfactants. The double-tail trisiloxane surfactants 1B (x = 8.4; y = 2) and 2C (x = 12.9; y = 6) can be stable for 8 days in an acidic solution (pH 4.0) and 11 days in an alkaline environment (pH 10.0). |
| abstractGer |
Abstract To improve the hydrolysis resistant ability of trisiloxane surfactants, ethoxylated single-tail and double-tail trisiloxane surfactants of the general formulas $ Me_{3} %$ SiOSiMeR^{1} %$ OSiMe_{3} $ (R1 = ($ CH_{2} $)3$ NHCH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; x = 8.4, 12.9, 17.5, 22) and $ Me_{3} %$ SiOSiMeR^{2} %$ OSiMe_{3} $ (R2 = ($ CH_{2} $)3$ NR^{3} %$ CH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; R3 = $ CH_{2} $($ CH_{2} $)y$ CH_{3} $; x = 8.4, 12.9, 17.5, 22; y = 2, 6) were synthesized. Their structures were characterized by 1H NMR and 13C NMR. The surface activity and hydrolysis resistant properties of the trisiloxane surfactants prepared were also studied. The values of the critical micelle concentration of all trisiloxane surfactants prepared were at levels of $ 10^{−5} $ and $ 10^{−4} $ mol/L. They can reduce the surface tension of water to less than 24 mN/m. The hydrolysis resistant properties of double-tail trisiloxane surfactants are superior to those of single-tail trisiloxane surfactants. The double-tail trisiloxane surfactants 1B (x = 8.4; y = 2) and 2C (x = 12.9; y = 6) can be stable for 8 days in an acidic solution (pH 4.0) and 11 days in an alkaline environment (pH 10.0). |
| abstract_unstemmed |
Abstract To improve the hydrolysis resistant ability of trisiloxane surfactants, ethoxylated single-tail and double-tail trisiloxane surfactants of the general formulas $ Me_{3} %$ SiOSiMeR^{1} %$ OSiMe_{3} $ (R1 = ($ CH_{2} $)3$ NHCH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; x = 8.4, 12.9, 17.5, 22) and $ Me_{3} %$ SiOSiMeR^{2} %$ OSiMe_{3} $ (R2 = ($ CH_{2} $)3$ NR^{3} %$ CH_{2} $CH(OH)$ CH_{2} $($ OCH_{2} %$ CH_{2} $)x$ OCH_{3} $; R3 = $ CH_{2} $($ CH_{2} $)y$ CH_{3} $; x = 8.4, 12.9, 17.5, 22; y = 2, 6) were synthesized. Their structures were characterized by 1H NMR and 13C NMR. The surface activity and hydrolysis resistant properties of the trisiloxane surfactants prepared were also studied. The values of the critical micelle concentration of all trisiloxane surfactants prepared were at levels of $ 10^{−5} $ and $ 10^{−4} $ mol/L. They can reduce the surface tension of water to less than 24 mN/m. The hydrolysis resistant properties of double-tail trisiloxane surfactants are superior to those of single-tail trisiloxane surfactants. The double-tail trisiloxane surfactants 1B (x = 8.4; y = 2) and 2C (x = 12.9; y = 6) can be stable for 8 days in an acidic solution (pH 4.0) and 11 days in an alkaline environment (pH 10.0). |
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4 |
| title_short |
Synthesis and Properties of Novel Double-Tail Trisiloxane Surfactants |
| url |
https://dx.doi.org/10.1007/s11743-009-1134-6 |
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| author2 |
Lu, Caifeng Lai, Jianxiong |
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| doi_str |
10.1007/s11743-009-1134-6 |
| up_date |
2024-07-04T02:02:20.517Z |
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| score |
7.399617 |