Cationic organobismuth complex as an effective catalyst for conversion of $ CO_{2} $ into cyclic carbonates
Abstract In order to achieve high-efficiency conversion of $ CO_{2} $ into valuable chemicals, and to exploit new applications of organobismuth compounds, cationic organobismuth complex with 5,6,7,12-tetrahydrodibenz[c,f][1,5] azabismocine framework was examined for the first time for the coupling o...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zhang, Xiaowen [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2008 |
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| Schlagwörter: |
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| Anmerkung: |
© Higher Education Press and Springer-Verlag GmbH 2008 |
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| Übergeordnetes Werk: |
Enthalten in: Frontiers of environmental science & engineering in China - Beijing : Higher Education Press, 2007, 3(2008), 1 vom: 21. Nov., Seite 32-37 |
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| Übergeordnetes Werk: |
volume:3 ; year:2008 ; number:1 ; day:21 ; month:11 ; pages:32-37 |
| Links: |
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| DOI / URN: |
10.1007/s11783-008-0068-y |
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| Katalog-ID: |
SPR022391533 |
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| 100 | 1 | |a Zhang, Xiaowen |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Cationic organobismuth complex as an effective catalyst for conversion of $ CO_{2} $ into cyclic carbonates |
| 264 | 1 | |c 2008 | |
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| 520 | |a Abstract In order to achieve high-efficiency conversion of $ CO_{2} $ into valuable chemicals, and to exploit new applications of organobismuth compounds, cationic organobismuth complex with 5,6,7,12-tetrahydrodibenz[c,f][1,5] azabismocine framework was examined for the first time for the coupling of $ CO_{2} $ into cyclic carbonates, using terminal epoxides as substrates and tetrabutylammonium halide as co-catalyst in a solvent-free environment under mild conditions. It is shown that the catalyst exhibited high activity and selectivity for the coupling reaction of $ CO_{2} $ with a wide range of terminal epoxide. The selectivity of propylene carbonates could reach 100%, and the maximum turnover frequency was up to 10740 $ h^{−1} $ at 120°C and 3 MPa $ CO_{2} $ pressure when tetrabutylammonium iodide was used as co-catalyst. Moreover, the catalyst is environment friendly, resistant to air and water, and can be readily reused and recycled without any loss of activity, demonstrating a potential in industrial application. | ||
| 650 | 4 | |a cationic organobismuth complex |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a terminal epoxide |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a carbon dioxide |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a coupling |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a cyclic carbonate |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Dai, Weili |4 aut | |
| 700 | 1 | |a Yin, Shuangfeng |4 aut | |
| 700 | 1 | |a Luo, Shenglian |4 aut | |
| 700 | 1 | |a Au, Chak-Tong |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Frontiers of environmental science & engineering in China |d Beijing : Higher Education Press, 2007 |g 3(2008), 1 vom: 21. Nov., Seite 32-37 |w (DE-627)545787661 |w (DE-600)2388869-6 |x 1673-7520 |7 nnns |
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10.1007/s11783-008-0068-y doi (DE-627)SPR022391533 (SPR)s11783-008-0068-y-e DE-627 ger DE-627 rakwb eng Zhang, Xiaowen verfasserin aut Cationic organobismuth complex as an effective catalyst for conversion of $ CO_{2} $ into cyclic carbonates 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag GmbH 2008 Abstract In order to achieve high-efficiency conversion of $ CO_{2} $ into valuable chemicals, and to exploit new applications of organobismuth compounds, cationic organobismuth complex with 5,6,7,12-tetrahydrodibenz[c,f][1,5] azabismocine framework was examined for the first time for the coupling of $ CO_{2} $ into cyclic carbonates, using terminal epoxides as substrates and tetrabutylammonium halide as co-catalyst in a solvent-free environment under mild conditions. It is shown that the catalyst exhibited high activity and selectivity for the coupling reaction of $ CO_{2} $ with a wide range of terminal epoxide. The selectivity of propylene carbonates could reach 100%, and the maximum turnover frequency was up to 10740 $ h^{−1} $ at 120°C and 3 MPa $ CO_{2} $ pressure when tetrabutylammonium iodide was used as co-catalyst. Moreover, the catalyst is environment friendly, resistant to air and water, and can be readily reused and recycled without any loss of activity, demonstrating a potential in industrial application. cationic organobismuth complex (dpeaa)DE-He213 terminal epoxide (dpeaa)DE-He213 carbon dioxide (dpeaa)DE-He213 coupling (dpeaa)DE-He213 cyclic carbonate (dpeaa)DE-He213 Dai, Weili aut Yin, Shuangfeng aut Luo, Shenglian aut Au, Chak-Tong aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 3(2008), 1 vom: 21. Nov., Seite 32-37 (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:3 year:2008 number:1 day:21 month:11 pages:32-37 https://dx.doi.org/10.1007/s11783-008-0068-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 3 2008 1 21 11 32-37 |
| spelling |
10.1007/s11783-008-0068-y doi (DE-627)SPR022391533 (SPR)s11783-008-0068-y-e DE-627 ger DE-627 rakwb eng Zhang, Xiaowen verfasserin aut Cationic organobismuth complex as an effective catalyst for conversion of $ CO_{2} $ into cyclic carbonates 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag GmbH 2008 Abstract In order to achieve high-efficiency conversion of $ CO_{2} $ into valuable chemicals, and to exploit new applications of organobismuth compounds, cationic organobismuth complex with 5,6,7,12-tetrahydrodibenz[c,f][1,5] azabismocine framework was examined for the first time for the coupling of $ CO_{2} $ into cyclic carbonates, using terminal epoxides as substrates and tetrabutylammonium halide as co-catalyst in a solvent-free environment under mild conditions. It is shown that the catalyst exhibited high activity and selectivity for the coupling reaction of $ CO_{2} $ with a wide range of terminal epoxide. The selectivity of propylene carbonates could reach 100%, and the maximum turnover frequency was up to 10740 $ h^{−1} $ at 120°C and 3 MPa $ CO_{2} $ pressure when tetrabutylammonium iodide was used as co-catalyst. Moreover, the catalyst is environment friendly, resistant to air and water, and can be readily reused and recycled without any loss of activity, demonstrating a potential in industrial application. cationic organobismuth complex (dpeaa)DE-He213 terminal epoxide (dpeaa)DE-He213 carbon dioxide (dpeaa)DE-He213 coupling (dpeaa)DE-He213 cyclic carbonate (dpeaa)DE-He213 Dai, Weili aut Yin, Shuangfeng aut Luo, Shenglian aut Au, Chak-Tong aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 3(2008), 1 vom: 21. Nov., Seite 32-37 (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:3 year:2008 number:1 day:21 month:11 pages:32-37 https://dx.doi.org/10.1007/s11783-008-0068-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 3 2008 1 21 11 32-37 |
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10.1007/s11783-008-0068-y doi (DE-627)SPR022391533 (SPR)s11783-008-0068-y-e DE-627 ger DE-627 rakwb eng Zhang, Xiaowen verfasserin aut Cationic organobismuth complex as an effective catalyst for conversion of $ CO_{2} $ into cyclic carbonates 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag GmbH 2008 Abstract In order to achieve high-efficiency conversion of $ CO_{2} $ into valuable chemicals, and to exploit new applications of organobismuth compounds, cationic organobismuth complex with 5,6,7,12-tetrahydrodibenz[c,f][1,5] azabismocine framework was examined for the first time for the coupling of $ CO_{2} $ into cyclic carbonates, using terminal epoxides as substrates and tetrabutylammonium halide as co-catalyst in a solvent-free environment under mild conditions. It is shown that the catalyst exhibited high activity and selectivity for the coupling reaction of $ CO_{2} $ with a wide range of terminal epoxide. The selectivity of propylene carbonates could reach 100%, and the maximum turnover frequency was up to 10740 $ h^{−1} $ at 120°C and 3 MPa $ CO_{2} $ pressure when tetrabutylammonium iodide was used as co-catalyst. Moreover, the catalyst is environment friendly, resistant to air and water, and can be readily reused and recycled without any loss of activity, demonstrating a potential in industrial application. cationic organobismuth complex (dpeaa)DE-He213 terminal epoxide (dpeaa)DE-He213 carbon dioxide (dpeaa)DE-He213 coupling (dpeaa)DE-He213 cyclic carbonate (dpeaa)DE-He213 Dai, Weili aut Yin, Shuangfeng aut Luo, Shenglian aut Au, Chak-Tong aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 3(2008), 1 vom: 21. Nov., Seite 32-37 (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:3 year:2008 number:1 day:21 month:11 pages:32-37 https://dx.doi.org/10.1007/s11783-008-0068-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 3 2008 1 21 11 32-37 |
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10.1007/s11783-008-0068-y doi (DE-627)SPR022391533 (SPR)s11783-008-0068-y-e DE-627 ger DE-627 rakwb eng Zhang, Xiaowen verfasserin aut Cationic organobismuth complex as an effective catalyst for conversion of $ CO_{2} $ into cyclic carbonates 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag GmbH 2008 Abstract In order to achieve high-efficiency conversion of $ CO_{2} $ into valuable chemicals, and to exploit new applications of organobismuth compounds, cationic organobismuth complex with 5,6,7,12-tetrahydrodibenz[c,f][1,5] azabismocine framework was examined for the first time for the coupling of $ CO_{2} $ into cyclic carbonates, using terminal epoxides as substrates and tetrabutylammonium halide as co-catalyst in a solvent-free environment under mild conditions. It is shown that the catalyst exhibited high activity and selectivity for the coupling reaction of $ CO_{2} $ with a wide range of terminal epoxide. The selectivity of propylene carbonates could reach 100%, and the maximum turnover frequency was up to 10740 $ h^{−1} $ at 120°C and 3 MPa $ CO_{2} $ pressure when tetrabutylammonium iodide was used as co-catalyst. Moreover, the catalyst is environment friendly, resistant to air and water, and can be readily reused and recycled without any loss of activity, demonstrating a potential in industrial application. cationic organobismuth complex (dpeaa)DE-He213 terminal epoxide (dpeaa)DE-He213 carbon dioxide (dpeaa)DE-He213 coupling (dpeaa)DE-He213 cyclic carbonate (dpeaa)DE-He213 Dai, Weili aut Yin, Shuangfeng aut Luo, Shenglian aut Au, Chak-Tong aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 3(2008), 1 vom: 21. Nov., Seite 32-37 (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:3 year:2008 number:1 day:21 month:11 pages:32-37 https://dx.doi.org/10.1007/s11783-008-0068-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 3 2008 1 21 11 32-37 |
| allfieldsSound |
10.1007/s11783-008-0068-y doi (DE-627)SPR022391533 (SPR)s11783-008-0068-y-e DE-627 ger DE-627 rakwb eng Zhang, Xiaowen verfasserin aut Cationic organobismuth complex as an effective catalyst for conversion of $ CO_{2} $ into cyclic carbonates 2008 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag GmbH 2008 Abstract In order to achieve high-efficiency conversion of $ CO_{2} $ into valuable chemicals, and to exploit new applications of organobismuth compounds, cationic organobismuth complex with 5,6,7,12-tetrahydrodibenz[c,f][1,5] azabismocine framework was examined for the first time for the coupling of $ CO_{2} $ into cyclic carbonates, using terminal epoxides as substrates and tetrabutylammonium halide as co-catalyst in a solvent-free environment under mild conditions. It is shown that the catalyst exhibited high activity and selectivity for the coupling reaction of $ CO_{2} $ with a wide range of terminal epoxide. The selectivity of propylene carbonates could reach 100%, and the maximum turnover frequency was up to 10740 $ h^{−1} $ at 120°C and 3 MPa $ CO_{2} $ pressure when tetrabutylammonium iodide was used as co-catalyst. Moreover, the catalyst is environment friendly, resistant to air and water, and can be readily reused and recycled without any loss of activity, demonstrating a potential in industrial application. cationic organobismuth complex (dpeaa)DE-He213 terminal epoxide (dpeaa)DE-He213 carbon dioxide (dpeaa)DE-He213 coupling (dpeaa)DE-He213 cyclic carbonate (dpeaa)DE-He213 Dai, Weili aut Yin, Shuangfeng aut Luo, Shenglian aut Au, Chak-Tong aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 3(2008), 1 vom: 21. Nov., Seite 32-37 (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:3 year:2008 number:1 day:21 month:11 pages:32-37 https://dx.doi.org/10.1007/s11783-008-0068-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_266 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 3 2008 1 21 11 32-37 |
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Enthalten in Frontiers of environmental science & engineering in China 3(2008), 1 vom: 21. Nov., Seite 32-37 volume:3 year:2008 number:1 day:21 month:11 pages:32-37 |
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Enthalten in Frontiers of environmental science & engineering in China 3(2008), 1 vom: 21. Nov., Seite 32-37 volume:3 year:2008 number:1 day:21 month:11 pages:32-37 |
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cationic organobismuth complex terminal epoxide carbon dioxide coupling cyclic carbonate |
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Frontiers of environmental science & engineering in China |
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Zhang, Xiaowen @@aut@@ Dai, Weili @@aut@@ Yin, Shuangfeng @@aut@@ Luo, Shenglian @@aut@@ Au, Chak-Tong @@aut@@ |
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2008-11-21T00:00:00Z |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">SPR022391533</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230330074232.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">201006s2008 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s11783-008-0068-y</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)SPR022391533</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(SPR)s11783-008-0068-y-e</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Zhang, Xiaowen</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Cationic organobismuth complex as an effective catalyst for conversion of $ CO_{2} $ into cyclic carbonates</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2008</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Higher Education Press and Springer-Verlag GmbH 2008</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract In order to achieve high-efficiency conversion of $ CO_{2} $ into valuable chemicals, and to exploit new applications of organobismuth compounds, cationic organobismuth complex with 5,6,7,12-tetrahydrodibenz[c,f][1,5] azabismocine framework was examined for the first time for the coupling of $ CO_{2} $ into cyclic carbonates, using terminal epoxides as substrates and tetrabutylammonium halide as co-catalyst in a solvent-free environment under mild conditions. It is shown that the catalyst exhibited high activity and selectivity for the coupling reaction of $ CO_{2} $ with a wide range of terminal epoxide. The selectivity of propylene carbonates could reach 100%, and the maximum turnover frequency was up to 10740 $ h^{−1} $ at 120°C and 3 MPa $ CO_{2} $ pressure when tetrabutylammonium iodide was used as co-catalyst. 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Zhang, Xiaowen |
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Zhang, Xiaowen misc cationic organobismuth complex misc terminal epoxide misc carbon dioxide misc coupling misc cyclic carbonate Cationic organobismuth complex as an effective catalyst for conversion of $ CO_{2} $ into cyclic carbonates |
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Cationic organobismuth complex as an effective catalyst for conversion of $ CO_{2} $ into cyclic carbonates cationic organobismuth complex (dpeaa)DE-He213 terminal epoxide (dpeaa)DE-He213 carbon dioxide (dpeaa)DE-He213 coupling (dpeaa)DE-He213 cyclic carbonate (dpeaa)DE-He213 |
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Cationic organobismuth complex as an effective catalyst for conversion of $ CO_{2} $ into cyclic carbonates |
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Zhang, Xiaowen Dai, Weili Yin, Shuangfeng Luo, Shenglian Au, Chak-Tong |
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cationic organobismuth complex as an effective catalyst for conversion of $ co_{2} $ into cyclic carbonates |
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Cationic organobismuth complex as an effective catalyst for conversion of $ CO_{2} $ into cyclic carbonates |
| abstract |
Abstract In order to achieve high-efficiency conversion of $ CO_{2} $ into valuable chemicals, and to exploit new applications of organobismuth compounds, cationic organobismuth complex with 5,6,7,12-tetrahydrodibenz[c,f][1,5] azabismocine framework was examined for the first time for the coupling of $ CO_{2} $ into cyclic carbonates, using terminal epoxides as substrates and tetrabutylammonium halide as co-catalyst in a solvent-free environment under mild conditions. It is shown that the catalyst exhibited high activity and selectivity for the coupling reaction of $ CO_{2} $ with a wide range of terminal epoxide. The selectivity of propylene carbonates could reach 100%, and the maximum turnover frequency was up to 10740 $ h^{−1} $ at 120°C and 3 MPa $ CO_{2} $ pressure when tetrabutylammonium iodide was used as co-catalyst. Moreover, the catalyst is environment friendly, resistant to air and water, and can be readily reused and recycled without any loss of activity, demonstrating a potential in industrial application. © Higher Education Press and Springer-Verlag GmbH 2008 |
| abstractGer |
Abstract In order to achieve high-efficiency conversion of $ CO_{2} $ into valuable chemicals, and to exploit new applications of organobismuth compounds, cationic organobismuth complex with 5,6,7,12-tetrahydrodibenz[c,f][1,5] azabismocine framework was examined for the first time for the coupling of $ CO_{2} $ into cyclic carbonates, using terminal epoxides as substrates and tetrabutylammonium halide as co-catalyst in a solvent-free environment under mild conditions. It is shown that the catalyst exhibited high activity and selectivity for the coupling reaction of $ CO_{2} $ with a wide range of terminal epoxide. The selectivity of propylene carbonates could reach 100%, and the maximum turnover frequency was up to 10740 $ h^{−1} $ at 120°C and 3 MPa $ CO_{2} $ pressure when tetrabutylammonium iodide was used as co-catalyst. Moreover, the catalyst is environment friendly, resistant to air and water, and can be readily reused and recycled without any loss of activity, demonstrating a potential in industrial application. © Higher Education Press and Springer-Verlag GmbH 2008 |
| abstract_unstemmed |
Abstract In order to achieve high-efficiency conversion of $ CO_{2} $ into valuable chemicals, and to exploit new applications of organobismuth compounds, cationic organobismuth complex with 5,6,7,12-tetrahydrodibenz[c,f][1,5] azabismocine framework was examined for the first time for the coupling of $ CO_{2} $ into cyclic carbonates, using terminal epoxides as substrates and tetrabutylammonium halide as co-catalyst in a solvent-free environment under mild conditions. It is shown that the catalyst exhibited high activity and selectivity for the coupling reaction of $ CO_{2} $ with a wide range of terminal epoxide. The selectivity of propylene carbonates could reach 100%, and the maximum turnover frequency was up to 10740 $ h^{−1} $ at 120°C and 3 MPa $ CO_{2} $ pressure when tetrabutylammonium iodide was used as co-catalyst. Moreover, the catalyst is environment friendly, resistant to air and water, and can be readily reused and recycled without any loss of activity, demonstrating a potential in industrial application. © Higher Education Press and Springer-Verlag GmbH 2008 |
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Cationic organobismuth complex as an effective catalyst for conversion of $ CO_{2} $ into cyclic carbonates |
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https://dx.doi.org/10.1007/s11783-008-0068-y |
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Dai, Weili Yin, Shuangfeng Luo, Shenglian Au, Chak-Tong |
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Dai, Weili Yin, Shuangfeng Luo, Shenglian Au, Chak-Tong |
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10.1007/s11783-008-0068-y |
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2024-07-04T02:54:37.777Z |
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| score |
7.4019165 |