Experimental determination of $ Cd^{2+} $ adsorption mechanism on low-cost biological waste

Abstract Carbonate shells have an astonishing ability in the removal of $ Cd^{2+} $ in a short time period with emphasis on being a low cost adsorbent. In the present study, the sorption capacity of carbonate shells was studied for $ Cd^{2+} $ in batch experiments. The influence of different carbona...
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Autor*in:	Ismail, Farhah Amalya [verfasserIn] Aris, Ahmad Zaharin

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2013

Schlagwörter:	carbonate shell cadmium heavy metal adsorption mechanism saturation state

Anmerkung:	© Higher Education Press and Springer-Verlag Berlin Heidelberg 2013

Übergeordnetes Werk:	Enthalten in: Frontiers of environmental science & engineering in China - Beijing : Higher Education Press, 2007, 7(2013), 3 vom: 06. Feb., Seite 356-364
Übergeordnetes Werk:	volume:7 ; year:2013 ; number:3 ; day:06 ; month:02 ; pages:356-364

Links:	Volltext

DOI / URN:	10.1007/s11783-013-0488-1

Katalog-ID:	SPR022394982

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520			\|a Abstract Carbonate shells have an astonishing ability in the removal of $ Cd^{2+} $ in a short time period with emphasis on being a low cost adsorbent. In the present study, the sorption capacity of carbonate shells was studied for $ Cd^{2+} $ in batch experiments. The influence of different carbonate shell sizes and physico-chemical factors were evaluated and the results were analyzed for its correlation matrices by using Predictive Analytics Software (PASW). The mineralogy state of aqueous solution regarding the saturation index was simulated using PHREEQC to identify the $ Cd^{2+} $ uptake mechanism. The Cd uptake rates were calculated as well as $ Ca^{2+} $, HCO3− concentration, pH, ambient humidity and temperature were measured. $ Cd^{2+} $ removal of 91.52% was achieved after 5 h adsorption. The adsorption efficiencies were significantly influenced by pH as they increased with the increase of pH from acidic solution (5.50±0.02) to slightly alkaline (7.60±0.05). In addition, the mineralogy state of aqueous solution calculated from PHREEQC confirmed that the increment of $ Ca^{2+} $ and HCO3− concentrations in solution was attributed to the dissolution of carbonate shells. Moreover, the ion exchange adsorption mechanism of $ Cd^{2+} $ toward $ Ca^{2+} $ was identified as the process involved in $ Cd^{2+} $ uptake.
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allfields	10.1007/s11783-013-0488-1 doi (DE-627)SPR022394982 (SPR)s11783-013-0488-1-e DE-627 ger DE-627 rakwb eng Ismail, Farhah Amalya verfasserin aut Experimental determination of $ Cd^{2+} $ adsorption mechanism on low-cost biological waste 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013 Abstract Carbonate shells have an astonishing ability in the removal of $ Cd^{2+} $ in a short time period with emphasis on being a low cost adsorbent. In the present study, the sorption capacity of carbonate shells was studied for $ Cd^{2+} $ in batch experiments. The influence of different carbonate shell sizes and physico-chemical factors were evaluated and the results were analyzed for its correlation matrices by using Predictive Analytics Software (PASW). The mineralogy state of aqueous solution regarding the saturation index was simulated using PHREEQC to identify the $ Cd^{2+} $ uptake mechanism. The Cd uptake rates were calculated as well as $ Ca^{2+} $, HCO3− concentration, pH, ambient humidity and temperature were measured. $ Cd^{2+} $ removal of 91.52% was achieved after 5 h adsorption. The adsorption efficiencies were significantly influenced by pH as they increased with the increase of pH from acidic solution (5.50±0.02) to slightly alkaline (7.60±0.05). In addition, the mineralogy state of aqueous solution calculated from PHREEQC confirmed that the increment of $ Ca^{2+} $ and HCO3− concentrations in solution was attributed to the dissolution of carbonate shells. Moreover, the ion exchange adsorption mechanism of $ Cd^{2+} $ toward $ Ca^{2+} $ was identified as the process involved in $ Cd^{2+} $ uptake. carbonate shell (dpeaa)DE-He213 cadmium (dpeaa)DE-He213 heavy metal (dpeaa)DE-He213 adsorption mechanism (dpeaa)DE-He213 saturation state (dpeaa)DE-He213 Aris, Ahmad Zaharin aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 7(2013), 3 vom: 06. Feb., Seite 356-364 (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:7 year:2013 number:3 day:06 month:02 pages:356-364 https://dx.doi.org/10.1007/s11783-013-0488-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 7 2013 3 06 02 356-364
spelling	10.1007/s11783-013-0488-1 doi (DE-627)SPR022394982 (SPR)s11783-013-0488-1-e DE-627 ger DE-627 rakwb eng Ismail, Farhah Amalya verfasserin aut Experimental determination of $ Cd^{2+} $ adsorption mechanism on low-cost biological waste 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013 Abstract Carbonate shells have an astonishing ability in the removal of $ Cd^{2+} $ in a short time period with emphasis on being a low cost adsorbent. In the present study, the sorption capacity of carbonate shells was studied for $ Cd^{2+} $ in batch experiments. The influence of different carbonate shell sizes and physico-chemical factors were evaluated and the results were analyzed for its correlation matrices by using Predictive Analytics Software (PASW). The mineralogy state of aqueous solution regarding the saturation index was simulated using PHREEQC to identify the $ Cd^{2+} $ uptake mechanism. The Cd uptake rates were calculated as well as $ Ca^{2+} $, HCO3− concentration, pH, ambient humidity and temperature were measured. $ Cd^{2+} $ removal of 91.52% was achieved after 5 h adsorption. The adsorption efficiencies were significantly influenced by pH as they increased with the increase of pH from acidic solution (5.50±0.02) to slightly alkaline (7.60±0.05). In addition, the mineralogy state of aqueous solution calculated from PHREEQC confirmed that the increment of $ Ca^{2+} $ and HCO3− concentrations in solution was attributed to the dissolution of carbonate shells. Moreover, the ion exchange adsorption mechanism of $ Cd^{2+} $ toward $ Ca^{2+} $ was identified as the process involved in $ Cd^{2+} $ uptake. carbonate shell (dpeaa)DE-He213 cadmium (dpeaa)DE-He213 heavy metal (dpeaa)DE-He213 adsorption mechanism (dpeaa)DE-He213 saturation state (dpeaa)DE-He213 Aris, Ahmad Zaharin aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 7(2013), 3 vom: 06. Feb., Seite 356-364 (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:7 year:2013 number:3 day:06 month:02 pages:356-364 https://dx.doi.org/10.1007/s11783-013-0488-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 7 2013 3 06 02 356-364
allfields_unstemmed	10.1007/s11783-013-0488-1 doi (DE-627)SPR022394982 (SPR)s11783-013-0488-1-e DE-627 ger DE-627 rakwb eng Ismail, Farhah Amalya verfasserin aut Experimental determination of $ Cd^{2+} $ adsorption mechanism on low-cost biological waste 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013 Abstract Carbonate shells have an astonishing ability in the removal of $ Cd^{2+} $ in a short time period with emphasis on being a low cost adsorbent. In the present study, the sorption capacity of carbonate shells was studied for $ Cd^{2+} $ in batch experiments. The influence of different carbonate shell sizes and physico-chemical factors were evaluated and the results were analyzed for its correlation matrices by using Predictive Analytics Software (PASW). The mineralogy state of aqueous solution regarding the saturation index was simulated using PHREEQC to identify the $ Cd^{2+} $ uptake mechanism. The Cd uptake rates were calculated as well as $ Ca^{2+} $, HCO3− concentration, pH, ambient humidity and temperature were measured. $ Cd^{2+} $ removal of 91.52% was achieved after 5 h adsorption. The adsorption efficiencies were significantly influenced by pH as they increased with the increase of pH from acidic solution (5.50±0.02) to slightly alkaline (7.60±0.05). In addition, the mineralogy state of aqueous solution calculated from PHREEQC confirmed that the increment of $ Ca^{2+} $ and HCO3− concentrations in solution was attributed to the dissolution of carbonate shells. Moreover, the ion exchange adsorption mechanism of $ Cd^{2+} $ toward $ Ca^{2+} $ was identified as the process involved in $ Cd^{2+} $ uptake. carbonate shell (dpeaa)DE-He213 cadmium (dpeaa)DE-He213 heavy metal (dpeaa)DE-He213 adsorption mechanism (dpeaa)DE-He213 saturation state (dpeaa)DE-He213 Aris, Ahmad Zaharin aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 7(2013), 3 vom: 06. Feb., Seite 356-364 (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:7 year:2013 number:3 day:06 month:02 pages:356-364 https://dx.doi.org/10.1007/s11783-013-0488-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 7 2013 3 06 02 356-364
allfieldsGer	10.1007/s11783-013-0488-1 doi (DE-627)SPR022394982 (SPR)s11783-013-0488-1-e DE-627 ger DE-627 rakwb eng Ismail, Farhah Amalya verfasserin aut Experimental determination of $ Cd^{2+} $ adsorption mechanism on low-cost biological waste 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013 Abstract Carbonate shells have an astonishing ability in the removal of $ Cd^{2+} $ in a short time period with emphasis on being a low cost adsorbent. In the present study, the sorption capacity of carbonate shells was studied for $ Cd^{2+} $ in batch experiments. The influence of different carbonate shell sizes and physico-chemical factors were evaluated and the results were analyzed for its correlation matrices by using Predictive Analytics Software (PASW). The mineralogy state of aqueous solution regarding the saturation index was simulated using PHREEQC to identify the $ Cd^{2+} $ uptake mechanism. The Cd uptake rates were calculated as well as $ Ca^{2+} $, HCO3− concentration, pH, ambient humidity and temperature were measured. $ Cd^{2+} $ removal of 91.52% was achieved after 5 h adsorption. The adsorption efficiencies were significantly influenced by pH as they increased with the increase of pH from acidic solution (5.50±0.02) to slightly alkaline (7.60±0.05). In addition, the mineralogy state of aqueous solution calculated from PHREEQC confirmed that the increment of $ Ca^{2+} $ and HCO3− concentrations in solution was attributed to the dissolution of carbonate shells. Moreover, the ion exchange adsorption mechanism of $ Cd^{2+} $ toward $ Ca^{2+} $ was identified as the process involved in $ Cd^{2+} $ uptake. carbonate shell (dpeaa)DE-He213 cadmium (dpeaa)DE-He213 heavy metal (dpeaa)DE-He213 adsorption mechanism (dpeaa)DE-He213 saturation state (dpeaa)DE-He213 Aris, Ahmad Zaharin aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 7(2013), 3 vom: 06. Feb., Seite 356-364 (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:7 year:2013 number:3 day:06 month:02 pages:356-364 https://dx.doi.org/10.1007/s11783-013-0488-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 7 2013 3 06 02 356-364
allfieldsSound	10.1007/s11783-013-0488-1 doi (DE-627)SPR022394982 (SPR)s11783-013-0488-1-e DE-627 ger DE-627 rakwb eng Ismail, Farhah Amalya verfasserin aut Experimental determination of $ Cd^{2+} $ adsorption mechanism on low-cost biological waste 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013 Abstract Carbonate shells have an astonishing ability in the removal of $ Cd^{2+} $ in a short time period with emphasis on being a low cost adsorbent. In the present study, the sorption capacity of carbonate shells was studied for $ Cd^{2+} $ in batch experiments. The influence of different carbonate shell sizes and physico-chemical factors were evaluated and the results were analyzed for its correlation matrices by using Predictive Analytics Software (PASW). The mineralogy state of aqueous solution regarding the saturation index was simulated using PHREEQC to identify the $ Cd^{2+} $ uptake mechanism. The Cd uptake rates were calculated as well as $ Ca^{2+} $, HCO3− concentration, pH, ambient humidity and temperature were measured. $ Cd^{2+} $ removal of 91.52% was achieved after 5 h adsorption. The adsorption efficiencies were significantly influenced by pH as they increased with the increase of pH from acidic solution (5.50±0.02) to slightly alkaline (7.60±0.05). In addition, the mineralogy state of aqueous solution calculated from PHREEQC confirmed that the increment of $ Ca^{2+} $ and HCO3− concentrations in solution was attributed to the dissolution of carbonate shells. Moreover, the ion exchange adsorption mechanism of $ Cd^{2+} $ toward $ Ca^{2+} $ was identified as the process involved in $ Cd^{2+} $ uptake. carbonate shell (dpeaa)DE-He213 cadmium (dpeaa)DE-He213 heavy metal (dpeaa)DE-He213 adsorption mechanism (dpeaa)DE-He213 saturation state (dpeaa)DE-He213 Aris, Ahmad Zaharin aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 7(2013), 3 vom: 06. Feb., Seite 356-364 (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:7 year:2013 number:3 day:06 month:02 pages:356-364 https://dx.doi.org/10.1007/s11783-013-0488-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 7 2013 3 06 02 356-364
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source	Enthalten in Frontiers of environmental science & engineering in China 7(2013), 3 vom: 06. Feb., Seite 356-364 volume:7 year:2013 number:3 day:06 month:02 pages:356-364
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author	Ismail, Farhah Amalya
spellingShingle	Ismail, Farhah Amalya misc carbonate shell misc cadmium misc heavy metal misc adsorption mechanism misc saturation state Experimental determination of $ Cd^{2+} $ adsorption mechanism on low-cost biological waste
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topic_title	Experimental determination of $ Cd^{2+} $ adsorption mechanism on low-cost biological waste carbonate shell (dpeaa)DE-He213 cadmium (dpeaa)DE-He213 heavy metal (dpeaa)DE-He213 adsorption mechanism (dpeaa)DE-He213 saturation state (dpeaa)DE-He213
topic	misc carbonate shell misc cadmium misc heavy metal misc adsorption mechanism misc saturation state
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title	Experimental determination of $ Cd^{2+} $ adsorption mechanism on low-cost biological waste
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title_full	Experimental determination of $ Cd^{2+} $ adsorption mechanism on low-cost biological waste
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title_sort	experimental determination of $ cd^{2+} $ adsorption mechanism on low-cost biological waste
title_auth	Experimental determination of $ Cd^{2+} $ adsorption mechanism on low-cost biological waste
abstract	Abstract Carbonate shells have an astonishing ability in the removal of $ Cd^{2+} $ in a short time period with emphasis on being a low cost adsorbent. In the present study, the sorption capacity of carbonate shells was studied for $ Cd^{2+} $ in batch experiments. The influence of different carbonate shell sizes and physico-chemical factors were evaluated and the results were analyzed for its correlation matrices by using Predictive Analytics Software (PASW). The mineralogy state of aqueous solution regarding the saturation index was simulated using PHREEQC to identify the $ Cd^{2+} $ uptake mechanism. The Cd uptake rates were calculated as well as $ Ca^{2+} $, HCO3− concentration, pH, ambient humidity and temperature were measured. $ Cd^{2+} $ removal of 91.52% was achieved after 5 h adsorption. The adsorption efficiencies were significantly influenced by pH as they increased with the increase of pH from acidic solution (5.50±0.02) to slightly alkaline (7.60±0.05). In addition, the mineralogy state of aqueous solution calculated from PHREEQC confirmed that the increment of $ Ca^{2+} $ and HCO3− concentrations in solution was attributed to the dissolution of carbonate shells. Moreover, the ion exchange adsorption mechanism of $ Cd^{2+} $ toward $ Ca^{2+} $ was identified as the process involved in $ Cd^{2+} $ uptake. © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013
abstractGer	Abstract Carbonate shells have an astonishing ability in the removal of $ Cd^{2+} $ in a short time period with emphasis on being a low cost adsorbent. In the present study, the sorption capacity of carbonate shells was studied for $ Cd^{2+} $ in batch experiments. The influence of different carbonate shell sizes and physico-chemical factors were evaluated and the results were analyzed for its correlation matrices by using Predictive Analytics Software (PASW). The mineralogy state of aqueous solution regarding the saturation index was simulated using PHREEQC to identify the $ Cd^{2+} $ uptake mechanism. The Cd uptake rates were calculated as well as $ Ca^{2+} $, HCO3− concentration, pH, ambient humidity and temperature were measured. $ Cd^{2+} $ removal of 91.52% was achieved after 5 h adsorption. The adsorption efficiencies were significantly influenced by pH as they increased with the increase of pH from acidic solution (5.50±0.02) to slightly alkaline (7.60±0.05). In addition, the mineralogy state of aqueous solution calculated from PHREEQC confirmed that the increment of $ Ca^{2+} $ and HCO3− concentrations in solution was attributed to the dissolution of carbonate shells. Moreover, the ion exchange adsorption mechanism of $ Cd^{2+} $ toward $ Ca^{2+} $ was identified as the process involved in $ Cd^{2+} $ uptake. © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013
abstract_unstemmed	Abstract Carbonate shells have an astonishing ability in the removal of $ Cd^{2+} $ in a short time period with emphasis on being a low cost adsorbent. In the present study, the sorption capacity of carbonate shells was studied for $ Cd^{2+} $ in batch experiments. The influence of different carbonate shell sizes and physico-chemical factors were evaluated and the results were analyzed for its correlation matrices by using Predictive Analytics Software (PASW). The mineralogy state of aqueous solution regarding the saturation index was simulated using PHREEQC to identify the $ Cd^{2+} $ uptake mechanism. The Cd uptake rates were calculated as well as $ Ca^{2+} $, HCO3− concentration, pH, ambient humidity and temperature were measured. $ Cd^{2+} $ removal of 91.52% was achieved after 5 h adsorption. The adsorption efficiencies were significantly influenced by pH as they increased with the increase of pH from acidic solution (5.50±0.02) to slightly alkaline (7.60±0.05). In addition, the mineralogy state of aqueous solution calculated from PHREEQC confirmed that the increment of $ Ca^{2+} $ and HCO3− concentrations in solution was attributed to the dissolution of carbonate shells. Moreover, the ion exchange adsorption mechanism of $ Cd^{2+} $ toward $ Ca^{2+} $ was identified as the process involved in $ Cd^{2+} $ uptake. © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013
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title_short	Experimental determination of $ Cd^{2+} $ adsorption mechanism on low-cost biological waste
url	https://dx.doi.org/10.1007/s11783-013-0488-1
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In addition, the mineralogy state of aqueous solution calculated from PHREEQC confirmed that the increment of $ Ca^{2+} $ and HCO3− concentrations in solution was attributed to the dissolution of carbonate shells. 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Experimental determination of $ Cd^{2+} $ adsorption mechanism on low-cost biological waste

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