Effects of phosphorus concentration on Cr(VI) sorption onto phosphorus-rich sludge biochar
Abstract To investigate effects of phosphorus content on Cr(VI) sorption onto phosphorus-rich biochar, sewage sludge of different phosphorus concentrations from 4 to 60 mg·$ g^{−1} $ by dry weight were prepared and carbonized to make biochar for batch sorption experiments. Test results revealed that...
Ausführliche Beschreibung
Autor*in: |
Ding, Wenchuan [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
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2013 |
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Anmerkung: |
© Higher Education Press and Springer-Verlag Berlin Heidelberg 2013 |
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Übergeordnetes Werk: |
Enthalten in: Frontiers of environmental science & engineering in China - Beijing : Higher Education Press, 2007, 8(2013), 3 vom: 04. Dez., Seite 379-385 |
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Übergeordnetes Werk: |
volume:8 ; year:2013 ; number:3 ; day:04 ; month:12 ; pages:379-385 |
Links: |
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DOI / URN: |
10.1007/s11783-013-0606-0 |
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Katalog-ID: |
SPR022396136 |
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520 | |a Abstract To investigate effects of phosphorus content on Cr(VI) sorption onto phosphorus-rich biochar, sewage sludge of different phosphorus concentrations from 4 to 60 mg·$ g^{−1} $ by dry weight were prepared and carbonized to make biochar for batch sorption experiments. Test results revealed that different phosphorous concentration of raw sludge had respective impacts on surface area, pore surface area, average pore diameter and pH value of derived biochar. The adsorption kinetics of phosphorus-rich biochar could be described by the pseudo-second-order model. The sorption isotherm data followed Langmiur model better than Freundlich model. Biochar produced from sludge with phosphorus concentration of 20 mg·$ g^{−1} $ gave the largest chromium sorption capacity, which could be attributed to its largest surface area and pores surface area comparing with those of biochars from sludge with other phosphorus concentrations. The chromium loaded biochar was analyzed using Fourier Transform Infrared Spectroscopy and X-ray Diffraction measurement. The results indicated that chemical functional groups hydroxyl and methyl on surface of biochar were involved in Cr(VI) binding and its reducing to Cr(III). Then, a portion of Cr (III) in form of various phosphate precipitates was bound onto biochar surface and the rest was released into the solution. The experimental results suggested that phosphorus played an important role in pore and surface area development of sludge biochar during pyrolytic process. It also could react with Cr(III) on the biochar surface that impacted on capacity of Cr(VI) removal from solution by sludge biochar. Therefore, phosphorus concentration in sludge should be considered when sludge pyrolytic residue would be reused for heavy metals sorbing. | ||
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10.1007/s11783-013-0606-0 doi (DE-627)SPR022396136 (SPR)s11783-013-0606-0-e DE-627 ger DE-627 rakwb eng Ding, Wenchuan verfasserin aut Effects of phosphorus concentration on Cr(VI) sorption onto phosphorus-rich sludge biochar 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013 Abstract To investigate effects of phosphorus content on Cr(VI) sorption onto phosphorus-rich biochar, sewage sludge of different phosphorus concentrations from 4 to 60 mg·$ g^{−1} $ by dry weight were prepared and carbonized to make biochar for batch sorption experiments. Test results revealed that different phosphorous concentration of raw sludge had respective impacts on surface area, pore surface area, average pore diameter and pH value of derived biochar. The adsorption kinetics of phosphorus-rich biochar could be described by the pseudo-second-order model. The sorption isotherm data followed Langmiur model better than Freundlich model. Biochar produced from sludge with phosphorus concentration of 20 mg·$ g^{−1} $ gave the largest chromium sorption capacity, which could be attributed to its largest surface area and pores surface area comparing with those of biochars from sludge with other phosphorus concentrations. The chromium loaded biochar was analyzed using Fourier Transform Infrared Spectroscopy and X-ray Diffraction measurement. The results indicated that chemical functional groups hydroxyl and methyl on surface of biochar were involved in Cr(VI) binding and its reducing to Cr(III). Then, a portion of Cr (III) in form of various phosphate precipitates was bound onto biochar surface and the rest was released into the solution. The experimental results suggested that phosphorus played an important role in pore and surface area development of sludge biochar during pyrolytic process. It also could react with Cr(III) on the biochar surface that impacted on capacity of Cr(VI) removal from solution by sludge biochar. Therefore, phosphorus concentration in sludge should be considered when sludge pyrolytic residue would be reused for heavy metals sorbing. phosphorus (dpeaa)DE-He213 biochar (dpeaa)DE-He213 sewage sludge (dpeaa)DE-He213 hexavalent chromium (dpeaa)DE-He213 adsorption (dpeaa)DE-He213 Peng, Wenlong aut Zeng, Xiaolan aut Tian, Xiumei aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 8(2013), 3 vom: 04. Dez., Seite 379-385 (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:8 year:2013 number:3 day:04 month:12 pages:379-385 https://dx.doi.org/10.1007/s11783-013-0606-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 8 2013 3 04 12 379-385 |
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10.1007/s11783-013-0606-0 doi (DE-627)SPR022396136 (SPR)s11783-013-0606-0-e DE-627 ger DE-627 rakwb eng Ding, Wenchuan verfasserin aut Effects of phosphorus concentration on Cr(VI) sorption onto phosphorus-rich sludge biochar 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013 Abstract To investigate effects of phosphorus content on Cr(VI) sorption onto phosphorus-rich biochar, sewage sludge of different phosphorus concentrations from 4 to 60 mg·$ g^{−1} $ by dry weight were prepared and carbonized to make biochar for batch sorption experiments. Test results revealed that different phosphorous concentration of raw sludge had respective impacts on surface area, pore surface area, average pore diameter and pH value of derived biochar. The adsorption kinetics of phosphorus-rich biochar could be described by the pseudo-second-order model. The sorption isotherm data followed Langmiur model better than Freundlich model. Biochar produced from sludge with phosphorus concentration of 20 mg·$ g^{−1} $ gave the largest chromium sorption capacity, which could be attributed to its largest surface area and pores surface area comparing with those of biochars from sludge with other phosphorus concentrations. The chromium loaded biochar was analyzed using Fourier Transform Infrared Spectroscopy and X-ray Diffraction measurement. The results indicated that chemical functional groups hydroxyl and methyl on surface of biochar were involved in Cr(VI) binding and its reducing to Cr(III). Then, a portion of Cr (III) in form of various phosphate precipitates was bound onto biochar surface and the rest was released into the solution. The experimental results suggested that phosphorus played an important role in pore and surface area development of sludge biochar during pyrolytic process. It also could react with Cr(III) on the biochar surface that impacted on capacity of Cr(VI) removal from solution by sludge biochar. Therefore, phosphorus concentration in sludge should be considered when sludge pyrolytic residue would be reused for heavy metals sorbing. phosphorus (dpeaa)DE-He213 biochar (dpeaa)DE-He213 sewage sludge (dpeaa)DE-He213 hexavalent chromium (dpeaa)DE-He213 adsorption (dpeaa)DE-He213 Peng, Wenlong aut Zeng, Xiaolan aut Tian, Xiumei aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 8(2013), 3 vom: 04. Dez., Seite 379-385 (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:8 year:2013 number:3 day:04 month:12 pages:379-385 https://dx.doi.org/10.1007/s11783-013-0606-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 8 2013 3 04 12 379-385 |
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10.1007/s11783-013-0606-0 doi (DE-627)SPR022396136 (SPR)s11783-013-0606-0-e DE-627 ger DE-627 rakwb eng Ding, Wenchuan verfasserin aut Effects of phosphorus concentration on Cr(VI) sorption onto phosphorus-rich sludge biochar 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013 Abstract To investigate effects of phosphorus content on Cr(VI) sorption onto phosphorus-rich biochar, sewage sludge of different phosphorus concentrations from 4 to 60 mg·$ g^{−1} $ by dry weight were prepared and carbonized to make biochar for batch sorption experiments. Test results revealed that different phosphorous concentration of raw sludge had respective impacts on surface area, pore surface area, average pore diameter and pH value of derived biochar. The adsorption kinetics of phosphorus-rich biochar could be described by the pseudo-second-order model. The sorption isotherm data followed Langmiur model better than Freundlich model. Biochar produced from sludge with phosphorus concentration of 20 mg·$ g^{−1} $ gave the largest chromium sorption capacity, which could be attributed to its largest surface area and pores surface area comparing with those of biochars from sludge with other phosphorus concentrations. The chromium loaded biochar was analyzed using Fourier Transform Infrared Spectroscopy and X-ray Diffraction measurement. The results indicated that chemical functional groups hydroxyl and methyl on surface of biochar were involved in Cr(VI) binding and its reducing to Cr(III). Then, a portion of Cr (III) in form of various phosphate precipitates was bound onto biochar surface and the rest was released into the solution. The experimental results suggested that phosphorus played an important role in pore and surface area development of sludge biochar during pyrolytic process. It also could react with Cr(III) on the biochar surface that impacted on capacity of Cr(VI) removal from solution by sludge biochar. Therefore, phosphorus concentration in sludge should be considered when sludge pyrolytic residue would be reused for heavy metals sorbing. phosphorus (dpeaa)DE-He213 biochar (dpeaa)DE-He213 sewage sludge (dpeaa)DE-He213 hexavalent chromium (dpeaa)DE-He213 adsorption (dpeaa)DE-He213 Peng, Wenlong aut Zeng, Xiaolan aut Tian, Xiumei aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 8(2013), 3 vom: 04. Dez., Seite 379-385 (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:8 year:2013 number:3 day:04 month:12 pages:379-385 https://dx.doi.org/10.1007/s11783-013-0606-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 8 2013 3 04 12 379-385 |
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10.1007/s11783-013-0606-0 doi (DE-627)SPR022396136 (SPR)s11783-013-0606-0-e DE-627 ger DE-627 rakwb eng Ding, Wenchuan verfasserin aut Effects of phosphorus concentration on Cr(VI) sorption onto phosphorus-rich sludge biochar 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013 Abstract To investigate effects of phosphorus content on Cr(VI) sorption onto phosphorus-rich biochar, sewage sludge of different phosphorus concentrations from 4 to 60 mg·$ g^{−1} $ by dry weight were prepared and carbonized to make biochar for batch sorption experiments. Test results revealed that different phosphorous concentration of raw sludge had respective impacts on surface area, pore surface area, average pore diameter and pH value of derived biochar. The adsorption kinetics of phosphorus-rich biochar could be described by the pseudo-second-order model. The sorption isotherm data followed Langmiur model better than Freundlich model. Biochar produced from sludge with phosphorus concentration of 20 mg·$ g^{−1} $ gave the largest chromium sorption capacity, which could be attributed to its largest surface area and pores surface area comparing with those of biochars from sludge with other phosphorus concentrations. The chromium loaded biochar was analyzed using Fourier Transform Infrared Spectroscopy and X-ray Diffraction measurement. The results indicated that chemical functional groups hydroxyl and methyl on surface of biochar were involved in Cr(VI) binding and its reducing to Cr(III). Then, a portion of Cr (III) in form of various phosphate precipitates was bound onto biochar surface and the rest was released into the solution. The experimental results suggested that phosphorus played an important role in pore and surface area development of sludge biochar during pyrolytic process. It also could react with Cr(III) on the biochar surface that impacted on capacity of Cr(VI) removal from solution by sludge biochar. Therefore, phosphorus concentration in sludge should be considered when sludge pyrolytic residue would be reused for heavy metals sorbing. phosphorus (dpeaa)DE-He213 biochar (dpeaa)DE-He213 sewage sludge (dpeaa)DE-He213 hexavalent chromium (dpeaa)DE-He213 adsorption (dpeaa)DE-He213 Peng, Wenlong aut Zeng, Xiaolan aut Tian, Xiumei aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 8(2013), 3 vom: 04. Dez., Seite 379-385 (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:8 year:2013 number:3 day:04 month:12 pages:379-385 https://dx.doi.org/10.1007/s11783-013-0606-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 8 2013 3 04 12 379-385 |
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10.1007/s11783-013-0606-0 doi (DE-627)SPR022396136 (SPR)s11783-013-0606-0-e DE-627 ger DE-627 rakwb eng Ding, Wenchuan verfasserin aut Effects of phosphorus concentration on Cr(VI) sorption onto phosphorus-rich sludge biochar 2013 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013 Abstract To investigate effects of phosphorus content on Cr(VI) sorption onto phosphorus-rich biochar, sewage sludge of different phosphorus concentrations from 4 to 60 mg·$ g^{−1} $ by dry weight were prepared and carbonized to make biochar for batch sorption experiments. Test results revealed that different phosphorous concentration of raw sludge had respective impacts on surface area, pore surface area, average pore diameter and pH value of derived biochar. The adsorption kinetics of phosphorus-rich biochar could be described by the pseudo-second-order model. The sorption isotherm data followed Langmiur model better than Freundlich model. Biochar produced from sludge with phosphorus concentration of 20 mg·$ g^{−1} $ gave the largest chromium sorption capacity, which could be attributed to its largest surface area and pores surface area comparing with those of biochars from sludge with other phosphorus concentrations. The chromium loaded biochar was analyzed using Fourier Transform Infrared Spectroscopy and X-ray Diffraction measurement. The results indicated that chemical functional groups hydroxyl and methyl on surface of biochar were involved in Cr(VI) binding and its reducing to Cr(III). Then, a portion of Cr (III) in form of various phosphate precipitates was bound onto biochar surface and the rest was released into the solution. The experimental results suggested that phosphorus played an important role in pore and surface area development of sludge biochar during pyrolytic process. It also could react with Cr(III) on the biochar surface that impacted on capacity of Cr(VI) removal from solution by sludge biochar. Therefore, phosphorus concentration in sludge should be considered when sludge pyrolytic residue would be reused for heavy metals sorbing. phosphorus (dpeaa)DE-He213 biochar (dpeaa)DE-He213 sewage sludge (dpeaa)DE-He213 hexavalent chromium (dpeaa)DE-He213 adsorption (dpeaa)DE-He213 Peng, Wenlong aut Zeng, Xiaolan aut Tian, Xiumei aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 8(2013), 3 vom: 04. Dez., Seite 379-385 (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:8 year:2013 number:3 day:04 month:12 pages:379-385 https://dx.doi.org/10.1007/s11783-013-0606-0 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 8 2013 3 04 12 379-385 |
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effects of phosphorus concentration on cr(vi) sorption onto phosphorus-rich sludge biochar |
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Effects of phosphorus concentration on Cr(VI) sorption onto phosphorus-rich sludge biochar |
abstract |
Abstract To investigate effects of phosphorus content on Cr(VI) sorption onto phosphorus-rich biochar, sewage sludge of different phosphorus concentrations from 4 to 60 mg·$ g^{−1} $ by dry weight were prepared and carbonized to make biochar for batch sorption experiments. Test results revealed that different phosphorous concentration of raw sludge had respective impacts on surface area, pore surface area, average pore diameter and pH value of derived biochar. The adsorption kinetics of phosphorus-rich biochar could be described by the pseudo-second-order model. The sorption isotherm data followed Langmiur model better than Freundlich model. Biochar produced from sludge with phosphorus concentration of 20 mg·$ g^{−1} $ gave the largest chromium sorption capacity, which could be attributed to its largest surface area and pores surface area comparing with those of biochars from sludge with other phosphorus concentrations. The chromium loaded biochar was analyzed using Fourier Transform Infrared Spectroscopy and X-ray Diffraction measurement. The results indicated that chemical functional groups hydroxyl and methyl on surface of biochar were involved in Cr(VI) binding and its reducing to Cr(III). Then, a portion of Cr (III) in form of various phosphate precipitates was bound onto biochar surface and the rest was released into the solution. The experimental results suggested that phosphorus played an important role in pore and surface area development of sludge biochar during pyrolytic process. It also could react with Cr(III) on the biochar surface that impacted on capacity of Cr(VI) removal from solution by sludge biochar. Therefore, phosphorus concentration in sludge should be considered when sludge pyrolytic residue would be reused for heavy metals sorbing. © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013 |
abstractGer |
Abstract To investigate effects of phosphorus content on Cr(VI) sorption onto phosphorus-rich biochar, sewage sludge of different phosphorus concentrations from 4 to 60 mg·$ g^{−1} $ by dry weight were prepared and carbonized to make biochar for batch sorption experiments. Test results revealed that different phosphorous concentration of raw sludge had respective impacts on surface area, pore surface area, average pore diameter and pH value of derived biochar. The adsorption kinetics of phosphorus-rich biochar could be described by the pseudo-second-order model. The sorption isotherm data followed Langmiur model better than Freundlich model. Biochar produced from sludge with phosphorus concentration of 20 mg·$ g^{−1} $ gave the largest chromium sorption capacity, which could be attributed to its largest surface area and pores surface area comparing with those of biochars from sludge with other phosphorus concentrations. The chromium loaded biochar was analyzed using Fourier Transform Infrared Spectroscopy and X-ray Diffraction measurement. The results indicated that chemical functional groups hydroxyl and methyl on surface of biochar were involved in Cr(VI) binding and its reducing to Cr(III). Then, a portion of Cr (III) in form of various phosphate precipitates was bound onto biochar surface and the rest was released into the solution. The experimental results suggested that phosphorus played an important role in pore and surface area development of sludge biochar during pyrolytic process. It also could react with Cr(III) on the biochar surface that impacted on capacity of Cr(VI) removal from solution by sludge biochar. Therefore, phosphorus concentration in sludge should be considered when sludge pyrolytic residue would be reused for heavy metals sorbing. © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013 |
abstract_unstemmed |
Abstract To investigate effects of phosphorus content on Cr(VI) sorption onto phosphorus-rich biochar, sewage sludge of different phosphorus concentrations from 4 to 60 mg·$ g^{−1} $ by dry weight were prepared and carbonized to make biochar for batch sorption experiments. Test results revealed that different phosphorous concentration of raw sludge had respective impacts on surface area, pore surface area, average pore diameter and pH value of derived biochar. The adsorption kinetics of phosphorus-rich biochar could be described by the pseudo-second-order model. The sorption isotherm data followed Langmiur model better than Freundlich model. Biochar produced from sludge with phosphorus concentration of 20 mg·$ g^{−1} $ gave the largest chromium sorption capacity, which could be attributed to its largest surface area and pores surface area comparing with those of biochars from sludge with other phosphorus concentrations. The chromium loaded biochar was analyzed using Fourier Transform Infrared Spectroscopy and X-ray Diffraction measurement. The results indicated that chemical functional groups hydroxyl and methyl on surface of biochar were involved in Cr(VI) binding and its reducing to Cr(III). Then, a portion of Cr (III) in form of various phosphate precipitates was bound onto biochar surface and the rest was released into the solution. The experimental results suggested that phosphorus played an important role in pore and surface area development of sludge biochar during pyrolytic process. It also could react with Cr(III) on the biochar surface that impacted on capacity of Cr(VI) removal from solution by sludge biochar. Therefore, phosphorus concentration in sludge should be considered when sludge pyrolytic residue would be reused for heavy metals sorbing. © Higher Education Press and Springer-Verlag Berlin Heidelberg 2013 |
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title_short |
Effects of phosphorus concentration on Cr(VI) sorption onto phosphorus-rich sludge biochar |
url |
https://dx.doi.org/10.1007/s11783-013-0606-0 |
remote_bool |
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author2 |
Peng, Wenlong Zeng, Xiaolan Tian, Xiumei |
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Peng, Wenlong Zeng, Xiaolan Tian, Xiumei |
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doi_str |
10.1007/s11783-013-0606-0 |
up_date |
2024-07-04T02:55:34.114Z |
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