Effect of alumina and zirconia as binders on the activity of Fe-BEA for $ NH_{3} $-SCR of NO
Abstract Fe-BEA catalysts are active for the NH3-SCR of NO. For industrial application, a binder should be added to the Fe-BEA catalysts to make them tightly adhere to the monoliths. The addition of alumina and zirconia as binders to the Fe-BEA led to a different effect on NO conversion. The catalyt...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Shi, Jin [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2017 |
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| Anmerkung: |
© Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2017 |
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| Übergeordnetes Werk: |
Enthalten in: Frontiers of environmental science & engineering in China - Beijing : Higher Education Press, 2007, 12(2017), 1 vom: 05. Dez. |
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| Übergeordnetes Werk: |
volume:12 ; year:2017 ; number:1 ; day:05 ; month:12 |
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| DOI / URN: |
10.1007/s11783-018-1012-4 |
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| Katalog-ID: |
SPR022400397 |
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| 520 | |a Abstract Fe-BEA catalysts are active for the NH3-SCR of NO. For industrial application, a binder should be added to the Fe-BEA catalysts to make them tightly adhere to the monoliths. The addition of alumina and zirconia as binders to the Fe-BEA led to a different effect on NO conversion. The catalytic activity of the mixed samples was evaluated by the temperature programmed procedure in a flow-reactor system, and the mechanism was analyzed via SEM, BET, XRD and XPS. It was found that larger iron particles were formed by the migration of parent iron particles in the Fe-BEA catalyst with alumina. This led to the increase of $ Fe^{3+} $ magnitude and iron cluster, enhancing the abilities of NO oxidation and storage. Accordingly, the SCR activity increased slightly in low temperature but decreased sharply in high temperature. For the Fe-BEA with zirconia sample, NO oxidation and storage abilities decreased due to the less iron clusters. The increase of $ Fe^{3+} $ magnitude resulted in higher catalytic oxidation ability, which gave rise to little change in the SCR activity compared with the Fe-BEA. | ||
| 650 | 4 | |a NH |7 (dpeaa)DE-He213 | |
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| 650 | 4 | |a NO |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Fe-BEA |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Binder |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Alumina |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Zirconia |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Zhang, Zihao |4 aut | |
| 700 | 1 | |a Chen, Mingxia |4 aut | |
| 700 | 1 | |a Zhang, Zhixiang |4 aut | |
| 700 | 1 | |a Shangguan, Wenfeng |4 aut | |
| 700 | 1 | |a Gu, Shunchao |4 aut | |
| 700 | 1 | |a Shin-ichi, Hirano |4 aut | |
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10.1007/s11783-018-1012-4 doi (DE-627)SPR022400397 (SPR)s11783-018-1012-4-e DE-627 ger DE-627 rakwb eng Shi, Jin verfasserin aut Effect of alumina and zirconia as binders on the activity of Fe-BEA for $ NH_{3} $-SCR of NO 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2017 Abstract Fe-BEA catalysts are active for the NH3-SCR of NO. For industrial application, a binder should be added to the Fe-BEA catalysts to make them tightly adhere to the monoliths. The addition of alumina and zirconia as binders to the Fe-BEA led to a different effect on NO conversion. The catalytic activity of the mixed samples was evaluated by the temperature programmed procedure in a flow-reactor system, and the mechanism was analyzed via SEM, BET, XRD and XPS. It was found that larger iron particles were formed by the migration of parent iron particles in the Fe-BEA catalyst with alumina. This led to the increase of $ Fe^{3+} $ magnitude and iron cluster, enhancing the abilities of NO oxidation and storage. Accordingly, the SCR activity increased slightly in low temperature but decreased sharply in high temperature. For the Fe-BEA with zirconia sample, NO oxidation and storage abilities decreased due to the less iron clusters. The increase of $ Fe^{3+} $ magnitude resulted in higher catalytic oxidation ability, which gave rise to little change in the SCR activity compared with the Fe-BEA. NH (dpeaa)DE-He213 -SCR (dpeaa)DE-He213 NO (dpeaa)DE-He213 Fe-BEA (dpeaa)DE-He213 Binder (dpeaa)DE-He213 Alumina (dpeaa)DE-He213 Zirconia (dpeaa)DE-He213 Zhang, Zihao aut Chen, Mingxia aut Zhang, Zhixiang aut Shangguan, Wenfeng aut Gu, Shunchao aut Shin-ichi, Hirano aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 12(2017), 1 vom: 05. Dez. (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:12 year:2017 number:1 day:05 month:12 https://dx.doi.org/10.1007/s11783-018-1012-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 12 2017 1 05 12 |
| spelling |
10.1007/s11783-018-1012-4 doi (DE-627)SPR022400397 (SPR)s11783-018-1012-4-e DE-627 ger DE-627 rakwb eng Shi, Jin verfasserin aut Effect of alumina and zirconia as binders on the activity of Fe-BEA for $ NH_{3} $-SCR of NO 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2017 Abstract Fe-BEA catalysts are active for the NH3-SCR of NO. For industrial application, a binder should be added to the Fe-BEA catalysts to make them tightly adhere to the monoliths. The addition of alumina and zirconia as binders to the Fe-BEA led to a different effect on NO conversion. The catalytic activity of the mixed samples was evaluated by the temperature programmed procedure in a flow-reactor system, and the mechanism was analyzed via SEM, BET, XRD and XPS. It was found that larger iron particles were formed by the migration of parent iron particles in the Fe-BEA catalyst with alumina. This led to the increase of $ Fe^{3+} $ magnitude and iron cluster, enhancing the abilities of NO oxidation and storage. Accordingly, the SCR activity increased slightly in low temperature but decreased sharply in high temperature. For the Fe-BEA with zirconia sample, NO oxidation and storage abilities decreased due to the less iron clusters. The increase of $ Fe^{3+} $ magnitude resulted in higher catalytic oxidation ability, which gave rise to little change in the SCR activity compared with the Fe-BEA. NH (dpeaa)DE-He213 -SCR (dpeaa)DE-He213 NO (dpeaa)DE-He213 Fe-BEA (dpeaa)DE-He213 Binder (dpeaa)DE-He213 Alumina (dpeaa)DE-He213 Zirconia (dpeaa)DE-He213 Zhang, Zihao aut Chen, Mingxia aut Zhang, Zhixiang aut Shangguan, Wenfeng aut Gu, Shunchao aut Shin-ichi, Hirano aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 12(2017), 1 vom: 05. Dez. (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:12 year:2017 number:1 day:05 month:12 https://dx.doi.org/10.1007/s11783-018-1012-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 12 2017 1 05 12 |
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10.1007/s11783-018-1012-4 doi (DE-627)SPR022400397 (SPR)s11783-018-1012-4-e DE-627 ger DE-627 rakwb eng Shi, Jin verfasserin aut Effect of alumina and zirconia as binders on the activity of Fe-BEA for $ NH_{3} $-SCR of NO 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2017 Abstract Fe-BEA catalysts are active for the NH3-SCR of NO. For industrial application, a binder should be added to the Fe-BEA catalysts to make them tightly adhere to the monoliths. The addition of alumina and zirconia as binders to the Fe-BEA led to a different effect on NO conversion. The catalytic activity of the mixed samples was evaluated by the temperature programmed procedure in a flow-reactor system, and the mechanism was analyzed via SEM, BET, XRD and XPS. It was found that larger iron particles were formed by the migration of parent iron particles in the Fe-BEA catalyst with alumina. This led to the increase of $ Fe^{3+} $ magnitude and iron cluster, enhancing the abilities of NO oxidation and storage. Accordingly, the SCR activity increased slightly in low temperature but decreased sharply in high temperature. For the Fe-BEA with zirconia sample, NO oxidation and storage abilities decreased due to the less iron clusters. The increase of $ Fe^{3+} $ magnitude resulted in higher catalytic oxidation ability, which gave rise to little change in the SCR activity compared with the Fe-BEA. NH (dpeaa)DE-He213 -SCR (dpeaa)DE-He213 NO (dpeaa)DE-He213 Fe-BEA (dpeaa)DE-He213 Binder (dpeaa)DE-He213 Alumina (dpeaa)DE-He213 Zirconia (dpeaa)DE-He213 Zhang, Zihao aut Chen, Mingxia aut Zhang, Zhixiang aut Shangguan, Wenfeng aut Gu, Shunchao aut Shin-ichi, Hirano aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 12(2017), 1 vom: 05. Dez. (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:12 year:2017 number:1 day:05 month:12 https://dx.doi.org/10.1007/s11783-018-1012-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 12 2017 1 05 12 |
| allfieldsGer |
10.1007/s11783-018-1012-4 doi (DE-627)SPR022400397 (SPR)s11783-018-1012-4-e DE-627 ger DE-627 rakwb eng Shi, Jin verfasserin aut Effect of alumina and zirconia as binders on the activity of Fe-BEA for $ NH_{3} $-SCR of NO 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2017 Abstract Fe-BEA catalysts are active for the NH3-SCR of NO. For industrial application, a binder should be added to the Fe-BEA catalysts to make them tightly adhere to the monoliths. The addition of alumina and zirconia as binders to the Fe-BEA led to a different effect on NO conversion. The catalytic activity of the mixed samples was evaluated by the temperature programmed procedure in a flow-reactor system, and the mechanism was analyzed via SEM, BET, XRD and XPS. It was found that larger iron particles were formed by the migration of parent iron particles in the Fe-BEA catalyst with alumina. This led to the increase of $ Fe^{3+} $ magnitude and iron cluster, enhancing the abilities of NO oxidation and storage. Accordingly, the SCR activity increased slightly in low temperature but decreased sharply in high temperature. For the Fe-BEA with zirconia sample, NO oxidation and storage abilities decreased due to the less iron clusters. The increase of $ Fe^{3+} $ magnitude resulted in higher catalytic oxidation ability, which gave rise to little change in the SCR activity compared with the Fe-BEA. NH (dpeaa)DE-He213 -SCR (dpeaa)DE-He213 NO (dpeaa)DE-He213 Fe-BEA (dpeaa)DE-He213 Binder (dpeaa)DE-He213 Alumina (dpeaa)DE-He213 Zirconia (dpeaa)DE-He213 Zhang, Zihao aut Chen, Mingxia aut Zhang, Zhixiang aut Shangguan, Wenfeng aut Gu, Shunchao aut Shin-ichi, Hirano aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 12(2017), 1 vom: 05. Dez. (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:12 year:2017 number:1 day:05 month:12 https://dx.doi.org/10.1007/s11783-018-1012-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 12 2017 1 05 12 |
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10.1007/s11783-018-1012-4 doi (DE-627)SPR022400397 (SPR)s11783-018-1012-4-e DE-627 ger DE-627 rakwb eng Shi, Jin verfasserin aut Effect of alumina and zirconia as binders on the activity of Fe-BEA for $ NH_{3} $-SCR of NO 2017 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2017 Abstract Fe-BEA catalysts are active for the NH3-SCR of NO. For industrial application, a binder should be added to the Fe-BEA catalysts to make them tightly adhere to the monoliths. The addition of alumina and zirconia as binders to the Fe-BEA led to a different effect on NO conversion. The catalytic activity of the mixed samples was evaluated by the temperature programmed procedure in a flow-reactor system, and the mechanism was analyzed via SEM, BET, XRD and XPS. It was found that larger iron particles were formed by the migration of parent iron particles in the Fe-BEA catalyst with alumina. This led to the increase of $ Fe^{3+} $ magnitude and iron cluster, enhancing the abilities of NO oxidation and storage. Accordingly, the SCR activity increased slightly in low temperature but decreased sharply in high temperature. For the Fe-BEA with zirconia sample, NO oxidation and storage abilities decreased due to the less iron clusters. The increase of $ Fe^{3+} $ magnitude resulted in higher catalytic oxidation ability, which gave rise to little change in the SCR activity compared with the Fe-BEA. NH (dpeaa)DE-He213 -SCR (dpeaa)DE-He213 NO (dpeaa)DE-He213 Fe-BEA (dpeaa)DE-He213 Binder (dpeaa)DE-He213 Alumina (dpeaa)DE-He213 Zirconia (dpeaa)DE-He213 Zhang, Zihao aut Chen, Mingxia aut Zhang, Zhixiang aut Shangguan, Wenfeng aut Gu, Shunchao aut Shin-ichi, Hirano aut Enthalten in Frontiers of environmental science & engineering in China Beijing : Higher Education Press, 2007 12(2017), 1 vom: 05. Dez. (DE-627)545787661 (DE-600)2388869-6 1673-7520 nnns volume:12 year:2017 number:1 day:05 month:12 https://dx.doi.org/10.1007/s11783-018-1012-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_152 GBV_ILN_161 GBV_ILN_171 GBV_ILN_187 GBV_ILN_224 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2018 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2059 GBV_ILN_2064 GBV_ILN_2068 GBV_ILN_2106 GBV_ILN_2108 GBV_ILN_2111 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 AR 12 2017 1 05 12 |
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effect of alumina and zirconia as binders on the activity of fe-bea for $ nh_{3} $-scr of no |
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Effect of alumina and zirconia as binders on the activity of Fe-BEA for $ NH_{3} $-SCR of NO |
| abstract |
Abstract Fe-BEA catalysts are active for the NH3-SCR of NO. For industrial application, a binder should be added to the Fe-BEA catalysts to make them tightly adhere to the monoliths. The addition of alumina and zirconia as binders to the Fe-BEA led to a different effect on NO conversion. The catalytic activity of the mixed samples was evaluated by the temperature programmed procedure in a flow-reactor system, and the mechanism was analyzed via SEM, BET, XRD and XPS. It was found that larger iron particles were formed by the migration of parent iron particles in the Fe-BEA catalyst with alumina. This led to the increase of $ Fe^{3+} $ magnitude and iron cluster, enhancing the abilities of NO oxidation and storage. Accordingly, the SCR activity increased slightly in low temperature but decreased sharply in high temperature. For the Fe-BEA with zirconia sample, NO oxidation and storage abilities decreased due to the less iron clusters. The increase of $ Fe^{3+} $ magnitude resulted in higher catalytic oxidation ability, which gave rise to little change in the SCR activity compared with the Fe-BEA. © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2017 |
| abstractGer |
Abstract Fe-BEA catalysts are active for the NH3-SCR of NO. For industrial application, a binder should be added to the Fe-BEA catalysts to make them tightly adhere to the monoliths. The addition of alumina and zirconia as binders to the Fe-BEA led to a different effect on NO conversion. The catalytic activity of the mixed samples was evaluated by the temperature programmed procedure in a flow-reactor system, and the mechanism was analyzed via SEM, BET, XRD and XPS. It was found that larger iron particles were formed by the migration of parent iron particles in the Fe-BEA catalyst with alumina. This led to the increase of $ Fe^{3+} $ magnitude and iron cluster, enhancing the abilities of NO oxidation and storage. Accordingly, the SCR activity increased slightly in low temperature but decreased sharply in high temperature. For the Fe-BEA with zirconia sample, NO oxidation and storage abilities decreased due to the less iron clusters. The increase of $ Fe^{3+} $ magnitude resulted in higher catalytic oxidation ability, which gave rise to little change in the SCR activity compared with the Fe-BEA. © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2017 |
| abstract_unstemmed |
Abstract Fe-BEA catalysts are active for the NH3-SCR of NO. For industrial application, a binder should be added to the Fe-BEA catalysts to make them tightly adhere to the monoliths. The addition of alumina and zirconia as binders to the Fe-BEA led to a different effect on NO conversion. The catalytic activity of the mixed samples was evaluated by the temperature programmed procedure in a flow-reactor system, and the mechanism was analyzed via SEM, BET, XRD and XPS. It was found that larger iron particles were formed by the migration of parent iron particles in the Fe-BEA catalyst with alumina. This led to the increase of $ Fe^{3+} $ magnitude and iron cluster, enhancing the abilities of NO oxidation and storage. Accordingly, the SCR activity increased slightly in low temperature but decreased sharply in high temperature. For the Fe-BEA with zirconia sample, NO oxidation and storage abilities decreased due to the less iron clusters. The increase of $ Fe^{3+} $ magnitude resulted in higher catalytic oxidation ability, which gave rise to little change in the SCR activity compared with the Fe-BEA. © Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2017 |
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| title_short |
Effect of alumina and zirconia as binders on the activity of Fe-BEA for $ NH_{3} $-SCR of NO |
| url |
https://dx.doi.org/10.1007/s11783-018-1012-4 |
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Zhang, Zihao Chen, Mingxia Zhang, Zhixiang Shangguan, Wenfeng Gu, Shunchao Shin-ichi, Hirano |
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| doi_str |
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