Scalable synthesis of carbon-embedded ordered macroporous titania spheres with structural colors
Abstract Carbon-embedded ordered macroporous titania (C-MAC $ TiO_{2} $) spheres are prepared in solution by the cooperative self-assembly of polymer beads and a titania precursor within evaporative emulsions and subsequent direct carbonization. Because the highly reactive titania precursors are eas...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Jung, Dae-Woong [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2018 |
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| Schlagwörter: |
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| Anmerkung: |
© Korean Institute of Chemical Engineers, Seoul, Korea 2018 |
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| Übergeordnetes Werk: |
Enthalten in: The Korean journal of chemical engineering - Seoul : Inst., 1984, 35(2018), 10 vom: 20. Aug., Seite 2138-2144 |
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| Übergeordnetes Werk: |
volume:35 ; year:2018 ; number:10 ; day:20 ; month:08 ; pages:2138-2144 |
| Links: |
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| DOI / URN: |
10.1007/s11814-018-0111-z |
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| Katalog-ID: |
SPR022521984 |
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| 100 | 1 | |a Jung, Dae-Woong |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Scalable synthesis of carbon-embedded ordered macroporous titania spheres with structural colors |
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| 520 | |a Abstract Carbon-embedded ordered macroporous titania (C-MAC $ TiO_{2} $) spheres are prepared in solution by the cooperative self-assembly of polymer beads and a titania precursor within evaporative emulsions and subsequent direct carbonization. Because the highly reactive titania precursors are easily crosslinked to form gels early in evaporation before the polymer beads are self-organized, non-reactive toluene-in-formamide emulsions are used. These non-aqueous emulsions should be stable at relatively high temperatures (~80 °C) for the evaporation process. We found that amphiphilic triblock copolymers of poly(ethylene oxide) (PEO) and poly(phenylene oxide) (PPO) with longer PEO chains (Pluronic® F108 ($ EO_{125} $-b-$ PO_{64} $-b-$ EO_{125} $) are required to stabilize those non-aqueous emulsions, and become more important at higher concentrations used for bulk fabrication. The carbon inside our C-MAC $ TiO_{2} $ significantly suppresses strong multiple scattering from structural defects or imperfections, thus emphasizing their Bragg reflection colors. | ||
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| 650 | 4 | |a Structural Color |7 (dpeaa)DE-He213 | |
| 650 | 4 | |a Sphere |7 (dpeaa)DE-He213 | |
| 700 | 1 | |a Park, Kyung Jin |4 aut | |
| 700 | 1 | |a Lee, Seungwoo |4 aut | |
| 700 | 1 | |a Kim, Jaeyun |4 aut | |
| 700 | 1 | |a Lee, Gaehang |4 aut | |
| 700 | 1 | |a Yi, Gi-Ra |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t The Korean journal of chemical engineering |d Seoul : Inst., 1984 |g 35(2018), 10 vom: 20. Aug., Seite 2138-2144 |w (DE-627)391337246 |w (DE-600)2152566-3 |x 1975-7220 |7 nnns |
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10.1007/s11814-018-0111-z doi (DE-627)SPR022521984 (SPR)s11814-018-0111-z-e DE-627 ger DE-627 rakwb eng Jung, Dae-Woong verfasserin aut Scalable synthesis of carbon-embedded ordered macroporous titania spheres with structural colors 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Korean Institute of Chemical Engineers, Seoul, Korea 2018 Abstract Carbon-embedded ordered macroporous titania (C-MAC $ TiO_{2} $) spheres are prepared in solution by the cooperative self-assembly of polymer beads and a titania precursor within evaporative emulsions and subsequent direct carbonization. Because the highly reactive titania precursors are easily crosslinked to form gels early in evaporation before the polymer beads are self-organized, non-reactive toluene-in-formamide emulsions are used. These non-aqueous emulsions should be stable at relatively high temperatures (~80 °C) for the evaporation process. We found that amphiphilic triblock copolymers of poly(ethylene oxide) (PEO) and poly(phenylene oxide) (PPO) with longer PEO chains (Pluronic® F108 ($ EO_{125} $-b-$ PO_{64} $-b-$ EO_{125} $) are required to stabilize those non-aqueous emulsions, and become more important at higher concentrations used for bulk fabrication. The carbon inside our C-MAC $ TiO_{2} $ significantly suppresses strong multiple scattering from structural defects or imperfections, thus emphasizing their Bragg reflection colors. Inverse Opal (dpeaa)DE-He213 Titania (dpeaa)DE-He213 Macropore (dpeaa)DE-He213 Structural Color (dpeaa)DE-He213 Sphere (dpeaa)DE-He213 Park, Kyung Jin aut Lee, Seungwoo aut Kim, Jaeyun aut Lee, Gaehang aut Yi, Gi-Ra aut Enthalten in The Korean journal of chemical engineering Seoul : Inst., 1984 35(2018), 10 vom: 20. Aug., Seite 2138-2144 (DE-627)391337246 (DE-600)2152566-3 1975-7220 nnns volume:35 year:2018 number:10 day:20 month:08 pages:2138-2144 https://dx.doi.org/10.1007/s11814-018-0111-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 35 2018 10 20 08 2138-2144 |
| spelling |
10.1007/s11814-018-0111-z doi (DE-627)SPR022521984 (SPR)s11814-018-0111-z-e DE-627 ger DE-627 rakwb eng Jung, Dae-Woong verfasserin aut Scalable synthesis of carbon-embedded ordered macroporous titania spheres with structural colors 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Korean Institute of Chemical Engineers, Seoul, Korea 2018 Abstract Carbon-embedded ordered macroporous titania (C-MAC $ TiO_{2} $) spheres are prepared in solution by the cooperative self-assembly of polymer beads and a titania precursor within evaporative emulsions and subsequent direct carbonization. Because the highly reactive titania precursors are easily crosslinked to form gels early in evaporation before the polymer beads are self-organized, non-reactive toluene-in-formamide emulsions are used. These non-aqueous emulsions should be stable at relatively high temperatures (~80 °C) for the evaporation process. We found that amphiphilic triblock copolymers of poly(ethylene oxide) (PEO) and poly(phenylene oxide) (PPO) with longer PEO chains (Pluronic® F108 ($ EO_{125} $-b-$ PO_{64} $-b-$ EO_{125} $) are required to stabilize those non-aqueous emulsions, and become more important at higher concentrations used for bulk fabrication. The carbon inside our C-MAC $ TiO_{2} $ significantly suppresses strong multiple scattering from structural defects or imperfections, thus emphasizing their Bragg reflection colors. Inverse Opal (dpeaa)DE-He213 Titania (dpeaa)DE-He213 Macropore (dpeaa)DE-He213 Structural Color (dpeaa)DE-He213 Sphere (dpeaa)DE-He213 Park, Kyung Jin aut Lee, Seungwoo aut Kim, Jaeyun aut Lee, Gaehang aut Yi, Gi-Ra aut Enthalten in The Korean journal of chemical engineering Seoul : Inst., 1984 35(2018), 10 vom: 20. Aug., Seite 2138-2144 (DE-627)391337246 (DE-600)2152566-3 1975-7220 nnns volume:35 year:2018 number:10 day:20 month:08 pages:2138-2144 https://dx.doi.org/10.1007/s11814-018-0111-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 35 2018 10 20 08 2138-2144 |
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10.1007/s11814-018-0111-z doi (DE-627)SPR022521984 (SPR)s11814-018-0111-z-e DE-627 ger DE-627 rakwb eng Jung, Dae-Woong verfasserin aut Scalable synthesis of carbon-embedded ordered macroporous titania spheres with structural colors 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Korean Institute of Chemical Engineers, Seoul, Korea 2018 Abstract Carbon-embedded ordered macroporous titania (C-MAC $ TiO_{2} $) spheres are prepared in solution by the cooperative self-assembly of polymer beads and a titania precursor within evaporative emulsions and subsequent direct carbonization. Because the highly reactive titania precursors are easily crosslinked to form gels early in evaporation before the polymer beads are self-organized, non-reactive toluene-in-formamide emulsions are used. These non-aqueous emulsions should be stable at relatively high temperatures (~80 °C) for the evaporation process. We found that amphiphilic triblock copolymers of poly(ethylene oxide) (PEO) and poly(phenylene oxide) (PPO) with longer PEO chains (Pluronic® F108 ($ EO_{125} $-b-$ PO_{64} $-b-$ EO_{125} $) are required to stabilize those non-aqueous emulsions, and become more important at higher concentrations used for bulk fabrication. The carbon inside our C-MAC $ TiO_{2} $ significantly suppresses strong multiple scattering from structural defects or imperfections, thus emphasizing their Bragg reflection colors. Inverse Opal (dpeaa)DE-He213 Titania (dpeaa)DE-He213 Macropore (dpeaa)DE-He213 Structural Color (dpeaa)DE-He213 Sphere (dpeaa)DE-He213 Park, Kyung Jin aut Lee, Seungwoo aut Kim, Jaeyun aut Lee, Gaehang aut Yi, Gi-Ra aut Enthalten in The Korean journal of chemical engineering Seoul : Inst., 1984 35(2018), 10 vom: 20. Aug., Seite 2138-2144 (DE-627)391337246 (DE-600)2152566-3 1975-7220 nnns volume:35 year:2018 number:10 day:20 month:08 pages:2138-2144 https://dx.doi.org/10.1007/s11814-018-0111-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 35 2018 10 20 08 2138-2144 |
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10.1007/s11814-018-0111-z doi (DE-627)SPR022521984 (SPR)s11814-018-0111-z-e DE-627 ger DE-627 rakwb eng Jung, Dae-Woong verfasserin aut Scalable synthesis of carbon-embedded ordered macroporous titania spheres with structural colors 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Korean Institute of Chemical Engineers, Seoul, Korea 2018 Abstract Carbon-embedded ordered macroporous titania (C-MAC $ TiO_{2} $) spheres are prepared in solution by the cooperative self-assembly of polymer beads and a titania precursor within evaporative emulsions and subsequent direct carbonization. Because the highly reactive titania precursors are easily crosslinked to form gels early in evaporation before the polymer beads are self-organized, non-reactive toluene-in-formamide emulsions are used. These non-aqueous emulsions should be stable at relatively high temperatures (~80 °C) for the evaporation process. We found that amphiphilic triblock copolymers of poly(ethylene oxide) (PEO) and poly(phenylene oxide) (PPO) with longer PEO chains (Pluronic® F108 ($ EO_{125} $-b-$ PO_{64} $-b-$ EO_{125} $) are required to stabilize those non-aqueous emulsions, and become more important at higher concentrations used for bulk fabrication. The carbon inside our C-MAC $ TiO_{2} $ significantly suppresses strong multiple scattering from structural defects or imperfections, thus emphasizing their Bragg reflection colors. Inverse Opal (dpeaa)DE-He213 Titania (dpeaa)DE-He213 Macropore (dpeaa)DE-He213 Structural Color (dpeaa)DE-He213 Sphere (dpeaa)DE-He213 Park, Kyung Jin aut Lee, Seungwoo aut Kim, Jaeyun aut Lee, Gaehang aut Yi, Gi-Ra aut Enthalten in The Korean journal of chemical engineering Seoul : Inst., 1984 35(2018), 10 vom: 20. Aug., Seite 2138-2144 (DE-627)391337246 (DE-600)2152566-3 1975-7220 nnns volume:35 year:2018 number:10 day:20 month:08 pages:2138-2144 https://dx.doi.org/10.1007/s11814-018-0111-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 35 2018 10 20 08 2138-2144 |
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10.1007/s11814-018-0111-z doi (DE-627)SPR022521984 (SPR)s11814-018-0111-z-e DE-627 ger DE-627 rakwb eng Jung, Dae-Woong verfasserin aut Scalable synthesis of carbon-embedded ordered macroporous titania spheres with structural colors 2018 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier © Korean Institute of Chemical Engineers, Seoul, Korea 2018 Abstract Carbon-embedded ordered macroporous titania (C-MAC $ TiO_{2} $) spheres are prepared in solution by the cooperative self-assembly of polymer beads and a titania precursor within evaporative emulsions and subsequent direct carbonization. Because the highly reactive titania precursors are easily crosslinked to form gels early in evaporation before the polymer beads are self-organized, non-reactive toluene-in-formamide emulsions are used. These non-aqueous emulsions should be stable at relatively high temperatures (~80 °C) for the evaporation process. We found that amphiphilic triblock copolymers of poly(ethylene oxide) (PEO) and poly(phenylene oxide) (PPO) with longer PEO chains (Pluronic® F108 ($ EO_{125} $-b-$ PO_{64} $-b-$ EO_{125} $) are required to stabilize those non-aqueous emulsions, and become more important at higher concentrations used for bulk fabrication. The carbon inside our C-MAC $ TiO_{2} $ significantly suppresses strong multiple scattering from structural defects or imperfections, thus emphasizing their Bragg reflection colors. Inverse Opal (dpeaa)DE-He213 Titania (dpeaa)DE-He213 Macropore (dpeaa)DE-He213 Structural Color (dpeaa)DE-He213 Sphere (dpeaa)DE-He213 Park, Kyung Jin aut Lee, Seungwoo aut Kim, Jaeyun aut Lee, Gaehang aut Yi, Gi-Ra aut Enthalten in The Korean journal of chemical engineering Seoul : Inst., 1984 35(2018), 10 vom: 20. Aug., Seite 2138-2144 (DE-627)391337246 (DE-600)2152566-3 1975-7220 nnns volume:35 year:2018 number:10 day:20 month:08 pages:2138-2144 https://dx.doi.org/10.1007/s11814-018-0111-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_SPRINGER SSG-OLC-PHA GBV_ILN_11 GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_39 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_120 GBV_ILN_138 GBV_ILN_150 GBV_ILN_151 GBV_ILN_152 GBV_ILN_161 GBV_ILN_170 GBV_ILN_171 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_250 GBV_ILN_281 GBV_ILN_285 GBV_ILN_293 GBV_ILN_370 GBV_ILN_602 GBV_ILN_636 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2031 GBV_ILN_2034 GBV_ILN_2037 GBV_ILN_2038 GBV_ILN_2039 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2057 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2070 GBV_ILN_2086 GBV_ILN_2088 GBV_ILN_2093 GBV_ILN_2106 GBV_ILN_2107 GBV_ILN_2108 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2116 GBV_ILN_2118 GBV_ILN_2119 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2144 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2188 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2446 GBV_ILN_2470 GBV_ILN_2472 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_2548 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4246 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4336 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 AR 35 2018 10 20 08 2138-2144 |
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Jung, Dae-Woong @@aut@@ Park, Kyung Jin @@aut@@ Lee, Seungwoo @@aut@@ Kim, Jaeyun @@aut@@ Lee, Gaehang @@aut@@ Yi, Gi-Ra @@aut@@ |
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Jung, Dae-Woong |
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Jung, Dae-Woong misc Inverse Opal misc Titania misc Macropore misc Structural Color misc Sphere Scalable synthesis of carbon-embedded ordered macroporous titania spheres with structural colors |
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Scalable synthesis of carbon-embedded ordered macroporous titania spheres with structural colors Inverse Opal (dpeaa)DE-He213 Titania (dpeaa)DE-He213 Macropore (dpeaa)DE-He213 Structural Color (dpeaa)DE-He213 Sphere (dpeaa)DE-He213 |
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Scalable synthesis of carbon-embedded ordered macroporous titania spheres with structural colors |
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Scalable synthesis of carbon-embedded ordered macroporous titania spheres with structural colors |
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Jung, Dae-Woong |
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Jung, Dae-Woong Park, Kyung Jin Lee, Seungwoo Kim, Jaeyun Lee, Gaehang Yi, Gi-Ra |
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scalable synthesis of carbon-embedded ordered macroporous titania spheres with structural colors |
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Scalable synthesis of carbon-embedded ordered macroporous titania spheres with structural colors |
| abstract |
Abstract Carbon-embedded ordered macroporous titania (C-MAC $ TiO_{2} $) spheres are prepared in solution by the cooperative self-assembly of polymer beads and a titania precursor within evaporative emulsions and subsequent direct carbonization. Because the highly reactive titania precursors are easily crosslinked to form gels early in evaporation before the polymer beads are self-organized, non-reactive toluene-in-formamide emulsions are used. These non-aqueous emulsions should be stable at relatively high temperatures (~80 °C) for the evaporation process. We found that amphiphilic triblock copolymers of poly(ethylene oxide) (PEO) and poly(phenylene oxide) (PPO) with longer PEO chains (Pluronic® F108 ($ EO_{125} $-b-$ PO_{64} $-b-$ EO_{125} $) are required to stabilize those non-aqueous emulsions, and become more important at higher concentrations used for bulk fabrication. The carbon inside our C-MAC $ TiO_{2} $ significantly suppresses strong multiple scattering from structural defects or imperfections, thus emphasizing their Bragg reflection colors. © Korean Institute of Chemical Engineers, Seoul, Korea 2018 |
| abstractGer |
Abstract Carbon-embedded ordered macroporous titania (C-MAC $ TiO_{2} $) spheres are prepared in solution by the cooperative self-assembly of polymer beads and a titania precursor within evaporative emulsions and subsequent direct carbonization. Because the highly reactive titania precursors are easily crosslinked to form gels early in evaporation before the polymer beads are self-organized, non-reactive toluene-in-formamide emulsions are used. These non-aqueous emulsions should be stable at relatively high temperatures (~80 °C) for the evaporation process. We found that amphiphilic triblock copolymers of poly(ethylene oxide) (PEO) and poly(phenylene oxide) (PPO) with longer PEO chains (Pluronic® F108 ($ EO_{125} $-b-$ PO_{64} $-b-$ EO_{125} $) are required to stabilize those non-aqueous emulsions, and become more important at higher concentrations used for bulk fabrication. The carbon inside our C-MAC $ TiO_{2} $ significantly suppresses strong multiple scattering from structural defects or imperfections, thus emphasizing their Bragg reflection colors. © Korean Institute of Chemical Engineers, Seoul, Korea 2018 |
| abstract_unstemmed |
Abstract Carbon-embedded ordered macroporous titania (C-MAC $ TiO_{2} $) spheres are prepared in solution by the cooperative self-assembly of polymer beads and a titania precursor within evaporative emulsions and subsequent direct carbonization. Because the highly reactive titania precursors are easily crosslinked to form gels early in evaporation before the polymer beads are self-organized, non-reactive toluene-in-formamide emulsions are used. These non-aqueous emulsions should be stable at relatively high temperatures (~80 °C) for the evaporation process. We found that amphiphilic triblock copolymers of poly(ethylene oxide) (PEO) and poly(phenylene oxide) (PPO) with longer PEO chains (Pluronic® F108 ($ EO_{125} $-b-$ PO_{64} $-b-$ EO_{125} $) are required to stabilize those non-aqueous emulsions, and become more important at higher concentrations used for bulk fabrication. The carbon inside our C-MAC $ TiO_{2} $ significantly suppresses strong multiple scattering from structural defects or imperfections, thus emphasizing their Bragg reflection colors. © Korean Institute of Chemical Engineers, Seoul, Korea 2018 |
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10 |
| title_short |
Scalable synthesis of carbon-embedded ordered macroporous titania spheres with structural colors |
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https://dx.doi.org/10.1007/s11814-018-0111-z |
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| author2 |
Park, Kyung Jin Lee, Seungwoo Kim, Jaeyun Lee, Gaehang Yi, Gi-Ra |
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Park, Kyung Jin Lee, Seungwoo Kim, Jaeyun Lee, Gaehang Yi, Gi-Ra |
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| doi_str |
10.1007/s11814-018-0111-z |
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2024-07-03T13:25:42.331Z |
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|
| score |
7.40047 |